• Composites Research
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• 제35권6호
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• pp.365-370
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• 2022

전기자동차 및 E-모빌리티 시장이 급속히 성장함에 따라 리튬이온전지는 현재 가장 주목받는 기술 중 하나로 여겨지고 있다. 따라서 높은 용량 및 출력, 급속 충전 성능을 가지는 고에너지밀도 전극 개발이 매우 중요한 상황이다. 고에너지밀도 전극 구현을 위해서 음극의 경우 실리콘, 주석 등 고용량 활물질 소재에 대한 연구가 진행되고 있는 상황이다. 하지만 이러한 고용량 활물질 소재는 전지의 충방전 과정 시 발생하는 부피팽창이 전지의 성능을 저하시키는 주된 원인이 된다고 알려져 있다. 따라서 활물질의 부피팽창을 완화할 수 있는 바인더 소재 개발이 매우 중요한 상황이며, 기존 PVDF, CMC/SBR계 바인더 뿐만 아니라 수용성 고분자(polyacrylic acid, polyvinyl alcohol, aliginate 등)를 이용한 바인더 소재 개발 연구가 많이 보고되고 있다. 이처럼 앞으로 리튬이온전지의 고성능화를 위해서 바인더는 매우 중요한 기술이 되었으며, 본 논문에서는 리튬이온전지용 음극 바인더 소재의 연구 동향을 살펴보고자 한다.

• 플랜트 저널
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• 제18권3호
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• pp.28-40
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• 2022

신재생에너지 발전 비중 확대가 예상됨에 따라 공공 발전사업자들은 바이오매스 혼소의 확대 시행을 적극적으로 검토해야 할 필요가 있다. 본 연구에서는 500MW 석탄화력에서 바이오매스 혼소율을 0wt.%에서 5.0wt.%까지 변화하며 미분기 주요 운전 특성을 측정하였다. 먼저, 목질계 바이오매스에 대한 구성성분 분석과 분쇄 특성을 알아보았고, 혼합연료의 부피 증가가 미분기 보울 압력 차이, 모터 전류, 이물질 처리횟수, 출구 온도, 내부 화재횟수에 미치는 영향을 분석하였다. 혼소율 증가에 따라 미분기 보울 압력 차이와 모터 전류, 이물질 처리횟수는 상승함을 확인하였고, 출구 온도는 상승 폭이 미미하였다. 내부 화재횟수는 명확한 상관관계를 찾기 힘드나, 다른 운전인자와 결합하여 발생할 가능성이 크다는 것을 확인하였다.

• Advances in concrete construction
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• 제12권5호
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• pp.377-389
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• 2021

Reinforced concrete vertical silos are universal structures that store large amounts of granular materials. Due to the asymmetric structure, heavy load, uneven storage material distribution, and the difference between the storage volume and the storage material bulk density, the corresponding earthquake is very complicated. Some scholars have proposed the calculation method of horizontal forces on reinforced concrete vertical silos under the action of earthquakes. Without considering the effect of torsional effect, this article aims to reveal the expansion factor of the silo group considering the torsional effect through experiments. Through two-way seismic simulation shaking table tests on reinforced concrete column-supported group silo structures, the basic dynamic characteristics of the structure under earthquake are obtained. Taking into account the torsional response, the structure has three types of storage: empty, half and full. A comprehensive analysis of the internal force conditions under the material conditions shows that: the different positions of the group bin model are different, the side bin displacement produces a displacement difference, and a torsional effect occurs; as the mass of the material increases, the structure's natural vibration frequency decreases and the damping ratio Increase; it shows that the storage material plays a role in reducing energy consumption of the model structure, and the contribution value is related to the stiffness difference in different directions of the model itself, providing data reference for other researchers; analyzing and calculating the model stiffness and calculating the internal force of the earthquake. As the horizontal side shift increases in the later period, the torsional effect of the group silo increases, and the shear force at the bottom of the column increases. It is recommended to consider the effect of the torsional effect, and the increase factor of the torsional effect is about 1.15. It can provide a reference for the structural safety design of column-supported silos.

• 한국분말재료학회지
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• 제29권6호
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• pp.468-476
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• 2022

Yttria-stabilized zirconia (YSZ) has a low thermal conductivity, high thermal expansion coefficient, and excellent mechanical properties; thus, it is used as a thermal barrier coating material for gas turbines. However, during long-time exposure of YSZ to temperatures of 1200℃ or higher, a phase transformation accompanied by a volume change occurs, causing the YSZ coating layer to peel off. To solve this problem, YSZ has been doped with trivalent and tetravalent oxides to obtain coating materials with low thermal conductivity and suppressed phase transformation of zirconia. In this study, YSZ is doped with trivalent oxides, Nd₂O₃, Yb₂O₃, Al₂O₃, and tetravalent oxide, TiO₂, and the thermal conductivity of the obtained materials is analyzed according to the composition; furthermore, the relative density change, microstructure change, and m-phase formation behavior are analyzed during long-time heat treatment at high temperatures.

• 한국재료학회지
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• 제32권12호
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• pp.545-552
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• 2022

Tin-antimony sulfide nanocomposites were prepared via hydrothermal synthesis and a N₂ reduction process for use as a negative electrode in a sodium ion battery. The electrochemical energy storage performance of the battery was analyzed according to the tin-antimony composition. The optimized sulfides exhibited superior charge/discharge capacity (770 mAh g^-1 at a current density of 100 mA g^-1) and stable lifespan characteristics (71.2 % after 200 cycles at a current density of 500 mA g^-1). It exhibited a reversible characteristic, continuously participating in the charge-discharge process. The improved electrochemical energy storage performance and cycle stability was attributed to the small particle size, by controlling the composition of the tin-antimony sulfide. By optimizing the tin-antimony ratio during the synthesis process, it did not deviate from the solubility limit. Graphene oxide also acts to suppress volume expansion during reversible electrochemical reaction. Based on these results, tin-antimony sulfide is considered a promising anode material for a sodium ion battery used as a medium-to-large energy storage source.

• Journal of Korea Trade
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• 제26권7호
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• pp.185-202
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• 2022

Purpose - As overseas direct purchase transactions using e-commerce increase, the scale and scope of international trade are diversified, and the transaction volume using online platforms in e-commerce is increasing. The e-commerce market share will become more important because it is not only a medium connecting B2C, but also because it will expand the scope of trade. This study aims to reveal the factors that influence purchase intention according to Korean-Chinese consumers in e-commerce. In addition, the study has comprehensively confirmed the influence between each factor in the e-commerce environment by integrating and analyzing the characteristic factors of online information sources and platforms in one structural equation. Finally, the study confirmed that there is a significant difference in the influence relationship between Korean and Chinese consumers. Through this, the study will contribute to content production in the e-commerce market according to the target market and the expansion of the mutual entry of Korea and China. Design/methodology - This study aims to confirm the mediating effect of the details of the online information source characteristics and platform characteristics when the perceived quality affects purchase intention. It is confirmed that the factors affecting Korean and Chinese consumers differ. Findings - It was confirmed that differences exist according to the group of Korean or Chinese consumers for the entire research model. In the case of Korean consumers, the mediating factors when perceived quality affects purchase intention are expertise, reliability, entertainment, informativity, and convenience; in the case of Chinese consumers, the factors are expertise and informativity. Originality/value - This study proved that Korean and Chinese consumers cannot be regarded as having the same characteristics, and therefore, strategies aimed at each e-commerce market should be differentiated. In addition, although previous studies on online information sources and platform characteristics were not integrated, this study confirmed a significant influence relationship among the factors that could affect purchase intention in the actual e-commerce environment.

• 한국프랜차이즈경영연구
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• 제2권2호
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• pp.84-94
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• 2011

현재 국내 프랜차이즈 업계의 가맹점주 관리 시스템의 필요성이 점차 대두되고 있다. 국내 프랜차이즈 업계가 외형에 집중되고 부피가 커지고 있는 반면에 내부적인 가맹점 관리 시스템의 부재 및 부실이 가맹점의 폐점과 분쟁으로 나타나고 있으며 본사의 가맹점 관리 시스템이 필요하다는 것을 증명해 주고 있다. 본 연구에서는 이런 문제점을 보완하고 시스템화 시키는 방안을 보험사와 보완하고 새로운 시스템 구축 및 활용하도록 연구해 본다.

• 무역학회지
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• 제46권3호
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• pp.135-149
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• 2021

This study analyzes the economic effect through the use of the RCEP direct transport rules, and suggests the necessacity of logistics efficiency and policy alternatives. The advantage of the hub network has been widely applied to the international logistics system, but there is a limit in the FTA logistics system in which goods must be directly transported between two contracting parties. Therefore, based on the new RCEP direct transport rules and the theoretical review on the possibility of an FTA logistics hub, FTA logistics efficiency improvement is estimated. This study quantitatively estimated the economic effect of direct transportation, unlike the previous studies, which were limited to the analysis of judicial precedents or surveys. GTAP model was used through five scenarios according to the impact of the RCEP tariff cut and the FTA logistics hub establishment in Singapore or Korea. As a result of the analysis, Korea's trade volume increased by 0.38% of exports and 1.63% of imports, and RCEP would increase exports by 0.27% and imports by 0.42%. In particular, the establishment of an FTA logistics hub (0.71%) was found to have a greater effect on the improvement of terms of trade than a tariff cut (0.12%), confirming the necessity of establishing an FTA logistics hub in RCEP. As a policy proposal, the institutional support of the customs authorities for the use of RCEP, the expansion of the free trade area where BWT traded cargo can be stored, and the establishment of a system for issuing back-to-back certificates of origin with approved exporters.

• 한국염색가공학회지
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• 제35권4호
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• pp.246-255
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• 2023

In this study, we investigated for natural rubber foam to replace petrochemical-based neoprene foam. Experiments were conducted on vulcanization system and 2-step foaming process of natural rubber. The vulcanization system were EV(Efficient Vulcanization Cure), Semi-EV(Semi-Efficient Vulcanization Cure) and CV(Conventional Vulcanization Cure). In the 2-step foaming process, first molding temperature was 140℃, times were 15, 20, 25, and 30minutes, and the second molding temperature was 160℃, the times 5, 10, 15, and 20minutes. The cure and viscosity characterization were evaluated by oscillating disc rheometer (ODR) and mooney viscosmeter. Various mechanical characteristics, including hardness, tensile strength, elongation at the point of rupture, and tear strength, were quantified. Subsequently, an assessment of alterations in these mechanical attributes was conducted post-immersion in a NaCl solution. In addition degree of volume change was measured after immersing the NR foam in NaCl solution and the low-temperature permanent compression set was evaluated at 4℃. And expansion ratio and shrinkage ratio of NR foam were evaluated for 28 days. As a result the EV vulcanization system showed the least change in physical properties before and after salt water immersion, and the lowest shrinkage ratio for 28 days. In addition it was confirmed that the 2-step foaming optimum condition differed depending on the appropriate vulcanization condition.

• 한국결정성장학회지
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• 제33권6호
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• pp.203-209
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• 2023

차세대 나트륨이온전지용 음극 소재로 유망한 코발트 황화물 나노복합체를 간단한 수열법을 통해 합성하였다. 본 연구에서는 배터리의 전기화학적 에너지 저장 성능 향상을 위해 코발트 황화물 나노입자와 환원된 산화그래핀과 복합화 된 코발트 황화물 나노복합체를 제조하여 비교해주었다. 제조된 나노복합체 전극은 가역적이고 안정적인 사이클 성능(전류밀도 200 mA g^-1에서 30 사이클 후 62 %)을 보였다. 개선된 전기화학적 특성은 수열합성 과정에서 코발트 황화물의 입자 크기가 작고 균일하게 분포되어 나트륨 이온의 확산 경로를 극대화함에서 기인하였다. 뿐만 아니라 전환 반응 중 음극재의 박리 및 부피 팽창을 효과적으로 억제함으로써 차세대 나트륨이온전지용 유망한 음극 소재로써의 가능성을 보여주었다.