• The Journal of the Korea Contents Association
• /
• v.12 no.8
• /
• pp.388-398
• /
• 2012

In this study, Entropy method and PROMETHEE(Preference Ranking organization METHod for Enrichment Evaluations) which is one of the multi criteria decision making methods are applied to estimate the relative inundation risk ranking of the urban sewer systems. Then, the evaluation factors were selected considering two main items to estimate the inundation risk using Entropy and PROMETHEE. In the first item considering topographical and environmental factor, average elevation, average slope, width of area, population, density of conduit were selected as the detailed factors of first item which have influence of the overflow occurrence and damage scale in urban sewer system. And, the relative reliability of sewer network was considered as the second item which can quantify the inundation appearance. Then, the reliability is estimated considering the number of overflow nodes and overflow volume simultaneously. Therefore, the suggested inundation risk evaluation method can be used as the evaluation index for sewer networks and contribute to decision making for the sewer rehabilitation policy.

• Journal of the Institute of Electronics Engineers of Korea TC
• /
• v.45 no.6
• /
• pp.34-51
• /
• 2008

Today, the Internet is a part of our life. For that reason, we regard revealing characteristics of Internet traffic as an important research theme. However, Internet traffic cannot be easily manipulated because it usually occupy huge capacity. This problem is a serious obstacle to analyze Internet traffic. Many researchers use various sampling techniques to reduce capacity of Internet traffic. In this paper, we compare several famous sampling techniques, and propose efficient sampling scheme. We chose some sampling techniques such as Systematic Sampling, Simple Random Sampling and Stratified Sampling with some sampling intensities such as 1/10, 1/100 and 1/1000. Our observation focused on Traffic Volume, Entropy Analysis and Packet Size Analysis. Both the simple random sampling and the count-based systematic sampling is proper to general case. On the other hand, time-based systematic sampling exhibits relatively bad results. The stratified sampling on Transport Layer Protocols, e.g.. TCP, UDP and so on, shows superior results. Our analysis results suggest that efficient sampling techniques satisfactorily maintain variation of traffic stream according to time change. The entropy analysis endures various sampling techniques well and fits detecting anomalous traffic. We found that a traffic volume diminishment caused by bottleneck could induce wrong results on the entropy analysis. We discovered that Packet Size Distribution perfectly tolerate any packet sampling techniques and intensities.

• Journal of the Korean Mathematical Society
• /
• v.37 no.4
• /
• pp.579-592
• /
• 2000

We study the variational principle for quantum unbounded spin systems interacting via superstable and regular interactions. We show that the (weak) KMS state constructed via the thermodynamic limit of finite volume Green's functions satisfies the Gibbs variational equality.

• Journal of the Korean Applied Science and Technology
• /
• v.26 no.1
• /
• pp.45-50
• /
• 2009

Three-dimensional, statistical-mechanical formulations of problems are usually untractable analytically, and therefore they are commonly solved numerically. However, their one-dimensional counterparts are always to be solved analytically. In general analytical solutions sheds more insights to the problems than numerical solutions. Hence, solutions of one-dimensional problems may provide key properties to the problems, when they are extended to three dimensions. In this article, thermodynamic properties of one-dimensional fluid comprising molecules of rigid rods are analyzed statistical-mechanically. Molecules of rigid rods are characterized with repulsive or excluded volume effect. It is observed that this feature is well reflected in thermodynamic functions such as Helmholtz free energy. volumetric equation of state. chemical potential, entropy, etc.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.2 no.3
• /
• pp.218-225
• /
• 1990

Studies on the performance of a heat pump using non-azeotropic refrigerant mixtures are done. In order to estimate the thermodynamic properties for the selected non-azeotropic refrigerant mixtures including R22/R152a, R22/R142b, R22/R114 and R13B1/R152a, Peng-Robinson equation of state is adopted. The pressure-enthalpy diagram and the temperature-entropy diagram are plotted for each refrigerant mixture. Considerations on the capacity modulation for the heat pump system using refrigerant mixtures are taken into. Results show that when the heating load varies, the possibility for the capacity modulation is found in the heat pump system using a compressor with constant volume flow rate. Under a constant heating capacity condition in the heat pump system, the coefficient of performance increases when the refrigerant mixtures are used. The volume flow rate decreases as the mass fraction of lower boiler increases in this case.

• Bulletin of the Korean Chemical Society
• /
• v.15 no.2
• /
• pp.106-112
• /
• 1994

Six physical properties (molecular weight, heat capacity, side chain weight, side chain volume, standard entropy and partial molar volume) of amino acids, peptides and their derivatives were examined by molecular modeling techniques. The molecular connectivity index, Wiener distance index and ad hoc descriptor are employed as structural parameters to encode information about branching, size, cyclization, unsaturation, heteroatom content and polarizability. This paper examines the correlation of the molecular modeling techique's parameters and the physicochemical properties of amino acids and their derivatives. As a result, calculated values were in agreement with experimental data in the above six physical properties of amino acids, peptides and their derivatives and the molecular connectivity index was superior to the other indices in fitting the calculated data.

• Bulletin of the Korean Chemical Society
• /
• v.6 no.5
• /
• pp.266-269
• /
• 1985

The dissociation constants(K) of m-chloroanilinium ion in water-ethanol mixture, where the volume percentage of water is 89.5%, were evaluated by UV-spectroscopic method at $20{\sim}50^{\circ}C$, up to 1500 bars with changing ionic strength from 0.04 to 0.10 mol $kg^{-1}$ by use of acetate buffer. K values enhance with increasing ionic strength and temperature, but decrease with elevating pressure. From K values, we obtained the partial molar volume change and some other thermodynamic parameters. From the values of enthalpy, entropy and isoequilibrium temperature (649 K), we concluded that the dissociation of m-chloroanilinium ion mentioned above is controlled by enthalpy.

• Journal of the Korea Institute of Information and Communication Engineering
• /
• v.10 no.3
• /
• pp.459-466
• /
• 2006

Numerical values of thermodynamic properties such as temperature, pressure, dryness, volume, enthalpy and entropy are required in numerical analysis on evaluating the thermal performance. But the steam table itself cannot be used without modelling. From this point of view the neural network with function approximation characteristics can be an alternative. the multi-layer neural networks were made for saturated vapor region and superheated vapor region separately. For saturated vapor region the neural network consists of one input layer with 1 node, two hidden layers with 10 and 20 nodes each and one output layer with 7 nodes. For superheated vapor region it consists of one input layer with 2 nodes, two hidden layers with 15 and 25 nodes each and one output layer with 3 nodes. The proposed model gives very successful results with ${\pm}0.005%$ of percentage error for temperature, enthalpy and entropy and ${\pm}0.025%$ for pressure and specific volume. From these successful results, it is confirmed that the neural networks could be powerful method in function approximation of the steam table.

• Journal of the Korean Chemical Society
• /
• v.35 no.1
• /
• pp.64-69
• /
• 1991

Kinetics of the reaction of p-methylphenacyl arenesulfonates with pyridine in acetonitrile were investigated by an electric conductivity method at 1∼2000 bars and 35∼55$^{\circ}C$. The rates of these reactions were increased with raising pressures and temperatures. The activation enthalpy(${\Delta}H^{\neq}$), entropy(${\Delta}S^{\neq}$) and activation volume(${\Delta}V^{\neq}$) of the reaction were obtained with the rate constants. Activation volume and entropy were both negative valued, and activation enthalpy was positive. The acteivation parameters (${\Delta}V^{\neq}$ and ${\Delta}S^{\neq}$) were decreased with increasing pressure. From all of the above results, it was found that this reaction proceeds on the S$_N$2 in which C${\cdots}$O bond breaking is more advanced as pressure increases.

• YAKHAK HOEJI
• /
• v.36 no.6
• /
• pp.518-528
• /
• 1992

To determine the optimal conformation of sulfonylureas, the correlation between conformation and hypoglycemic activity of the two sulfonylureas of tolbutamide and chlorpropamide as hypoglycemic agent was studied using an empirical potential function (ECEPP/2) and the hydration shell model in the unhydrated and hydrated states. The conformational energy was minimized from several starting conformations with possible torsion angles in each molecule. The conformational entropy change of each conformation was computed using a harmonic approximation. To understand the hydration effect on the conformation of the molecules in aqueous solution, the contribution of water-accessible volume of each group or atom in the lowest-free-energy conformation was calculated and compared each other. From comparison of the computed lowest-free-energy conformations of two sulfonylureas, it could be suggested that the hydration of sulfonylurea moiety is related to increase the hypoglycemic activity. From the calculation results, it was known that the conformational entropy is the major contribution to stabilize the low-free-energy conformations of two sulfonylureas in unhydrated state. Whereas, in hydrated state, the hydration free energy largely contributes to the total free energies of low-free-energy conformations of tolbutamide and conformational entropy contributes to stabilize the low-free-energy conformations of chlorpropamide. The torsion angles from phenyl ring to urea moiety of the low-free-energy conformations of the two sulfonylureas were shown the nearly regular trend. On the basis of these results, the conformation exhibiting the optimal hypoglycemic activity of sulfonylureas and the binding direction to pancreatic receptor site A could be predicted. Also, according to the side chain lengthening of urea moiety, tolbutamide showed various conformational change. Therefore, steric effect may be important factor in the interaction between sulfonylureas and the putative pancreatic receptor.