• Title/Summary/Keyword: volatile substances

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A Study on Combustion Characteristics of Purverized Fuel Made from Food Waste (음식물쓰레기로부터 제조한 분체연료 연소특성)

  • Son, Hyun-Suk;Park, Yung-Sung;Yun, Jong-Deuk;Lee, Ho-Nam;Lee, Seung-Hoon;Kim, Sang-Guk
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.149-152
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    • 2008
  • Three properties of food waste are water 80%, ash 3%, volatile matter 17%. When food waste goes through treatment process such as removal of foreign substances, removal of water as well as sodium, dryness, and pulverization, it transforms into 4,000Kcal/kg purverized fuel if moisture content is below 13%. Fuel ratio(fixed carbon/volatile matter) of purverized fuel is low compared with bituminuous coal. Ignition temperature measured by thermogravimetry analyzer is about $460^{\circ}C$. Combustion test of purverized fuel have been performed using energy recovery facility which include storage tank of dewatered cake, dryer, hammer mill, combuster including burner, boiler, flue gas treatment equipment. When 160-180 kg/hr of fuel is steadily supplied to burner for 3 hours, combueter temperature reaches about $1000^{\circ}C$ and CO is 77-103ppm at 1.55 excess air ratio and SOx and Cl are under 2ppm and 1ppm, respectively. This experiment demonstrate that purverized fuel made from food waste could be an alternative clean energy for high oil price era

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Pproperties of formaldehyde and CO2 adsorption type matrix using TiO2 photocatalysis (광촉매를 활용한 흡착형 경화체의 포름알데히드 및 CO2 특성)

  • Lee, Won-Gyu;Pyeon, Su-Jeong;Kyoung, In-Soo;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.153-154
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    • 2018
  • As the air pollution progresses, the pollution degree of the indoor air quality is increased, and when the pollution degree of the indoor air quality is increased, it causes respiratory diseases and skin diseases. In addition, volatile organic compounds are released from the materials used for architectural interior decoration, and volatile organic compounds are the main cause of polluting indoor air quality. In order to improve indoor air quality, we tried to secure indoor air quality pollution by using photocatalyst which has the function of decomposing harmful substances. photocatalyst is a material that promotes chemical reaction by absorbing light. The photocatalyst used in the experiment was TiO2, In this study, an adsorption type hardener for reducing volatile organic compounds was prepared by photocatalytic reaction. the formaldehyde and CO2 concentrations of the cured products were analyzed according to the TiO2 content.

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Calculation of Film Diffusion Coefficients and Surface Diffusion Coefficients of Volatile Organic Compounds Using Activated Carbon Adsorption Model and Small Column Test (활성탄 흡착모델과 칼럼실험을 통한 Volatile Organic Compounds의 막확산계수와 표면확산계수의 도출)

  • Lee, Byoung-Ho;Lee, Joon-Hee
    • Journal of Korean Society of Water and Wastewater
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    • v.13 no.1
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    • pp.72-80
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    • 1999
  • Separation of VOCs(Volatile Organic Compounds) in Water Using Activated Carbon is known to be effective. Activated Carbon has been and will be employed in many water treatment plants. Simplified plug flow homogeneous surface diffusion model(PFHSDM) has been used to predict adsorption of organic matter. Finite Element Method(FEM) was used to analyze the model. Out of water quality control substances, benzene, toluene and tetrachloroethylene were used in the small column test. Film diffusion coefficients and surface diffusion coefficients were obtained from the column test, and were compared with the modeling results. Mc Cune, Williamson, William and Kataoka model, were compared with film diffusion coefficients obtained in the test. McCune model was fitted best for those VOCs used in this experiment. Film diffusion coefficients of VOCs obtained were benzene 0.265 cm/min, toluene 0.348 cm/min and tetrachloroethylene 0.298 cm/min. Surface diffusion coefficients of VOCs obtained were benzene $6.36{\times}10^{-8}cm^2/min$, toluene $3.20{\times}10-8cm2/min$, and tetrachloruethylene $4.94{\times}10^{-8}cm^2/min$.

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Advances in the Field of Thermal Procedures in Direct Combination with Thin-layer Chromatography

  • Stahl, Egon
    • Korean Journal of Pharmacognosy
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    • v.7 no.1
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    • pp.3-13
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    • 1976
  • The hitherto existing gap in the field of chromatographic methods has been filled by the direct coupling of a suitable oven (TAS-oven) with TLC. The sample to be examined is heated either isothermally or linearly within the temperature gradient of $50{\sim}450^{\circ}C$. The volatile and/or thermolytically evolved substances are fractionated on the TLC-layer and subsequently chromatographed under standard conditions. Transport mechanisms from the sample to the TLC-layer, applications of the TAS-procedure and further developments are discussed. Thermofractography, developed from the TAS-procedure, is demonstrated on different groups of natural substances such as alkaloids, amino acids, nucleic acids. nucleosides, nucleotides, triglycerides and other lipids, pyrone glycosides and aglycon. Experimental work and results on the thermolysis of macromolecular natural and synthetic substances, natural polyphenols, tanning agents and leather and the possibilities of differentiating various lignins, carbohydrate and synthetic polymers are reported. Further, it is shown that classical reactions in the microgram range, e.g. zinc dust distillation, sulphur-and selenium dehydrogenation and catalytic dehydrogenation, can be coupled directly with TLC. Also described is a method which allows to investigate the gaseous compounds evolved during thermofractography in the range of up to $450^{\circ}C$. Thermal procedures coupled with TLC open up the following new possibilities for chemical microanalysis: fractionated separation of distillable and sublimable components, fractionated thermolysis and carrying out of thermal reactions in the ultra micro range.

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A review of Spice Phenomenon Therapy (향신(香身)요법에 관한 문헌 고찰)

  • Lee, Seung-Ho;Park, Pil-Sang;Kwon, Dong-Yeul
    • Herbal Formula Science
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    • v.18 no.2
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    • pp.15-23
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    • 2010
  • The spice phenomenon therapy is to adhibit aromatic herbs or materials to the human body or clothing, for the purpose of preventing and treating diseases. Mankind found the fire, and found that some plants and trees give off smoke when they are burning. Then, they found that some of aromatic substances had certain actions after being absorbed through the respiratory organ, which was the beginning of the spice phenomenon therapy. The spice phenomenon therapy is effective to relieve the exterior syndrome, to eliminate dampness, to regulate Qi flow, and to induce resuscitation. It has two actions. One is that the aromas that permeated the body, refreshes the mind, stimulates the appetite, strengthens the spleen and the stomach, and makes a relaxing sleep. The other is that the aromatic substances, absorbed into the human body, have pharmacological actions. The volatile aromatic substances have various pharmacological actions such as stimulating cranial nerves, dilating cardiac blood vessels, promoting gastric secretion, relaxing and sleep-inducing. It has been proved that the spice phenomenon therapy is anti-inflammatory and anti-microbial and is effective to dilate cerebral blood vessels and to ease the pain. It is expected to be studied more aggressively.

Sick House/Building Syndrome in JAPAN -Current Status and Practical Research on Indoor Air Quality-

  • Sekine Yoshika
    • Journal of Environmental Health Sciences
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    • v.31 no.3
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    • pp.207-214
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    • 2005
  • Many Japanese today are suffering from health disorders related to their living environment, such as allergies and hypersensitivity to chemical substances. The Sick House/Building Syndrome has been a serious problem since 1996, due to low level exposure to hazardous chemicals such as formaldehyde and volatile organic compounds (VOCs) emitted in airtight houses. This paper aims to show current status of the syndrome in Japan and practical researches to promote prevention of, and improvement to indoor air pollution due to chemicals.

Sick House/ Building Syndrome in Japan - Current Status and Practical Research on Indoor Air Quality -

  • Sekine, Yoshika
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2005.06a
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    • pp.143-167
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    • 2005
  • Many Japanese today are suffering from health disorders related to their living environment, such as allergies and hypersensitivity to chemical substances. The Sick House/Building Syndrome has been a serious problem since 1996, due to low level exposure to hazardous chemicals such as formaldehyde and volatile organic compounds (VOCs) emitted in airtight houses. This paper aims to show current status of the syndrome in Japan and practical researches to promote prevention of, and improvement to indoor air pollution due to chemicals.

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Exposure to Volatile Organic Compounds and Possibility of Exposure to By-product Volatile Organic Compounds in Photolithography Processes in Semiconductor Manufacturing Factories

  • Park, Seung-Hyun;Shin, Jung-Ah;Park, Hyun-Hee;Yi, Gwang-Yong;Chung, Kwang-Jae;Park, Hae-Dong;Kim, Kab-Bae;Lee, In-Seop
    • Safety and Health at Work
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    • v.2 no.3
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    • pp.210-217
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    • 2011
  • Objectives: The purpose of this study was to measure the concentration of volatile organic compound (VOC)s originated from the chemicals used and/or derived from the original parental chemicals in the photolithography processes of semiconductor manufacturing factories. Methods: A total of four photolithography processes in 4 Fabs at three different semiconductor manufacturing factories in Korea were selected for this study. This study investigated the types of chemicals used and generated during the photolithography process of each Fab, and the concentration levels of VOCs for each Fab. Results: A variety of organic compounds such as ketone, alcohol, and acetate compounds as well as aromatic compounds were used as solvents and developing agents in the processes. Also, the generation of by-products, such as toluene and phenol, was identified through a thermal decomposition experiment performed on a photoresist. The VOC concentration levels in the processes were lower than 5% of the threshold limit value (TLV)s. However, the air contaminated with chemical substances generated during the processes was re-circulated through the ventilation system, thereby affecting the airborne VOC concentrations in the photolithography processes. Conclusion: Tens of organic compounds were being used in the photolithography processes, though the types of chemical used varied with the factory. Also, by-products, such as aromatic compounds, could be generated during photoresist patterning by exposure to light. Although the airborne VOC concentrations resulting from the processes were lower than 5% of the TLVs, employees still could be exposed directly or indirectly to various types of VOCs.

Risk Assessment of Aldehydes and Volatile Organic Compounds in the National Library of Korea Archive (국립중앙도서관 귀중서고 내 알데히드류 및 휘발성유기화합물(VOCs)에 대한 건강위해성평가)

  • Lee, Hye-Won;Lim, Hui Been;Lee, Kwi-Bok;Park, So Yeon;Jeon, Jeong In;Lee, Cheol Min
    • Journal of Environmental Science International
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    • v.29 no.6
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    • pp.673-682
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    • 2020
  • This study investigates the concentration distribution of aldehydes and volatile organic compounds (VOCs) in the archive of the National Library in Korea and evaluates the health risks to workers from hazardous chemicals. Acetaldehyde had the highest concentration among the nine species of aldehydes present in the archive and the concentration of toluene was the highest among the six species of VOCs. Most of the detected substances showed that their indoor concentrations were higher than the outdoor ones, suggesting the possibility of indoor sources of aldehydes and VOCs. The evaluation of health risks for workers based on these measurement results showed that not all substances were hazardous to the human body. However, considering the possibility of the presence of indoor sources and the potential limits of our study owing its short period, it is necessary to conduct long-term studies on the concentration distribution of indoor pollutants in the archive environment.

Permeation Characteristics of Hazardous Substances in Tattoo Dye using Franz Diffusion Cells (Franz Diffusion Cell을 이용한 문신용 염료 내 유해물질의 피부 투과특성 연구)

  • Park, Kyo-Hyun;Jung, Se-Hoon;Shin, Ho-Sang;Kim, Bae-Hwan
    • Journal of Environmental Health Sciences
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    • v.42 no.1
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    • pp.61-70
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    • 2016
  • Objectives: The purpose of this study is to determine the exposure risk to tattoo components by analyzing skin absorption using the in vitro method. Tattoos are commonly used for cosmetic purposes, and the skin of not only the operator but of the people who are undergoing the cosmetic procedure is continuously exposed to hazardous chemicals. Methods: Skin permeation risk determination was conducted by the in vitro Franz diffusion cell method according to the ingredient types of tattoo dyes, such as volatile organic compounds (VOCs), non-volatile organic compounds and heavy metals, using hairless mouse full skin and human cadaver epidermis. Results: The major components with good skin penetration for each type of tattoo dye ingredient were clarified. Among the tatto dye ingredients, 1,2-Dichlorobenzene, Zn, Al, Pb and Ti showed good skin penetration. Most of the skin transmission rates were higher in hairless mouse full skin than in human cadaver epidermis. Conclusion: A possible exposure risk to hazardous substances in tattoo dyes was confirmed from this study. These results are expected to provide a positive contribution to the establishment of management regulations for tattoo dyes.