• Title/Summary/Keyword: volatile substances

검색결과 316건 처리시간 0.028초

허베이스피릿호 원유유출 사고 이후 태안주민의 식생활 변화 - 포커스 그룹 면담 결과 - (Changes of Eating Habits of the Residents of Taean, Korea after the Herbei Oil Spill Accident Based on Focus Group Interviews)

  • 박지현;권성옥;정우철;허종일;오세영
    • 대한지역사회영양학회지
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    • 제16권4호
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    • pp.466-472
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    • 2011
  • Hazardous chemicals, such as polycyclic aromatic hydrocarbons (PAHs), volatile organic compounds (VOCs) and heavy metals, are known as being harmful to human health were included in oils released by the Herbei Spirit Oil Spill accident in December 2007. To investigate changes of eating habits by the exposure to harmful substances, we conducted 5 focus group interviews for residents at Taean coast areas, who had experienced the oil spill accident. Participants included 46 women (mean age: $57.2{\pm}10.9$) who were mainly responsible for preparing family meals. Focus group discussions were audio-taped, transcribed and categorized by themes. Participants expressed more frequent illness symptoms such as dizziness, vomiting, visual loss, and skin diseases after the accident. They mentioned that their worries about economic hardship and worsened health status since the accident induced mental problems, such as depression about their children. Regarding eating habits, participants reported less intakes of fishes and meats and relatively more intakes of vegetables and kimchi due to the lack of household incomes after the accident. Although the participants had been used to collecting or catching fish or shellfish for their consumption previously, they mainly purchased these foods from local markets after the accident. Changes of eating habits induced by the accident included drinking boiled water and having steamed or fried seafood rather than raw seafood. Changes of food intakes occurred less frequently in older adults due to their longterm fixed eating habits, although they felt uncomfortable for having raw fish. The findings of this study clearly present that the exposure of hazardous substances by the oil spill accident had a significant impact on changes in eating habits besides economic, physical, and mental problems among the residents in Taean. Continuous health and nutrition monitoring and support are needed.

전통양념으로 발효숙성하여 진공포장한 돼지고기의 저장 중 품질 변화 (Changes of Qualities in Vacuum Packed Fermented Pork Using a Korean Traditional Sensoning During Storage)

  • 진상근;김일석;하경희;허선진;박기훈;류현지;배대순
    • Journal of Animal Science and Technology
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    • 제47권1호
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    • pp.39-48
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    • 2005
  • Outside muscle of pork ham were cut to cube(7 $\times$ 10 $\times$2 ern) and three Korea traditional seasonings such as soybean paste(Tl), garlic paste(T2), red pepper paste(T3) were seasoned by the proportions of meat to seasonings(1 : 1), respectively. The seasoned samples were fermented by fill into plastic box at 0 $\pm$ 1 $^{\circ}C$ for 10 days. And then, the fermented meat from each pack was vacuum-packaged and stored at 0 $\pm$ 1 $^{\circ}C$ for up to 9 weeks. pH and shear force were decreased during storage periods in all treatment groups and WHC was decreased with storage in T2. The saccarinity of T1 was increased and salinity increased during storage in all treatment groups. pH of T2 was increased than that of other treatments, while decreased saccarinity and shear force of in T2. The salinity were higher in the order of T1 > T2 > T3. Volatile basic nitrogen (VBN) value were increased with storage in all treatment groups. Thiobarbituric acid reactive substances (TSARS) value of Tl was increased with storage while it was decreased T2. Thiobarbituric acid reactive substances(TSARS) value was higher in the order of T1 > T3 > T2 at 9weeks of storage. Surface meat L' values of T1 was increased with storage and T3 decreased with storage whereas, surface meat a' values of T1 was decreased with storage, and T2 was increased with storage. Surface meat b' values of T3 was decreased with storage. Escherichia coli were decreased during storage periods in all treatment groups.

Development and Interlaboratory Validation of an Analytical Method for the Determination of Saflufenacil in Agricultural Products by HPLC-UVD and LC-MS

  • Do, Jung-Ah;Park, Hyejin;Kwon, Ji-Eun;Oh, Jae-Ho;Cho, Yoon-Jae;Chang, Moon-Ik;Choi, Won-Jo;Lee, Hyun-Sook;Hong, Jin-Hwan
    • 한국식품위생안전성학회지
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    • 제29권4호
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    • pp.285-291
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    • 2014
  • 농산물 중에 있는 제초제 saflufenacil의 잔류량을 검사하기 위해 HPLC-UVD와 LC-MS를 이용한 정확하고 감도가 좋은 분석방법을 개발하였다. Saflufenacil 잔류물은 acetone 추출, dichloromethane을 이용한 액-액 분배, silica와 carbon 카트리지 정제를 거쳐 기기분석을 수행하였다. 검량선 작성을 위해 $0.1{\sim}5.0{\mu}gmL^{-1}$ 범위로 표준품을 만들어 실험한 결과 상관계수($r^2$)는 0.999로 높은 직선성을 보였다. $0.02{\sim}0.5mgkg^{-1}$ 처리수준으로 회수율을 실험한 결과는 80.5~110.2% 이었으며, 상대표준편차는 10% 미만이었다. 분석방법의 검출한계와 정량한계는 각각 0.005와 $0.02mgL^{-1}$ 이었다. 확립된 시험법으로 본청, 부산지방식품의 약품안전청과 경인지방식품의약품안전청에서 실험실간 검증을 실시한 결과 만족스런 결과를 얻었다. 이러한 결과들을 통해 확립된 시험법은 농산물 중 saflufenacil의 잔류량 분석에 적합함을 확인할 수 있었다.

과일 숙성 에틸렌가스 지시계 기술개발 현황 (Ethylene Gas Indicator for Monitoring Climacteric Fruit Ripening)

  • 신동운;이승주
    • 한국포장학회지
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    • 제28권1호
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    • pp.47-53
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    • 2022
  • 최근 식품의 품질을 확인하는 소비자의 관심이 높아짐에 따라 지능형 식품포장 기술이 점차 발전하고 있다. 지능형 포장의 중요한 요소인 indicator는 특정 물질을 감지하거나 식품 품질 변화를 나타내기 위한 색변화를 나타낸다. Gas indicator는 식품 품질이 변할 때 방출되는 휘발성 물질을 감지하기 위해 식품 포장에 내장될 수 있다. 에틸렌 가스는 후숙과일의 호흡을 증가 시키며 후숙과일이 숙성이 진행됨에 따라서 에틸렌가스가 다시 생성된다. 포장된 과일의 경우 headspace의 에틸렌가스 농도는 과일의 숙성도와 밀접한 관련이 있다. 이와 관련하여 에틸렌 가스 흡수제를 제조하여 에틸렌가스를 제거하는 방법도 적용된다. 하지만 이는 소비자가 적숙기의 과일을 섭취하는데 도움이 되지 않는다. 과일 포장에 사용할 수 있는 에틸렌가스 지시계가 있다면 소비자는 최적의 시간에 과일을 섭취할 수 있을 것이다. 본 논문에서는 금속 물질 환원반응 활용 지시계, fluorescence 활용 지시계, pH 지시약 활용 지시계, 리포솜 활용 지시계 등의 다양한 에틸렌가스 지시계를 비교하여 지금까지 개발된 에틸렌가스 지시계의 특성과 장단점을 분석하였다. 각 지표를 분석한 결과, 금속 물질 환원반응 기반 지표인 몰리브덴(Mo)에 팔라듐(Pd)을 촉매화하여 물리적 장벽의 수단인 SiO2와 30PDDA(polydiallyl dimethyl ammonium chloride)의 다중층에 적용한 지시계가 안정성, 에틸렌가스에 대한 민감도, 시각적 변화를 통한 정보 제공력에서 가장 적합한 지시계로 가능성이 높을 것으로 사료된다.

건축 마감재와 가구재의 VOCs, HCHO 유해물질에 따른 공동주택 적정 환기량 산정에 관한 연구 (A Study on the Calculation of Ventilation Rate in Apartment House according to VOCs and HCHO Substances of Building Material and Furniture)

  • 최정민;박진석;손영환;박창섭;박민용;이경희
    • 한국주거학회논문집
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    • 제16권4호
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    • pp.101-108
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    • 2005
  • Because of the airtightness of building, misuse of building materials and abuse of furniture, indoor air pollution problems have been increasingly concerned especially with apartment buildings. To improve the IAQ(Indoor Air Quality) in apartment building, this study was aimed at analyzing the factor of interior building material and furniture and calculating the ventilation rate of living room and bed room according to the surface area of interior building material and furniture in terms of VOCs(Volatile Organic Compounds) and HCHO(Formaldehyde). The results of this study are as follows; 1) In the concerned rooms, the living room has less pollution emission rate L(surface area/volume) than that of the bed room but, the living room needs more ventilation rate than that of the bed room because of built-in furniture in terms of VOCs and HCHO. 2) Built-in interior furniture is very important factor in IAQ problems of apartment building, but until now there is no provision about the built-in furniture, so that the provision must be regulated to control the IAQ. 3) To control the IAQ problem, the effective ventilation plans must be established according to the required ventilation rate by means of natural or mechanical ventilation method.

Quercetin의 급여가 우육의 항산화 효과 및 품질에 미치는 영향 (Effect of dietary supplementation of quercetin on antioxidant activity and meat quality of beef cattle)

  • 강민구;김현주;장애라;감동근;윤관식;조철훈
    • 농업과학연구
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    • 제39권1호
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    • pp.61-68
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    • 2012
  • This study was carried out to investigate the effects of dietary supplementation of quercetin ($Kocetin^{TM}$, QR) on antioxidative activity and meat quality of beef cattle (Holstein-Friesian). Beef cattle were divided into 3 groups; dietary supplementation of QR at 21 (n=4) and 42 ppm (n=3), and non-supplemented control (n=4). The QR comprised of 10% of quercetin. After slaughtering the beef cattle, loins were obtained and analyzed. Dietary supplementation of QR at 42 ppm showed significantly higher final pH of loin but did not affect the water holding capacity, drip loss, cooking loss, surface color, total phenolics content, 1,1-diphenyl-2-picrylhydrazyl radical scavenging activity. Dietary QR showed no difference in both 2-thiobarbituric acid reactive substances and volatile basic nitrogen values. Textural characteristic results also showed no difference, except for cohesiveness. Cohesiveness was significantly higher in loin from beef cattle treated by dietary QR at 42 ppm when compared to control. Results suggest that dietary QR, which has only 10% of quercetin is not sufficient to have positive biochemical effects on beef meat quality.

국내 일부 주유소 내에서의 휘발성 유기화합물 노출에 관한 연구 (A Study on Exposure to Volatile Organic Compounds at Gas Stations in Korea)

  • 송상환;백남원;하권철
    • 한국산업보건학회지
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    • 제10권1호
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    • pp.58-73
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    • 2000
  • Objectives : This study was performed to evaluate BTEX exposure to gas station service attendants and the critical affect of benzene and MtBE airborne concentration. Methods : the degree of exposure to airborne BTEX and MtBE was examined in the service attendants at seven gas stations across the country during a summer season. The TWAs(time-weighted averages) of atmospheric concentration of substances in personal and area samples, were calculated. The component ratio of BTEX and MtBE in the samples of bulk gasoline from each station studied was also measured. Results : The airborne concentrations of BTEX and MtBE showed a lognormal distribution and The TWA concentrations of benzene in personal samples from each station were 0.089 ppm - 0.18 ppm, and those of toluene were 0.097 ppm - 0.2 ppm. The average TWA concentrations of xylene and ethyl benzene was 0.03 ppm and 0.001 ppm, respectively. The TWA concentrations of MtBE were 0.4 ppm - 1.3 ppm. The volume concentrations of MtBE, toluene, ethyl benzene and xylene in the bulk gasoline samples were 3 - 7.4 %, 3 - 12 %, 0.64 % and 1.5 - 10 %, respectively. Conclusions : The benzene concentration was detected to exceed the ACGIH threshold benzene level of 0.5 ppm, in one of 74 personal and area samples. MtBE, a substitute for aromatic compounds such as benzene in gasoline, was found to bring about a greater chance of exposure to carcinogen, due to its high vapor pressure and carcinogenicity.

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양자전이 비행시간 질량분석기를 이용한 화학사고 원인물질 분석 (Analysis of Chemical Accident-Causing Substances Using a Proton Transfer Reaction-Time of Flight Mass Spectrometer)

  • 김소영
    • 한국화재소방학회논문지
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    • 제33권6호
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    • pp.80-86
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    • 2019
  • 국내에서는 2012년부터 2018년 까지 총 556건의 화학사고가 발생하였다. 화학사고 중 두 가지 이상의 화학물질 이상반응에 의해 발생하는 사고는 그 원인물질을 파악하는데 많은 시간이 필요하여 효과적인 사고대응과 수습을 위해서 신속한 분석이 필요하다. 본 논문은 이상반응에 의해 발생한 화학사고의 원인물질 파악을 위해 양자전이 비행시간 질량분석기를 사용하였다. 이 분석기는 시료채취와 전처리 없이 빠른 응답시간을 가져 실시간 분석이 가능하며 또한 수소친화도가 높은 대부분의 휘발성유기화합물질의 정량·정성 분석이 가능하여 이상반응에 의해 발생되는 화학사고의 원인 물질을 조사하는데 적합하다. 실제로 201◯년 ◯월에 ◯◯ 지역 화학사고 발생 시 양자전이 비행시간 질량분석기를 이용하여 측정한 결과 메탄올과 톨루엔 등이 검출되는 것을 알았으며 이상반응에 의해 발생된 황 계열 화합물이 사고 주변의 강한 악취의 원인임을 알 수 있었다.

조리 방법에 따른 맛나지의 저장 기간별 품질 특성 변화 (Quality Characteristics of Mannaji (Boiled Beef Down in Korean Soy Sauce) by Cooking Method during Storage Period)

  • 김지나;박영희;김영;이진영;한귀정
    • 동아시아식생활학회지
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    • 제25권5호
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    • pp.850-859
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    • 2015
  • For development of food of Jong-ga (Jeonju Hakindang) and its commercialization, this study investigated physico-chemical properties and quality characteristics of Mannaji (boiled beef down in Korean soy sauce) prepared with conventional or pre-heating methods during storage period (0, 4, 8, 12, 16, and 20 weeks) at $4^{\circ}C$. As storage period passed, pH decreased in both conventional and pre-heating methods. Forchromaticity, brightness ($L^*$) significantly decreasedwhile redness ($a^*$) and yellowness ($b^*$) significantly increased during storage period. After 4 weeks of storage, hardness of Mannaji with conventional methods was higher compared to before storage. Thiobarbituric acid reactive substances (TBARS) of both conventional and pre-heating methods increased above 1.2 MDA mg/km, which is the acceptable criteria for intake. Although volatile basic nitrogen (VBN) values slightly increased in 4 weeks of storage, there were no significant differences in VBN and maintained food acceptable level until 20 weeks of storage. Sensory panelists showed preference for Mannaji with pre-heating methods compared to conventional methods.

Changes in Quality Characteristics of Pork Patties Containing Antioxidative Fish Skin Peptide or Fish Skin Peptide-loaded Nanoliposomes during Refrigerated Storage

  • Bai, Jing-Jing;Lee, Jung-Gyu;Lee, Sang-Yoon;Kim, Soojin;Choi, Mi-Jung;Cho, Youngjae
    • 한국축산식품학회지
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    • 제37권5호
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    • pp.752-763
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    • 2017
  • Marine fish skin peptides (FSP) have been widely studied due to their antioxidant and antimicrobial properties. We aimed to use a natural antioxidant, FSP, to replacing synthetic preservatives in a pork patty model, which is safer for human body. Moreover, nano-liposome technology can be applied for masking the fishy smell and improving the stability of this peptide. Therefore, in this study, the effects of FSP and FSP-loaded liposomes (FSPL) on pork patty were evaluated through the tests of thiobarbituric acid reactive substances (TBARS), color, cooking loss, texture, volatile basic nitrogen (VBN), and the pH value, during 14 d of refrigerated ($4^{\circ}C$) storage. The results showed that all FSP-treated patties had lower TBARS values than control patties, which indicated an inhibitory effect of FSP on lipid oxidation. This effect in the patties depended on the FSP concentration. However, FSPL-treated patties showed significantly higher and undesirable TBARS values compared to the control, and this effect depended on the FSPL concentration. None of the physicochemical results showed remarkable changes except the pH and VBN values. Therefore, this study provides evidence that FSP has great potential to inhibit the lipid oxidation of pork patties and is capable of maintaining the quality and extending the shelf life. However, it is necessary to study the application of FSP treatments greater than 3% to improve the antioxidant effect on pork patties and search for other coating materials and technology to reduce the drawbacks of FSP.