• Title/Summary/Keyword: viscoelastic matrix

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The Effect of Compatibilizer on the Rheological Properties of Polypropylene/Glass-fiber Composites (폴리프로필렌/유리섬유 복합재료의 유변물성에 미치는 상용화제의 영향)

  • Lee Seung-Hwan;Youn Jae-Ryoun
    • Composites Research
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    • v.19 no.3
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    • pp.15-22
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    • 2006
  • In this study, we prepared glass fiber reinforced polypropylene composites using Brabender twin-screw extruder. Compatibilizer, polypropylene-based maleic anhydride (PP-g-MAH), was used to increase the molecular interaction between polypropylene matrix and glass fiber and to enhance melt processability. We also measured the shear and uniaxial elongational behaviors of glass-fiber reinforced composites in the absence or presence of compatibilizer. The effects of compatibilizer and fiber loading on the viscoelastic behaviors were examined. It was fuund that the PP-g-MAH compatibilizer improved the fluidity and increased the molecular bonding of composite melts in shear flow. Transient elongational viscosity was increased with fiber loadings in uniaxial elongational flow However, it was decreased with increasing elongational rates because of microscale shear flow between fibers.

Influence of Nanodispersed Organoclay on Rheological and Swelling Properties of Ethylene Propylene Diene Terpolymer

  • Acharya Himadri;Srivastava Suneel K.
    • Macromolecular Research
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    • v.14 no.2
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    • pp.132-139
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    • 2006
  • The dispersion of organoclay in ethylene propylene diene terpolymer (EPDM) matrix was correlated with the rheological and swelling properties of nanocomposites. X-ray diffraction pattern (XRD) and transmission electron microscopic (TEM) analysis exhibited the disordered-intercalated structure of EPDM/organoclay nanocomposite. The extent of the disordered phase increased with increasing organoclay content up to a limiting value of 3 wt% after which equilibrium tended towards intercalation. The dispersion effect of organoclay in EPDM matrix was clarified by the physicochemical properties like rheological response and swelling thermodynamics in toluene. The increase in viscoelastic properties of EPDM nanocomposite with increasing organoclay content up to 3 wt%, followed by a subsequent decrease up to 4 wt%, was correlated in terms of the disordered and ordered states of the dispersed nano-clay sheets. Swelling measurements revealed that the change in entropy of the swelling increased with the increase in disorder level but decreased with the increase in intercalation level of organoclay in the disordered-intercalated nanocomposite. The increase in solvent uptake was comparable with the free volume in EPDM matrix upon inclusion of silicate particles, whereas the inhibition in solvent uptake for higher organoclay loading was described by bridging flocculation.

Study on Mechanical Properties Modification of Styrene Butadiene Rubber Composites Filling with Graphene and Molybdenum Disulfide

  • Xu, Li Xiang;Sohn, Mi Hyun;Kim, Yu Soo;Jeong, Ye Rin;Cho, Ur Ryong
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.3
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    • pp.52-59
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    • 2019
  • Styrene-butadiene rubber (SBR) composites, incorporated with graphene, molybdenum disulfide and their hybrid in different filling ratio, were fabricated by a two roll-mill. The dispersion states of all the samples' matrix were employed by carbon black dispersion tester. The curing properties of the pre-vulcanized rubber composites were investigated, after molding by heating press machine, the tensile strength, storage modulus, friction coefficient, the swelling property had also been tested according to ASTM. The composite G1M10 (filling with 1 phr graphene and 10 phr molybdenum) showed the best mechanical properties and viscoelastic properties in this research with a better filler dispersion state and more compact matrix structure.

Three-Dimensional Boundary Element Analysis of Residual Stresses in Fiber Reinforced Viscoelastic composite Materials (섬유가 보강된 점탄성 복합 재료에 발생하는 잔류 응력의 3차원 경계요소 해석)

  • 이상순
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.12 no.3
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    • pp.309-317
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    • 1999
  • 이 논문에서는, 섬유가 보강된 직교 이방성 복합재료의 제작 과정에서 발생하는 잔류 응력을 조사하였다. 직교 이방성 복합 재료의 제작 과정은 경화 과정과 냉각 과정으로 나누어 지며 이 과정에서 발생하는 잔류 응력을 3차원 경계요소법을 이용하여 해석하였다. 모재는 선형 점탄성 거동을 한다고 가정하고, 종속 영역법을 도입하여 해석 모델을 섬유 영역과 모재 영역으로 나누었다. PATRAN을 사용하여 모재에서의 잔류 응력 분포를 도시하였으며 해석 결과를 검토하여 잔류 응력이 국부적으로 모재의 항복을 야기시킬 수 있음을 제시하였다.

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Numerical Evaluation of Phase Velocity and Attenuation of Ultrasonic Waves in Fiber-Reinforced Composites Using the Mass-Spring-Dashpot Lattice Model

  • Baek, Eun-Sol;Yim, Hyun-June
    • Journal of the Korean Society for Nondestructive Testing
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    • v.28 no.6
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    • pp.483-495
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    • 2008
  • The paper presents a numerical study to evaluate the phase velocities and attenuations of the average longitudinal and shear ultrasonic waves resulting from multiple scattering in fiber-reinforced composites. A computational procedure developed in this work is first used to produce a random, yet largely even distribution of fibers. Both the viscoelastic epoxy matrix and lossless randomly distributed graphite fibers are modeled using the mass-spring-dashpot lattice model, with no damping for the latter. By numerically simulating ultrasonic through-transmission tests using this direct model of composites, phase velocities and attenuations of the longitudinal and shear waves through the composite are found as functions of frequency or fiber concentration. The numerical results are observed to generally agree with the corresponding results in the literature. Discrepancies found in some detail aspects, particularly in the attenuation results, are also addressed.

자동차 파워스티어링용 유압호스의 맥동감쇠특성

  • 김도태;이종만;윤인균
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.04a
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    • pp.196-202
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    • 1997
  • A reinforced hydraulic hoses,caiied a resonator hoses,with fixible metal tube are commonly used in automotive power steering hydraulic systems to attenuate and eliminate the objectionable fluid borne noise(pressure ripple) or vibration produced by a pump or steering gear. To achieve better nose attenuation in automotile vehicles, the investigations on propagation and attenuation characteristics of fluid borne pressure ripple in power steering hydraulic ciruit are required. So, this paper descibes a mathematical model of hydraulic hoses to support design the power steering hydraulic circuit and analyze the attenuation characteristics of flow and pressure ripples. The model is based on the transfer matrix approach. The experimental results show that the pulsation attenuation characteristics of hydraulic house is remarkably affected by the flexible metal tube inserted coaxially inside a hydraulic hose with a finite length as well as viscoelastic properties of house wall. It is also shown that the predicted results bymodel proposed here agree well with the measured results over a wide frequency range. These results will assist in the modeling and design of hydraulic hoses, and hear, should provide a means for designing a quieter automotive power steering hydraulic systems.

Rheological Characterization of Polypropylene/Layered Silicate Nanocomposites Using Integral Constitutive Equations (적분형 구성방정식을 이용한 폴리프로필렌/층상 실리케이트 나노복합재료의 유변학적 특성 분석)

  • Lee, Seung-Hwan;Youn, Jae-Ryoun
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.137-140
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    • 2005
  • Exfoliated nanocomposites of polypropylene/layered silicate were prepared by a melt compounding process using maleic anhydride modified polypropylene (PP-g-MAH) and organoclay. It was found that polypropylene/layered silicate nanocomposites exhibited remarkable reinforcement compared with the pure polypropylene or conventional composite filled with agglomerated organoclay. The polypropylene /layered silicate nanocomposites showed stronger and earlier shear thinning behaviors and outstanding strain hardening behavior than pure polypropylene or other conventional composites in shear and uniaxial elongational flows, respectively. We simulated rheological modeling for the pure polymer matrix and polypropylene/layered silicate nanocomposite in shear and elongational flows using K-BKZ integral constitutive equation. The two types of K-BKZequations have been examined to describe experimental results of shear and uniaxial elongational viscosities of pure polypropylene and polypropylene/layered silicate nanocomposite.

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Polymer blends with a liquid crystalline polymer dispersed phase

  • Lee, Heon-Sang;Morton M. Denn
    • Korea-Australia Rheology Journal
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    • v.11 no.4
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    • pp.269-273
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    • 1999
  • Immiscible polymer blends containing a liquid crystalline polymer dispersed phase can be described by existing blend theories when the dispersed-phase droplets are large relative to the orientation correlation length ("domain size") of the LCP. There does not appear to be an interfacial contribution to the linear viscoelastic properties of the blend from droplets smaller than the correlation length. Polyester blends, where interfacial interactions occur between the LCP and the matrix, exhibit a reduction in viscosity to below the viscosity of either component at low shear rates, where the droplet morphology is spherical. These anomalies cannot be explained in the context of existing theory.ng theory.

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Frequency analysis of beams with multiple dampers via exact generalized functions

  • Failla, Giuseppe
    • Coupled systems mechanics
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    • v.5 no.2
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    • pp.157-190
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    • 2016
  • This paper deals with frequency analysis of Euler-Bernoulli beams carrying an arbitrary number of Kelvin-Voigt viscoelastic dampers, subjected to harmonic loads. Multiple external/internal dampers occurring at the same position along the beam axis, modeling external damping devices and internal damping due to damage or imperfect connections, are considered. The challenge is to handle simultaneous discontinuities of the response, in particular bending-moment/rotation discontinuities at the location of external/internal rotational dampers, shear-force/deflection discontinuities at the location of external/internal translational dampers. Following a generalized function approach, the paper will show that exact closed-form expressions of the frequency response under point/polynomial loads can readily be derived, for any number of dampers. Also, the exact dynamic stiffness matrix and load vector of the beam will be built in a closed analytical form, to be used in a standard assemblage procedure for exact frequency response analysis of frames.

Viscoelastic behavior on composite beam using nonlinear creep model

  • Jung, Sung-Yeop;Kim, Nam-Il;Shin, Dong Ku
    • Steel and Composite Structures
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    • v.7 no.5
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    • pp.355-376
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    • 2007
  • The purpose of this study is to predict and investigate the time-dependent creep behavior of composite materials. For this, firstly the evaluation method for the modulus of elasticity of whole fiber and matrix is presented from the limited information on fiber volume fraction using the singular value decomposition method. Then, the effects of fiber volume fraction on modulus of elasticity of GFRP are verified. Also, as a creep model, the nonlinear curve fitting method based on the Marquardt algorithm is proposed. Using the existing Findley's power creep model and the proposed creep model, the effect of fiber volume fraction on the nonlinear creep behavior of composite materials is verified. Then, for the time-dependent analysis of a composite material subjected to uniaxial tension and simple shear loadings, a user-provided subroutine UMAT is developed to run within ABAQUS. Finally, the creep behavior of center loaded beam structure is investigated using the Hermitian beam elements with shear deformation effect and with time-dependent elastic and shear moduli.