• Title/Summary/Keyword: vinyl chloride

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Introduction of vinyl Compounds Containing Hydroxyl Group into Polyamide Reverse Osmosis Membrane

  • 염민오;김학상;김성수;김재진
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.10a
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    • pp.54-55
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    • 1995
  • 현재 수처리용 분리막으로 널리 사용되고 있는 상업용 polyamide membrane은 주사슬을 이루고 있는 amide bond가 chlorine에 쉽게 분해됨으로써 주쇄의 절단이 일어나므로 막이 파괴되는 결과를 초래하여 역삼투 분리막의 기능이 저하되는 문제점을 갖고 있다. 또한 분리막의 성능으로써 수투과도의 향상도 기존의 분리막의 개선점으로 지적되고 있다. 본 연구에서는 재료 자체의 친수성이 강한 hydroxyl group을 가진 vinyl계 화합물을 기존의 amine계 monomer와 혼합하여 가교반응을 시킴으로써 전체적인 분리막의 수투과도 및 내염소성의 향상을 도모하였다. 기존의 polyamide 분리막의 소재인 1,3-phenylenediamine(MPDA)에 친수성기인 hydroxyethylmethacrylate(HEMA) monomer를 첨가하고 가교제인 trymesoyl chloride(TMC)로 이를 가교시켜 HEMA 및 PVA의 친수성에 의한 수투과도 및 내염소성의 향상을 유도하여 보았다.

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Mechanical Behaviors of Electrospun Non-woven of PVC/PU blend (전기방사된 PVC/PU의 기계적 거동)

  • Lee, Bong-Seok;Lee, Keun-Hyung;Kim, Hak-Yong;Pyo, Soo-ho;Park, Sun-Woong
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.269-270
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    • 2003
  • Thermoplastic polyurethane is a engineering plastic with elasticity, abrasion resistance and good resistance to oil, grease and many solvents. Characteristics of poly(vinyl chloride) (PVC) are good general chemical resistance, excellent weatherablility, good insulate. properties, and self-extinguishing or flame resistance, etc. So it is used in widespread industrial fields[2]. (omitted)

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Determination of Basic Drugs with Ion-Selective Membrane Electrodes Using Ion-Exchanger (이온교환체 이온선택성 전극을 이용한 염기성의약품 정량)

  • 이지연;정문모;허문회;김은정;안문규
    • YAKHAK HOEJI
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    • v.43 no.3
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    • pp.289-293
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    • 1999
  • Many poly (vinyl chloride : PVC) membrane electrodes were investigated for the determination of basic drugs, chlorpromazine, amitriptyline, nortriptyline, etc. These electrodes are based on the use of the ion-association complexes of the basic drugs with eriochrome cyanine R, chromoxane cyanine, chrome azurol S and picric acid as ion-exchange sites in a plasticized PVC matrix. All ion-exchangers except picrate complex were not proper for use, because those complexes in plasticized membrane were excluded into aqueous working solution. These drug electrodes show excellent Nernstian responses in the concentration ranges $10^{-2}~10^{-6}$ mol $dm^{-3}$. Their selectivity with respect to each other, as well as their work-able pH range have been investigated. The major advantages of the proposed methods are their simplicity and speed.

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Prediction of Pervaporation Performance Using Solubility Parameter Calculation

  • John R. Dorgan;Nam, Sang-Yong
    • Korean Membrane Journal
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    • v.5 no.1
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    • pp.36-42
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    • 2003
  • A Prediction of pervaporation performance was studied by solubility parameter calculation approach for the benzene/cyclohexane mixture system using rubbery blend membrane with various solubility parameters. The solubility parameter of the rubbery blend membranes were controlled with different blend ratio of the poly(acrylonitrile-co-butadiene), poly(styrene-co-butadiene) and poly(vinyl chloride). Screening of blend formulations was accomplished by simple swelling tests. When the content of NBR is increased, the swelling of both benzene and cyclohexane are decreased. However, the ratio of benzene swelling to swelling by cyclohexane (the swelling selectivity) increases. The same is true for blends in which the PVC content is increased. Adoption of a solubility parameter calculation provides an a priori methodology for seeking the best blend formulation.

Effects of Solvent Selection and Fabrication Method on the Characteristics of Biodegradable Poly(lactide-co-glycolide) Microspheres Containing Ovalbumin

  • Cho, Seong-Wan;Song, Seh-Hyon;Shoi, Young-Wook
    • Archives of Pharmacal Research
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    • v.23 no.4
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    • pp.385-390
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    • 2000
  • To demonstrate the effect of formulation conditions on the controlled release of protein from poly(lactide-co-glycolide) (PLGA) microspheres for use as a parenteral drug carrier, ovalbumin (OVA) microspheres were prepared using the W/O/W multiple emulsion solvent evaporation and extraction method. Methylene chloride or ethyl acetate was applied as an organic phase and poly(vinyl alcohol) as a secondary emulsion stabilizer. Low loading efficiencies of less than 20% were observed and the in vitro release of OVA showed a burst effect in all batches of different microspheres, followed by a gradual release over the next 6 weeks. Formulation processes affected the size and morphology, drug content, and the controlled release of OVA from PLGA microspheres.

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Properties of Original Thermoplastic Polyurethane (TPU)/Plasticized Poly(vinyl chloride) (PVC) and Recycling TPU/PVC Blends (열가소성 폴리우레탄과 가소화된 폴리비닐 클로라이드 블렌드의 특성)

  • Yoo, Hye-Jin;Lee, Young-Hee;Hyuk, Bang-Yun;Hyeob, Beak-Sung;Kim, Han-Do
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.9-12
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    • 2001
  • Blending is an easy and popular means to achieve a desired set of characteristic properties. The blends, by melt mixing of thermoplastic materials and elastomer, have received considerable attention in recent years. It is well known that nearly all blends comprise one polymer domain dispersed in the matrices of the other polymer [1]. (omitted)

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Overview on Development for Thermoplastic Solid Propellants (열가소성 고체추진제 개발 현황)

  • Cho, Joonhyun;Heo, Jinwook;Kim, Dukhyun;Lee, Hyoungjin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.495-497
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    • 2017
  • Thermoplastic propellants using thermoplastic elastomer binders show moderate performance and mechanical properties compared to thermoset propellants, but these propellants are widely used in a variety of fields due to low cost of raw materials, simple manufacturing process and stable handling process. In order to utilize thermoplastic solid propellants in various fields, we will study properties depending on the content of oxidants, metal fuels and additives.

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A Study on the Control of Harmful materials in Children's Goods -centering on school supplies- (어린이 제품에 함유된 유해 물질 관리 방안에 관한 연구 -학용품을 중심으로-)

  • Kwak, Soon-Jin;Kim, Kwang-Soo
    • Journal of the Korea Safety Management & Science
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    • v.19 no.1
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    • pp.115-122
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    • 2017
  • This study analyzed that the standard of school supplies affects the satisfaction of certification. Safety requirements of school supplies in the Republic of Korea is enforced by court duty certification. Therefore, a test was conducted to compare the safety requirements of the United States and Europe and the survey was conducted to know how much manufacturers and importers are satisfied with the certification. To prepare management measures for harmful substances contained in children's product, XRF(X-ray Fluorescence Spectrometry) is utilized to analyze lead(Pb) and cadmium(Cd) in PA(paint), SP(sheet) and PVC(Poly Vinyl Chloride). The results of comparative analysis of ICP(inductively coupled plasma) is analyzed statistically with measured values.

Potentiometric Characteristics of Nitroso.R-Salt-Metal Complex Based Basic Drug Selective Electrodes (금속 니트로소 R염 착물을 이용한 염기성 의약품 선택성 전극의 특성)

  • 이미나;안문규
    • YAKHAK HOEJI
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    • v.47 no.6
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    • pp.356-360
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    • 2003
  • Nitroso-2-naphthol-3,6-disulfonic acid, disodium salt (NRS) was used as an organic ligand to prepare basic drug-selective polymeric membrane electrode. The sensing membrane of the electrode consited of basic drug-meta1(II)-NRS as an ion-exchanger site in a poly(vinyl chloride) matrix plasticized with 2-nitrophenyl octyl ether (NPOE). The metal ions used were Fe$^{2+}$, Co$^{2+}$, Ni$^{2+}$ and Cu$^{2+}$. The electrodes exhibited fast and wide linear response in the basic drug concentration of 10$^{-5}$ ∼10$^{-3}$ mol/l with a response slope of 50∼60 mV/decade in a buffer solution of pH 4∼8. The electrodes exhibited good selectivity for many basic compounds.mpounds.

Analysis of Surface Heat Characteristics by Decoration Wood-based Wood Flooring Board (치장목질마루판 종류별 표면열전달성 분석)

  • Park, Cheul-Woo;Lim, Nam-Gi
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.171-172
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    • 2017
  • There is some recognition that Decoration Wood-based Flooring Board in Korea is a material that inhibits the heat transfer from the substrate to the room. There is a lack of substantial research literature on the surface heat transfer and condition of Decoration Wood-based Flooring Board, which is insufficient to deal with false perceptions. In this study, the purpose of this study is to analyze the surface heat transfer characteristics of Decoration Wood-based Flooring Board and to obtain basic data to cope with recognition.

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