• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
• /
• pp.416-416
• /
• 2014

탄소나노튜브(CNTs)의 비강도는 철합금에 비해 30~50배 높으며, 알루미늄 밀도($2.7g/cm^3$)보다 낮은 $1.3{\sim}1.4g/cm^3$의 값을 갖는 고강도 고경량의 탄소소재이다. 이러한 CNT를 금속기지에 복합화 하면 비강도가 매우 우수하고 고경량화 소재의 제조가 가능하다. 하지만, CNT는 반데르발스(Van der waals) 힘에 의해 서로 뭉쳐서 존재하며, 젖음성이 나쁘기 때문에 금속과 부상 분리되는 단점이 있다. 따라서, 이러한 문제점을 보완하기 위하여 무전해 도금법, 전해도금법 등으로 Cu, Ni등을 코팅하여 문제점을 해결하려는 연구가 진행되어 왔지만, 복합소재를 제조하기 위해 필요한 CNT를 대량으로 코팅하기엔 적합하지 않다. 본 연구에서는 CNT표면에 Cu를 대량으로 형성시킬 수 있는 시멘테이션법을 이용하여, 공정조건에 따른 CNT/Cu의 석출되는 형상 및 성분의 변화를 조사하였다.

• 한국염색가공학회지
• /
• 제7권2호
• /
• pp.1-8
• /
• 1995

Polymer cationic agent was prepared by the initial polymerization of epichlorohydrin followed by amination with diethyl-amine. Cotton fibre treated with the polymer (6∼8% o.w.f.) is highly cationic and exhibit increased substantivity for anionic dyes. The modified substrate could be dyed with direct dyes without salt or a little salt from dye bath. The increased concentration of cationic agents resulted in an increase the colour yield. Futhermore, treated cotton has an electropositive surface charge. Adsorption of direct dye can be attributed to both van der waals force and electrostatic attraction.

• 로봇학회논문지
• /
• 제4권3호
• /
• pp.225-232
• /
• 2009

In the high precision robot systems, the most popular tasks may be handling of micro-scale objects on a surface such as a micromanipulation robot system. In handling of micro-scale objects, the stiction effect becomes a fundamental issue since the micro-contact mechanics dominates the micromanipulation robot system. In the paper, a theoretical non-stick condition derived from the micro-contact mechanics is carried out for the propose of micro-scale object manipulation. To verify the non-stick condition, a micro-manipulation robot system equipped with a high precision stage system and a microscope system is developed. Experimental results show that the proposed non-stick condition guarantees successful micro-scale object manipulation.

• 한국소음진동공학회:학술대회논문집
• /
• 한국소음진동공학회 2011년도 춘계학술대회 논문집
• /
• pp.447-452
• /
• 2011

This paper predicted the dynamic behaviors of a cantilevered carbon nanotube(CNT) incorporating the electrostatic force, van der Waals interactions between the CNT and ground plane. The structural model of the CNT includes geometric and inertial nonlinearities for predicting various phenomena of nonlinear responses of the CNT due to the electrostatic force. In order to solve the problem, we used Galerkin's approximation and the numerical integration techniques and as a result, we predicted characteristics of nonlinear response of nano resonator. The cantilevered CNT shows complex dynamic responses and instabilities due to the applied ac and ac voltages, and driving frequencies. The results investigated in this paper are helpful to the modeling of nanotube based electromechanical devices such as nano-resonators and nano-sensors.

• 한국물환경학회지
• /
• 제20권6호
• /
• pp.676-684
• /
• 2004

Many researchers have been carrying on study to figure out the exact collision efficiency between bubble and floc. Collision efficiency can has generally been quantified by using trajectory analysis which uses the hydrodynamic, the electrostatic and van der waals forces. Two types of method are considered to induce the hydrodynamic force in the trajectory analysis. One is to use stream function and the other is to use mobility function. There was some difference between stream and mobility function depending upon modelling factors and conditions in trajectory analysis.

• 신재생에너지
• /
• 제3권2호
• /
• pp.47-52
• /
• 2007

Hydrate phase equilibrium for the binary $CO_{2}$+water and $CH_{4}$+water mixtures in silica gel pore of nominal 6, 30, and 100 nm were measured and compared with the cacluated results based on van der Waals and Platteeuw model. At a specific temperature three-phase hydrate-water-vapor (HLV) equilibrium curves for pore hydrates were shifted to the higher-pressure condition depending on pore sizes when compared with those of bulk hydrates. Notably, hydrate phase equilibria for the case of 100 nominal nm pore size were nearly identical with those of bulk hydrates. The activities of water in porous silica gels were modified to account for capillary effect, and the calculation results were generally in good agreement with the experimental data.

• 한국산학기술학회:학술대회논문집
• /
• 한국산학기술학회 2005년도 춘계학술발표논문집
• /
• pp.277-278
• /
• 2005

미생물 고정화를 위하여 PU 폼을 세 가지 처리 방법으로 처리하였다. 플라즈마 처리, 플라즈마 유도 그라프팅, 플라즈마 유도 그라프팅 후 플라즈마로 재처리 방법을 사용하였다. 플라즈마 처리는 bacteria adhesion에 큰 효과를 주지 못하였고, 아크릴산의 플라즈마 유도 그라프팅은 adhesion을 세 배 이상 증가시켰다. Bacteria의 adhesion 성능 향상은 표면의 친수성을 증가시키고 새로운 groove나 cavity들을 형성시킴으로 가능하였다. 반면, 그라프팅 후 plasma re-treatment는 미생물 고정화를 크게 향상시키지 못하였다. SEM 관찰을 통하여 대부분의 E.coli.는 groove나 cavities라는 shear-free area에 서식함을 알 수 있었다. PU폼의 bacteria adhesion은 미생물과 고분자 표면 사이의 정전기적 인력이나 van der Waals 인 력에 의해 주로 영향을 받는다고 사료된다.

• EDISON SW 활용 경진대회 논문집
• /
• 제3회(2014년)
• /
• pp.311-323
• /
• 2014

분자동역학 모의실험을 이용하여 간단한 van der Waals 상호작용하는 이성분 혼합물 계의 섞임 자유에너지 및 섞임 엔트로피 등 섞임과 관련된 열역학 함수들을 계산하는 방법을 소개한다. 각 혼합물의 과잉 자유에너지는 열역학 적분 (thermodynamic integration)방법을 이용하여 계산하고, 이성분 혼합물의 섞임 관련 열역학 함수들은 Hess의 법칙을 확장함으로써 구한다. 계산 결과로부터 온도가 증가할수록 계의 섞임 Helmholtz 자유에너지는 감소하며, 섞임 내부에너지도 감소함을 알 수 있다. 섞임 엔트로피는 온도가 증가할수록 이상기체의 섞임 엔트로피에 접근함을 알 수 있다. 섞임 Helmholtz 자유에너지에 대한 섞임 내부에너지와 섞임 엔트로피 기여도를 조사한 결과 이 계의 섞임 과정을 주도하는 추진력은 엔트로피에 의한 것임을 알 수 있다. 본 연구 방법과 결과를 이용함으로써 학부생들이 혼합물의 열역학 성질을 이해하는데 도움을 주리라 기대한다.

• 한국자기학회:학술대회 개요집
• /
• 한국자기학회 2013년도 자성 및 자성재료 국제학술대회
• /
• pp.32-32
• /
• 2013

Using the Vienna ab initio simulation package (VASP) incorporating van der Waals interaction, we have explored structural, adsorption, and magnetic properties of Ni(111)/BN/Co(111) systems. We have found that both Ni(111) and Co(111) layers shows half metallic state, while the spacer BN layer becomes weak metal for one monolayer (ML) thickness and an insulating barrier for two ML thickness. The half metallic states in both Ni(111) and Co(111) layers are robust because it is unchanged independently on the magnetic coupling of Ni(111) and Co(111). This finding suggests that the Ni(111)/BN/Co(111) systems can be utilized for perfect tunneling magnetoresistance system. Moreover, it can be applied for potential spin injecting into semiconductor in FM/semiconductor system due to the fact that the half metallic state in FM layers at the interface will be unchanged.

• Bulletin of the Korean Chemical Society
• /
• 제29권4호
• /
• pp.741-748
• /
• 2008

We have studied the folding mechanism of $\beta$ -hairpins in the proteins 1GB1, 3AIT and 1A2P by conducting unfolding simulations at moderately high temperatures. The analysis of trajectories obtained from molecular dynamics simulations in explicit aqueous solution suggests that the positions of the hydrophobic core residues lead to subtle differences in the details of folding dynamics. However, the folding of three different hairpins can be explained by a unified mechanism that is a blend of the hydrogen-bond-centric and the hydrophobiccentric models. The initial stage of $\beta$-hairpin folding involves various partially folded intermediate structures which are stabilized by both the van der Waals interactions of hydrophobic core residues and the electrostatic interactions of non-native hydrogen bonds. The native structure is obtained by forming native contacts in the final tune-up process. Depending on the relative positions of the hydrophobic residues, the actual mechanism of hairpi n folding may or may not exhibit well-defined intermediates.