• 제목/요약/키워드: value chains

검색결과 251건 처리시간 0.026초

고에너지 함유 옥세탄류의 정전기 전위 및 화학 반응성 연구 (A Study on Electrostatic Potentials and Chemical Reactivities of Energetic Oxetanes)

  • 전용구;조수경
    • 대한화학회지
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    • 제39권5호
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    • pp.329-337
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    • 1995
  • 산촉매하에서 중합반응을 하는 고에너지를 함유한 옥세탄 유도체들을 ab initio HF/3-21G 방법으로 구조, 전하, 정전기 전위 등을 계산하고 그 결과를 고찰하였다. 계산 결과에 의하면 큰 치환체가 도입되거나 양성자화나 $BF_3$ 착물화에 의해 옥세탄 고리의 구조는 상당히 변화하며, 이것은 정전기적 상호작용이나 구조적 척력으로 설명할 수 있다. 옥세탄 유도체들의 친핵성 및 염기성은 옥세탄 산소원자의 음전하와 최소 정전기 전위의 크기로 설명할 수 있다. 공중합하의 옥세탄 유도체들의 반응성은 (1) 옥세탄 유도체의 염기성과 (2) 옥세탄 유도체의 HOMO 에너지와 활성화 옥세탄 중합 고리의 LUMO 에너지의 차에 의해 설명되어진다. 계산에 의하면 3-azidomethyl-3-methyl oxetane (AMMO)이 3-nitratomethyl-3-methyl oxetane (NMMO)보다 염기성이 크며, AMMO나 NMMO 사슬에 관계없이 반응성이 큼을 알 수 있다. 이 계산 결과는 이미 알려진 실험 결과들과 잘 일치한다.

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시간 상태 변화를 적용한 범죄 발생 예측에 관한 연구 (A Study of the Probability of Prediction to Crime according to Time Status Change)

  • 박구락
    • 한국컴퓨터정보학회논문지
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    • 제18권5호
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    • pp.147-156
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    • 2013
  • 현대 사회의 각 분야는 산업화와 과학기술의 발전으로 빠르게 변화한다. 그러나 빠른 사회 변화의 부작용으로 다양한 문제가 발생하고 있는데, 그 중 범죄는 큰 문제이다. 본 논문은 범죄를 예측하기 위한 모델로 마코프 체인을 적용한 범죄 예측 모델링을 제안한다. 기존의 마코프 체인 모델링은 한 사건의 전체 상태만으로 미래 예측 확률을 구하였으나, 본 논문은 사건 발생 확률 예측을 높이기 위해 전체 상태 예측 확률과 최근 상태 예측 확률로 나누었다. 그리고 전체 상태 예측 확률과 최근 상태 예측 확률의 평균값을 적용하여 미래 예측 확률 모델링으로 구현했다. 데이터는 범죄 발생 건수를 적용하였다. 그 결과 전체 상태만을 대상으로 예측확률을 적용 하였을 때 보다, 전체 상태와 최근상태로 나누어 확률 값을 구한 후, 그 평균값을 예측 확률로 적용하였을 때, 범죄 발생 예측에 근접하다는 결론을 얻었다.

Characteristics and Gel Properties of Gelatin from Goat Skin as Influenced by Alkaline-pretreatment Conditions

  • Mad-Ali, Sulaiman;Benjakul, Soottawat;Prodpran, Thummanoon;Maqsood, Sajid
    • Asian-Australasian Journal of Animal Sciences
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    • 제29권6호
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    • pp.845-854
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    • 2016
  • Characteristics and properties of gelatin from goat skin pretreated with NaOH solutions (0.50 and 0.75 M) for various times (1 to 4 days) were investigated. All gelatins contained ${\alpha}$-chains as the predominant component, followed by ${\beta}$-chain. Gelling and melting temperatures of those gelatins were $23.02^{\circ}C$ to $24.16^{\circ}C$ and $33.07^{\circ}C$ to $34.51^{\circ}C$, respectively. Gel strength of gelatins increased as NaOH concentration and pretreatment time increased (p<0.05). Pretreatment for a longer time yielded gelatin with a decrease in $L^*$-value but an increase in $b^*$-value. Pretreatment of goat skin using 0.75 M NaOH for 2 days rendered the highest yield (15.95%, wet weight basis) as well as high gel strength (222.42 g), which was higher than bovine gelatin (199.15 g). Gelatin obtained had the imino acid content of 226 residues/1,000 residues and the gelatin gel had a fine and ordered structure. Therefore, goat skin gelatin could be used as a potential replacer of commercial gelatin.

A study on Classification of Insider threat using Markov Chain Model

  • Kim, Dong-Wook;Hong, Sung-Sam;Han, Myung-Mook
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제12권4호
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    • pp.1887-1898
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    • 2018
  • In this paper, a method to classify insider threat activity is introduced. The internal threats help detecting anomalous activity in the procedure performed by the user in an organization. When an anomalous value deviating from the overall behavior is displayed, we consider it as an inside threat for classification as an inside intimidator. To solve the situation, Markov Chain Model is employed. The Markov Chain Model shows the next state value through an arbitrary variable affected by the previous event. Similarly, the current activity can also be predicted based on the previous activity for the insider threat activity. A method was studied where the change items for such state are defined by a transition probability, and classified as detection of anomaly of the inside threat through values for a probability variable. We use the properties of the Markov chains to list the behavior of the user over time and to classify which state they belong to. Sequential data sets were generated according to the influence of n occurrences of Markov attribute and classified by machine learning algorithm. In the experiment, only 15% of the Cert: insider threat dataset was applied, and the result was 97% accuracy except for NaiveBayes. As a result of our research, it was confirmed that the Markov Chain Model can classify insider threats and can be fully utilized for user behavior classification.

Prediction of Deterioration Rate for Composite Material by Moisture Absorption

  • Kim, Yun-Hae;An, Seung-Jun;Jo, Young-Dae;Bae, Chang-Won;Moon, Kyung-Man
    • Journal of Advanced Marine Engineering and Technology
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    • 제34권2호
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    • pp.296-302
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    • 2010
  • If the fiber reinforced plastic is exposed to the moisture for a long period of time, most of moisture absorption occurs on the resin place, thus dropping cohesiveness between the molecules as the water molecules permeated between high molecular chains grant high molecular mobility and flexibility. Also as the micro crack occurs due to the permeation of moisture on the interface of glass fiber and epoxy resin, it is developed to the overall damage of interface place. Hence, the study on absorption is essential as the mechanical and physical properties of fiber reinforced composites are reduced. However, the study on absorption has the inconvenience needing to expose composite materials to fresh water or seawater for 1 month or up to 1 year. Therefore, this study has exposed fiber reinforced composites to fresh water and has developed a model with an accuracy of 98% after comparing the analysis value obtained by using ANSYS while basing on the experimental value of property decline by absorption and the basic properties of glass fiber and epoxy resin used in the experiment.

혼합 Self-assembled monolayer의 마이크로/나노 응착 및 마찰 특성 (Micro/nano adhesion and friction properties of mixed self-assembled monolayer)

  • 오현진;윤의성;한흥구;공호성;장경영
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2003년도 학술대회지
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    • pp.56-63
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    • 2003
  • Micro/nano adhesion and friction properties of mixed self-assembled monolayer (SAM) with different chain length for MEMS application were experimentally studied. Many kinds of SAM having different spacer chains(C6, C10 and C18) and their mixtures (1:1) were deposited onto Si-wafer, where the deposited SAM resulted in the hydrophobic nature. The adhesion and friction properties between tip and SAM surfaces under nano scale applied load were measured using an atomic force microscope (AFM) and micro scale applied load were measured using ball-on-flat type micro-tribotester. Surface roughness and water wetting angles were measured with SPM (scanning probe microscope) and contact anglemeter. Results showed that wetting angles of mixed SAMs showed the similar value of pure SAMs. The coating surface morphology was increased as mixing of SAM. Nano adhesion and nano friction decreased as increasing of the spacer chain length and mixing of SAM. Micro friction was decreased as increasing of the spacer chain, but micro friction of mixed SAM showed the value between pure SAMs. Nano adhesion and friction mechanism of mixed SAM was proposed in a view of stiffness of spacer chain modified chemically and topographically.

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팬데믹 시기의 패션 테크놀로지에 관한 시각 - 텍스트 마이닝과 내용 분석을 중심으로 - (Perspectives on Fashion Technology during the Pandemic Era - A Mixed Methods Approach Using Text Mining and Content Analysis -)

  • 김미경;임은혁
    • 한국의류산업학회지
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    • 제24권5호
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    • pp.545-556
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    • 2022
  • To overcome the pandemic, a new strategy for innovation is in demand throughout the value chains of the fashion industry that emphasize the importance of fashion technology. Accordingly, as various viewpoints and fields of debate are unfolding to consider the direction of change led by fashion technology, it is necessary to make an active value judgment precedent by understanding the differences between various opinions. This study aims to derive keywords from fashion technology used during the pandemic, to infer the characteristics of each type of perspective and to understand their characteristics. For the research, this study combines text mining analysis and content analysis. Text mining analysis is used to find statistical patterns by collecting keywords from big data from online media, and content analysis is used to interpret the data qualitatively. After analyzing the results of this study, the following observations are made. First, the perspective of positive acceptance seeks to maximize the perception and sensory action of fashion through technology; this amplifies experience, an opportunity for innovation and efficiency. Second, critical vigilance highlights the side effects of radical changes in fashion technology, characterized by concerns about capital-centered polarization, threats to human rights, and infringement of creative thinking. Lastly, the perspective of gradual adoption is the gradual convergence of technologies, characterized by the pursuit of an appropriate balance.

Predicting Consumers' Repurchase Intention of Ready-to-Drink Coffee: A Supply Chain from Thai Producers to Retailers

  • PUTITHANARAK, Naruecha;KLONGTHONG, Worasak;THAVORN, Jakkrit;NGAMKROECKJOTI, Chittipa
    • 유통과학연구
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    • 제20권5호
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    • pp.105-117
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    • 2022
  • Purpose: This research investigates ready-to-drink (RTD) coffee. Although the RTD coffee market is growing competitively, few studies have examined behavioral re-intention or repurchase intention in the context of this industry. Therefore, the objective of this study was to explore factors affecting the behavioral re-intention to purchase RTD coffee. Research design, data and methodology: Using the theory of planned behavior (TPB) as the underpinning theoretical framework, this study hypothesized that behavioral re-intention to purchase RTD coffee is influenced by the variables of the TPB and additional variables. A mixed-method research design was applied, starting with qualitative in-depth interviews and followed by a quantitative method. Data were collected using an online survey of coffee lovers. Multiple linear regression (MLR) was used to assess the hypothesized relationships in the proposed conceptual framework. Results: The results reveal that content sensory attribute beliefs are the strongest positive predictor of behavioral re-intention in Thailand, followed by perceived utilitarian value. In contrast, price signaling was negatively related to behavioral re-intention. Conclusions: The findings can help food and beverage companies to develop new coffee product lines to gain more market share, create integrated marketing communications to build brand awareness, and manage distribution channels and the supply chain.

Economic Complexity Index and Economic Development Level under Globalization: An Empirical Study

  • Mao, Zhuqing;An, Qinrui
    • Journal of Korea Trade
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    • 제25권7호
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    • pp.41-55
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    • 2021
  • Purpose - This paper empirically investigates the relationship between the Economic Complexity Index (ECI) and the level of development. Moreover, this research attempts to discover the determinants of ECI in the globalization wave. Design/methodology - Our empirical model considers the relationship between ECI and the level of development in middle- and high-income economies from 1995 to 2010 by using systemic qualitative analysis, including OLS, fixed-effects, and system GMM. Next, this research used OLS regression to find the determinants of ECI. In particular, we compared the effects of different factors on ECI in the different development stages. Findings - Our main findings can be summarized as follows: 1. If the ECI increases by 1, it could lead to an increase of about 30% in the level of development in middle- and high-income economies. 2. Human capital plays an important role in the development of and increase in ECI. 3. GVC participation and outflow FDI enhance an increase in ECI, in particular in middle-income economies. 4. The development of manufacturing industries is helpful to increase ECI; however, middle-income economies should pay more attention to their comparative advantage industries. 5. R&D has positive effects on the ECI. Originality/value - To the best of our knowledge, this is the first paper that uses systemic qualitative analysis to investigate the relationship between ECI and the level of development. The paper provides suggestions for policy makers to increase ECI under the current wave of globalization, in particular in middle-income economies.

The Effectiveness of the Cooperation Agenda in FTAs: Ways to Promote Foreign Investment and Development Assistance in Asia

  • Hur, Nany
    • Journal of Korea Trade
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    • 제25권6호
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    • pp.1-19
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    • 2021
  • Purpose - This paper aims at analyzing the functions and effectiveness of the cooperation agenda in Free Trade Agreements (FTAs), focusing on the cases of Asian countries. This paper estimates the contribution of this agenda to the sustainable development in Asia by providing the 'side payment' of the economic integration that encourages foreign investment and change in global value chains (GVC). Design/methodology - This study analyzes the functions of the cooperation chapter in FTAs by applying the cooperative game theory and reviewing the structures of the related FTAs. Also, as an empirical study, the existing FTA provisions and related development assistant programs in Asia are reviewed in this paper, especially focusing on the FTAs signed by Korea. Findings - Our main findings can be summarized as follows: The drawback of the economic integration, which would be the imbalanced economic benefit, can be redressed by the cooperation chapter in FTAs functioning as a 'side payment'. Indeed, as the examples of Korean FTAs show, more foreign investment and the GVC expansion in Asian countries have been encouraged thanks to the implementation of the cooperation chapters. Originality/value - This paper attempts to find how a legally binding agreement would influence the cooperation agenda in Asia which has never been analyzed despite the increasing number of so-called 'cooperation' chapters in the FTAs.