• 지질공학
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• 제32권1호
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• pp.127-142
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• 2022

This study explored the fluid transfer characteristics of simultaneous pneumatic blasting, plasma blasting, and vacuum suction (the PPV method), and assessed their effect. Chemical oxidation-an established soil remediation method-was compared as a control. Electrical resistivity surveys found that PPV reduced resistivity by about 1.5-2.5 times compared with the control group, indicating that it increased the diffusion of fluid between the injection and suction wells. Injection and suction tests comparing the injection flow rate, initial suction flow rate time, and suction flow rate showed that the PPV method offered an improvement over the existing method. Slug tests revealed that PPV increased the permeability coefficient by a greater amount than that by the control method. This study qualitatively and quantitatively confirmed that the PPV method clearly improves injection and suction efficiency by accelerating cracks in the ground and improving water permeability compared with the established chemical oxidation method.

• 한국진공학회지
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• 제20권6호
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• pp.416-421
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• 2011

이 논문에서 광방출 분석법을 응용하여 반응용기 내부 오염과 특정 파장 크기변화의 관계를 알아보았다. 광방출 분석법을 이용하면 $O_2$ 플라즈마에서 폴리머가 제거되는 것이 관찰된다. 하지만 광방출 분석법은 외부영향에 의한 노이즈로 분석이 힘들며 다양한 조건에서의 폴리머 제거 상태를 비교하는 건 쉽지 않다. 이를 해결하고자 diff_CO 함수를 정의하고, 여러 경우에서의 diff_CO 함수 변화를 확인하였다. diff_CO 함수는 RF 인가시간이 증가함에 따라 최대값의 크기 감소와 작은 꼭지점 개수의 증가를 관찰할 수 있으며, 이를 이용하면 반응용기를 열지 않고도 반응용기 내부 오염정도를 파악하여 반응용기 세정 시점을 정할 수 있었다.

• 상하수도학회지
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• 제31권4호
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• pp.311-319
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• 2017

Scale formation is inevitable problem when seawater is treated by vacuum membrane distillation. The reason is the high concentration of calcium ion($Ca^{2+}$), sulfate ion(${SO_4}^{2-}$) and bicarbonate ion(${HCO_3}^-$). These ions form calcium sulfate($CaSO_4$) and calcium carbonate($CaCO_3$) on the membrane. The scale formed on membrane has to be removed, because the flux can be severely reduced and membrane wetting can be incurred. This study was carried out to investigate scale formation and effectiveness of acid cleaning in vacuum membrane distillation for SWRO brine treatment. It was found that permeate flux gradually declined until volume concentration factor(VCF) reached around 1.55 and membrane wetting started over VCF over 1.6 in the formation of precipitates containing $CaSO_4$ during VMD operation. In contrast, when calcium carbonate formed on membrane, permeate flux was gradually reduced until VCF 3.0. The precipitates containing both $CaSO_4$ and $CaCO_3$ were formed on the membrane surface and in the membrane pore.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2007년도 제38회 하계학술대회
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• pp.2048-2049
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• 2007

광섬유 온도센서를 이용하여 밀폐형 폐쇄배전반 내부에 설치된 진공차단기(Vacuum Circuit Breaker: 이하 VCB)의 접촉부 및 부싱부 이상 온도변화를 상시 감시할 수 있는 On-line 온도 감시 시스템을 개발하였다. 본 시스템은 온도변화를 측정하는 광센서부, 광신호의 이동 통로역할을 하는 Optical Head부, 변환된 전기신호를 신호처리하고 상위 시스템으로 통신을 수행할 신호처리장치의 세 부분으로 구성되어 있다. 구현한 시스템은 측정 범위가 $-25\;{\sim}\;200^{\circ}C$인 희토류 원소가 첨가된 광섬유 온도센서를 사용하였고, 시스템의 측정 범위는 $-20\;{\sim}\;150^{\circ}C$, 측정 정밀도는 Full Scale의 ${\pm}2\;%$, 측정 주파수는 0.1 Hz이었다. 검출된 온도 값은 Modbus Protocol을 이용하여 상위 시스템으로 송신하도록 구현하였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.130-130
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• 2012

Axial bindings of diatomic molecules to metalloporphyrins involve in the dynamic processes of biological functions such as respiration, neurotransmission, and photosynthesis. The binding reactions are also useful in sensor applications and in control of molecular spins in metalloporphyrins for spintronic applications. Here, we present the binding structures of diatomic molecules to surface- supported Co-porphyrins studied using scanning tunneling microscopy. Upon gasexposure, three-lobed structures of Co-porphyrins transformed to bright ring shapes on Au(111), whereas H2-porphyrins of dark rings remained intact. The bright rings are explained by the structures of reaction complexes where a diatomic ligand, tilted away from the axis normal to the porphyrin plane, is under precession. Our results are consistent with previous bulk experiments using X-ray diffraction and nuclear magnetic resonance spectroscopy.

• 한국표면공학회지
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• 제41권5호
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• pp.245-253
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• 2008

The porous metal material is used for injection metal mold with a great deal of gas production because it makes plenty of gas exhausted through pores formed in the metal mold. A canning HIP method was conventionally used for manufacturing of porous metals, but because of difficulty of process control and high cost of production its application was limited. In this experiment, porous metal mold material was produced by an enhanced vacuum sintering method with simply controlled and economical process and porosities/mechanical properties with variation of sintering temperature and duration time during vacuum sintering were studied. As a result, quality goods were obtained at optimized conditions as follows: sintering temperature of $1230^{\circ}C$, duration time of 2 hr and showed superior properties in wear loss and thermal conductivity and the same properties in hardness, TRS (Transverse Rupture Strength), and thermal expansion coefficient in comparison with those under canning HIP.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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• pp.10-11
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• 2006

In this study, the Ni/Co/TiN (6/2/25 nm) structure was deposited for thermal stability estimation. Vacuum (30 mTorrs) annealing was carried out to compare with furnace annealing in nitrogen ambient. The proposed Ni/Co/TiN structure exhibited low temperature silicidation and wide range of rapid thermal process (RTP) windows. The sheet resistance was too high to measure after furnace annealing at $600^{\circ}C$ due to the thin thickness (15 nm) of the nickel silicide. However, the sheet resistance maintained stable characteristics up to $600^{\circ}C$ for 30 min after vacuum annealing. Therefore, the low resistance of thin film nickel silicide was obtained by vacuum annealing at $600^{\circ}C$.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.219-219
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• 2010

Silicides have been commonly used in the Si technology due to the compatibility with Si. Recently the silicide has been applied in solar cells [1] and nanoscale interconnects [2]. The modulation of Ni silicide phase is an important issue to satisfy the needs. The excellent electric-conductive nickel monosilicide (NiSi) nanowire has proven the low resistive nanoscale interconnects. Otherwise the Ni disilicide (NiSi2) provides a template to grow a crystalline Si film above it by the little lattice mismatch of 0.4% between Si and NiSi2. We present the formation of Ni silicide phases performed by the single deposition and the co-deposition methods. The co-deposition of Ni and Si provides a stable Ni silicide phase at a reduced processing temperature comparing to the single deposition method. It also discusses the Schottky contact formation between the Ni silicide and the grown crystalline Si film for the solar cell application.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.264-264
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• 2013

Strong metal-support interaction effect is an important issue in determining the catalytic ac-tivity for heterogeneous catalysis. In this study, we investigated the support effect and the role of organic capping layers of two-dimensional Pt nanocatalysts on reducible metal oxide supports under the CO oxidation. Several reducible metal oxide supports including CeO2, Nb2O5, and TiO2 thin films were prepared via sol-gel techniques. The structure, chemical state and optical property were characterized using XRD, XPS, TEM, SEM, and UV-VIS spectrometer. We found that the reducible metal oxide supports have a homogeneous thin thickness and crystalline structure after annealing at high temperature showing the different optical band gap energy. Langmuir-Blodgett technique and arc plasma deposition process were employed to ob-tain Pt nanoparticle arrays with capping and without capping layers, respectively on the oxide support to assess the role of the supports and capping layers on the catalytic activity of Pt catalysts under the CO oxidation. The catalytic performance of CO oxidation over Pt supported on metal oxide thin films under oxidizing reaction conditions (40 Torr CO and 100 Torr O2) was tested. The results show that the catalytic activity significantly depends on the metal oxide support and organic capping layers of Pt nanoparticles, revealing the strong metal-support interaction on these nanocatalysts systems.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.87-87
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• 2011

Oxide semiconductors are attractive materials for thin-film electronics and optoelectronics due to compatibility with synthesis on large-area, glass and flexible substrate. However, development of thin-film electronics has been hampered by the limited number of semiconducting oxides that are p-type. We report on the effect of the oxygen partial pressure ratio in the gas mixture on the electrical and optical properties of spinel Mg:$ZnCo_2O_4$ thin films deposited at room temperature using RF sputtering, that exhibit p-type conduction. The thin-films are deposited at room temperature in a background of oxygen using a polycrystalline Mg:$ZnCo_2O_4$ ablation target. The p-type conduction is confirmed by positive Seebeck coefficient and positive Hall coefficient. The electrical resistivity and carrier concentration in on dependent Mg:$ZnCo_2O_4$ thin films were found to be dependent on the oxygen partial pressure ratio. As a result, it is revealed that the Mg:$ZnCo_2O_4$ thin-films were greatly influenced on the electrical and optical properties by the oxygen partial pressure condition. The visible region of the spectrum of 36~85%, and hole mobility of 1.1~3.7 $cm^2$/Vs, were obtained.