• Economic and Environmental Geology
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• v.55 no.5
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• pp.511-519
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• 2022

In order to develop an air-stripping based remediation process to remove the TOC (Total Organic Carbon) in groundwater around the underground LPG storage cavern, the laboratory scale experiments at various conditions (change of air injection volume and temperature, the application of ultrasonic treatment, etc.) for two types of groundwater (initial TOC concentration of 608 mg/L and 153 mg/L, respectively). From results of experiment, as the air injection rate for stripping into groundwater increased from 2 L/min to 11 L/min and as the air-stripping time increased from 1 hour to 24 hour, the TOC removal efficiency of air-stripping increased. However, the TOC concentration of treated groundwater was higher than the discharge tolerance limit (100 mg/L) even after 24 hour stripping at the maximum air injection rate of 11 L/min. The main compounds of the TOC in groundwater were identified as methanol and propane and the long stripping time (more than 24 hour) was needed to separate the methanol from groundwater because of the affinity between water and methanol. At 20℃ and 4 L/min of air injection, the TOC removal efficiency increased to 59.1% after 24 hour air-stripping. When the temperature of groundwater increased to 30℃ and 40℃, the TOC removal efficiency increased up to 80.0% and 82.8%, suggesting that more than 24 hour air-stripping at 40℃ is needed to lower the TOC concentration to below 100 mg/L and the additional TOC removal process as well as the air-stripping is necessary. When the temperature increased to 60℃ and the ultrasonic treatment was conjugated with the air-stripping, the TOC removal efficiency increased to 87.8% within 5 hour stripping and the final TOC concentration (72.4 mg/L) was satisfied with the TOC discharge tolerance limit. The TOC removal efficiency for groundwater having low TOC concentration (153 mg/L) also showed similar removal efficiency of 89.7% (the final TOC concentration: 18.9 mg/L). Results in this study supported that the air-stripping conjugated with the ultrasonic treatment could remove successfully the TOC in groundwater around the underground LPG strorage cavern.

• Journal of the Korean Institute of Gas
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• v.1 no.1
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• pp.101-105
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• 1997

When the water curtain system is employed to keep the liquefied gas in the underground storage cavern, clogging is observed in borehole. Since this phenomenon causes serious difficulties in managing LPG storage cavern, it needs to detect the degree of clogging accurately under various circumstances. Thus, in this study the active factors of clogging, that is, groundwater head, injection water flowrate, and seepage water flowrate, were investigated experimentally using a physical model. Experimental results show that groundwater head around storage cavern increases as cavern Pressure increases, while it decreases as clogging becomes severe. The pressure in storage cavern is required to reduce up to atmospheric pressure in order to detect and identify the degree of clogging more accurately. The decrease of uroundwater head due to clogging slows down as the pressure in borehole increases. As amounts of suspended matters in injected water increase, both injection water flowrate and seepage water flowrate decrease linearly with time, and the flowrate of injection water drops rapidly compared with seepage water flowrate.

• Journal of the Korean earth science society
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• v.35 no.4
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• pp.225-236
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• 2014

Multivariate statistical analyses have been extensively applied to hydrochemical measurements to analyze and interpret the data. This study examines anthropogenic factors obtained from applications of correspondence analysis (CA) and principal component analysis (PCA) to a hydrogeochemical data set. The goal was to synthesize the hydrogeochemical information using these multivariate statistical techniques by incorporating hydrogeochemical speciation results calculated by the program, commonly used, WATEQ4F included in the NETPATH. The selected case study was LPG underground storage caverns, which is located in the southeastern Korea. The highly alkaline groundwaters at this study area are an analogue for the repository system. High pH, speciation of Al and possible precipitation of calcite characterize these groundwaters. Available groundwater quality monitoring data were used to confirm these statistical models. The present study focused on understanding the hydrogeochemical attributes and establishing the changes of phase when two anthropogenic effects (i.e., disinfection activity and cement pore water) in the study area have been introduced. Comparisons made between two statistical results presented and the findings of previous investigations highlight the descriptive capabilities of PCA using calculated saturation index and CA as exploratory tools in hydrogeochemical research.

• Journal of the Korean Geophysical Society
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• v.5 no.2
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• pp.75-86
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• 2002

A TSP(Tunnel Seismic Prediction) survey which is modified VSP(Vertical Seismic Profiling) survey applied in tunnel was carried out at Pyongtaek and Incheon liquefied petroleum gas(LPG) storage cavern during excavation. The TSP survey in Pyongtaek LPG storage cavern which is located below Namyangho was performed to confirm the location and orientation of the fault detected at pre-investigation stage. The TSP survey was carried out in access tunnel, construction tunnel, and watercurtain tunnel to characterize 3 dimensional figure of the fault. The results of TSP survey are compared four in vestigation boreholes drilled in shelter of access tunnel. The fault was also detected by borehole survey and the location was coincided with the result of TSP survey. Depending on the result of TSP survey and core logging, the design such as cavern layout and length was changed. Another TSP survey was performed in Incheon LPG storage cavern which is located below sea. Because of poor geological information at pre-investigation stage and suffering from heavy leakage of groundwater, the TSP survey to detect fracture zone was carried out. The support and grouting design was reflected by the result of TSP survey.

• Tunnel and Underground Space
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• v.19 no.2
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• pp.77-85
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• 2009

Flexible and lined segment air-tight tunnelling technology for Compressed Air Energy Storage-Gas Turbine(CAES-G/T) power generation was introduced. The distinguished characteristics of the air-tight tunnel system can be summarized by two facts. One is that the high inner pressure due to compressed air is sustained by surrounding rock mass with allowing sufficient displacement of lining segment. The other is that the air-tightness of storage tunnel was enhanced by adopting a specially designed rubber sheet. The flexible lined air-tight underground tunnel can be constructed at a comparatively shallow depth and near urban area so that the locally distributed CAES-G/T power generation can be accomplished. In addition, this air-tight tunnelling technology can be applied to a variety of energy underground storage tunnels such as Compressed Natural Gas(CNG), Liquifed Petroleum Gas(LPG), DeMethyl Ether(DME) etc.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1998.11a
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• pp.76-80
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• 1998

In order to identify the cause of ground water drawdown of a piezometer installed around the LPG storage cavern, parameter estimations were conducted by inverse and forward numerical models. An inverse model, SK-EST developed by SK Engineering & Construction Co., Ltd.(SKEC,1997) was performed to estimate the change of the hydraulic conductivity. It was verified by the commercial forward model, AQUA3D (VATNASKIL,1995). The simulation results showed that the hydraulic diffusivity of the rock mass between the piezometer and the cavern had been increased and the change rate of the hydraulic head had been abruptly increased in response to the change of the operation pressure. Finally the statistical analysis for observed data showed the increase of the change rate of the hydraulic head and thus proved the applicability of SK-EST.

• 한국가스학회:학술대회논문집
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• 1998.09a
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• pp.217-222
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• 1998

• 한국석유지질학회:학술대회논문집
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• autumn
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• pp.11-11
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• 2000

• 한국석유지질학회:학술대회논문집
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• autumn
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• pp.12-12
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• 2000

• Tunnel and Underground Space
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• v.8 no.2
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• pp.79-86
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• 1998

This study was performed to suggest to suggest suitable design conditions of water curtain system through analysis on pressure down in boreholes by hydraulic tests carried out I construction fields for underground oil storages. The influence by hydraulic conductivities of rock mass around boreholes on pressure down in boreholes was analysed. The relationship between array of boreholes and their pressure down was also analysed. Groundwater flow analysis on crude oil and LPG storages was carried out to evaluate results of field tests and to investigate distribution of hydraulic gradient in rock mass around cavern using finite difference method. As the results, hydraulic tests showed that pressure down in boreholes was inverse proportional to the hydraulic conductivity of surrounding rock mass. The rate of pressure down of boreholes was not influenced by water curtain system more than 20m over cavern and was proportional to installation interval of boreholes. The hydraulic gradient in rock mass around cavern was proportional to distance and interval of boreholes and its value was not satisfactory to oil tightness condition in case of no water curtain system.