• Title/Summary/Keyword: ultraviolet curing

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Nondestructive Interfacial Evaluation and Cure Monitoring of Carbon Fiber/Epoxyacrylate Composite with UV and Thermal Curing Using Electro-Micromechanical Technique (Electro-Micromechanical 시험법을 이용한 탄소 섬유 강화 에폭시아크릴레이트 복합재료의 자외선과 열경화에 따른 경화 모니터링 및 비파괴적 계면 평가)

  • 박종만;공진우;김대식;이재락
    • Polymer(Korea)
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    • v.27 no.3
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    • pp.189-194
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    • 2003
  • Interfacial evaluation, damage sensing and cure monitoring of single carbon fiber/thermo setting composite with different curing processes were investigated using electro-micromechanical test. After curing, the residual stress was monitored by measurement of electrical resistance and then compared to various curing processes. In thermal curing case, matrix tensile strength, modulus and interfacial shear strength were higher than those of ultraviolet curing case. The shrinkage measured during thermal curing occurred significantly by matrix shrinkage and residual stress due to the difference in thermal expansion coefficient. The apparent modulus measured in the thermal curing indicated that mechanical and interfacial properties were highly improved. The reaching time to the same stress of thermal curing was faster than that of UV curing case.

Nondestructive Damage Sensing and Cure Monitoring of Carbon Fiber/Epoxyacrylate Composite with UV and Thermal Curing using Electro-Micromechanical Technique (Electro-Micromechanical 시험법을 이용한 탄소섬유 강화 Epoxyacrylate 복합재료의 UV 및 열경화에 따른 비파괴적 손상 감지능 및 경화 Monitoring)

  • Kong, Jin-Woo;Kim, Dae-Sik;Park, Joung-Man;Lee, Jae-Rock
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.261-264
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    • 2002
  • Interfacial evaluation, damage sensing and cure monitoring of single carbon fiber/thermosetting composite with different curing processes was investigated using electro-micromechanical test. After curing, residual stress was monitored by measurement of electrical resistance (ER) and then it was compared to correlate with various curing processes. In thermal curing, curing shrinkage appeared significantly by matrix shrinkage and residual stress due to the difference in thermal expansion coefficient (TEC). The change in electrical resistance (ΔR) on thermal curing was higher than that on ultraviolet (UV) curing. For thermal curing, apparent modulus was the highest and reaching time until same strain was faster. So far thermal curing shows strong durability on the IFSS after boiling test.

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Preparation of UV protective cotton fabrics by novel UV-curing technique - Using a photocrosslinkable polymer, poly(ethylene glycol) dimethacylate -

  • Kim, Sin-Hee
    • Journal of Fashion Business
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    • v.11 no.6
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    • pp.52-61
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    • 2007
  • To increase the ultraviolet radiation (UVR) protection of cotton fabric, ultraviolet protection (UVP) materials were treated onto cotton fabric using a new technique, UV-curing. A photocrosslinkablepolymer, poly(ethylene glycol) dimethacrylate was used as a UV-curable resin in the presence of a small amount of photoinitiator. Two kinds of UVP materials were used, UV-absorber, 2,2'-dihydroxy-4-methoxy benzophenone, and UV-scatterer, $TiO_2/ZnO$ Pad-dry-cure method in employing these materials onto cotton was also conducted to compare the effectiveness and the washfastness of UVP treatment between curing methods. UVP treated cotton fabric showed a moderate increase in UVP in case of 2,2'-dihydroxy-4-methoxy benzophenone treatment and a high increase in case of $TiO_2/ZnO$. UV-curing method increased the washfastness of UVP property of $TiO_2/ZnO$ treated cotton fabrics. However, in case of 2,2'-dihydroxy-4-methoxy benzophenone, similar wash fastnesses of UV-cured and pad-dry-cured cotton were observed. It can be presumed that 2,2'-dihydroxy-4-methoxy benzophenone was not significantly affected by water since its hydrophobicity. In short, UV-curing of UVP materials onto cotton was successfully done, and treated cotton fabrics showed the increased UVP properties and an increased washfastness in some extent.

Electron Beam Curing of Hard Coating Resin for In-mold Decoration Foils (In-mold Decoration 포일에 사용되는 경질 코팅 수지의 전자빔 경화)

  • Sim, Hyun-Seog;Yun, Deok-Woo;Kim, Geon-Seok;Lee, Kwang-Hee;Lee, Byung-Cheol
    • Polymer(Korea)
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    • v.35 no.2
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    • pp.141-145
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    • 2011
  • The electron beam (EB) induced curing of a typical resin designed for the hard coating layer of in-mold decoration foils was investigated. The samples were irradiated with different doses of EB and the curing reaction was monitored by Fourier transform infrared (FTIR) spectroscopy. The change in coating properties such as surface hardness and anti-abrasion property was studied as a function of increasing dose. The effect of the addition of nano-particles on the improvement of coating properties was also examined. It was expected that the experimental results could be used for the commercial exploitation of the EB curing system comparable to the ultraviolet (UV) curing system.

Gamma radiation shielding properties of poly (methyl methacrylate) / Bi2O3 composites

  • Cao, Da;Yang, Ge;Bourham, Mohamed;Moneghan, Dan
    • Nuclear Engineering and Technology
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    • v.52 no.11
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    • pp.2613-2619
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    • 2020
  • This work investigated the gamma-ray shielding performance, and the physical and mechanical properties of poly (methyl methacrylate) (PMMA) composites embedded with 0-44.0 wt% bismuth trioxide (Bi2O3) fabricated by the fast ultraviolet (UV) curing method. The results showed that the addition of Bi2O3 had significantly improved the gamma shielding ability of PMMA composites. Mass attenuation coefficient and half-value layer were examined using five gamma sources (Cs-137, Ba-133, Cd-109, Co-57, and Co-60). The high loading of Bi2O3 in the PMMA samples improved the micro-hardness to nearly seven times that of the pure PMMA. With these enhancements, it was demonstrated that PMMA/Bi2O3 composites are promising gamma shielding materials. Furthermore, the fast UV curing exerts its great potential in significantly shortening the production cycle of shielding material to enable rapid manufacturing.

Comparison of polymerization by time of light curing for dental 3D printing (치과 3D 프린팅용 광중합 시간에 따른 중합도 비교)

  • Kim, Dong-Yeon;Lee, Gwang-Young
    • Journal of Technologic Dentistry
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    • v.44 no.3
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    • pp.76-80
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    • 2022
  • Purpose: The purpose of this study is to analyze the depth according to curing using photocurable resin for dental three-dimensional printing. Methods: A stainless mold with a height of 4 mm was prepared. Ultraviolet (UV) polymerization resin was injected into the mold. Photocuring was then performed for 5 minutes using a photopolymerizer, and the height was measured using a digital measuring instrument (first group). Second, light polymerization was also performed outside the mold for 5 minutes, and the height was measured using a digital measuring instrument. Third, light polymerization was further performed for 5 minutes, and the height was measured using a digital measuring instrument. Statistical analysis was performed with the Kruskal-Wallis test, which is a nonparametric test (α=0.05). Results: The third group had the largest measurement length, whereas the first group had the smallest. However, the difference between groups was not statistically significant (p>0.05). The color of the first group was different from that of the second and third groups. Conclusion: All of the 4-mm-thick photocured specimens had a curing reaction, but the part that was not directly irradiated with UV did not show its original color.

The Effect of EVA Sheet Gel Content Depending on Curing Condition for Photovoltaic Module (PV모듈용 EVA Sheet의 Curing조건에 따른 Gel Content 특성)

  • Kang, Gi-Hwan;Kim, Kyung-Soo;Park, Kyung-Eun;Kim, Hyun-Il;Yu, Kwon-Jong
    • Proceedings of the KIEE Conference
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    • 2006.07b
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    • pp.1155-1156
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    • 2006
  • In this paper, we analyzed the effect of EVA Sheet Gel Content depending on curing condition for photovoltaic module. Gel Content was measured by manufacturing Glass/EVA Sheet/Back Sheet scheme at several curing temperature and curing time. And the surface analysis of EVA Sheet depending on process condition could be observed using SEM(Scanning Electron Microscope). Through this experiment, we could confirm that there are differences on Gel Content of EVA Sheet and surface configuration depending on curing temperature and curing time. To find out the optical characteristic dependency on curing condition, Class/EVA Sheet/Glass scheme was fabricated. The optical transmittance of EVA Sheet at visible wavelength was enhanced 5% when compared to Glass/Glass scheme. And the transmittance of $130^{\circ}C$/4min, $110^{\circ}C$/4min, $160^{\circ}C$/6min process condition was higher at ultraviolet wavelength range. These curing conditions could be regarded as the best process for suppression the discoloration speed of EVA Sheet under UV light.

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A Study on Ulraviolet-cut Ability of Silk Fabric Dyed with Natural Dyestuffs (천연염재의 자외선 차단성능 연구)

  • 김월순;최인려
    • The Research Journal of the Costume Culture
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    • v.12 no.1
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    • pp.1-11
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    • 2004
  • This study was carried out on the process of natural dye substances which can flock ultraviolet rays without producing harmful substances by pollution, germs, etc. While making human body safe in contact, extracting Gardenia, Sappan wood, Radix scutellariae, Cromwell, Mugwort, Gallnut, Lac. Those are used for curing diseases, dyeing silk cloth with those extracts, and examining the color fastness, Ultraviolet protection. From this study, the following conclusion was produced. Brightness was lower in pre-mordanting than in post. And color difference showed that Radix scutellariae was the highest. Aluminum-mordanting showed a higher color difference than Fe. Colorfastness to washing was high in all samples, and the degree of color-changing by washing was the highest in the sample dyed by gardenia, pre-mordanted gallnut showed the highest degree. Colorfastness to perspiration was the highest in gardenia. UV-A test showed that all samples a high rate of 85% or higher compared with test white cloth. Especially, post-mordanted radix scutellariae, pre-mordanted gallnut and post-mordanted sappanwood showed a superior blocking rate.

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Comparative analysis of strain according to two wavelengths of light source and constant temperature bath deposition in ultraviolet-curing resin for dental three-dimensional printing (치과 3D 프린팅용 자외선 경화 레진에 광원의 두 가지 파장에 따른 경화 및 항온수조 침적에 따른 변형률의 비교 분석)

  • Kim, Dong-Yeon;Lee, Gwang-Young;Kang, Hoo-Won;Yang, Cheon-Seung
    • Journal of Technologic Dentistry
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    • v.42 no.3
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    • pp.208-212
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    • 2020
  • Purpose: This study aimed to analyze the shrinkage and expansion strain of ultraviolet (UV)-cured resin according to the wavelength of the light source and compare the shrinkage and expansion. Methods: We prepared the mold with according to the ISO 4049 specimen. The size of the circle in the mold was prepared with a height of 6.02 mm and a diameter of 4 mm. UV-curable resin for three-dimensional (3D) printing was injected into the circular mold. The control group was irradiated with a wavelength of 400~405 nm using UV-curing equipment (400 group), and the experimental group was irradiated with a wavelength of 460~465 nm (460 group). Both groups were produced ten specimens. The produced specimen was first measured with a digital micrometer. After the first measurement, the specimen was immersed in a constant temperature water bath for 15 days, after which the second measurement was performed, and the third measurement was taken after 30 days. The measured values were analyzed using the independent sample t-test (α=0.05). Results: In the non-immersion water tank, the contraction was 0.9% in the 400 group and 1.3% in the 460 group. In the constant temperature bath, the expansion was high at -0.4% in the 400 group for 15 days, and the smallest expansion was -0.03% for the 400 group for 30 days. There were significant differences between the two groups (p<0.05). Conclusion: The 400 group had a lower UV resin specimen strain than the 460 group. Therefore, it is recommended to use the wavelength required by the UV-curing resin.