• Title/Summary/Keyword: ultrasound synthesis

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Ultrasonic Synthesis of Silica Powder Using Emulsion Method (에멀젼법을 이용한 실리카 분말의 초음파 합성)

  • Lee, S.G.;Kim, H.S.;Kang, B.S.;Seo, G.S.;Park, S.S.;Park, H.C.
    • Korean Journal of Materials Research
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    • v.16 no.6
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    • pp.355-359
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    • 2006
  • Fine silica powders were synthesized via w/o emulsion method using sodium silicate, ammonium sulfate, Triton N-57, and cyclohexane as silica source, precipitating agent, surfactant, and oil phase, respectively. The powders were prepared under a conventional process and an ultrasonic process using the same reactants at room temperature for 1 hr varying the concentration of $Na_2SiO_3$ solution and the mol ratio of $H_2O$/surfactant, respectively. The particle size of the silica powder was reduced with decreasing the concentration of sodium silicate solution and with increasing the mol ratio of $H_2O$/surfactant under with and without ultrasounds. The size of powder with ultrasounds was smaller than that without ultrasounds, which indicates that the application of ultrasound in the synthesis of silica powder is an efficient way to reduce particle size.

Development of Tissue mimicking ultrasound phantom materials (Tissue mimicking 초음파 팬텀물질의 개발에 관한 연구)

  • Ma, Sang-Chull;Kong, Young-Kun;Park, Ki-Jung;Lee, Suk
    • Journal of radiological science and technology
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    • v.26 no.1
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    • pp.51-62
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    • 2003
  • We carried out studies on develop of the ultrasound tissue mimicking materials(TMM) by synthesis of polymer urethane(C, CCR, $TiO_2$, tungsten, graphite, silver type). The major finding were as follows; (1) C type TMM was shown good homogeneity, penetration, gray scale like as liver tissue and propagated speed 1,540 m/s, attenuation $0.5{\sim}0.7\;dB/cm/MHz$. (2) $TiO_2$ type TMM was shown heterogeneous dot echo pattern. (3) Silver type TMM was appear good homogeneous echo pattern like as echo texture of thyroid gland. Therefor, C type TMM will be useful for ultrasound Q/A phantom materials and previous phantom materials.

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Low-Intensity Pulsed Ultrasound Promotes BMP9 Induced Osteoblastic Differentiation in Rat Dedifferentiated Fat Cells

  • Fumiaki Setoguchi;Kotaro Sena;Kazuyuki Noguchi
    • International Journal of Stem Cells
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    • v.16 no.4
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    • pp.406-414
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    • 2023
  • Dedifferentiated fat cells (DFATs) isolated from mature adipocytes have a multilineage differentiation capacity similar to mesenchymal stem cells and are considered as promising source of cells for tissue engineering. Bone morphogenetic protein 9 (BMP9) and low-intensity pulsed ultrasound (LIPUS) have been reported to stimulate bone formation both in vitro and in vivo. However, the combined effect of BMP9 and LIPUS on osteoblastic differentiation of DFATs has not been studied. After preparing DFATs from mature adipose tissue from rats, DFATs were treated with different doses of BMP9 and/or LIPUS. The effects on osteoblastic differentiation were assessed by changes in alkaline phosphatase (ALP) activity, mineralization/calcium deposition, and expression of bone related genes; Runx2, osterix, osteopontin. No significant differences for ALP activity, mineralization deposition, as well as expression for bone related genes were observed by LIPUS treatment alone while treatment with BMP9 induced osteoblastic differentiation of DFATs in a dose dependent manner. Further, co-treatment with BMP9 and LIPUS significantly increased osteoblastic differentiation of DFATs compared to those treated with BMP9 alone. In addition, upregulation for BMP9-receptor genes was observed by LIPUS treatment. Indomethacin, an inhibitor of prostaglandin synthesis, significantly inhibited the synergistic effect of BMP9 and LIPUS co-stimulation on osteoblastic differentiation of DFATs. LIPUS promotes BMP9 induced osteoblastic differentiation of DFATs in vitro and prostaglandins may be involved in this mechanism.

Sulphamic Acid: an Efficient Catalyst for the Synthesis of α-HydroxyPhosphonates Using Ultrasound Irradiation (술팜산: 초음파 조사를 이용한 α-히드록시 인산염 합성의 효과적인 촉매)

  • Sadaphal, Sandip A.;Sonar, Swapnil S.;Pokalwar, Rajkumar U.;Shitole, Nanasaheb V.;Shingare, Murlidhar S.
    • Journal of the Korean Chemical Society
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    • v.53 no.5
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    • pp.536-541
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    • 2009
  • Sulphamic acid has been exploited as a cost-effective catalyst and green alternative for conventional acidic materials to synthesize $\alpha$-hydroxy phosphonates under solvent-free condition. The reaction carried out using ultrasound irradiation with better yields and shorter reaction time.

The Effect of Low Intensity Ultrasound on Osteoblast Activation (저강도 초음파가 조골세포 활성에 미치는 영향)

  • 홍성민;한승무;한은옥;임사비나;김창주
    • Journal of Biomedical Engineering Research
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    • v.25 no.3
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    • pp.201-206
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    • 2004
  • The bone formation and re-formation are regulated by two factors that are the synthesis of bone matrix by osteoblast and reabsorption by osteoclast. Recently, there are many studies about regeneration and healing of bone tissue by activation of osteoblast. In general, it is known that the activation of osteoblast is influenced by not only biological stimulus but physical stimulus. In this study, we verified that ostoeblast activation was influenced by low intensity ultrasound. Various ultrasonic properties were used to find out the most appropriate condition on cell activation. From this study, we could confirm that 0.3W/$\textrm{cm}^2$ intensity of ultrasound was the most appropriate to tell activation over whole duty cycles and the increasing rate of tell was the highest at 50% duty cycle. Thus, it is expected that optimal ultrasonic characteristics on regeneration of bone matrix may be applied to fracture and osteoporosis healing.

Long Chain Dicationic Phase Transfer Catalysts in the Condensation Reactions of Aromatic Aldehydes in Water Under Ultrasonic Effect

  • Esen, Ilker;Yolacan, Cigdem;Aydogan, Feray
    • Bulletin of the Korean Chemical Society
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    • v.31 no.8
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    • pp.2289-2292
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    • 2010
  • Long chain dicationic ammonium salts were used successfully as phase transfer catalyst in the condensation reactions of aromatic aldehydes in water under ultrasonic irradiation for the first time. The quaternary salt having longer distance between the cation centers was more effective than the mono- and dicationic ones having short chain.

An Improved Procedure for the Synthesis of 1,5-Benzothiazepines Using Ceric Ammonium Nitrate (CAN)

  • Chate, Asha V.;Joshi, Ratnadeep S.;Mandhane, Priyanka G.;Gill, Charansingh H.
    • Journal of the Korean Chemical Society
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    • v.55 no.5
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    • pp.776-780
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    • 2011
  • A mild and efficient procedure for the synthesis of various 1,5-benzothiazepines were developed. This method provides an easy access for preparation of 1,5-benzothiazepine derivatives in the presence of 10 mol% catalyst of CAN under ultrasonic irradiation. This method provided clean conversion, mild reaction condition, no use of toxic solvent and shorter reaction time compared to other reported method.

Properties of recycled steel fibre reinforced expanded perlite based geopolymer mortars

  • Celikten, Serhat
    • Advances in concrete construction
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    • v.13 no.1
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    • pp.25-34
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    • 2022
  • The production of geopolymer is considered as a cleaner process due to much lower CO2 emission than that from the production of Portland cement. This paper presents a study of the potential use of recycled steel fibre (RSF) coming from the recycling process of the old tires in geopolymer mortars. Ground expanded perlite (EP) is used as a source of alumino-silicate and sodium hydroxide (NaOH=5, 10, 15, and 20M) is used as alkaline medium for geopolymer synthesis. RSFs were added to the mortar mixtures in four different volume fractions (0, 0.5, 1.0, and 1.5% of the total volume of mortar). The unit weight, ultrasound pulse velocity, flexural and compressive strength of expanded perlite based geopolymer mortar (EPGM) mixtures were determined. The microstructures of selected EPGMs were examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) analyses. The optimum molarity of sodium hydroxide solution was found to be 15M for geopolymer synthesis by EP. The test results revealed that RSFs can be successfully used for fibre-reinforced geopolymer production.