• 제목/요약/키워드: ultrasound sonication

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토양 중금속의 초음파 연속추출 (Sequential Extraction of Soil Heavy Metals Aided by Ultrasound Sonication)

  • 서지원;윤혜온
    • 한국광물학회지
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    • 제23권1호
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    • pp.85-91
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    • 2010
  • NIST 표준시료인 SRM 2710(Montana Soil)을 대상으로, 중금속의 지화학적 존재형태 연구에 일반적으로 적용되는 Tessier 연속추출법과 최근 소개된 초음파연속추출법을 적용 및 비교하여 오염 토양 내 중금속의 효율적 분석방법을 제시하고자 하였다. As, Cd, Cu, Pb, Zn의 총함량을 USEPA Method 3050B, KBSI Method, 초음파 추출법을 적용하여 분석한 결과, 모두 공인 분석값에 가까운 값으로 측정되었다. Tessier 연속추출법과 초음파 연속추출법의 비교 결과, 원소별 및 단계별 추출 양상과 추출효율이 두 방법 모두 거의 동일한 것으로 나타났다. 초음파 연속추출에는 총 3시간 정도 소요되었으며, 기존의 Tessier 연속추출법의 12시간 정도와 비교할 때 크게 단축되었다. 유기오염 시료의 전처리법으로 흔히 사용되는 초음파 추출법은 비교적 짧은 시간 내 추출이 이루어지고, 고온의 가열이 필요치 않으며, 시료에 직접 강한 파장을 주어 추출하기 때문에 비교적 높은 추출효율을 보이는 효과적인 방법이라 할 수 있다.

필터재 투과성 효율 증대를 위한 초음파의 활용 (Effect of Sonication on Permeability of Filter Paper)

  • 오세헌;황명기;김형수;김영욱
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2003년도 봄 학술발표회 논문집
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    • pp.647-654
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    • 2003
  • This study investigated the effect of ultrasound on the permeability of the filter paper The investigation involves laboratory experiments, and the laboratory tests were conducted under abroad range of conditions Including energy levels of ultrasonic waves, time for treatment, and temperature. The results of the study show that sonication enhances the permeability of the filter paper significantly. The degree of enhancement varies with sonication power and duration of application. The effect of sonication on permeability with temperature variation and concentration of the test specimens seems not to be significant.

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투수계수에 미치는 초음파의 영향 (Effect of Ultrasound on Permeability)

  • 목진만;김영욱;김지형
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2003년도 봄 학술발표회 논문집
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    • pp.613-620
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    • 2003
  • This study investigated the effect of ultrasound on the permeability of the granular soil. The investigation laboratory experiments, and laboratory tests were conducted under a broad range of conditions including energy levels of ultrasonic waves, time for the treatment, and type of the soil. The results of the study show that sonication enhances the permeability of the soil specimens significantly. The degree of varies with sonication power and duration of application, and type of soil.

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혐기성 소화 효율 향상을 위한 초음파 주파수의 순차적 적용에 대한 연구 (A Study on Sequential-Frequency Sonication for Improving Anaerobic Digestion)

  • 황규대;박성한
    • 상하수도학회지
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    • 제25권6호
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    • pp.893-906
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    • 2011
  • The effect of ultrasound pretreatment on sludge degragability was investigated at different condotions: ultrasonic frequency(28, 40, 50kHz), intensity(10, 25, 50W), sonication time(10, 20, 30, 60min). Total suspended solid(TSS) and soluble chemical oxygen demand(SCOD) concentration were measured for the evaluation of pretreatment efficiency. The pretreated sludge was used as the feedstock for anaerobic digestion process. Biogas production and volatile suspended solid(VSS) removal were determined for evaluating the process performance. 1. TSS concentration of the sludge decreased at a constant rate as sonication operation was applied. The degradation rate of TSS increased when ultrasound frequency was decreased from 50kHz to 28kHz and intensity was increased from 10W to 50W. Efficiency of TSS degradation per input energy increased as ultrasonic frequency and intensity were decreased. At the frequency of 28 and 40kHz, SCOD concentration rapidly increased during the initial 30min of sonication time, and then it gradually increased. At 50kHz, SCOD concentration constantly increased for 60min of the sonication time. The SCOD production rate increased with increasing intensity under all ultrasound frequencies. 2. The optimum condition of ultrasound treatment was 28kHz, 50W and 60min for maximizing the biogas production, methane fraction, VSS removal. The highest values in biogas production, methane fraction in biogas, VSS removal were 370ml, 70%, 2.45g, respectively. Methane production rate per input energy increased at ultrasonic frequency and intensity decreased. 3. When raw sludge was pretreated at the condition of ultrasonic frequency of 28 and 40kHz in series, sequential-frequency sonication, intensity of 50W and 60min, biogas production, methane fraction, VSS removal were about the same that of 28kHz single-frequency sonication. When sequential-frequency sonication of 28 and 50kHz was applied in series, biogas production, methane fraction, VSS removal were 356 ~ 423ml, 69 ~ 71%, 2.41 ~ 2.78g, respectively. The pretreatment efficiency of 28-50kHz sequential-frequency sonication which sonication time of 28kHz and 50kHz was 40min and 20min was higher than that of 28kHz single-frequency sonication.

초미립자 탈수성 증대를 위한 초음파 활용에 관한 연구 (Ultrasonically Enhanced Dewaterability of Fine Particles)

  • 오철;김병일;김영욱
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2002년도 봄 학술발표회 논문집
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    • pp.313-320
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    • 2002
  • In accordance with the need of developing a methodology for the sludge reduction, this study investigates the effect of sonication on the dewaterability of the sewage sludge. The investigation involves laboratory experiments of the sewage sludge from Yongin Waste Treatment Plant. The Laboratory tests were conducted under a broad range of conditions including energy levels of ultrasonic waves, time for the treatment, pH, and effect of polymers. The results of the study show that sonication enhances the dewaterability significantly The degree of enhancement varies with sonication power, treatment time, the amount of sludge treated. The effect of sonication on the temperature and pH of the test specimens seems not to be significant. The polymer can be useful to enhance the effectiveness of ultrasound treatment.

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글리세롤 조직유사 팬텀을 이용한 초음파 중첩 조사에 따른 가열 특성 평가 (Heating Characteristics Evaluation of Superposed Sonication Using Glycerol Tissue Mimic Phantom)

  • 노시철;강상식;박지군;김주영;정봉재
    • 한국방사선학회논문지
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    • 제9권7호
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    • pp.523-528
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    • 2015
  • 본 연구에서는 단일 초음파 조사와 두 개의 저강도 초음파의 중첩 조사 시 발생하는 가열 특성을 평가하였다. 비교결과 단일 조사 조건보다 중첩 조사에서 보다 우수한 온열 효과를 보였으며 최대 상승 온도도 120-150% 증가하는 것을 확인할 수 있었다. 초음파 조사에 의한 가열 개시 시간이 중첩 조사에서 짧아지며, 최대 가열 온도까지 소요되는 시간 역시 짧아짐을 확인할 수 있었다. 초음파 조사 강도가 커지면 매질의 표면 손상을 유발하는데, 저강도 중첩조사의 경우 표면의 손상없이 동일한 온도 상승 효과를 확인할 수 있었다. 본 연구의 결과를 통하여 초음파 치료 시 적용 강도를 줄일 수 있을 것으로 생각되었으며, 저강도 초음파를 사용함으로써 보다 안전하고 효율적인 초음파 치료가 가능할 것으로 판단된다.

디이젤 오염토 수세시 초음파가 세척률 증가에 미치는 영향에 관한 연구 (Enhancement of Soil Flushing Method by Ultrasonic Radiation on Diesel Contaminated Soils)

  • 김영욱;김지형;이인모
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 2000년도 가을 학술발표회 논문집
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    • pp.401-406
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    • 2000
  • Spilling of petroleum hydrocarbons such as gasoline, motor oils, and diesel fuel from underground storage tanks (USTs) is a major source of contamination to ground water and soils. In response to the need of developing an effective and economical cleanup technique, this study investigates the effectiveness of using sonication to enhance the soil flushing method. The study involves laboratory testing, and the testing was conducted using a specially designed and fabricated device to determine the effect of sonication on contaminant removal. The sonication was applied at 20 kHz frequency under different power levels. Test soil was Joomoonjin Sand, and diesel fuel was used as a contaminant of soil flushing test. The results of the investigation show that sonication enhanced the contaminant removal from soils significantly, and the degree of enhancement varied with power levels of sonication. Based on the results of the study, it is concluded that the flushing method with sonication has a great potential to become an effective method for removing petroleum hydrocarbons from the contaminated ground.

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Characteristics of deodorization for malodorants in aqueous solution by sonication

  • Yoo, Young-Eok;Maeda, Yasuaki
    • 한국환경과학회지
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    • 제13권2호
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    • pp.167-173
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    • 2004
  • A aqueous solution of malodorants (i.e., n-valeraldehyde, n-valeric- acid, 2-methylisoborneol, and trimethylamine) was exposed to 200KHz ultrasound with a power of 6.0W/$\textrm{cm}^2$ per unit volume in a sonochemical reactor under room temperature and atmospheric pressure condition. The concentration of malodorants decreased with irradiation time, indicating pseudo-first-order kinetics. The removal efficiency of malodorants was about from 50% to 96% decomposed after 90 minutes sonication. At the deodorization, it was determined by triangle odor bag(TOB) method for odor sensory measurement, and it indicated that over 60% of relative odors were deodorized with degradation by the sonication.

Design of Ultra-sonication Pre-Treatment System for Microalgae CELL Wall Degradation

  • Yang, Seungyoun;Mariappan, Vinayagam;Won, Dong Chan;Ann, Myungsuk;Lee, Sung Hwa
    • International journal of advanced smart convergence
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    • 제5권2호
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    • pp.18-23
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    • 2016
  • Cell walls of microalgae consist of a polysaccharide and glycoprotein matrix providing the cells with a formidable defense against its environment. Anaerobic digestion (AD) of microalgae is primarily inhibited by the chemical composition of their cell walls containing biopolymers able to resist bacterial degradation. Adoption of pre-treatments such as thermal, thermal hydrolysis, ultrasound and enzymatic hydrolysis have the potential to remove these inhibitory compounds and enhance biogas yields by degrading the cell wall, and releasing the intracellular algogenic organic matter (AOM). This paper preproposal stage investigated the effect of different pre-treatments on microalgae cell wall, and their impact on the quantity of soluble biomass released in the media and thus on the digestion process yields. This Paper present optimum approach to degradation of the cell wall by ultra-sonication with practical design specification parameter for ultrasound based pretreatment system. As a result of this paper presents, a microalgae system in a wastewater treatment flowsheet for residual nutrient uptake can be justified by processing the waste biomass for energy recovery. As a conclusion on this result, Low energy harvesting technologies and pre-treatment of the algal biomass are required to improve the overall energy balance of this integrated system.