• Korean Journal of Materials Research
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• v.28 no.9
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• pp.516-521
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• 2018

Copper oxide thin films are deposited using an ultrasonic-assisted spray pyrolysis deposition (SPD) system. To investigate the effect of substrate temperature and incorporation of a chelating agent on the growth of copper oxide thin films, the structural and optical properites of the copper oxide thin films are analyzed by X-ray diffraction (XRD), field-emssion scanning electron microscopy (FE-SEM), and UV-Vis spectrophotometry. At a temperature of less than $350^{\circ}C$, three-dimensional structures consisting of cube-shaped $Cu_2O$ are formed, while spherical small particles of the CuO phase are formed at a temperature higher than $400^{\circ}C$ due to a Volmer-Weber growth mode on the silicon substrate. As a chelating agent was added to the source solutions, two-dimensional $Cu_2O$ thin films are preferentially deposited at a temperature less than $300^{\circ}C$, and the CuO thin film is formed even at a temperature less than $350^{\circ}C$. Therefore the structure and crystalline phase of the copper oxide is shown to be controllable.

• Advances in concrete construction
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• v.11 no.2
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• pp.173-181
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• 2021

The main objective of this work is to contribute to the valorization of plastic and glass waste in the improvement of concrete properties. Waste glass after grinding was used as a partial replacement of the cement with a percentage of 15%. The plastic waste was cut and introduced as fibers with 1% by the total volume of the mixture. Mechanical and durability tests were conducted for various mixtures of concrete as compressive and flexural strengths, water absorption, ultrasonic pulse velocity, and acid attack. Also, other in-depth analyses were performed on samples of each variant such as X-ray diffraction (XRD), thermogravimetric analysis (DSC-TGA), and scanning electron microscope (SEM). The results show that the addition of glass powder or plastic fibers or a combination of both in concrete improved in the compression and flexural strengths in the long term. The highest compressive strength was obtained in the mix which combines the two wastes about 26.72% of increase compared to the control concrete. The flexural strength increased in the mixture containing the glass powder. Therefore, the mixture with two wastes exhibits better resistance to aggressive sulfuric acid attack, and incorporating glass powder improves the ultrasonic pulse velocity.

• Journal of the Microelectronics and Packaging Society
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• v.11 no.4 s.33
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• pp.55-59
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• 2004

We fabricates the $TiO_2$ thin film from anatase phase $TiO_2$ powder having good photocatalytic property using aerosol deposition method at room temperature. Aerosol deposition method, which sprays an aerosol powder with ultrasonic velocity and deposits a thin film on substrate at low temperature, has the advantages of low thermal stress and low cost. To fabricate the $TiO_2$ thin film, the aerosol bath pressure and chamber pressure were 500 torr and 0.4 torr, respectively. The difference of aerosol bath pressure and chamber pressure accelerated the $TiO_2$ nano powder to ultrasonic velocity through the nozzle of $0.4 mm{\times}10 mm$ and $TiO_2$ thin film was finally formed. SS mesh with diameter of 50 mm was used as a substrate to apply the $TiO_2$ thin film to water quality purification. The raw powder was dehydrated for the good dispersion of $TiO_2$ powder. To suppress the formation of second particle, the powder was dispersed for 90 min in alcohol bath by ultrasonic treatment and desiccated. The grain size of $1 {\mu}m$ was observed in $TiO_2$ thin film deposited on SUS mesh by scanning electron microscopy (SEM). The anatase phase of $TiO_2$ thin film was also observed by X-ray diffraction (XRD) and the anatase phase of raw powder was nicely maintained after aerosol deposition. The results are applicable to water treatment filter having photocatalytic reaction.

• Journal of the Korean Society for Nondestructive Testing
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• v.19 no.6
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• pp.420-425
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• 1999

Time of flight diffraction(TOFD) method is used in nondestructive tests of piping and pressure vessels because of its advantages over a pulse echo technique: its speed, objectivity, repeatability and its insensitivity to specimen surface conditions and discontinuity orientation. But it is the one of weak points in TOFD method that it has the dead zone in sub-surface resolution induced by lateral waves. We solved the dead-zone problem near the sub-surface by using the deconvolution method and the developed ultrasonic testing system showed high performance.

• Journal of the Korean Society for Nondestructive Testing
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• v.20 no.6
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• pp.538-544
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• 2000

A phased array ultrasonic nondestructive inspection system is being developed to obtain images of the interior of steel structures by modifying a medical ultrasound imaging system. The medical system consists of 64 individual transceiver channels that can drive 128 array elements. Several modifications of the system were required mainly due to the change of sound speed. It was necessary to fabricate array transducers for steel structure and to obtain A-scan signal that is necessary for the nondestructive testing. Boundary diffraction wave model was used for the prediction of radiation beam field from array transducers, which provided guidelines to design array transducers. And a RF data acquisition board was fabricated for the A-scan signal acquisition along a selected un line within an image. For the proper beam forming in the transmission and reception for steel structure, delay time was controlled. To demonstrate the performance of the developed system and fabricated transducers, images of artificial specimens and A-scan signals for selected scan lines were obtained in a real time fashion.

• Korean Journal of Materials Research
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• v.25 no.3
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• pp.125-131
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• 2015

Fluorine-doped $SnO_2$ (FTO) thin film/Ag nanowire (NW) double layers were fabricated by means of spin coating and ultrasonic spray pyrolysis. To investigate the optimum thickness of the FTO thin films when used as protection layer for Ag NWs, the deposition time of the ultrasonic spray pyrolysis process was varied at 0, 1, 3, 5, or 10 min. The structural, chemical, morphological, electrical, and optical properties of the double layers were examined using X-ray diffraction, X-ray photoelectron spectroscopy, field-emission scanning electron microscopy, transmission electron microscopy, the Hall effect measurement system, and UV-Vis spectrophotometry. Although pure Ag NWs formed isolated droplet-shaped Ag particles at an annealing temperature of $300^{\circ}C$, Ag NWs covered by FTO thin films maintained their high-aspect-ratio morphology. As the deposition time of the FTO thin films increased, the electrical and optical properties of the double layers degraded gradually. Therefore, the double layer fabricated with FTO thin films deposited for 1 min exhibited superb sheet resistance (${\sim}14.9{\Omega}/{\Box}$), high optical transmittance (~88.6 %), the best FOM (${\sim}19.9{\times}10^{-3}{\Omega}^{-1}$), and excellent thermal stability at an annealing temperature of $300^{\circ}C$ owing to the good morphology maintenance of the Ag NWs covered by FTO thin films.

• Journal of Powder Materials
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• v.26 no.1
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• pp.34-39
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• 2019

Current synthesis processes for titanium dioxide ($TiO_2$) nanoparticles require expensive precursors or templates as well as complex steps and long reaction times. In addition, these processes produce highly agglomerated nanoparticles. In this study, we demonstrate a simple and continuous approach to synthesize $TiO_2$ nanoparticles by a salt-assisted ultrasonic spray pyrolysis method. We also investigate the effect of salt content in a precursor solution on the morphology and size of synthesized products. The synthesized $TiO_2$ nanoparticles are systematically characterized by X-ray diffraction, transmission electron micrograph, and UV-Vis spectroscopy. These nanoparticles appear to have a single anatase phase and a uniform particle-size distribution with an average particle size of approximately 10 nm. By extrapolating the plots of the transformed Kubelka-Munk function versus the absorbed light energy, we determine that the energy band gap of the synthesized $TiO_2$ nanoparticles is 3.25 eV.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.127.2-127.2
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• 2011

본 연구에서는 RF Magnetron Sputtering System을 이용하여 ZnO계 투명전도막 증착시 Vaporization된 MeOH를 유입함으로써 박막증착과 동시에 표면의 Roughness를 제어하여 이에따른 전기적 특성 및 광학적 특성의 개선에 대하여 연구하였다. 실험방법으로 기존의 RF Magnetron Sputtering System에 Vaporization이 가능한 Ultrasonic을 이용하여 MeOH를 Vaporized시켜 MFC Controll을 통해 챔버에 유입하여 ZnO계 투명전도막의 박막증착과 동시에 표면 Texturing을 하였다. ZnO계 투명전도막의 박막증착시 Vaporized MeOH의 유입에 따른 광학적 특성변화를 UV-visible-nIR spectrometry로 조사하였으며, 전기적 특성 변화를 4-Point-Probe로 조사하였으며, 표면적 특성 변화를 Atomic Force Microscope(AFM), Scanning Electron Microscopy(SEM)를 조사하였으며, 박막의 결정성장특성 변화를 X-ray Diffraction(XRD)으로 조사하였으며, Vaporized MeOH 유입에 따른 박막의 성분분석을 Secondary Ion Mass Spectrometry (SIMS)로 조사함으로써 최적의 조건 및 공정을 확립하였다.

• Transactions of the Korean Society of Automotive Engineers
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• v.7 no.6
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• pp.258-269
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• 1999

It is important to evaluate fatigue damage of in-service material in respect to assure safety and remaining fatigue life in structure and mechanical components under cyclic load . Fatigue damage is represented by mathematical modelling with crack growth rate da/dN and cycle ration N/Nf and is detected by X-ray diffraction and ultrasonic wave method etc. But this is estimated generally by single parameter but influenced by many test conditions The characteristics of it indicates fatigue damage has complex fracture mechanism. Therefore, in this study we propose that back-propagation neural networks on the basis of ration of X-ray half-value breath B/Bo, fractal dimension Df and fracture mechanical parameters can construct artificial intelligent networks estimating crack growth rate da/dN and cycle ratio N/Nf without regard to stress amplitude Δ $\sigma$.

• Journal of the Korean Society for Nondestructive Testing
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• v.19 no.6
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• pp.448-453
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• 1999

원전의 열성층 현상으로 발생하는 열 피로균열 및 입계응력부식균열(IGSCC) 등은 결함에 대해서 검사자의 특별한 관심과 노력 없이는 초음파를 이용해 이러한 종류의 결함검출 및 크기 측정이 쉽지 않다. 이러한 결함의 검출 및 크기 측정을 위해서 먼저 초음파 모드 변환 기법을 사용하여 결함 검출 및 결함 크기를 분류한 후에 결함 끝단에서의 초음파 회절파(tip diffraction)를 이용한 여러 가지의 초음파 기법 둥으로 정확한 결함 크기를 측정하여 가동전 중점검시 발견된 결함의 추적 관리 및 결함평가신뢰도 향상에 기여하고자 한다. 따라서, 여기서는 열 피로균열 및 입계응력부식균열 등과 같은 결함의 정확한 검출 및 크기 측정을 위해 초음파 모드 변환 기법의 특성을 철저히 이해하고 이에 관련된 초음파 신호들을 정확히 구분할 수 있는 방법을 기술하였다.