• Title/Summary/Keyword: ultrafine particles

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A Characteristic Study of the Aerosol Size Distribution in Pohang Province (포항 지역 대기에서 측정된 에어로졸 입자분포 특성 연구)

  • Seo, Moon Hyeok;Chang, Hyuk Sang
    • Particle and aerosol research
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    • v.8 no.4
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    • pp.151-160
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    • 2012
  • Health effects caused by the ultrafine particles in ambient air are great concern to the public health, and the strict measuring and monitoring of the ambient aerosol are required. In this work, the characteristics of the aerosol size distribution in Pohang province are studied. Optical particle counters (Grimm APS 1108 and 1109) were used to measure the aerosol size distribution in the area. Locations near the national monitoring site located in the industrial and the residence area were selected for the measuring sites of this study, and the locations in border area between the industry and the residence were selected for the reference of the comparison. In the industry site, it is found that the concentration of aerosol particles near the size of 5 ${\mu}m$ appear characteristically and the fluctuations in concentration with respect to time are minimal. The mass concentration of the aerosol above 10 ${\mu}m$ in diameter in the industry area was found to fluctuate significantly. The mass portion of $PM_{10}$ and PM2.5 to TSP in the residence area were 83% and 51% respectively. In the industrial regional, it was found that the mass portion of PM10 and $PM_{2.5}$ to TSP were 76% and 35% respectively. In the boundary area the mass portion of $PM_{10}$ and $PM_{2.5}$ to TSP were 78% and 54% respectively.

Understanding Three-dimensional Printing Technology, Evaluation, and Control of Hazardous Exposure Agents (3D 프린팅 기술의 이해, 유해 인자 노출 평가와 제어)

  • Park, Jihoon;Jeon, Haejoon;Oh, Youngseok;Park, Kyungho;Yoon, Chungsik
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.28 no.3
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    • pp.241-256
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    • 2018
  • Objectives: This study aimed to review the characteristics of three-dimensional printing technology focusing on printing types, materials, and health hazards. We discussed the methodologies for exposure assessment on hazardous substances emitted from 3D printing through article reviews. Methods: Previous researches on 3D printing technology and exposure assessment were collected through a literature review of public reports and research articles reported up to July 2018. We mainly focused on introducing the technologies, printing materials, hazardous emissions during 3D printing, and the methodologies for evaluation. Results: 3D printing technologies can be categorized by laminating type. Fused deposition modeling(FDM) is the most widely used, and most studies have conducted exposure assessment using this type. The printing materials involved were diverse, including plastic polymer, metal, resin, and more. In the FDM types, the most commonly used material was polymers, such as acrylonitrile-butadiene-styrene(ABS) and polylactic acids(PLA). These materials are operated under high-temperature conditions, so high levels of ultrafine particles(mainly nanoparticle size) and chemical compounds such as organic compounds, aldehydes, and toxic gases were identified as being emitted during 3D printing. Conclusions: Personal desktop 3D printers are widely used and expected to be constantly distributed in the future. In particular, hazardous emissions, including nano sized particles and various thermal byproducts, can be released under operation at high temperatures, so it is important to identify the health effects by emissions from 3D printing. Furthermore, appropriate control strategies should be also considered for 3D printing technology.

Magnetization and Magnetic Entropy Change in Superparamagnetic Co-Ferrite Nanoparticle (초상자성 코발트 페라이트 나노입자에 대한 자화 및 자기엔트로피 변화)

  • Ahn, Yang-Kyu;Choi, Eun-Jung
    • Journal of the Korean Magnetics Society
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    • v.18 no.2
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    • pp.63-66
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    • 2008
  • In order to the magnetization and magnetic entropy change for superparamagnetic ferrite nanoparticles, ultrafine cobalt ferrite particles were synthesized using a mircoemulsion method. The peak of X-ray diffraction pattern corresponds to a cubic spinel structure with the lattice constant 8.40 $\AA$. The average particle size, determined from X-ray diffraction line-broadening using Scherrer's, is 7.9 nm. The maximal magnetizations measured at 5 and 300 K are 24.3 emu/g and 17.2 emu/g, respectively. Superparamagnetic behavior of the sample is confirmed by the coincidence of the M vs. H/T plots at various temperatures. According to the thermodynamic theory, magnetic entropy change decreases with increasing temperature.

Fabrication and characterization of nano phosphor using ultrafine $Y_2O_3:EU^{3+}$ particles (초미세 $Y_2O_3:EU^{3+}$ 분말을 이용한 나노 형광체의 제조 및 특성 평가)

  • Hong, Sung-Jei;Kwak, Min-Gi;Cho, Kyoon-Woo;Kim, Won-Geun;Moon, Dae-Gyu;Han, Jeong-In
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.1062-1065
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    • 2003
  • 본 연구에서는 초미세 $Y_2O_3:EU^{3+}$ 분말을 이용하여 나노 형광체를 제조하였다. 나노 형광체는 소량의 Eu가 도핑된 $Y_2O_3$ 재질로 구성되어 있다. 형광체 분말의 결정화를 위해 $500{\sim}900^{\circ}C$의 온도로 열처리하였다. 제조된 나노 형광체를 HRTEM으로 관찰한 결과 입자 크기가 열처리 온도에 따라 약 $4{\sim}30nm$의 분포를 나타내었다. 또한 XRD로 결정상을 분석한 결과 주로 입방정 구조로 되어 있고 소량의 단사정 구조가 포함된 $Y_2O_3$ peak가 검출되었다. EDS 분석 결과 약 $6.7{\sim}7.5%$의 Eu가 검출되었다. 약 4nm 크기의 $Y_2O_3:EU^{3+}$ 분말로 제조한 나노 형광체의 발광 특성은 주요 파장대가 612nm인 PL spectrum이 관찰되어, 적색 형광체로서의 $Y_2O_3:EU^{3+}$ 나노 분말이 제조되었다.

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Air Pollution Exposure and Cardiovascular Disease

  • Lee, Byeong-Jae;Kim, Bumseok;Lee, Kyuhong
    • Toxicological Research
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    • v.30 no.2
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    • pp.71-75
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    • 2014
  • Ambient air pollution (AAP) and particulate matters (PM) have been closely associated with adverse health effects such as respiratory disease and cardiovascular diseases. Previous studies have examined the adverse health effects associated with short- and long-term exposure to AAP and outdoor PM on respiratory disease. However, the effect of PM size ($PM_{2.5}$ and $PM_{10}$) on cardiovascular disease has not been well studied. Thus, it remains unclear how the size of the inhalable particles (coarse, fine, or ultrafine) affects mortality and morbidity. Airborne PM concentrations are commonly used for ambient air quality management worldwide, owing to the known effects on cardiorespiratory health. In this article, we assess the relationship between cardiovascular diseases and PM, with a particular focus on PM size. We discuss the association of $PM_{2.5}$ and $PM_{10}$, nitrogen dioxide ($NO_2$), and elemental carbon with mortality and morbidity due to cardiovascular diseases, stroke, and altered blood pressure, based on epidemiological studies. In addition, we provide evidence that the adverse health effects of AAP and PM are more pronounced among the elderly, children, and people with preexisting cardiovascular and respiratory conditions. Finally, we critically summarize the literature pertaining to cardiovascular diseases, including atherosclerosis and stroke, and introduce potential studies to better understand the health significance of AAP and PM on cardiovascular disease.

Preparations of Nano-scale Mullite Powder from Solution Combustion Synthesis (용액연소합성에 의한 나노크기 물라이트 분말의 제조)

  • Lee, Sang-Jin;Yun, Jon-Do;Gwon, Hyeok-Bo;Jeon, Byeong-Se
    • Korean Journal of Materials Research
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    • v.11 no.9
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    • pp.797-801
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    • 2001
  • In this study, the solution combustion method was employed to synthesize stoichiometric mullite, and hence the attrition process was employed to prepare ultrafine mullite particles with nano size. The thermal decomposition behavior and partial pressure of equilibrium species of both oxidizer and fuel were considered during solution combustion process. The synthesized product was mullite phase with 40 nm crystalline size, and the alumina contents of the product by TEM/EDS quantity analysis was 3.12$\pm$04 mole. The result showed that the synthesized mullite was almost close to the it's stoichiometric composition. For attrition process, the dispersion behavior of the mullite suspension was controlled and was comminuted with the condition of 800 rpm for 4 hours using 0.3 mm zirconia ball media. As a result of comminution, the mean particle size was 80 nm.

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Microstructure and Consolidation of Gas Atomized Al-Si Powder

  • Hong, S.J.;Lee, M.K.;Rhee, C.K.;Chun, B.S.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.994-995
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    • 2006
  • The microstructure of the extruded Al-20Si bars showed a homogeneous distribution of eutectic Si and primary Si particles embedded in the Al matrix. The grain size of ${\alpha}-Al$ varied from 150 to 600 nm and the size of the eutectic Si and primary Si in the extruded bars was about 100 - 200 nm. The room temperature tensile strength of the alloy with a powder size $<26{\mu}m$ was 322 MPa, while for the coarser powder ($45-106{\mu}m$) it was 230 MPa. With decreasing powder size from $45-106{\mu}m$ to $<26{\mu}m$, the specific wear of all the alloys decreased significantly at all sliding speeds due to the higher strength achieved by ultrafine-grained constituent phases. The fracture mechanism of failure in tension testing and wear testing was also studied.

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Amorphous Ultrafine Particle Preparation for Improvement of Bioabailability of Insolube Drugs: Effect of Co-Grinding of UDCA with SLS (난용성 의약품의 생체이용률 증진을 위한 무정형 초미립자의 조제 : UDCA와 SLS의 혼합분쇄 효과)

  • 정한영;곽성신;김현일;최우식
    • YAKHAK HOEJI
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    • v.46 no.2
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    • pp.102-107
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    • 2002
  • The particle size of medicinal materials is an important physical property which affects the pharmaceutical behaviors such as dissolution, chemical stability, compressibility and bioavailability of solid dosage forms. The size reduction of raw pharmaceutical powder is needed to formulize insoluble drugs or slightly soluble drugs and to improve the pharmaceutical properties such as the solubility, the pharmaceutical mixing and the dispersion. The objective of the present study is to evaluate the grinding characteristics of ursodeoxycholic acid(UDCA) as a model of insoluble drugs. The effects of the grinding time and the amount of additive on particle size distribution of ground UDCA were investigated. Grinding of insoluble drug, UDCA and a series of dry co-grinding experiments of UDCA with sodium lauryl sulfate(SLS) as an additive were carried out using a planetary ball mill. It was measured that the median diameter and the particle size distribution of ground products with grinding UDCA and additive SLS by Mastersizer. As a result of co-grinding of UDCA and SLS, the particle size of co-grinding products was decreased more than single grinding one. However, it was observed that co-grinding products were reaggregated to larger particles after 120 min.

Microstructure and Mechanical Behavior of Ultrafine Grained Bulk Al Processed by High Pressure Torsion of the Al Powders (고압비틀림 성형 공정에 의한 Al 분말의 초미세결정 벌크화 및 특성 평가)

  • Joo, Soo-Hyun;Yoon, Seung-Chae;Lee, Chong-Soo;Kim, Hyong-Seop
    • Journal of Powder Materials
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    • v.17 no.1
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    • pp.52-58
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    • 2010
  • Bulk nanostructured metallic materials are generally synthesized by bottom-up processing which starts from powders for assembling bulk materials. In this study, the bottom-up powder metallurgy and High Pressure Torsion (HPT) approaches were combined to achieve both full density and grain refinement at the same time. After the HPT process at 473K, the disk samples reached a steady state condition when the microstructure and properties no longer evolve, and equilibrium boundaries with high angle grain boundaries (HAGBs) were dominant. The well dispersed alumina particles played important role of obstacles to dislocation glide and to grain growth, and thus, reduced the grain size at elevated temperature. The small grain size with HAGBs resulted in high strength and good ductility.

A Study on Optimum Design of an Axial Cylcone structure using Response Surface Method (반응표면법을 활용한 축류형 사이클론 구조 최적화 설계에 관한 연구)

  • Cho, Jinill;Yun, Junho;Cho, Yeongkwang;Seok, Hyunho;Kim, Taesung
    • Particle and aerosol research
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    • v.17 no.3
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    • pp.71-79
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    • 2021
  • Ultrafine dust, which is emitted from industrial factories or all kinds of vehicles, threatens the human's respiratory system and our environment. In this regard, separating airborne particles is essential to mitigate the severe problem. In this work, an axial cyclone for the effective technology of eliminating harmful dust is investigated by numerical simulation using Ansys 2020, Fluent R2. In addition, the optimized structure of the cyclone is constructed by means of multi objective optimization based on the response surface method which is a representative method to analyze the effect of design parameter on response variables. Among several design parameters, the modified length of the vortex finder and dust collector is a main point in promoting the performance of the axial cyclone. As a result, the optimized cyclone exhibits remarkable performance when compared to the original model, resulting in pressure drop of 307 Pa and separator efficiency of 98.5%.