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Electrolytic Decontamination of the Dismantled Metallic Wastes Contaminated with Uanium Compounds in Neutral Salt Solutions (중성염 용액 내에서 우라늄으로 오염된 금속성 해체폐기물의 전해제염)

  • 최왕규;이성렬;김계남;원휘준;정종헌;오원진
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.72-80
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    • 2004
  • Electrolytic dissolution study was carried out to evaluate the applicability of electrochemical decontamination process using a neutral salt electrolyte as a decontamination technology for the recycle or self disposal with authorization of large amount of metallic wastes contaminated with uranium compounds generated by dismantling a retired uranium conversion plant using SUS-304 and Inconel-600 specimen as the main materials of internal system components of the plant. The effects of type of neutral salt as an electrolyte, current density, and concentration of electrolyte on the dissolution of the materials were evaluated. On the basis of the results obtained through the basic inactive experiments, electrochemical decontamination tests using the specimens contaminated with uranium compounds such as $UO_2$, AUC (ammonium uranyl carbonate) and ADU (ammonium diuranate) taken from an uranium conversion plant were peformed in $Na_2SO_4$ and $NaNO_3$ solution. It was verified that the electrochemical decontamination of the dismantled metallic wastes was quite successful in $Na_2SO_4$ and $NaNO_3$ neutral salt electrolyte by reducing $\beta$ radioactivities below the level of self disposal with authorization within 10 minutes regardless of the type of contaminants and the degree of contamination.

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Shear Friction Strength Model of Concrete considering Transverse Reinforcement and Axial Stresses (축응력 및 횡보강근을 고려한 콘크리트의 전단마찰내력 평가모델)

  • Hwnag, Yong-Ha;Yang, Keun-Hyeok
    • Journal of the Korea Concrete Institute
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    • v.28 no.2
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    • pp.167-176
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    • 2016
  • Shear friction strength model of concrete was proposed to explain the direct friction mechanism at the concrete interfaces intersecting two structural elements. The model was derived from a mechanism analysis based on the upper-bound theorem of concrete plasticity considering the effect of transverse reinforcement and applied axial loads on the shear strength at concrete interfaces. Concrete was modelled as a rigid-perfectly plastic material obeying modified Coulomb failure criteria. To allow the influence of concrete type and maximum aggregate size on the effectiveness strength of concrete, the stress-strain models proposed by Yang et al. and Hordijk were employed in compression and tension, respectively. From the conversion of these stress-strain models into rigidly perfect materials, the effectiveness factor for compression, ratio of effective tensile strength to compressive strength and angle of concrete friction were then mathematically generalized. The proposed shear friction strength model was compared with 91 push-off specimens compiled from the available literature. Unlike the existing equations or code equations, the proposed model possessed an application of diversity against various parameters. As a result, the mean and standard deviation of the ratios between experiments and predictions using the present model are 0.95 and 0.15, respectively, indicating a better accuracy and less variation than the other equations, regardless of concrete type, the amount of transverse reinforcement, and the magnitude of applied axial stresses.

The Effect of Interfacial Properties and RTM Process of Composites with Different Cross-linking Density by Molecular Weight of Hardener (경화제의 분자량에 의한 가교밀도 차이에 따른 복합재료의 계면 물성 및 RTM 성형성에 미치는 영향)

  • Park, Ha-Seung;Shin, Pyeong-Su;Kim, Jong-Hyun;Baek, Yeong-Min;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.30 no.3
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    • pp.169-174
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    • 2017
  • Demand of glass fiber reinforced composites (GFRC) increased with developing aircraft and defense industries using resin transfer molding (RTM) process to produce complex product. In this research, wetting, interfacial, and mechanical properties were evaluated with different Cross-linking Density by Molecular Weight of Hardener. Epoxy resin as matrices was used bisphenol-A type and amine-type hardeners with different molecular weight. Specimens were manufactured via RTM and wetting property of resin and glass fiber (GF) mat was evaluated to viscosity of epoxy and injection time of epoxy matrix. Mechanical property of GFRC was determined via flexural strength whereas interfacial properties were determined by interlaminar shear strength (ILSS) and interfacial shear strength (IFSS). The difference in mechanical property depends upon the fiber weight fraction (wt %) of GFRC by RTM as well as the different Molecular Weight of Hardener.

Differences in percussion-type measurements of implant stability according to height of healing abutments and measurement angle (임플란트 healing abutment 높이와 타진각도에 따른 타진방식 임플란트 안정성 측정기기의 수치 차이)

  • Park, Yang-Hoon;Leesungbok, Richard;Lee, Suk-Won;Paek, Janghyun;Lee, Jeong-Yol
    • The Journal of Korean Academy of Prosthodontics
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    • v.56 no.4
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    • pp.278-286
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    • 2018
  • Purpose: The purpose of this study was to evaluate the effect of healing abutment height and measurement angle on implant stability when using Periotest and AnyCheck. Materials and methods: 60 implants were placed into artificial bone blocks. After implant insertion, 2, 3, 4 and 5 mm healing abutments were installed on 15 specimens, respectively. Insertion torque value, implant stability test, Periotest value were measured. Insertion torque value was controlled between 45 - 55 Ncm. AnyCheck was used for measuring implant stability test and Periotest M was used for measuring Periotest value. Implant stability test and Periotest value were measured at the angles of 0 and 30 degrees to the horizontal plane. Measured values were analyzed statistically. Results: Insertion torque value had no significant difference among groups. When healing abutment height was higher, implant stability test and Periotest value showed lower stability. Also when measurement angle was decreased, implant stability test and Periotest value showed lower stability. Conclusion: When measuring stability of implants with percussion type devices, measured values should be evaluated considering height of healing abutments and measurement angle.

The Effects of Thermocycling on the Shear Bond Strength between Metal Denture Base and Relining Resin (Thermocycling이 첨상용 레진과 금속 의치상간의 전단결합강도에 미치는 영향)

  • Lee, Joon-seok
    • Journal of Dental Rehabilitation and Applied Science
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    • v.21 no.2
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    • pp.95-103
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    • 2005
  • Purpose: Recently, various metal primers have been developed, and these are known to increase the bond strength between metal and relining resin. In this study, the change in bond strength according to amount of thermocycling was evaluated. Materials and Methods: In this study, 216 specimens were fabricated. Tokuyama Rebase $II^{(R)}$(Tokuyama Corp., Japan) and $Kooliner^{(R)}$(GC America Inc., Japan) as relining material, and MR. $Bond^{(R)}$(Tokuyama Corp., Japan) and Alloy $Primer^{(R)}$(Kuraray Medical Inc., Japan) as a metal primers were used. Using Ni-Cr and various metal surface treatment methods, resin was bonded and the change in bond strength during thermocycling was measured. The data was analyzed by one-way ANOVA, t-test(p<.05 level of significance). Results: When comparing the groups with only sandblasting, rapid decrease in shear bond strength could be seen. In the groups using Tokuyama Rebase $II^{(R)}$, with the exception of the 1000 and 2000 cycle groups, each group showed statistically significant decrease in shear bond strength(p<0.05). In comparison according to relining materials, $Kooliner^{(R)}$ showed higher shear bond strength than Tokuyama Rebase $II^{(R)}$ in all groups. In groups using MR $bond^{(R)}$, $Kooliner^{(R)}$ had higher shear bond strength than Tokuyama Rebase $II^{(R)}$ but, there was no statistical significance(p<0.05). In the other groups, $Kooliner^{(R)}$ showed significantly higher shear bond strength(p<0.05). There was significant difference between groups with sandblasting and metal primer treatments(p<0.05). In comparison according to metal primer materials, Alloy $Primer^{(R)}$ showed the highest shear bond strength but there was no statistical significance(p>0.05). According to the number of thermocycling cycles, when using Tokuyama Rebase $II^{(R)}$, there were no significant differences between the 0, 1000 and 2000 cycle groups regardless of the type of metal primer. There were no differences between the 2000 and 3000 cycle groups. When using $Kooliner^{(R)}$, regardless of the type of metal primer, there were no significant differences between the 0, 1000, 2000 and 3000 cycle groups(p>0.05). Conclusion: The use of metal primers showed increase in bond strength, and the stability after to thermocycling has been authenticated. Thus, the use of metal primers in relining and rebasing of metal frameworks is essential. But when selecting the material various physical properties should be considered.

Flexural Strengthening Effects of RC Beam Reinforced with Pre-stressing Plate (긴장을 가한 보강 플레이트로 보강된 RC 보의 휨보강 효과)

  • Ha, Sang-Su
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.1
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    • pp.171-178
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    • 2019
  • Fiber-reinforced polymer (FRP) composites have proved to be reliable as strengthening materials. Most of existing studies used single types of FRP composites. Therefore, in this experimental study, carbon FRP sheet, aramid FRP sheet, and hybrid FRP plate including glass fibers were fabricated, and the effect of pre-stressed FRP composites on flexural strengthening of reinforced concrete (RC) beams was investigated. In total, eight RC beam specimens were fabricated, including one control beam (specimen N) without FRP composites and seven FRP-strengthened beams. The main parameters were type of FRP composite, the number of anchors used for pre-stressing, and thickness of FRP plates. As a result, the beam strengthened with pre-stressed FRP plate showed superior performance to the non-strengthened one in terms of initial strength, strength and stiffness at yielding, and ultimate strength. As the number of anchors and thickness of FRP plate (i.e., amount of FRP plates) increased, the strengthening effect increased as well. When hybrid FRP plates were pre-stressed, the strengthening effect was higher in comparison with pre-stressed single type FRP plate.

An Experimental Study on the Girder-Abutment Connection for the Steel-Concrete Composite Rigid-Frame Bridge Integrated with PS Bars (PS 강봉으로 일체화된 강합성 라멘교의 거더-교대 접합부의 거동에 관한 실험적 연구)

  • Lee, Sang-Yoon;Ahn, Young-Soo;Oh, Min-Ho;Chung, Jee-Seung;Yang, Sung-Don
    • Journal of the Korea Concrete Institute
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    • v.24 no.4
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    • pp.453-463
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    • 2012
  • Steel-concrete composite rigid-frame bridge is a type of integral bridge having advantages in bridge maintenance and structural efficiency from eliminating expansion joints and bridge supports, the main problems in bridge maintenance. The typical steel-concrete composite rigid-frame bridge has the girder-abutment connection where a part of its steel girder is embedded in abutment for integrity. However, the detail of typical girder-abutment connection is complex and increases the construction cost, especially when a part of steel girder is embedded. Recently, a new type of bridge was proposed to compensate for the disadvantages of complex details and cost increase. The compensation are expected to improve efficiency of construction by simplifying the construction detail of the girder-abutment connection. In this study, a static load test has been carried out to examine the behavior of the girder-abutment connection using real-scale specimens. The results of the test showed that the girder-abutment connection of proposed girder bridge has sufficient flexural capacity and rebars to control concrete crack should be placed on the top of abutment.

Corrosion-Inhibition and Durability of Polymer-Modified Mortars Using Bisphenol A and F Type Epoxy Resin with Calumite (비스페놀 A 및 F형 에폭시수지와 칼루마이트를 병용한 폴리머 시멘트 모르타르의 방청성 및 내구성)

  • Kim, Joo-Young;Kim, Wan-Ki
    • Journal of the Korea Concrete Institute
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    • v.26 no.4
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    • pp.517-524
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    • 2014
  • Nitrite-Type hydrocalumite (calumite) is a material that can adsorb chloride ions ($Cl^-$) that cause corrosion of reinforce bars and liberate the nitrite ions ($NO_2{^-}$) that inhibit corrosion in reinforced concrete. In this study, polymer-modified mortars using two types of epoxy resin with calumite are prepared with various polymer binder-ratios of 0, 5, 10, 15, 20% and calumite contents of 0, 5%. The specimens are tested for chloride ion penetration, carbonation, drying shrinkage and corrosion inhibition. As a result, the chloride ion penetration and carbonation depth of PMM using epoxy resin somewhat increases with increasing calumite contents, but those remarkably decreases depending on the polymer-binder ratios. The 28-d drying shrinkage shows a tendency to decrease with increasing polymer-binder ratio and calumite content. Unmodified mortars with calumite content of 5% did not satisfy quality requirement by KS. However, it was satisfied with KS requirement by the modification of epoxy resin in cement mortar. On the whole, the carbonation and chloride ion penetration depth of epoxy-modified mortars with calumite is considerably improved with an increase in the polymer-binder ratio regardless of the calumite content, and is remarkably improved over unmodified mortar. And, the replacement of the portland cement with the calumite has a marked effect in the corrosion-inhibiting property of the epoxy-modified mortars.

Behavior of Stud Shear Connectors in Precast Deck using Lightweight Concrete (경량콘크리트를 사용한 프리캐스트 바닥판에서 스터드 전단연결재의 거동)

  • Cho, Sun Kyu;Lee, Jong Min;Youn, Seok Goo;Choi, Yun Wang
    • Journal of Korean Society of Steel Construction
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    • v.20 no.2
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    • pp.227-236
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    • 2008
  • The kind of concrete generally used in steel concrete composite bridges is normal-weight concrete whose unit weight is ${2,300kg/m^{3}}$. However, using lightweight concrete in composite bridges diminishes the sectional forces due to the self-weight of concrete decks. As a result, this will make the bridge design more economical. The type of concrete deck that could be adopted in composite bridges using lightweight con crete may be classified into Cast-In-Place (C.I.P.) concrete deck and precast concrete deck. These two types of decks have some differences with respect to structural behavior and constructional method, and hence,structural behavior of stud shear connectors that connect a concrete deck to a steel girder is changed with the type of deck used. In this study, push-out tests were conducted to evaluate the characteristics of static behavior of the stud shear connectors with a precast deck using lightweight concrete. Also, additional precast deck specimens with bedding layer that had shear keys and devices for transverse confinement of the bedding layer for the prevention of cracks occurring in the bedding layer were tested. These cracks The efficiency of these devices was then evaluated.

A Fundamental Study on Induction Technology of Separation Behavior Using Two-sided Adhesion of Joint of Composites Waterproofing System (시트-도막 복합방수공법의 접합부 2면 접착을 통한 분리거동 유도 기술에 관한 기초적 연구)

  • Park, Jin-Sang;Lee, Tae-Yang;Kim, Dong-Bum;Park, Wan-Goo;Heo, Neung-Hoe;Oh, Sang-Keun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.3
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    • pp.212-219
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    • 2015
  • This study focuses evaluating the efficiency and performance evaluation of composite type sheet-membrane waterproofing method that utilizes a separation behavior inducement system designed to resolve the chronic problems of disintegration and damage of overlap areas of waterproofing layers. As the result of the test, the tensile strength value was at 13.8N/mm and elongation rate at 587% for the separation behavior inducement type specimen, and the compared specimens had 14.2N/mm for tensile strength and 335% for elongation rate. For the separation behavior adhesion method specimen, when tensile stress or displacement occurred, the Zero-Span tension occurrence did not follow, which resulted in that the bottom sheet layer and the top membrane layer did not simultaneously becoming damaged. When undergoing the top and bottom layers were separated through separation behavior due to lack of flexibility, the bottom layer began to damage at the primary stage, and with the allowed boundary the upper membrane layer began to display flexibility and showed continuous displaced resulting in secondary phase damaging.