• Bulletin of the Korean Chemical Society
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• v.33 no.1
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• pp.95-99
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• 2012

Two novel copper(II) complexes, [Cu(dmamhp)$(H_2O)_2(SO_4)]_n$ (1) and [Cu(dmamhp)$(NO_3)_2(H_2O)]{\cdot}H_2O$ (2) [dmamhp = 2-dimethylaminomethyl-3-hydroxypyridine] have been synthesized and structurally characterized by single crystal X-ray diffraction analysis. Compound 1 displays a double one-dimensional chains structure, in which each chain is constituted with the distorted octahedral copper(II) complex bridged through bidentate sulfate ligands resulting in a coordination polymer. The bifurcated hydrogen bonds and $\pi-\pi$ interactions play important roles in the formation of the double chains structure. On the other hand, compound 2 adopts a distorted square pyramidal geometry around copper(II) ion and exists as a discrete monomer. There are intermolecular bifurcated hydrogen bonds and $\pi-\pi$ stacking interactions between the monomeric units. The magnetic properties revealed that the paramagnetic behaviors are dominantly manifested and there are no intermolecular magnetic interactions in both compound 1 and 2.

• Journal of the Society of Naval Architects of Korea
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• v.35 no.1
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• pp.61-71
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• 1998

This paper describes a dynamic fracture behaviors of structural elements under elastic or elasto-plastic stress waves in two dimensional space. The governing equation of this problem has the type of hyperbolic partial differential equation, which consists of the equation of motions and incremental elasto-plastic constitutive equations. To solve this problem we introduce Zwas' method which is based on the finite difference method. Additionally, in order to deal with the dynamic behavior of elasto-plastic problems, an elasto-plastic loading path in the stress space is proposed to model the plastic yield phenomenon. Based on the result of this computation, the dynamic stress intensity factor at the crack tip of an elastic material is calculated, and the time history of a plastic zone of a elasto-plastic material is to be shown.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2002.10a
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• pp.191-196
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• 2002

The paper presents a numerical and experimental investigation on dynamic behaviors of a towed low tension cable. In the numerical study, an implicit finite difference algorithm is employed for three-dimensional cable equations. Fluid and geometric non-linearity and bending stiffness are considered and solved by Newton-Raphson iteration. Block tri-diagonal matrix method is applied for the fast calculation of the huge size of matrices. In order to verify the numerical results and to see real physical phenomena, an experiment is carried out for a 6m cable in a deep and long towing tank. The cable is towed in two different ways; one is towed at a constant speed and the other is towed at a constant speed with top end horizontal oscillations. Cable tension and shear forces are measured at the top end. Numerical and experimental results are compared with good agreements in most cases but with some differences in a few cases. The differences are due to drag coefficients caused by vortex shedding. In the numerical modeling, non-uniform element length needs to be employed to cope with the sharp variation of tension and shear forces at near top end.

• Applied Microscopy
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• v.46 no.4
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• pp.217-226
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• 2016

Monolayer hexagonal boron nitride (h-BN) is a phenomenal two-dimensional material; most of its physical properties rival those of graphene because of their structural similarities. This intriguing material has thus spurred scientists and researchers to develop novel synthetic methods to attain scalability for enabling its practical utilization. When probing the growth behaviors and structural characteristics of h-BN, the use of appropriate characterization techniques is important. In this review, we detail the use of scanning and transmission electron microscopies to investigate the atomic configurations of monolayer and bilayer h-BN grown via chemical vapor deposition. These advanced microscopy techniques have been demonstrated to provide intimate insights to the atomic structures of h-BN, which can be interpreted directly or indirectly using known growth mechanisms and existing theoretical calculations. This review provides a collective understanding of the structural characteristics and defects of synthetic h-BN films and facilitates a better perspective toward the development of new and improved synthesis techniques.

• Proceedings of the Korean Society of Broadcast Engineers Conference
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• 1999.06a
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• pp.83-88
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• 1999

In this paper, a novel gray-scale lossless image coder combining context-based minimum mean squared error (MMSE) prediction and entropy coding is proposed. To obtain context of prediction, this paper first defines directional difference according to sharpness of edge and gradients of localities of image data. Classification of 4 directional differences forms“geometry context”model which characterizes two-dimensional general image behaviors such as directional edge region, smooth region or texture. Based on this context model, adaptive DPCM prediction coefficients are calculated in MMSE sense and the prediction is performed. The MMSE method on context-by-context basis is more in accord with minimum entropy condition, which is one of the major objectives of the predictive coding. In entropy coding stage, context modeling method also gives useful performance. To reduce the statistical redundancy of the residual image, many contexts are preset to take full advantage of conditional probability in entropy coding and merged into small number of context in efficient way for complexity reduction. The proposed lossless coding scheme slightly outperforms the CALIC, which is the state-of-the-art, in compression ratio.

• Steel and Composite Structures
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• v.32 no.5
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• pp.657-670
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• 2019

This paper proposes a one-dimensional fiber beam element model taking account of materially non-linear behavior, benefiting the highly efficient elastic-plastic analysis of girders with shear-lag effects. Based on the displacement-based fiber beam-column element, two additional degrees of freedom (DOFs) are added into the proposed model to consider the shear-lag warping deformations of the slabs. The new finite element (FE) formulations of the tangent stiffness matrix and resisting force vector are deduced with the variational principle of the minimum potential energy. Then the proposed element is implemented in the OpenSees computational framework as a newly developed element, and the full Newton iteration method is adopted for an iterative solution. The typical materially non-linear behaviors, including the cracking and crushing of concrete, as well as the plasticity of the reinforcement and steel girder, are all considered in the model. The proposed model is applied to several test cases under elastic or plastic loading states and compared with the solutions of theoretical models, tests, and shell/solid refined FE models. The results of these comparisons indicate the accuracy and applicability of the proposed model for the analysis of both concrete box girders and steel-concrete composite girders, under either elastic or plastic states.

• Journal of the Korean Geosynthetics Society
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• v.18 no.1
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• pp.1-9
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• 2019

This study investigated settlement and scouring characteristics of artificial reef reinforced with various reinforcement types to reduce settlement and scouring. Three reinforcement types were prepared: geogrid, geogrid-bamboo mat (GBM) and seaweed-pile mat (SPM). Various laboratory tests such as bearing capacity test, large size settlement test, two-dimensional flow scour test were performed according to different soil types (sand, silt, clay). Laboratory test results indicated that bearing capacity of seabed with a reinforced artificial reef increased and its settlement and scour depth reduced for all reinforcement types. Especially, reinforcement effect tends to be greater in clay soft ground rather than sand and silt grounds.

• Structural Engineering and Mechanics
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• v.82 no.6
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• pp.713-724
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• 2022

Effects of coal tensile strength and plow configuration on the coal fragmentation process was modeled by two-dimensional particles flow code (PFC2D). Three tensile strength values, 0.5, 1,5 and 3.5 MPa were considered in this numerical study. The cutters of plow penetrated in the coal for 4 mm at a rate of 0.016 m/s. According to the PFC manual, the local damping factor was 0.7. Three failure mechanism of coal during the fragmentation process by plow were modelled. The coal material beneath the cutters showed the elastic, plastic and fracturing behaviors in this analysis. In all the models, the plastic zone was fractured and some micro-cracks were induced but the elastic zone remained undamaged. It was observed that the tensile strength affected the failure mechanism of coal significantly and as it increased the extent of the fractured zone underneath the plow cutter decreased during the fragmentation process.

• Structural Engineering and Mechanics
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• v.64 no.5
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• pp.543-555
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• 2017

The non-linear behaviour of integral infilled frames (in which the infill and the frame are bonded together with help of various interface materials) is studied both experimentally and numerically. The experiments were carried out on one-sixth scale two-bay and three-storey reinforced concrete frames with and without infill against static cyclic loading. Three interface materials - cement mortar, cork and foam have been used in between the infill and the frame. The infill, interface and the frame are bonded together is called integral frame. The linear and non-linear behaviors of two dimensional bare frame and integral infilled frame have been studied numerically using the commercial finite element software SAP 2000. Linear finite element analysis has been carried out to quantify the effect of various interface materials on the infilled frames with various combinations of 21 cases and the results compared. The modified configuration that used all three interface materials offered better resistance above others. Therefore, the experiments were limited to this modified infilled frame case configuration, in addition to conventional (A1-integral infilled frame with cement mortar as interface) and bare frame (A0-No infill). The results have been compared with the numerical results done initially. It is found that stiffness of bare frame increased by infilling and the strength of modified frame increased by 20% compare to bare frame. The ductility ratio of modified infilled frame was 42% more than that of the conventional infilled frame. In general, the numerical result was found to be in good agreement with experimental results for initial crack load, ultimate load and deformed pattern of infill.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.23 no.12
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• pp.843-851
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• 2011

A two-dimensional immiscible water meniscus deformation phenomena on a moving tip in a channel has been investigated by using lattice Boltzmann method involving two-phase model. We studied the behavior of a water meniscus between the tip and a solid surface. The contact angles of the tip and a solid surface considered are in the range from $10^{\circ}$ to $170^{\circ}$. The velocity of the tip used in the study are 0.01, 0.001, and 0.0001. The shapes of tip considered are rectangular and circular. The behavior of water confined between the tip and a solid surface depends on the contact angles of the tip and a solid surface, and the tip velocity. When the tip is moving, we can observe the various behaviors of shear deformation of a water meniscus. As time goes on, the behavior of a water meniscus can be classified into three different patterns which are separated from the tip or adhered to the tip or sticked to a solid surface according to the contact angles and the tip velocity.