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Scanning Tunneling Microscopy Study of Alcohol Adsorption on NiAl(110) Deposited by Pulsed Injection

  • Choi, Eun-Yeoung;Lee, Youn-Joo;Lyo, In-Whan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.353-353
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    • 2010
  • Alcohol is a vesatile polar solvent for molecules. As a preparation to deposit large molecules, we studied interaction of solvent molecules on metallic surface. in this work, we report on methanol adsorption on NiAl(110) with scanning tunneling microscopy (STM). These alcohol solvent molecules were deposited by a pulse injection method suitable for deposition of thermally unstable molecules. The injection of liquid alcohol onto the substrate in UHV was performed by using a high-speed solenoid valve with the back-pressure reduced down to 100 Torr. This technique allowed precise control over the amount of dosing of molecules to less than 1 L. Alcohol-induced features, attributed to methoxy, were found on bare NiAl(110) surface.

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Numerical investigation on the effect of backfill grouting on ground behavior during shield TBM tunneling in sandy ground (사질토 지반을 통과하는 쉴드 TBM에서 뒤채움 그라우팅이 지반 거동에 미치는 영향에 대한 수치해석적 연구)

  • Oh, Ju-Young;Park, Hyunku;Chang, Seokbue;Choi, Hangseok
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.20 no.2
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    • pp.375-392
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    • 2018
  • The shield TBM method is widely adopted for tunneling works in urban area because it has more beneficial ways to control settlement at ground surface than conventional mined tunneling. In the shield tunneling, backfill grouting at tail void is crucial because it is supposed not only to restraint ground deformation around tail void during excavation but also to compensate precedent ground settlement by pushing up the ground with highly pressurized grout. However, the tail void grouting has been found to be ineffective for settlement compensation particularly in sandy ground, which might be caused by complicate interaction between ground and tail void grouting. In this paper, the effects of tail void grouting on behavior of ground in shield TBM tunneling were investigated based on 3-dimensional finite element analyses. The results of numerical analyses indicated that backfill grouting actually reduces settlement by degrading settlement increasing rate in excavation, which means decrease of volume loss. Meanwhile, the grouting could not contribute to compensate the precedent settlement, because reduction of volume loss by grouting was found to be counterbalanced by volume change of ground.

A Study On a Method of Improvement From Domestic NATM Case (NATM 시공 사고 사례에 의한 개선방안 연구)

  • 이상웅
    • Explosives and Blasting
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    • v.13 no.3
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    • pp.19-30
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    • 1995
  • NATM as method of tunneling has been applied to construction of domestic subway, roads, rail way, water way etc. Accordingly, we have NATM's many drafts and constructional results, but many problems and accidents have occurred under construction of tunnel using NATM for shortage of technical data. Poorness of constructional improvement, systemic inconsistency etc. Especially, everyone was shocked at Gupo's train wrecking accident lately. The purpose of this thesis is presentation of means for setting technical problems, by looking into Gupo's train wrecking accident and home records that applying NATM in tunneling failed, to minimize future safety accidents we find that the general problems of home fifteen sites having occured accidents is badly geological survey, nonconfirmationi of base rock's state, formal measuring management, shortage of specialists, systemical discrepancy and that disregarding NATM's rules makes general problems. The results of this study are Summarised as follows : 1. We advise repletion of design standards to practice crosshole test for confirming connected rock base on vertical section of tunnel. 2. We advise to practice pre0boring and pre-grouting for a weak layer difficult in applying NATM. 3. We advise systemic improvements that field servicer can construct tunnel of his own free will considering base rock's state at tunnel . 4. We advise that specialist, who can make a conduct and supervise above mentioned items as well as measuring management, should be posted at field.

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The impact of EPB pressure on surface settlement and face displacement in intersection of triple tunnels at Mashhad metro

  • Eskandari, Fatemeh;Goharrizi, Kamran Goshtasbi;Hooti, Amir
    • Geomechanics and Engineering
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    • v.15 no.2
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    • pp.769-774
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    • 2018
  • The growth of cities requires the construction of new tunnels close to the existing ones. Prediction and control of ground movement around the tunnel are important especially in urban area. The ground respond due to EPB (Earth Pressure Balance) pressure are investigated using the finite element method by ABAQUS in intersection of the triplet tunnels (Line 2, 3 and 4) of Mashhad Urban Railway in Iran. Special attention is paid to the effect of EPB pressure on the tunnel face displacement. The results of the analysis show that in EPB tunneling, surface settlement and face displacement is related to EPB pressure. Moreover, it is found that tunnel construction sequence is a great effect in face displacement value. For this study, this value in Line 4 where is excavated after line 3, is smaller than that line. In addition, the trend of the displacement curves are changed with the depth for all lines where is located in above and below, close to and above the centerline tunnel face for Line 2, 3 and 4, respectively. It is concluded that: (i) the surface settlement decreases with increasing EPB pressure on the tunnel face; (ii) at a constant EPB pressure, the tunnel face displacement values increase with depth. In addition, this is depended on the tunneling sequence; (iii) the trend of the displacement curves change with the depth.

A Study on a Method of Improvement from Domestic NATM Case (국내 NATM시공 사고사례에 의한 개선방안 연구)

  • 김무일;이상웅
    • Journal of the Korean Society of Safety
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    • v.9 no.4
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    • pp.92-102
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    • 1994
  • NATM as method of tunneling has been applied to construction of domestic subway, roads, rail way, water way etc. Accordingly we have NATM's many drafts and constructional results, but many problems and accidents have occurred under construction of tunnel using NATM for shortage of technical data, poorness of constructional improvement, systemic inconsistency etc. Especially, everyone was shocked at Gupo's train wrecking accident lately. The purpose of this thesis is presentation of means for settling technical problems, by looking into Gupo's train wrecking accident and home records that applying NATM in tunneling failed, to minimize future safety accidents we find that the general problems of home fifteen sites haying occured accidents is badly geological survey, nonconfirmation of base rock's state, formal measuring management, shortage of specialists, systemical discrepancy and that disregarding NATM's rules makes general problems. The results of this study are summarised as follows ; 1. We advise repletion of design standards to practice crosshole test for confirming connected rock base on vertical section of tunnel. 2. We advise to practice pre-boring and pre-grouting for a weak layer difficult in applying NATM. 3. We advise systemic improvements that field servicer can construct tunnel of his own free will considering base rock's state at tunnel. 4. We advise that specialist, who can make a conduct and supervise above mentioned items as well as measuring managements, should be posted at field.

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The Continuously Underwater Tunnelling Methods by Incremental launching Methods (연속압출공법(ILM)을 이용한 수저(水底)터널공법에 관한 연구)

  • Jung, Byung-Ryul;Ryu, Dong-Hun;Kim, Joon-Mo
    • Proceedings of the KSR Conference
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    • 2009.05a
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    • pp.28-41
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    • 2009
  • We know the several construction methods for underwater tunnel, but properly submerged concrete box type tunnel was mostly good structure stability and mostly shot length of tunnels. Submerged box type tunnel was buildup the unit segments in dry dock or ship yard by 10 to 20meters. The submerged box was composed with segments was join each together. It was installing the gate and waterproofing the coupling the front hull of a box. The complete submerged box rise up to the surface water, tow in the submerged box by tugboat, going to the destination of tunnel construction site. Beforehand dredge up soil at the bottom of a underwater, sinking the submerged box, connection together complete submerged box in underwater. The research and development ILM tunneling method is receiving careful study. Biggest weakness in submerged concrete box type tunnel was pressure waterproofing, box to box connecting, complete submerged boxes navigation and installation, after operation the submerged tunnel and management concrete box structure. It was positive evidence in submerged concrete box type tunnel. We make a practical application of the principle "the ILM tunneling method in underwater construction methods."

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High Crystalline Epitaxial Bi2Se3 Film on Metal and Semiconductor Substrates

  • Jeon, Jeong-Heum;Jang, Won-Jun;Yun, Jong-Geon;Gang, Se-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.302-302
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    • 2011
  • The binary chalcogenide semiconductor Bi2Se3 is at the center of intensive research on a new state of matter known as topological insulators. It has Dirac point in their band structures with robust surface states that are protected against external perturbations by strong spin-orbit coupling with broken inversion symmetry. Such unique band configurations were confirmed by recent angle-resolved photoelectron emission spectroscopy experiments with an unwanted n-type doping effect, showing a Fermi level shift of about 0.3 eV caused by atomic defects such as Se vacancies. Since the number of defects can be reduced using the molecular beam epitaxy (MBE) method. We have prepared the Bi2Se3 film on noble metal Au(111) and semiconductor Si(111) substrates by MBE method. To characterize the film, we have introduced several surface sensitive techniques including x-ray photoemission electron spectroscopy (XPS) and micro Raman spectroscopy. Also, crystallinity of the film has been confirmed by x-ray diffraction (XRD). Using home-built scanning tunneling microscope, we observed the atomic structure of quintuple layered Bi2Se3 film on Au(111).

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Surface Potential Change Depending on Molecular Orientation of Hexadecanethiol Self-Assembled Monolayers on Au(111)

  • Ito, Eisuke;Arai, Takayuki;Hara, Masahiko;Noh, Jaegeun
    • Bulletin of the Korean Chemical Society
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    • v.30 no.6
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    • pp.1309-1312
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    • 2009
  • Surface potential and growth processes of hexadecanethiol (HDT) self-assembled monolayers (SAMs) on Au(111) surfaces were examined by Kelvin probe method and scanning tunneling microscopy. It was found that surface potential strongly depends on surface structure of HDT SAMs. The surface potential shift for the striped phase of HDT SAMs chemisorbed on Au(111) surface was +0.45 eV, which was nearly the same as that of the flat-lying hexadecane layer physisorbed on Au(111) surface. This result indicates that the interfacial dipole layer induced by adsorption of alkyl chains is a main contributor to the surface potential change. In the densely-packed HDT monolayer, further change of the surface potential was observed, suggesting that the dipole moment of the alkanethiol molecules is an origin of the surface potential change. These results indicate that the work function of a metal electrode can be modified by controlling the molecular orientation of an adsorbed molecule.

Percolation threshold and piezoresistive response of multi-wall carbon nanotube/cement composites

  • Nam, I.W.;Souri, H.;Lee, H.K.
    • Smart Structures and Systems
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    • v.18 no.2
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    • pp.217-231
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    • 2016
  • The present work aims to develop piezoresistive sensors of excellent piezoresistive response attributable to change in nanoscale structures of multi-wall carbon nanotube (MWNT) embedded in cement. MWNT was distributed in a cement matrix by means of polymer wrapping method in tandem with the ultrasonication process. DC conductivity of the prepared samples exhibited the electrical percolation behavior and therefore the dispersion method adopted in this study was deemed effective. The integrity of piezoresistive response of the sensors was assessed in terms of stability, the maximum electrical resistance change rate, and sensitivity. A composite sensor with MWNT 0.2 wt.% showed the lowest stability and sensitivity, while the maximum electrical resistance change rate exhibited by this sample was the highest (96 %) among others and even higher than those found in the literature. This observation was presumably attributed by the percolation threshold and the tunneling effect. As a result of the MWNT content (0.2 wt.%) of the sensor being near the percolation threshold (0.25 wt.%), MWNTs were close to each other to trigger tunneling in response of external loading. The sensor with MWNT 0.2 wt.% was able to maintain the repeatable sensing capability while sustaining a vehicular loading on road, demonstrating the feasibility in traffic flow sensing application.

The pedicled anterolateral thigh flap for trochanteric pressure sore reconstruction: Technical notes to optimize surgical outcomes

  • Hifny, Mahmoud A.
    • Archives of Plastic Surgery
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    • v.48 no.1
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    • pp.114-120
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    • 2021
  • Background The pedicled anterolateral thigh (ALT) flap has become more popular for the reconstruction of soft-tissue defects in neighboring areas. Nonetheless, few studies in the literature have explored the use of this flap for trochanteric ulcer reconstruction. The aim of our study is to present the author's experience of utilizing the ALT flap, with a focus on technical elements regarding the flap design and the tunneling method to maximize the reach of the flap. Methods The medical records of patients who received pedicled ALT flaps for the reconstruction of trochanteric pressure sores were retrospectively reviewed. The patients' demographic data, operative details, and postoperative complications were evaluated. Results Between October 2018 and December 2019, 10 consecutive patients (age range, 13-45 years) underwent 11 pedicled ALT myocutaneous flaps for trochanteric pressure sore reconstruction. Each flap was designed around the most distal cutaneous perforator that was included in the proximal third of the skin paddle. The flaps ranged in size from 11×6 to 14×8 cm. The ALT flap was transposed through a lateral subcutaneous tunnel in five patients, while the open tunnel technique was used in six patients. All flaps survived, and no vascular compromise was observed. Conclusions The pedicled ALT flap is a safe and reliable option for reconstructing trochanteric pressure sores. An appropriate flap design and a good choice of the tunneling method are crucial for successful flap transposition.