• Title/Summary/Keyword: transport and diffusion

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Applicability of hiding-exposure effect to suspension simulation of fine sand bed (가는 모래의 부유 모의시 차폐효과 고려의 영향)

  • Byun, Jisun;Son, Minwoo
    • Journal of Korea Water Resources Association
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    • v.54 no.8
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    • pp.607-616
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    • 2021
  • The purpose of this study is to simulate the transport of nonuniform sediment considering the hiding-exposure effect numerically. In order to calculate the transport of multi-disperse suspended sediment mixtures, the set of advection-diffusion equations for each particle class is solved. The applicability of the numerical model is examined by comparing the simulation results with experimental data. In this study, we calculate the vertical distribution of total concentration of sediment particles using two approaches: (1) by considering the mixture as represented by a single size; and (2) by combining the concentration of the sediment corresponding to several particle size classes; From the simulation results, it is shown that both approaches calculate reasonable results due to the narrow range of size distribution. Under the condition of nonuniform sediment, the critical shear stress of the sediment particle is influenced by the size-selective entrainment, i.e., hiding-exposure effect. It is shown in this study that the effect of hiding-exposure effect on the erosion rates of fine sand is negligibly small.

Uncertainty Analysis of the Net Flow Discharge and Diffusion Model in Gyeonggi Bay and Han River Estuary (경기만 및 한강하구의 순유량 및 확산모형의 불확실성 분석)

  • Kim, Jeong-Dae;Jeong, Shin-Taek;Cho, Hong-Yeon;Kim, Tae-Heon
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.22 no.5
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    • pp.344-351
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    • 2010
  • Uncertainty analysis on the net flow discharge (NFD) influencing the long-term material transport and the simulation results of the salinity and COD concentration distribution using the MIKE21 diffusion model in Gyeonggi bay and Han-River estuary is carried out. The NFD flowing the Gyodongdo - Seokmodo channel via the North channel of Ganghwado is estimated about 97% of the total NFD and the NFD of the Yeomha channel is estimated as only $2.5{\sim}3.0%$. On the other hand, the uncertainty defined as the difference by the different time-scale data input is analysed by the comparison of the model simulation result of the salinity and COD concentration distribution. One is computed based on the daily river flow data, and the other is computed based on the monthlymean river flow data. The results show that the salinity and COD concentration differences are about -10~20 psu and ${\pm}1.0\;mg/L$ during the summer season having a high flow discharge in Yeomha channel, respectively. The difference is clearly negligible in the open sea area.

TRANSPORT AND DIFFUSION OF POLLUTANTS IN THE COASTAL WATERS OF ONSAN INDUSTRIAL COMPLEX (온산공단 부근의 해양오염물질 이동)

  • CHANG Sun-duck;LEE Jong-Sub;HAN Kyeong-Hwa
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.13 no.4
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    • pp.151-162
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    • 1980
  • To clarify the dispersion of pollutants introduced in the coastal region, a series of current measurements, the drogue and drift bottle experiments as well as the dye diffusion experiments were carried out in Onsan Bay and in the coastal waters of Ubong-ri near Ulsan. In the southeastern coastal region of Korean peninsula, that is, in the outside of Onsan Bay, the flood tidal current flows south-south-westward, and the ebb current flows north-north-eastward at a maximum speed of 1.0-1.1 knots at spring tide. In an inlet south of Cape Ubong, an anticyclonic eddy of 1 km in diameter is usually formed during both flood and ebb flows. The tidal current predominates in Onsan Bay at around spring tide. The maximum speed around spring tide was observed to be approximately 0.14 knot, while it was slower than 0.1 knot and variable at neap tide when the wind drift current played an important role. The flood tidal current flows westward while the ebb flow flows eastward in the northern region of the bay. The flood tidal current in the southern region of the bay flows west-north-westward, while the ebb current east-north-eastward. Wind drift currents in the coastal region of southern Korea are generally deduced to be southward in winter, the monthly mean speed being approximately 0.1 knot. Dye solution released at the northwestern corner in Onsan Bay was transported by eastward ebb tidal current toward the mouth of the bay dispersing by the wind. The apparent diffusion coefficient at 150 minutes after release in the bay was calculated to be $4.4\times10^4\;cm^2.sec^{-1}$, whereas that in the anticyclonic eddy was more or less smaller.

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First flush modeling of the radial type surface runoff and a placement strategy for stormwater inlets to improve the effectiveness of the first flush treatment in a small impervious catchment (방사형 강우 유출의 초기세척 모의 및 소규모 불투수 배수구역에서의 초기우수 처리효과 상승을 위한 집수시설 배치 방안)

  • Kang, Joo-Hyon;Lee, Dong Hoon;Kim, Jin Hwi
    • Journal of Wetlands Research
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    • v.19 no.4
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    • pp.375-382
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    • 2017
  • In this study, general characteristics of dynamic behavior of stormwater runoff from a small impervious catchment was investigated from a series of simulations for a radial type surface runoff. Based on the simulation results, a better placement strategy for stormwater inlets to improve performance of a structural best management practice (BMP) was suggested. The degree of pollutant first flush from an ideal radial type impervious catchment was simulated using a 1-D diffusion wave equation coupled with a pollutant transport equation. The results showed that the first flush of the chemical oxygen demand was the strongest when the catchment length ranged 30-50m at a bed slope of 0.02. This result suggested that a required degree of the first flush can be intentionally obtained by just changing the locations and numbers of stormwater inlets, and thereby adjusting the catchment length. Particularly, the overall performance of a structural BMP in reducing pollutant load can be improved by placing the stormwater inlets at locations for obtaining a required first flush strength.

Synthesis and Characterization of Sulfonated Poly(arylene ether) Polyimide Multiblock Copolymers for Proton Exchange Membranes

  • Lee, Hae-Seung;Roy Abhishek;Badami Anand S.;McGrath James E.
    • Macromolecular Research
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    • v.15 no.2
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    • pp.160-166
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    • 2007
  • Novel multiblock copolymers, based on segmented sulfonated hydrophilic-hydrophobic blocks, were synthesized and investigated for their application as proton exchange membranes. A series of segmented sulfonated poly(arylene ether sulfone)-b-polyimide multiblock copolymers, with various block lengths, were synthesized via the coupling reaction between the terminal amine moieties on the hydrophilic blocks and naphthalene anhydride functionalized hydrophobic blocks. Successful imidization reactions required a mixed solvent system, comprised of NMP and m-cresol, in the presence of catalysts. Proton conductivity measurements revealed that the proton conductivity improved with increasing hydrophilic and hydrophobic block lengths. The morphological structure of the multiblock copolymers was investigated using tapping mode atomic force microscopy (TM-AFM). The AFM images of the copolymers demonstrated well-defined nanophase separated morphologies, with the changes in the block length having a pronounced effect on the phase separated morphologies of the system. The self diffusion coefficient of water, as measured by $^1H$ NMR, provided a better understanding of the transport process. Thus, the block copolymers showed higher values than Nafion, and comparable proton conductivities in liquid water, as well as under partially hydrated conditions at $80^{\circ}C$. The new materials are strong candidates for use in PEM systems.

A Numerical Model for the Freeze-Thaw Damages in Concrete Structures

  • Cho Tae-Jun
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.857-868
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    • 2005
  • This paper deals with the accumulated damage in concrete structures due to the cyclic freeze-thaw as an environmental load. The cyclic ice body nucleation and growth processes in porous systems are affected by the thermo-physical and mass transport properties, and gradients of temperature and chemical potentials. Furthermore, the diffusivity of deicing chemicals shows significantly higher value under cyclic freeze-thaw conditions. Consequently, the disintegration of concrete structures is aggravated at marine environments, higher altitudes, and northern areas. However, the properties of cyclic freeze-thaw with crack growth and diffusion of chloride ion effects are hard to be identified in tests, and there has been no analytic model for the combined degradations. The main objective is to determine the driving force and evaluate the reduced strength and stiffness by freeze-thaw. For the development of computational model of those coupled deterioration, micro-pore structure characterization, pore pressure based on the thermodynamic equilibrium, time and temperature dependent super-cooling with or without deicing salts, nonlinear-fracture constitutive relation for the evaluation of internal damage, and the effect of entrained air pores (EA) has been modeled numerically. As a result, the amount of ice volume with temperature dependent surface tensions, freezing pressure and resulting deformations, and cycle and temperature dependent pore volume has been calculated and compared with available test results. The developed computational program can be combined with DuCOM, which can calculate the early aged strength, heat of hydration, micro-pore volume, shrinkage, transportation of free water in concrete. Therefore, the developed model can be applied to evaluate those various practical degradation cases as well.

Effects of chemical reaction on the polishing rate and surface planarity in the copper CMP

  • Kim, Do-Hyun;Bae, Sun-Hyuk;Yang, Seung-Man
    • Korea-Australia Rheology Journal
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    • v.14 no.2
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    • pp.63-70
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    • 2002
  • Chemical mechanical planarization (CMP) is the polishing process enabled by both chemical and mechanical actions. CMP is used in the fabrication process of the integrated circuits to achieve adequate planarity necessary for stringent photolithography depth of focus requirements. And recently copper is preferred in the metallization process because of its low resistivity. We have studied the effects of chemical reaction on the polishing rate and surface planarity in copper CMP by means of numerical simulation solving Navier-Stokes equation and copper diffusion equation. We have performed pore-scale simulation and integrated the results over all the pores underneath the wafer surface to calculate the macroscopic material removal rate. The mechanical abrasion effect was not included in our study and we concentrated our focus on the transport phenomena occurring in a single pore. We have observed the effects of several parameters such as concentration of chemical additives, relative velocity of the wafer, slurry film thickness or ash)tract ratio of the pore on the copper removal rate and the surface planarity. We observed that when the chemical reaction was rate-limiting step, the results of simulation matched well with the experimental data.

Diffusion Coefficients in $SF_6-Ar$ Gas used by MCS-BE Algorithm (MCS-BEq 알고리즘에 의한 $SF_6-Ar$ 혼합기체의 확산계수)

  • Kim, Sang-Nam
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2006.05a
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    • pp.298-301
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    • 2006
  • This paper describes the electron energy distribution function characteristics in $SF_6-Ar$ gas calculated for range of E/N values from $50\sim700[Td]$ by the Monte Carlo simulation(MCS) and Boltzmann equation(BE) method using a set of electron collision cross sections determined by the authors and the values of electron swarm parameters are obtained by time of flight(TOF) method. In this dissertation the results of the combined experimental and theoretical studies designed to understand and predict the spatial growth and transport coefficients for electrons in $SF_6$ and $SF_6-Ar$ mixtures have described. The ionization and attachment coefficients in pure $SF_6$ and $SF_6-Ar$ mixtures have been calculated over the range of 10$SF_6$ molecule and for Ar atom proposed by other authors. The results obtained in this work will provide valuable information on the fundamental behaviors of electrons in weakly ionized gases and the role of electron attachment in the choice of better gases and unitary gas dielectrics or electro negative components in dielectric gas mixtures.

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Performance of Double Composite Landfill Liner considering Leakage Rate and Mass Flux

  • Nguyen, The Bao;Lee, Chul-Ho;Choi, Hang-Seok
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.03a
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    • pp.295-304
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    • 2010
  • Performance of a landfill liner is evaluated based on leakage rate and mass flux. In this study, the recently utilized double composite liner system, which consists of a geomembrane (GM), a geosynthetic clay liner (GCL), a GM, and a compacted clay layer (61 or 91.5 cm) is compared with other popular composite liners including the single GCL system, the Subtitle D liner system, and the Wisconsin NR500 liner system. The leakage rate through circular and long defects in the GM of the landfill liners is analyzed using numerical models. For the mass flux criterion, the analyses of inorganic contaminant transport through defects in the GM component of liner systems and diffusion of organic compounds through intact landfill liners are conducted using three- and one-dimensional numerical models, respectively. Cadmium and toluene are used in the analyses as a typical inorganic and organic substance, respectively, which will be chemical species encountered during landfill operation. The comparison shows that the double composite liner systems are superior to the other liner systems according to the performance-based evaluation.

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Particle deposition on a semiconductor wafer larger than 100 mm with electrostatic effect (정전효과가 있는 100mm보다 큰 반도체 웨이퍼로의 입자침착)

  • Song, Gen-Soo;Yoo, Kyung-Hoon;Lee, Kun-Hyung
    • Particle and aerosol research
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    • v.5 no.1
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    • pp.17-27
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    • 2009
  • Particle deposition on a semiconductor wafer larger than 100 mm was studied experimentally and numerically. Particularly the electrostatic effect on particle deposition velocity was investigated. The experimental apparatus consisted of a particle generation system, a particle deposition chamber and a wafer surface scanner. Experimental data of particle deposition velocity were obtained for a semiconductor wafer of 200 mm diameter with the applied voltage of 5,000 V and PSL particles of the sizes between 83 and 495 nm. The experimental data of particle deposition velocity were compared with the present numerical results and the existing experimental data for a 100 mm wafer by Ye et al. (1991) and Opiolka et al. (1994). The present numerical method took into consideration the particle transport mechanisms of convection, Brownian diffusion, gravitational settling and electrostatic attraction in an Eulerian frame of reference. Based on the comparison of the present experimental and numerical results with the existing experimental results the present experimental method for a 200 mm semiconductor wafer was found to be able to present reasonable data.

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