• 제목/요약/키워드: transport and diffusion

검색결과 732건 처리시간 0.024초

부분 도핑을 이용한 청색 인광 OLEDs의 전기 및 광학적 특성 (Electrical and Optical Properties of Partially Doped Blue Phosphorescent OLEOs)

  • 서유석;문대규
    • 한국전기전자재료학회논문지
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    • 제22권6호
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    • pp.512-515
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    • 2009
  • We have fabricated blue phosphorescent organic light emitting diodes (PHOLEDs) using a 3,5'-N,N'-dicarbazole-benzene (mCP) host and iridium (III) bis[(4,6-difluorophenyl)-pyridinato-N,$C^{2'}$] picolinate (Flrpic) guest materials, The Flrpic was partially doped into the mCP host layer, for investigating recombination zone, current efficiency, and emission characteristics of the blue PHOLEDs. The recombination of electrons and holes takes place inside the mCP layer adjacent to the mCP/hole blocking layer interface. The best current efficiency was obtained in a device with an emission layer structure of mCP (10 nm)/mCP:Flrpic (20 nm, 10%). The high current efficiency in this device was attributed to the confinement of Ffrpic triplet excitons by the undoped mCP layer with high triplet energy, which blocks diffusion of Ffrpic excitons to the adjacent hole transport layer with a lower triplet energy.

A Conceptual Two-Layer Model of Thermohaline Circulation in a Pie-Shaped $\beta$-Plane Basin

  • Park, Young-Gyu
    • Journal of the korean society of oceanography
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    • 제38권1호
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    • pp.11-16
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    • 2003
  • The three dimensional structure of thermohaline circulation in a D-plane is investigated using a conceptual two layer model and a scaling argument. In this simple model, the water mass formation region is excluded. The upper layer represents the oceans above the main thermocline. The lower layer represents the deep ocean below the thermocline and is much thicker than the upper layer. In each layer, geostrophy and the linear vorticity balance are assumed. The cross interfacial velocity that compensates for the deep water mass formation balances downward heat diffusion from the top. From the above relations, we can determine the thickness of the upper layer, which is the same as thermocline depth. The results we get is basically the same as that we get for an f-plane ocean or the classical thermocline theory. Mass budget using the velocity scales from the scaling argument shows that western boundary and interior transports are much larger than the net meridional transport. Therefore in the thermohaline circulation, horizontal circulation is much stronger than the vertical circulation occuring on a meridional plane.

유동에 의한 연층 확산에 관한 실험적 연구 (An experimental study of convective smoke filling)

  • 김명배;한용식
    • 한국화재소방학회논문지
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    • 제11권3호
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    • pp.3-14
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    • 1997
  • An experimental investigation of smoke spread in a corridor is made using thermocouples and visualization technique with a laser beam sheet. A speed of smoke front under a ceiling is measured by thermocouple trees. Visualization of the ceiling jet formation and of smoke filling process is carried out to observe lowering of the smoke layer. From the results, a large-scale convective motion the corridor plays dominant roles for smoke spread from visualized photos together with temperature records. A circulating motion of fluid transports some smokes to some regions where its momentum is effective. It is therefore showed that the conventional concept of lowering smoke with two-layer zone model has some restrictions for the corridor because the lowering of smoke layer has been thought to be mass transport due to relatively small scale motion such as decrease of buoyancy, mass diffusion and momentum exchange.

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Determination of the Convective and Diffusive Fluxes from the Transient Profiles of Solute and Solvent under Evaporation Experiment

  • Wei, Dai;Lee, Sunhoon;Yu, Amemiya
    • 환경영향평가
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    • 제11권3호
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    • pp.173-187
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    • 2002
  • 토양 속에서 발생될 수 있는 용질과 용매의 복합 수송시스템을 대상으로 한 연구 중 회석상태로부터 포화상태에 이르기까지의 넓은 농도분포를 가지는 토양 용액에 적용될 수 있는 물리 화학적 이론에 입각한 지배방정식을 발표한 연구는 전무한 실정이다. 본 연구는 용매와 토양기체간 그리고 용질과 결정간의 상변화를 고려한 연립물질수지방정식을 제시하고, 여기에 타율적 대류를 포함하는 상호확산 분산수송방정식을 도입하여 대류와 확산에 관한 프럭스를 분리, 결정하는 것을 목적으로 한다. 대류 플럭스의 결정은 타율적으로 이루어지는 것이 이론적으로 타당하며, 이러한 타율적 대류 플럭스가 제공된다면 본 연구에서 제시된 지배방정식을 이용해서 토양용액의 복합수송 시스템을 범용적으로 해석, 예측할 수 있을 것으로 판단된다.

LIF Conforcal Microscope을 이용한 Y-channel 마이크로믹서의 최적설계 연구 (The Study of Optimum Design of Y-Channel Micro-Mixer by Using LIF Conforcal Microscope)

  • 김상우;현석호;신태석;이도형
    • 대한기계학회논문집B
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    • 제33권5호
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    • pp.311-317
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    • 2009
  • Due to extremely small device size and velocity scale, mixing in microchannel take place very slowly by way of molecular diffusion transport. Mixing enhancement becomes a central issue in microfluidics for biomedical and chemical applications. In this work, The optimization results and validation through experiment and fabrication. In this efficient micromixer design, it is essential to evaluate mixing efficiency with good precision. Mixing efficiency for Y-channel micromixer is measured by fluorescence intensity using LIF(Laser Induced Fluorescence) Confocal Microscope. The Y-channel micromixers are fabricated with polydimethylsiloxane(PDMS). Nile Blue A is injected into the micromixer as a fluorescence dye for measuring of fluorescence intensity by He/Ne laser. Throughout the experiments and computer simulation, accurate mixing efficiency evaluation process for a PDMS Y-channel micromixer is established.

Combustion Characteristics of Hydrogen by the Thermodynamic Properties Analysis

  • Han, Sung Bin
    • 에너지공학
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    • 제24권2호
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    • pp.84-90
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    • 2015
  • Hydrogen has some remarkably high values of the key properties for transport processes, such as kinematic viscosity, thermal conductivity and diffusion coefficient. Hydrogen, as an energy medium, has some distinct benefits for its high efficiency and convenience in storage, transportation and conversion. Hydrogen has much wider limits of flammability in air than methane, propane or gasoline and the minimum ignition energy is about an order of magnitude lower than for other combustibles. Statistical thermodynamics provides the relationships that we need in order to bridge this gap between the macro and the micro. Our most important application will involve the calculation of the thermodynamic properties of the ideal gas.

Spin Valve Effect in Lateral Py/Au/Py Devices

  • Ku, Jang-Hae;Chang, Joon-Yeon;Koo, Hyun-Cheol;Eom, Jong-Hwa;Han, Suk-Hee;Kim, Gyu-Tae
    • Journal of Magnetics
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    • 제12권4호
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    • pp.152-155
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    • 2007
  • Spin dependent transport was investigated in lateral $Py(Ni_{81}Fe_{19})/Au/Py$ spin valve devices. Clear spin valve effect was observed in conventional four-terminal measurement geometry. Higher resistance was found in antiparallel magnetization field of two Py electrodes which is determined by anisotropy magnetoresistance (AMR) measurements. The rectangular shape of spin signal together with good agreement of switching field convinces observed spin valve signal is resulted from effective spin injection and detection. The magnetoresistance ratio decays exponentially with channel length by which spin diffusion length of Au channel was estimated to be 76 nm.

Optimization of Vane Diffuser in a Mixed-Flow Pump for High Efficiency Design

  • Kim, Jin-Hyuk;Kim, Kwang-Yong
    • International Journal of Fluid Machinery and Systems
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    • 제4권1호
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    • pp.172-178
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    • 2011
  • This paper presents an optimization procedure for high-efficiency design of a mixed-flow pump. Optimization techniques based on a weighted-average surrogate model are used to optimize a vane diffuser of a mixed-flow pump. Validation of the numerical results is performed through experimental data for head, power and efficiency. Three-level full factorial design is used to generate nine design points within the design space. Three-dimensional Reynoldsaveraged Navier-Stokes equations with the shear stress transport turbulence model are discretized by using finite volume approximation and solved on hexahedral grids to evaluate the efficiency as the objective function. In order to reduce pressure loss in the vane diffuser, two variables defining the straight vane length ratio and the diffusion area ratio are selected as design variables in the present optimization. As the results of the design optimization, the efficiency at the design flow coefficient is improved by 7.05% and the off-design efficiencies are also improved in comparison with the reference design.

자동차탑재용 연료개질시스템을 위한 마이크로채널개발 (Microchannel Development for Fuel Processor of Automotive Applications)

  • 배중면
    • 한국전기화학회:학술대회논문집
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    • 한국전기화학회 2003년도 연료전지심포지움 2003논문집
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    • pp.89-95
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    • 2003
  • Fuel processing is an enabling technology for faster commercialization under lack of hydrogen infrastructures. It has been reported that the development of novel catalysts that are active and selective for hydrocarbon reforming reactions. It has been realized, however, that with pellet or conventional honeycomb catalysts, the reforming process is mass transport limited. This paper reports the development of catalyst structures with microchannels that are able to reduce the diffusion resistance and thereby achieve the same production rate within a smaller reactor bed. These microchannel reforming catalysts were prepared and tested with natural gas and gasoline-type fuels in a microreactor (1-cm dia.) at space velocities of up to 250,000 per hour. These catalysts have also been used in engineering-scale reactors (10 kWe, 7-cm dia.) with similar product qualities. Compared to pellet catalysts. the microchannel catalysts enable a nearly 5-fold reduction in catalyst weight and volume.

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Accurate Prediction Method of Breakdown Voltage in Air at Atmospheric Pressure

  • Kim, Nam-Kyung;Lee, Se-Hee;Georghiou, G.E.;Kim, Dong-Wook;Kim, Dong-Hun
    • Journal of Electrical Engineering and Technology
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    • 제7권1호
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    • pp.97-102
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    • 2012
  • To predict accurately the breakdown voltage in air at atmospheric pressure, a fully coupled finite element analysis combining the hydrodynamic diffusion-drift equations with Poisson's equation is proposed in the current paper. As three kinds of charged transport particles are nonlinearly coupled with spatial electric fields, the equations should be solved by an iterative numerical scheme, in which secondary effects, such as photoemission and photoionization, are considered. The proposed method has been successfully applied to evaluate the breakdown voltage in circular parallel-plane electrodes. Its validity has been proved through the comparison of the predicted and experimental results. The effects of numerical conditions of the initial charge, photoemission, and background ionization on the discharge phenomena are quantitatively assessed through Taguchi's design of experiment method.