• Title/Summary/Keyword: transport and diffusion

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Hydrogen Separation from Binary and Quaternary Gas Mixtures Using Organic Templating Silica Membrane (유기템플레이팅 실리카막을 이용한 이성분 및 사성분 수소 분리)

  • Moon, Jong-Ho;Bae, Ji-Han;Chung, Jong-Tae;Lee, Jae-Wook;Lee, Chang-Ha
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.9-12
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    • 2007
  • The transport mechanisms of the MTES (methyltriethoxysilane) templating silica/a-alumina composite membrane were evaluated by using four binary and one quaternary hydrogen mixtures through permeation experiments at unsteady- and steady-states. Since the permeation flux in the MTES membrane, through the experimental and theoretical studies, was affected by molecular sieving effects as well as surface diffusion properties, the kinetic and equilibrium separation should be considered simultaneously according to molecular properties. In order to depict the transient multi-component permeation on the templating silica membrane, the GMS (generalized Maxwell-Stefan) and DGM (dust gas model) were adapted to unsteady-state material balance.

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Hydrogen Separation by Compact-type Silica Membrane Process (컴팩트 타입 실리카막 공정을 이용한 수소 분리)

  • Moon, Jong-Ho;Bae, Ji-Han;Lee, Sang-Jin;Chung, Jong-Tae;Lee, Chang-Ha
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.336-339
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    • 2006
  • With the steady depletion off fossil fuel reserves, hydrogen based energy sources become increasingly attractive. Therefore hydrogen production or separation technologies, such as Bas separation membrane based on adsorption technology, have received enormous attention in the industrial and academic fields. In this study, the transport mechanisms of the MTES (methyltriethoxysilane) templating silica/a-alumina composite membrane were evaluated by using unary, binary and quaternary hydrogen gas mixtures permeation experiments at unsteady- and steady-states. Since the permeation flux in the MTES membrane, through the experimental and theoretical study, was affected by molecular sieving effects as well as surface diffusion properties, the kinetic and equilibrium separation should be considered simultaneously in the membrane according to molecular properties. In order to depict the transient multi-component permeation on the templating silica membrane, the GMS (generalized Maxwell-Stefan) and DGM (dust Bas model) were adapted to unsteady-state material balance

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Electron Swarm Drift Velocity and Characteristic Energy in e$^{[-10]}$ -CF$_4$Scattering (e ̄-CF$_4$산란의 전자이동속도 및 특성에너지 연구)

  • 임상원;유회영;김상남;하성철
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.169-174
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    • 1996
  • In this paper, the electron transport characteristic in CF$_4$has been analysed over the E/N range 1~300(Td) by a two-term approximation Boltzmann equation method and by a Monte Carlo simulation. The alteration of cross sections from the literature is avoided as much as possible in the analysis. The motion has been calculated to give swarm parameters for the electron drift velocity(W), diffusion coefficient(D$_{L}$), the ratio of the diffusion coefficient to the mobility(D$_{L}$/$\mu$), mean energy($\varepsilon$), the electron energy distribution function. The electron energy distribution function has been analysed in CF$_4$at E/N=50, 100 and 200(Td) for a case of the equilibrium region in the mean electron energy. The results of Boltzmann equation and Monte Carlo simulation have been compared with experimental data by Y. Nakamura and M. Hayashi.shi.

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Partitioning and Diffusion Properties of Hydrogen Gases In Porous Membranes Using the Nonoverlapping Sphere Model (비겹침 구형 모델을 이용한 세공 박막 내 수소 기체의 분산 및 확산 특성)

  • Suh, Soong-Hyuck;Ha, Ki-Ryong
    • Journal of Hydrogen and New Energy
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    • v.9 no.3
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    • pp.119-125
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    • 1998
  • The modified statistical-mechanical theory for dense fluid mixtures of rigid spheres has been applied to rigid sphere fluids in the nonoverlapping pore model. The resulting expressions for the partition coefficient and diffusivity illustrate the influence of steric hindrance on the thermodynamic and transport properties in such systems. The open membrane model without the size-exclusion and shielding effects shows considerable overestimation of the diffusion flux when the effective mean pore radii of the order of $20{\AA}$ or less are involved. Theoretical predictions investigated here were also compared with experimental data for hydrogen gases in inorganic porous membranes and it was observed a qualitative agreement in the low pressure limit.

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The Characteristics of Turbulent Diffusion Flame Impinging on the Wall (벽면 충돌 난류 확산화염의 특성)

  • Park, Yong Youl;Kim, Ho Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.2
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    • pp.175-184
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    • 1999
  • A theoretical study on the turbulent round jet diffusion flame impinging on the wall was carried out to predict the characteristics and structure of Impinging jet flame and heat transfer to the wall. Finite chemistry via Arrhenius equation and eddy dissipation model was adopted as a combustion model, and the Favre averaging and $k-{\varepsilon}$ model were Introduced In the theoretical modeling. The SIMPLE algorithm was applied to the calculation. All the transport properties were considered as the variable depending on the temperature and composition. For the parametric study, the distance from nozzle to impinging wall and Reynolds number at nozzle exit were chosen 88 the major parameters. As the results of the present study, the characteristics of flow fields, the distributions of main variables and each chemical species and the flame shapes were obtained. The heat transfer rate from the flame to the wall and the effective heating area were calculated to investigate the Influences of the major parameters on the heat transfer characteristics.

Gamma-Ray and Neutrino Emissions from Starburst Galaxies

  • Ha, Ji-Hoon;Ryu, Dongsu;Kang, Hyesung
    • The Bulletin of The Korean Astronomical Society
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    • v.45 no.1
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    • pp.37.1-37.1
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    • 2020
  • Cosmic-ray protons (CRp) are efficiently produced at starburst galaxies (SBGs), where the star formation rate (SFR) rate is high. In this talk, we present estimates of gamma-ray and neutrino emissions from nearby SBGs, M82, NGC253, and Arp220. Inside the starburst nucleus (SBN), CRp are accelerated at supernova remnant (SNR) shocks as well as at stellar wind (SW) termination shocks, and their transport is governed by the advection due to starburst-driven wind and diffusion mediated by turbulence. We here model the momentum distributions of SNR and SW-produced CRp with single or a double power-law forms. We also employ two different diffusion models, where CRp are resonantly scattered off large-scale turbulence in SBN or self-excited waves driven by CR streaming instability. We then calculate gamma-ray/neutrino fluxes. The observed gamma-ray fluxes by Fermi-LAT, Veritas, and H.E.S.S are well reproduced with double power-law distribution for SNR-produced CRp and the CRp diffusion by self-excited turbulence. The estimated neutrino fluxes are <~10-3 of the atmospheric neutrino flux in the energy range of Eneutrino <~100 GeV and <~10-1 of the IceCube point source sensitivity in the energy range of Eneutrino >~60 TeV.

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Characteristics of Electron Transport in $SiH_4$ Gas used by MCS-BEq Algorithm (MCS-BEq 알고리즘에 의한 $SiH_4$ 기체의 전자수송특성)

  • Kim, Sang-Nam;Seong, Nak-Jin
    • Proceedings of the KIEE Conference
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    • 2006.10b
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    • pp.159-162
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    • 2006
  • In this paper energy distribution function in $SiH_4$ has been analysed over the E/N range 0.5${\sim}$300Td and Pressure value 0.5, 1.0, 2.5 Torr by a two-term approximation Boltzmann equation method and by a Monte Carlo simulation. The motion has been calculated to give swarm parameters for the electron drift velocity, diffusion coefficient, electron ionization, mean energy and the electron energy distribution function. The electron energy distribution function has been analysed in $SiH_4$ at E/N=30, 50Td for a case of the equilibrium region in the mean electron energy and respective set of electron collision cross sections. The results show that the deduced electron drift velocities, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients and mean energy agree reasonably well with theoretical for a rang of E/N values.

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A study on the electron energy diffusion function of the sulphur hexaflouride ($SF_6$ 가스의 전자에너지 분포함수에 관한 연구)

  • 김상남;유회영;서상현;박동화;하성철
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 1996.11a
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    • pp.134-139
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    • 1996
  • The electron energy distributions function were analysed in sulphur hexaflouride at E/N : 500~800(Td) for a case of non-equilibrium ion in the mean electron energy. This paper describes the electron transport characteristics in SF$_{6}$ gas calculated for range of E/N values from 150~800(Td) by the Monte Carlo simulation and Boltzmann equation method using a set of electron collision cross sections determined by the authors and the values of electron swarm parameters. The results gained that the value of an electron swarm parameter such as the electron drift velocity, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients agree with the experimental and theoretical for a range of E/N. The properties of electron avalanches in an electron energy non-equilibrium region.n.

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A Design Evaluation of Strained Si-SiGe on Insulator (SSOI) Based Sub-50 nm nMOSFETs

  • Nawaz, Muhammad;Ostling, Mikael
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.5 no.2
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    • pp.136-147
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    • 2005
  • A theoretical design evaluation based on a hydrodynamic transport simulation of strained Si-SiGe on insulator (SSOI) type nMOSFETs is reported. Although, the net performance improvement is quite limited by the short channel effects, simulation results clearly show that the strained Si-SiGe type nMOSFETs are well-suited for gate lengths down to 20 nm. Simulation results show that the improvement in the transconductance with decreasing gate length is limited by the long-range Coulomb scattering. An influence of lateral and vertical diffusion of shallow dopants in the source/drain extension regions on the device performance (i.e., threshold voltage shift, subthreshold slope, current drivability and transconductance) is quantitatively assessed. An optimum layer thickness ($t_{si}$ of 5 and $t_{sg}$ of 10 nm) with shallow Junction depth (5-10 nm) and controlled lateral diffusion with steep doping gradient is needed to realize the sub-50 nm gate strained Si-SiGe type nMOSFETs.

A Study on the Microbial Contaminant Transport and Control Method According to Government Building Bio- Attack (청사 건물의 Bio-Attack에 따른 미생물 오염원 확산 및 제어방안에 관한 연구)

  • Lee, Hyun-Woo;Choi, Sang-Gon;Hong, Jin-Kwan
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.20 no.4
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    • pp.252-259
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    • 2008
  • The purpose of this study is to estimate the movement of microbial contaminant caused by bio-attack using bio-agent such as bacillus anthracis for preventing contaminant diffusion. multizone simulation was carried out in the case of three types of bio-attack scenario in the government building. Simulation results show that severe contaminant diffusion is brought about in all cases of bio-attack scenario in one hour, though pollution boundaries have different mode according to bio-attack scenarios. Simulation results also show that immune building technology such as filter and UVGI technology gives us powerful alternatives to meet the emergent situation caused by unexpected bio-attack.