• 한국전기전자재료학회논문지
• /
• 제31권6호
• /
• pp.408-411
• /
• 2018

We fabricated highly flexible Mn-doped $SnO_2$ (MTO)/Ag/MTO/polydimethylsiloxane (PDMS)/MTO multilayer transparent conducting films. To reduce refractive-index mismatching of the MTO/Ag/MTO/polyethylene terephthalate (PET), index-matching layers were inserted between the oxide-metal-oxide-structured films and the PET substrate. The PDMS layer was deposited by spin-coating after adjusting the mixing ratio of PDMS and hexane. We investigated the effects of the index-matching layer on the color and reflectance differences with different PDMS dilution ratios. As the dilution ratio increased from 1:100 to 1:130, the color difference increased slightly, while the reflectance difference decreased from 0.62 to 0.32. The MTO/Ag/MTO/PDMS/MTO film showed a transmittance of 87.18~87.68% at 550 nm. The highest value of the Haacke figure of merit was $47.54{\times}10^{-3}{\Omega}^{-1}$ for the dilution ratio of 1:130.

• 한국안광학회지
• /
• 제20권4호
• /
• pp.471-476
• /
• 2015

목적: 다양한 안경렌즈의 투과율 분포를 국소 투과율 현미경을 이용하여 분석함으로써 렌즈의 광학적 균일성을 연구하고자 한다. 방법: 안경렌즈 표면에 집광된 레이저의 국소적 투과율을 광검출기, 락인앰프 그리고 전동이송장치로 측정하였다. 5종 25장의 멀티코팅된 무착색렌즈와 9종 45장의 멀티코팅된 착색렌즈가 시료로서 분석되었다. 결과: 굴절률과 코팅 종류에 따른 무착색렌즈의 투과율과 렌즈별 투과율 편차는 거의 균일하게 측정되었다. 하지만 착색렌즈의 경우 렌즈별 투과율 편차가 무착색렌즈에 비해 약 3.7배 크게 측정되었다. 또한 렌즈의 국소적 투과율 불균일도도 무착색렌즈에 비해 착색렌즈가 평균 약 3.1배 큰 것으로 분석되었다. 결론: 무착색렌즈에 비해 착색렌즈가 렌즈별 투과율의 편차와 투과율 불균일도가 모두 큰 것을 국소 투과율 현미경을 이용하여 분석할 수 있었다. 국소 투과율 현미경을 통한 이러한 분석은 렌즈의 성능 평가와 광학적 균일성 향상에 적용될 수 있다.

• 대한화학회지
• /
• 제60권4호
• /
• pp.261-266
• /
• 2016

The major physical characteristics of macromolecules used in silicone hydrogel ophthalmic lenses include optical transmittance, oxygen permeability, water content, and refractive index. For the preparation of highly functional silicone hydrogel lens materials, two silicone monomers were used in the presence of 2-hydroxyethyl methacrylate (HEMA) and hydroxypropyl methacrylate (HPMA). The samples containing HEMA and HPMA had oxygen transmissibility (Dk) values in the range of 73.38–50.98 × 10^-11 (cm²/s) (mLO₂/mL×mmHg) and 71.94–42.80 × 10^-11 (cm²/s) (mLO₂/mL×mmHg), respectively. Furthermore, the water contents of samples containing HEMA and HPMA were in the range of 32.73–34.67% and 31.94–33.74%, respectively, and the refractive indices were in the range of 1.4348–1.4364 and 1.4385–1.4407, respectively. Thus, silicone monomers containing HEMA and HPMA are expected to be useful for fabricating high-oxygen-permeability silicon hydrogel ophthalmic lenses.

• 한국표면공학회지
• /
• 제52권4호
• /
• pp.211-226
• /
• 2019

Optical thin films were deposited by using a reactive pulsed DC magnetron sputtering method with a high density plasma(HDP). In this study, the effect of sputtering process conditions on the microstructure and optical properties of $SiO_2$, $TiO_2$, $Nb_2O_5$ thin films was clarified. These thin films had flat and dense microstructure, stable stoichiometric composition at the optimal conditions of low working pressure, high pulsed DC power and RF power(HDP). Also, the refractive index of the $SiO_2$ thin films was almost constant, but the refractive indices of $TiO_2$ and $Nb_2O_5$ thin films were changed depending on the microstructure of these films. Antireflection films of $Air/SiO_2/Nb_2O_5/SiO_2/Nb_2O_5/SiO_2/Nb_2O_5/Glass$ structure designed by Macleod program were manufactured by our developed sputtering system. Transmittance and reflectance of the manufactured multilayer films showed outstanding value with the level of 95% and 0.3%, respectively, and also had excellent durability.

• 한국재료학회지
• /
• 제32권12호
• /
• pp.560-564
• /
• 2022

In this study, lanthanum boron silicate glasses were prepared with a composition of x Li₂O-(60-x)B₂O₃-5CaO-5BaO-7ZnO-10SiO₂-10La₂O₃-3Y₂O₃ where x = 1,3,5,7, and 9 mol%. Each composition was melted in a platinum crucible under atmospheric conditions at 1,400 ℃ for 2 h. Clear glasses with a transmittance exceeding 85 % were fabricated. Their optical, thermal, and physical properties, such as refractive index, Abbe number, density, glass transition (T_g) and Knoop hardness were studied. The results demonstrated that refractive index was between 1.6859 and 1.6953 at 589.3 nm. The Abbe number was calculated using an equation for 589.3 nm (nd), 656.3 nm (nf) and 486.1 nm (nc) and was observed to be in the range from 57.5 to 62.6. As the Li₂O content increased, the glass transition temperature of the optical glass decreased from 608 ℃ to 564 ℃. If glass mold pressing is performed using a material with a low transition temperature and high mechanical strength, then the optical glasses developed in this study can be completely commercialized.

• 한국군사과학기술학회지
• /
• 제17권5호
• /
• pp.672-679
• /
• 2014

To improve sensing capability of infrared, heat-resistance and mechanical properties, the $SiO_2$ and $TiO_2$ anti-reflective layers were coated on sapphire substrate by MOCVD. The standard wavelength was 4,600nm, and the thickness of anti-reflective layers were 379 and 758nm in case of ${\lambda}/4$ and ${\lambda}/2$ of incident angle($65^{\circ}$), respectively. The $SiO_2$ and $TiO_2$ anti-reflective layers were coated 12.6 and 9.7nm/min of deposition rates by increasing oxygen pressure to set the ideal refractive index of 1.283. In case of $SiO_2({\lambda}/2)$ coating, the transmittance increased from 55.0 to 62.7%. The transmittance of $TiO_2({\lambda}/2)$ anti-reflective layer also increased from 55.0 to 64.8%. The flexural strength of $SiO_2({\lambda}/2)$ and $TiO_2({\lambda}/2)$ layer coated sapphire increased from 337.8 to 362.9 and 371.8MPa, respectively. The flexural strength at $500^{\circ}C$ of these materials also increased respectively to 304.5, 358.2MPa from 265.9MPa. From these results, we confirmed these materials can be used as transmission window of infrared light.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
• /
• pp.167.2-167.2
• /
• 2016

태양에너지는 전자기파로써 파장에 따라 여러 부분으로 나뉜다. 파장이 780nm 이상인 부분의 영역을 IR (infra Red) 즉 적외선으로 불린다. 이 부분이 열선에 해당하는 부분인데 대부분의 창문에 설치된 커튼이나 vertical 등은 빛을 차단하는 수단일 뿐, 유입되는 열 (적외선)을 차단시킬 수는 없다. 열은 결국 실내의 온도를 높이기 때문에 난방비 등 에너지 손실을 막긴 어렵다. 단열필름은 커튼이나 vertical과 달리 실내로 유입되는 열 (적외선)을 다시 실외로 반사시켜 실내로 유입되는 열을 최소화 한다. 본 연구는 IR 차폐를 목적으로 연구 되었고, 거기서 한 발 나아가 실내 분위기 등을 고려하여 소비자의 구호에 맞는 제품에 더 맞추기 위해 연구되었다. 기존 제품들과 차별된 점은 색상을 위한 추가적인 작업없이 굴절률과 두께 factor 등을 변화시켜 바로 7가지 색을 구현한다는 장점을 가지고 있다. 따라서 가격 경쟁력에서도 우위를 점 할 수 있는 중요한 기술이라 할 수 있겠다. 박막제조 장비로는 DC pulse In-line Sputter를 사용하였으며, 굴절률과 광학적인 두께 측정을 위한 ellipsometer, 그리고 UV-vis 를 통한 Transmittance 측정으로 제품 능력을 확인하였다.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2010년도 하계학술대회 논문집
• /
• pp.365-365
• /
• 2010

In this paper, silicon nitride thin films with different silane and ammonia gas ratios were deposited and characterized for the antireflection and passivation layer of high efficiency single crystalline silicon solar cells. As the flow rate of the ammonia gas increased, the refractive index decreased and the band gap increased. Consequently, the transmittance increased due to the higher band gap and the decrease of the defect states which existed for the 1.68 and 1.80 eV in the SiNx films. The reduction in the carrier lifetime of the SiNx films deposited by using a higher $NH_3/SiH_4$ flow ratio was caused by the increase of the interface traps and the defect states in/on the interface between the SiNx and the silicon wafer. The silicon and nitrogen rich films are not suitable for generating both higher carrier lifetimes and transmittance. These results indicate that the band gap and the defect states of the SiNx films should be carefully controlled in order to obtain the maximum efficiency for c-Si solar cells.

• 전기전자학회논문지
• /
• 제24권2호
• /
• pp.435-440
• /
• 2020

고주파 마그네트론 스퍼터링으로~500 nm 두께의 ZnO:Al막을 증착하였다. 증착된 ZnO:Al막을 100 ℃, 200 ℃, 300 ℃ 및 400 ℃에서 10시간 동안 열처리하였다. ZnO:Al막의 열처리에 따른 저항률, 캐리어 농도 및 이동도 변화를 측정하였다. XRD, FESEM 결과를 통해 열처리에 따른 ZnO:Al막의 저항률 변화 원인을 조사하였다. ZnO:Al막의 광 투과율을 측정한 후 에너지 밴드 갭, Urbach 에너지 및 굴절률을 도출하였다. ZnO:Al막의 전기적 특성 변화를 광특성과 연관지어 설명하였다.

• 한국재료학회지
• /
• 제28권12호
• /
• pp.714-718
• /
• 2018

Anti-reflection thin films are fabricated on glass substrates using the screen printing method. Tetra ethyl silicate(TEOS) and methyl tri methoxy silane(MTMS) are used as starting materials and buthyl carbitol acetate(BCA) and buthyl cellusolve(BC) are mixed to improve the viscosity of the solution. Anti-reflection thin films are fabricated according to the number of the screen mesh and the characteristics improve as the mesh size increases. The transmittance and reflectance of the coated thin film using 325 mesh are about 94 % and 0.43 % in the visible wavelength. The thickness and refractive index of the AR thin film are 107 nm and n = 1.26, respectively.