• Title/Summary/Keyword: transmittance refractive index

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Effective Refractive Index of Dye-Sensitized Solar Cell Using Transmittance and Reflectance Measurements (투과 및 반사율 측정을 이용한 염료감응태양전지의 유효 굴절률 모델링)

  • Kim, Hyeong Seok;Lee, Joocheol;Shin, Myunghun
    • Current Photovoltaic Research
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    • v.3 no.3
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    • pp.91-96
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    • 2015
  • Optical modeling and characterization of transparent dye-sensitized solar cells (DSC) are presented to design and estimate DSC devices numerically. In order to model the inhomogeneous active layer of DSC, the porous structure of titanium oxide ($TiO_2$) and dye mixture, we prepared films consisting of layer by layer of the DSC's basic materials sequentially, and characterized the optical parameters of the films with the effective refractive index, which was extracted from the transmittance and reflectance measurements in ultra violet to near infra-red range. By using the effective refractive index, we made the optical model for DSC, and demonstrated that the optical model based on effective refractive index can be used to design and evaluate the performance of transparent-type DSC modules.

Convective Deposition of Silica Nano-Colloidal Particles and Preparation of Anti-Reflective Film by Controlling Refractive Index (콜로이드 실리카 나노입자의 부착에 의한 반사방지막 제조 및 굴절율 조절)

  • Hwang Yeon;Prevo Brian;Velev Orlin
    • Korean Journal of Materials Research
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    • v.15 no.5
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    • pp.285-292
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    • 2005
  • Anti-reflection film was coated by using spherical silica nano colloids. Silica colloid sol was reserved between two inclined slide glasses by capillary force, and particles were convectively stacked to form a film onto the substrate as the water evaporates. As the sliding speed increased, the thickness of the film decreased and the wavelength at the maximum transmittance decreased. The microstructure observed by SEM showed that silica particles were nearly close packed, which enabled the calculation of the effective refractive index of the film. The film thickness was measured by proffer and calculated from the wavelength of maximum transmittance and the effective refractive index. The effective refractive index of the film could be controlled by a subtle controlling of the coating speed and by mixing two different sized silica particles. When the 100 nm and 50 m particles were mixed at 4:1-5:1 volume ratio, the maximum transmittance of $95.2\%$ for one-sided coating was obtained. This is the one that has increased by $3.8\%$ compared to bare glass substrate, and shows that $99.0\%$ of transmittance or $1.0\%$ of reflectance can be achieved by the simple process if both sides of the substrate are coated.

Preparation and Characterization of Alumina Thin Film by Sol-Gel Method (III) Preparation of Anti-Reflective Coating Glass (졸겔법에 의한 알루미나 박막의 제조 및 특성 (III) 저반사 코팅유리의 제조)

  • 이재호;최세영
    • Journal of the Korean Ceramic Society
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    • v.32 no.1
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    • pp.57-62
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    • 1995
  • The coating condition of reproducible anti-reflective coating film and the light transmittance characteristics of the prepared anti-reflective coating glass were investigated as a study for the preparation of single-layer anti-reflective coating glasss. In case of coating with the sol in which the solvent was substituted with the ethanol with the addition of 0.1 mol HNO3, the coated glass showed the minimum value of the refractive index of 1.464, light transmittance of 94.2% at 550nm standard wavelength which is 3.2% higher than that of the parent glass, and the reflectance in the entire wave range of visible light. The refractive index represented its minimum at the sol concentration of 1.0 mol per 100mols of water and the higher the sol concentration, the higher the refractive index, resulting in the decrease of the light transmitance. The production condition of the reproducible anti-reflective coating on glass with the maximum transmittance of 94.2% was 4cm/min of withdrawal speed, 40$0^{\circ}C$ and 1 hour of heat treatment temperature and time, resulting in the film thickness of 94nm.

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Polymerization and Preparation of Functional Ophthalmic Material Containing Carbon Nanoparticles

  • Lee, Min-Jae;Sung, A-Young
    • Korean Journal of Materials Research
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    • v.28 no.8
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    • pp.452-458
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    • 2018
  • This research is conducted to create a functional hydrogel ophthalmic lens containing nanoparticles. Carbon nanoparticles and PEGMEMA are used as additives for the basic combination of HEMA, MA, and MMA, and the materials are copolymerized with EGDMA as the cross-linking agent and AIBN as the thermal initiator. The hydrogel lens is produced using a cast-mold method, and the materials are thermally polymerized at $100^{\circ}C$ for an hour. The polymerized lens sample is hydrated in a 0.9 % saline solution for 24 hours before the optical and physical characteristics of the lens are measured. The refractive index, water content, contact angle, light transmittance, and tensile strength are measured to evaluate the physical and optical characteristics of the hydrogel lens. The refractive index, water content, contact angle, UV-B light transmittance, UV-A light transmittance, visible light transmittance, tensile strength and breaking strength of the hydrogel lens polymer are 1.4019~1.4281, 43.05~51.18 %, $31.95{\sim}68.61^{\circ}$, 21.69~58.11 %, 35.59~84.26 %, 45.85~88.06 %, 0.1075~0.1649 kgf and 0.1520~0.2250 kgf, respectively. The results demonstrate an increase in refractive index, tensile strength and breaking strength and a decrease in contact angle and light transmittance. Furthermore, the visible light transmissibility is significantly increased at PEG 10 %. It is clear that this material can be used for high-performance ophthalmic lenses with wettability, ultraviolet ray blocking effect, and tensile strength.

Thermally Stable Antireflective Coatings based on Nanoporous Organosilicate

  • Kim, Su-Han;Cho, Jin-Han;Char, Kook-Heon
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.282-282
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    • 2006
  • Nanoporous organosilicate thin films were realized by the microphase separation of pore generating components mixed with an organosilicate matrix. The refractive index of such nanoporous organosilicate films can be tuned in the range of $1.40{\sim}1.22$. With a nanoporous single layer with n ${\sim}1.225,\;99.85\;%$ transmittance in the visible range was achieved. In order to overcome the limitation on the narrow wavelength for high transmittance imposed by single nanoporous thin films, bilayer thin films with different reflectance for each layer were prepared by inserting high refractive index layer with a refractive index of 1.447. It is demonstrated that the novel broadband antireflection coating with improved transmittance can be easily achieved by the nanoporous bilayer thin films described in present study.

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High-Transmittance Films Coated from Silica Colloidal Nano-Particles (II) (실리카 콜로이드 나노입자를 이용한 반사 방지막의 제조 (II))

  • Hwang, Yeon
    • Journal of the Korean Ceramic Society
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    • v.42 no.6 s.277
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    • pp.399-404
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    • 2005
  • Anti-reflection film was coated by using spherical silica nano colloidal particles and fumed silica particles. Silica colloid sol was reserved between two inclined slide glasses by capillary force, and particles were stacked to form a film onto the substrate as the upper glass was sliding. The deposition processes were studied to enhance the wavelength dependency of the light transmittance and to control the effective refractive index of the film. Both of the spherical and fumed silica particles showed an enhancement of $4.0-4.4\%$ in light transmittance by one step coating. The dependence of the transmittance on wavelength was largely improved at the longer wavelength by partial coating of fumed particles on the film of spherical particles. The effective refractive index of the film was controlled by removing latex particles that were co-deposited with silica particles. Using this process the light reflectance from one side of the glass substrate could be reduced from $4.2\%$ to $0.6\%$ although zero reflectance was not achieved due to the agglomeration of the latex particles.

The Optical Properties of Plasma Polymerized Organic Thin Films Using Spectrophotometry (분광광도계법을 이용한 플라즈마 중합 유기박막의 광학특성)

  • Choi, C.S.;Park, B.K.;Park, C.B.;Lee, D.C.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1993.05a
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    • pp.28-32
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    • 1993
  • A deposition rate of styrene thin films is linearly increased, but one of benzene thin films is nonlinearly increased with increasing discharge power under maintaining a polymerization time, pressure and monomer flow rate. And, the reduction of transmittance at shortwave is larger than that of transmittance at longwave. The refractive index with wavelength is various from 1.55 to 1.65. The refractive index of their thin films is decreased with increasing discharge power. Also, it is known that measured results are valid because the calculation of the extinction coefficient is about $10^3$ within variation of refractive index.

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Preparation of High-Transmittance Glass Thin Films by the Sol-Gel Process (졸-겔법을 이용한 고투과율 유리 박막의 제조)

  • Hwang, Kyuseog;Song, Jongeun;Lee, Hyungmin;Lim, Yongmu;Kim, Sangmoon;Shim, Moonsik;Yun, Yeomhum
    • Journal of Korean Ophthalmic Optics Society
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    • v.4 no.1
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    • pp.45-49
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    • 1999
  • To prepare high-transmittance films, thin films were fabricated on the microscope slide glasses with silicon alkoxides and boric acids as starting materials by using a dip-coating technique. Thicknesses of the thin films were controled as viscosity of the sol used and composition of the $B_2O_3$ was changed at 5, 10, 15 and 20 mol%. Transmittance at visible range and IR transmittance of the films according to the composition were measured, and refractive index of the films were analyzed also. Maximum transmittance at visible range and minimum refractive index were obtained at 15 mol% $B_2O_3$. We will discuss a decrease of the transmittance at 20 mol% on the basis of the refractive index.

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Influence of Artificial Tear Containing Carboxymethyl Cellulose Component on Physical Properties of Hydrogel Contact lens (카르복시메칠 셀룰로오스 성분이 포함된 인공누액이 하이드로젤 콘택트렌즈의 물성에 미치는 영향)

  • Cho, Seon-Ahr;Sung, A-Young
    • Journal of Korean Ophthalmic Optics Society
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    • v.18 no.4
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    • pp.457-463
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    • 2013
  • To determine the impact of artificial tears which include carboxymethyl cellulose on a hydrogel contact lenses. Methods: A contact lenses made of the cross-linking agent, EGDMA (ethylene glycol dimethacrylate) and HEMA (2-hydroxyethyl methacrylate) and with added NVP (n-vinyl-2-pyrrolidone) and MMA (methyl methacrylate) was evaluated for water content, refractive index, spectral transmittance and contact angle of produced contact lens. Results: The physical properties of the sampled copolymerized polymers showed that water content, refractive index, visible ray transmittance and contact angle were in the range of 26.61%~48.58%, 1.422~1.455, 80.8%~91.4% and $33.93^{\circ}{\sim}65.70^{\circ}$, respectively. In addition, after soaking with artificial tears, the water content, refractive index and contact angle were in the range of 24.46%~48.25%, 1.422~1.457, 77.0%~91.0% and $37.25^{\circ}{\sim}77.33^{\circ}$, respectively. The changes of the physical property depending on hydration time and showed an increase of refractive index and contact angle, decrease of water content and visible ray transmittance. Conclusions: Artificial tears which include carboxymethyl cellulose sodium which is used as a wetting agent influenced water content, refractive index, contact angle and spectral transmittance of a hydrogel contact lenses.

Optical Studies of a Pure and Dye Doped Nematic Liquid Crystal E-24

  • Chandel, V.S.;Manohar, S.;Shukla, J.P.;Manohar, R.
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.5
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    • pp.221-224
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    • 2012
  • The present paper reports the comparative optical behavior of a pure nematic mixture E-24 and its anthraquinone dye doped sample. The variation in the ordinary and extraordinary refractive index ($n_o$, $n_e$) of the pure and dye doped samples with temperature has been discussed and it has been found that doped sample have a less refractive index compared to the pure sample. The variation in the order parameter for pure and doped samples with temperature has been discussed and it has been seen that the doped sample has a higher order parameter; the possible reasons have been discussed. The variations in birefringence and optical transmittance have also been presented here.