• 제목/요약/키워드: transition-edge

검색결과 221건 처리시간 0.029초

NEXAFS 분광법에 의한 Alq3/Ba과 Alq3/Au의 계면에서의 전자 천이에 관한 연구 (A Study on the Electron Transfer at the Alq3/Ba and Alq3/Au Interfaces by NEXAFS Spectroscopy)

  • 임수용;주성후;양재웅
    • 한국표면공학회지
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    • 제45권1호
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    • pp.15-19
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    • 2012
  • Tris(8-quinolinolato)aluminum(III); $Alq_3$ has been frequently used as an electron transporting layer in organic light-emitting diodes. Either Ba with a low work function or Au with a high work function was deposited on $Alq_3$ layer in vacuum. And then, the behaviors of electron transition at the $Alq_3$/Ba and $Alq_3$/Au interfaces were investigated by using the near edge x-ray absorption fine structure (NEXAFS) spectroscopy. In the each interface, the energy levels of unoccupied obitals were assigned as ${\pi}^*$(LUMO, LUMO+1, LUMO+2 and LUMO+3) and ${\sigma}^*$. And the relative intensities of these peaks were investigated. In an oxygen atom composing $Alq_3$ molecule, the relative intensities for a transition from K-edge to LUMO+2 were largely increased as Ba coverage (${\Theta}_{Ba}$, 2.7 eV) with a low work function was in-situ sequentially increased on $Alq_3$ layer. In contrast, the relative intensities for the LUMO+2 peak were reduced as Au coverage (${\Theta}_{Au}$, 5.1 eV) with a high work function were increased on $Alq_3$ layer. This means that the electron transition by photon in oxygen atom which consists in the unoccupied orbitals in $Alq_3$ molecule, largely depends on work function of a metal. Meanwhile, in the case of electron transition in a carbon atom, as ${\Theta}_{Ba}$ was increased on $Alq_3$, the relative intensity from K-edge to ${\pi}_1{^*}$ (LUMO and LUMO+1) was slightly decreased, and from K-edge to ${\pi}_2{^*}$ (LUMO+2 and LUMO+3) was somewhat increased. This rising of the energy state from ${\pi}_1{^*}$ to ${\pi}_2{^*}$ exhibits that electrons provided by Ba would contribute to the process of electron transition in the $Alq_3$/Ba interfaces. As shown in above observation, the analyses of NEXAFS spectra in each interface could be important as a basic data to understand the process of electron transition by photon in pure organic materials.

In situ Structural Investigation of Iron Phthalocyanine Monolayer Adsorbed on Electrode Surface by X-ray Absorption Fine Structure

  • 김성현;;강광훈
    • Bulletin of the Korean Chemical Society
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    • 제21권6호
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    • pp.588-594
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    • 2000
  • Structural changes of an iron phthalocyanine (FePC) monolayer induced by adsorption and externally applied potential on high area carbon surface have been investigated in situ by iron K-edge X-ray absorption fine structure (XAFS) in 0.5 M $H_2S0_4.$ Fine structures shown in the X-ray absorption near edge structure (XANES) for microcrystalline FePC decreased upon adsorption and further diminished under electrochemical conditions. Fe(II)PC(-2) showed a 1s ${\rightarrow}$ 4p transition as poorly resolved shoulder to the main absorption edge rather than a distinct peak and a weak 1s ${\rightarrow}$ 3d transition. The absorption edge position measured at half maximum was shifted from 7121.8 eV for Fe(lI)PC(-2) to 7124.8 eV for $[Fe(III)PC(-2)]^+$ as well as the 1s ${\rightarrow}$ 3d pre-edge peak being slightly enhanced. However, essentially no absorption edge shift was observed by the 1-electron reduction of Fe(Il)PC(-2), indicating that the species formed is $[Fe(II)PC(-3)]^-$. Structural parameters were obtained by analyzing extended X-ray absorption fine structure (EXAFS) oscillations with theoretical phases and amplitudes calculated from FEFF 6.01 using multiple-scattering theory. When applied to the powder FePC, the average iron-to-phthalocyanine nitrogen distance, d(Fe-$N_p$) and the coordination number were found to be 1.933 $\AA$ and 3.2, respectively, and these values are the same, within experimental error, as those reported ( $1.927\AA$ and 4). Virtually no structural changes were found upon adsorption except for the increased Debye-Wailer factor of $0.005\AA^2$ from $0.003\AA^2.$ Oxidation of Fe(II)PC(-2) to $[Fe(III)PC(-2)]^+$ yielded an increased d(Fe-Np) (1 $.98\AA)$ and Debye-Wailer factor $(0.005\AA^2).$ The formation of $[Fe(II)PC(-3)]^-$, however, produced a shorter d(Fe-$N_p$) of $1.91\AA$ the same as that of crystalline FePC within experimental error, and about the same DebyeWaller $factor(0.006\AA^2)$.

선택적 복호화를 이용한 MPEG-1 비디오의 장면 변화 재생 기법 (The Method for scene Transition plyback of MPEG-1 Video using Selective Decoding)

  • 김희숙;천승환황민이귀상
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 1998년도 추계종합학술대회 논문집
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    • pp.859-862
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    • 1998
  • Many playback methods of MPEG-1 video were developed and are have beendeveloped now. But nomal playback method demands great time. In this paper we designed and implemented the scene transition playback method of the MPEG-1 video data. The previous studies of scene transition playback have used to the DC or edge information after decoding process of picture. In this paper, scene transition is detected by macroblock information from MPEG-1 compressed area, then decodes and playbacks the only scene transition picture. This MPEG-1 video player was implemented by decoding control. So it is possible to add special playback method to MPEG-1 video player. As the result, which is proposed in this paper the scene transition method can minimize to decoding calculation and decrease to playback time of the MPEG-1 video data.

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Image registration using Hough transform and Phase correlation in Wavelet domain

  • Summar, Bhuttichai;Chitsobhuk, Orachat;Kasemsiri, Watjanapong
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2005년도 ICCAS
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    • pp.2006-2009
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    • 2005
  • This paper presents a method for registering images using phase correlation technique in fourier domain, hough transform and multi-resolution wavelet. To register images, source and input images are transformed to wavelet domain. An angular transition can be obtained by applying hough transform technique followed by phase correlation. Then we apply phase correlation technique to find x-axis and y-axis transition. We apply wavelet transform to reduce processing time and also use its coefficients as edge information instead of canny detector. With multi-resolution property of wavelet transform, registration time can be greatly reduced. After we get all transition parameters, we transform the input images according to these parameters. Then, we compose and blend all images into a new large image with details of all source images. From our experiment, we can find the accurate transition both x-y translation and angular transition with less error.

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Analog CMOS Performance Degradation due to Edge Direct Tunneling (EDT) Current in sub-l00nm Technology

  • Navakanta Bhat;Thakur, Chandrabhan-Singh
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제3권3호
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    • pp.139-144
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    • 2003
  • We report the results of extensive mixed mode simulations and theoretical analysis to quantify the contribution of the edge direct tunneling (EDT) current on the total gate leakage current of 80nm NMOSFET with SiO2 gate dielectric. It is shown that EDT has a profound impact on basic analog circuit building blocks such as sample-hold (S/H) circuit and the current mirror circuit. A transistor design methodology with zero gate-source/drain overlap is proposed to mitigate the EDT effect. This results in lower voltage droop in S/H application and better current matching in current mirror application. It is demonstrated that decreasing the overlap length also improves the basic analog circuit performance metrics of the transistor. The transistor with zero gate-source/drain overlap, results in better transconductance, input resistance, output resistance, intrinsic gain and unity gain transition frequency.

DMS $Zn_{1-x}Mn_xTe$ 단결정 박막의 광발광 특성연구 (Photoluminescence characteristics of DMS $Zn_{1-x}Mn_xTe$ epilayers)

  • 윤만영;양정모;신종순;현명학;유영문;최용대
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 연구회
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    • pp.204-207
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    • 2001
  • HWE 법으로 전 영역의 ZnMnTe 단결정 박막을 성장하였다. 상온 반사 스펙트럼으로부터 상온에서의 에너지 띠 간격이 Mn 조성비 증가에 따라 선형적으로 증가함을 알았다. 외부 자기장이 없는 10 K에서의 photoluminescence 스펙트럼에서 엑시톤 관련 near edge emission과 큰 조성비에서 지배적인 inta-$Mn^{2+}$ transition($^4T_1{\rightarrow}^6A_1$)을 관측하였다. edge emission은 조성비에 따라 선형적이고, intra-ion transition은 거의 변화가 없었다.

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고온 채널 내부 에지화염의 소염 한계 영역에서의 화염 안정화 및 구조에 관한 실험적 연구 (Experimental Study on the Edge Flame Stabilization and its Structure Nearby Quenching Limits in a High Temperature Channel)

  • 이민정;김남일
    • 한국연소학회지
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    • 제15권3호
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    • pp.1-7
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    • 2010
  • Edge flames have been interested as a basic structure that is concerned to flame stabilization and re-ignition of non-premixed flames. The edge flame consists of a lean premixed flame, a rich premixed flame, and a diffusion flame. In order to investigate fundamental structures of the edge flames at the conditions near the flammability limits, edge flames were stabilized within a heated narrow channel. Highly diluted partially premixed methane was used, and the flow rates of air and the partially premixed mixture were controlled. Various flame behaviors, including a transition between ordinary edge flames and premixed flames, were observed. Flame stabilization characteristics were examined as well. All flame stabilization conditions in this study showed a similar trend: characteristic time scales were inversely proportional to the equivalence ratio defined at the burner inlet. Finally, an interesting flame structure having a weak diffusion branch enveloped by a closed premixed branch was found near the flammability limits even in a fuel-air mixing layer. This structure was named as a "flame-drop" and the importance of this structure was first suggested.

Level-Set 방법이 적용된 Flame Hole Dynamics 모델을 통한 난류 혼합층 확산화염 모사 (Simulation of a Diffusion Flame in Turbulent Mixing Layer by the Flame Hole Dynamics Model with Level-Set Method)

  • 김준홍;정석호;안국영;김종수
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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    • pp.102-111
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    • 2004
  • Partial quenching structure of turbulent diffusion flames in a turbulent mixing layer is investigated by the method of flame hole dynamics to develope a prediction model for the turbulent lift off. The present study is specifically aimed to remedy the problem of the stiff transition of the conditioned partial burning probability across the crossover condition by adopting level-set method which describes propagating or retreating flame front with specified propagation speed. In light of the level-set simulations with two model problems for the propagation speed, the stabilizing conditions for a turbulent lifted flame are suggested. The flame hole dynamics combined with level-set method yields a temporally evolving turbulent extinction process and its partial quenching characteristics is compared with the results of the previous model employing the flame-hole random walk mapping. The probability to encounter reacting' state, conditioned with scalar dissipation rate, demonstrated that the conditional probability has a rather gradual transition across the crossover scalar dissipation rate in contrast to the stiff transition of resulted from the flame-hole random walk mapping and could be attributed to the finite response of the flame edge propagation.

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