• 한국정보디스플레이학회:학술대회논문집
• /
• 2009.10a
• /
• pp.806-809
• /
• 2009

Epoxy functionalized organic-inorganic hybrid materials (hybrimers) were synthesized by sol-gel reaction for application in OLED barrier coating. By using the calcium degradation method, the oxygen transition rate (OTR) and water vapor transition rate (WVTR) measured so far is $10^{-2}cc/m^2$-day for oxygen and $10^{-1}g/m^2$-day for water molecules with single hybrimer coating film, respectively. Encapsulated OLED devices have life time of 14hrs of a single hybrimer barrier coating and 29hrs of hybrimer/inorganic double barrier coatings at $25^{\circ}C$ and 60% relative humidity.

• Bulletin of the Korean Chemical Society
• /
• v.28 no.6
• /
• pp.936-940
• /
• 2007

The aminolyses of diphenyl phosphinic chloride (1) with substituted anilines in acetonitrile at 55.0 oC are investigated kinetically. Large Hammett ρ X (ρnuc = ?4.78) and Bronsted β X (βnuc = 1.69) values suggest extensive bond formation in the transition state. The primary normal kinetic isotope effects (kH/kD = 1.42-1.82) involving deuterated aniline (XC6H4ND2) nucleophiles indicate that hydrogen bonding results in partial deprotonation of the aniline nucleophile in the rate-limiting step. The faster rate of diphenyl phosphinic chloride (1) than diphenyl chlorophosphate (2) is rationalized by the large proportion of a frontside attack in the reaction of 1. These results are consistent with a concerted mechanism involving a partial frontside nucleophilic attack through a hydrogen-bonded, four-center type transition state.

• Bulletin of the Korean Chemical Society
• /
• v.18 no.7
• /
• pp.749-754
• /
• 1997

Rate constants have been measured spectrophotometrically for the reactions of alkali metal ethoxides (EtOM) with S-p-nitrophenyl 2-thiofuroate (1b) and 2-thiophenethiocarboxylate (2b) in absolute ethanol at 25.0±0.1 ℃. 1b is observed to be more reactive than 2b toward all the EtOM studied. The reactivity of EtOM is in the order EtOK > EtONa > EtO- > EtOLi for both substrates, indicating that K+ and Na+ behave as a catalyst while Li+ acts as an inhibitor in the present system. Equilibrium association constants of alkali metal ions with the transition state (KaTS) have been calculated from the known equilibrium association constants of alkali metal ion with ethoxide ion (Ka) and the rate constants for the reactions of EtOM with 1b and 2b. The catalytic effect (KaTS/Ka) is larger for the reaction of 1b than 2b, and decreases with decreasing the size of the alkali metal ions. Formation of 5-membered chelation at the transition state appears to be responsible for the catalytic effect.

• Bulletin of the Korean Chemical Society
• /
• v.20 no.12
• /
• pp.1418-1420
• /
• 1999

Kinetics and mechanism of the aminolysis of Z-thiophenyl acetates with X-benzylamines are investigated in acetonitrile at 45.0 ℃. The magnitudes of Bronsted coefficients β$_x$ (=1.3~-1.6) and β$_z$ (= -2.1~-2.4) are all large and cross-interaction constant ρxz is relatively large and positive (0.90). These trends are consistent with the rate-limiting breakdown of a tetrahedral intermediate, $T^±$. The proposed mechanism is also supported by adherence of the rate data to the reactivity-selectivity principle (RSP). The kinetic isotope effects, $k_H/k_D$, are greater than unity (1.3-1.4) suggesting a possibility of hydrogen-bonded four-centered transition state. The activation parameters, ΔH$^≠$ and ΔS$^≠$, are consistent with this transition-state structure.

• Bulletin of the Korean Chemical Society
• /
• v.17 no.2
• /
• pp.192-198
• /
• 1996

We present a theoretical formulation of diffusion process on solid surface based on multidimensional transition state theory (TST). Surface diffusion of single adatom results from hopping processes on corrugated potential surface and is affected by surface vibrations of surface atoms. The rate of rare events such as hopping between lattice sites can be calculated by transition state theory. In order to include the interactions of the adatom with surface vibrations, it is assumed that the coordinates of adatom are coupled to the bath of harmonic oscillators whose frequencies are those of surface phonon modes. When nearest neighbor surface atoms are considered, we can construct Hamiltonians which contain terms for interactions of adatom with surface vibrations for the well minimum and the saddle point configurations, respectively. The escape rate constants, thus the surface diffusion parameters, are obtained by normal mode analysis of the force constant matrix based on the Hamiltonian. The analysis is applied to the diffusion coefficients of W, Ir, Pt and Ta atoms on the bcc(110) plane of W in the zero-coverage limit. The results of the calculations are encouraging considering the limitations of the model considered in the study.

• Journal of the Korea Institute of Information Security & Cryptology
• /
• v.10 no.3
• /
• pp.29-36
• /
• 2000

It is very import role to increase communication quality that fast detection of random sequence synchronization fail in synchronous stream cipher system using initial synchronization mode. Generally it sends additional information to detect random sequency synchronization fail. But we can't transmit additional informations to decide synchronization fail in a system using RMVD to correct channel error. In this paper we propose a method to detect synchronization fail in the receiver even though a system using RMVD has no margin to send additional information, For detecting random sequency synchronization fail we decipher receiver data analyze probability of transition rate for pre-determined period and decide synchronization fail using calculated transition rate probability. This proposed method is fast very reliable and robust in noisy channel and is easily implemented with hardware.

• Journal of ILASS-Korea
• /
• v.27 no.3
• /
• pp.144-154
• /
• 2022

Gas injection is a technique applied to improve throttling in liquid rocket engines and atomization in effervescent injectors. When a gas is injected into a liquid, it creates a two-phase flow inside the injector. The changes (bubbly flow, slug flow, annular flow, etc.) in the two-phase flow affect the injector's spray characteristics. In this study, cold-flow tests were performed by using three injectors with different orifice diameters and four aerators with different gas injection hole diameters. The experiments were done by changing the thrust ratio (liquid mass flow rate ratio) and gas-liquid mass flow rate ratio. Two-phase flow transition, breakup length, and discharge coefficient according to the injector/aerator design and flow conditions were investigated in detail.

• The Korean Journal of Applied Statistics
• /
• v.24 no.2
• /
• pp.253-268
• /
• 2011

In this paper, we estimate systematic risk from credit migration (or transition) matrices under "Asymptotic Single Risk Factor" model. We analyzed transition matrices issued by KR(Korea Ratings) and concluded that systematic risk implied on credit migration somewhat coincide with the real economic cycle. Especially, we found that systematic risk implied on credit migration is better than that implied on the default rate. We also emphasize how to conduct a stress test using systematic risk extracted from transition migration. We argue that the proposed method in this paper is better than the usual method that is only considered for the conditional probability of default(PD). We found that the expected loss critically increased when we explicitly consider the change of credit quality in a given portfolio, compared to the method considering only PD.

• Proceedings of the Korean Magnestics Society Conference
• /
• 1991.11a
• /
• pp.86-87
• /
• 1991

• Proceedings of the KSME Conference
• /
• 2004.11a
• /
• pp.1494-1498
• /
• 2004

Transition sequence of rocket to ramjet was simulated numerically for a two-dimensional axisymmetric can-type ramjet engine. Multi-species preconditioned Navier-Stokes equations with $k-{\varepsilon}$ turbulence model and finite-rate chemistry model was employed. To calculate transition sequence, initial flow-field conditions for inlet diffuser with closed port-cover was computed first, and then that result was applied as initial conditions after port-cover opened. Terminal shock was developed as a result of increased pressure in a combustor due to combustion and ramjet operated at supercritical condition. For a smaller nozzle throat area, buzz instability was occurred. Strong pressure oscillations were observed as a result of forward and backward movement of terminal shock and those oscillations were not damped out.