• BMB Reports
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• 제39권2호
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• pp.167-170
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• 2006

Bovine adenosine deaminase undergoes a nondenaturational conformational change at $29^{\circ}C$ upon heating which is characterized by a large increase in heat capacity. We have determined the transition state thermodynamics of the conformational change using a novel application of differential scanning calorimetry (DSC) which employs very slow scan rates. DSC scans at the conventional, and arbitrary, scan rate of $1^{\circ}C/min$ show no evidence of the transition. Scan rates from 0.030 to $0.20^{\circ}C/min$ reveal the transition indicating it is under kinetic control. The transition temperature $T_t$ and the transition temperature interval ${\Delta}T$ increase with scan rate. A first order rate constant $k_1$ is calculated at each $T_t$ from $k_1\;=\;r_{scan}/{\Delta}T$, where $r_{scan}$ is the scan rate, and an Arrhenius plot is constructed. Standard transition state analysis reveals an activation free energy ${\Delta}G^{\neq}$ of 88.1 kJ/mole and suggests that the conformational change has an unfolding quality that appears to be on the direct path to the physiological-temperature conformer.

• East Asian Economic Review
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• 제21권4호
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• pp.385-432
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• 2017

This paper investigates how firm age, size and ownership are related with job creation and destruction, and how these patterns differ across transition and non-transition economies. The analysis finds that age is inversely related with gross job creation and net job creation in the two samples. This finding is consistent with the theory of the learning effect. The relationship between age and job destruction is indifferent in non-transition economies. On the contrary, old firms in transition economies destroy more jobs than young ones. The paper further establishes an inverse relationship between size and gross job creation in the two groups. However, there is divergence between the two samples; small firms in non-transition economies also exhibit a higher gross job destruction rate. Consequently large firms have a higher net job creation rate. In transition economies, small and large firms exhibit similar rates of job destruction. But small firms retain a higher net job creation rate. A more intriguing finding is that state owned firms do not underperform domestic private ones. This means these countries may be using soft budget constraint which allows state owned firms to overstaff. Finally, crowding out of SMEs by foreign owned firms is not evident in transition economies.

• 인터넷정보학회논문지
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• 제5권6호
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• pp.59-66
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• 2004

본 논문에서는 MPEG 비디오 데이터를 GoP 단위로 분할하여 장면전환 특성을 파악하고 그에 따라 칼만필터를 사용하여 비디오 데이터의 전송량을 예측하는 방법을 제안하고자 한다. 비디오 데이터의 정확한 장면전환을 파악하기 위해서 압축 도메인에서 고속으로 장면에 대한 정보를 검출하는 알고리즘을 사용하여 급진적 장면전환 유형과 점진적 장면전환 유형으로 분류하였다. 분류된 정보는 칼만필터의 세부 인자로 사용되어 비디오 데이터의 전송량을 예측한다. 본 논문에서 제안한 방법은 압축 도메인에서 장면전환 탐지와 비디오 데이터의 전송량을 예측하여 처리 시간을 감소시키고자 하였다. 세 종류의 서로 다른 비디오 데이터 911개의 1프레임을 사용한 실험에서 96.2- 97.6%로 전송량을 예측하였다.

• 품질경영학회지
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• 제20권1호
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• pp.11-21
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• 1992

The Purpose of this paper contribute to design the multistate Markov process for the reliability of a system when the transition-rates of each unit depend on the current state of the system. The system transition-rate matrix has the form of the kronecker sum of transition rate matrices for the units, is analyzed and investigated. As a result, the system which has the state-dependent units is detaily analyzed and introduced by the approach of an algorithm for the system transition-rate matrix based on the kronecker algebra.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1994년도 춘계학술대회 논문집
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• pp.30-33
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• 1994

This paper studies on the effect of DSC(Differential Scanning Calorimeter) analysis condition on the glass transition temperature of silica filled epoxy network polymer used for ultra-high voltage apparatus. The effects of temperature scanning rate specimen size and gas flow rate on measured glass transition temperature have been studied in order to select optimum thermal analysis condition.

• 한국주조공학회지
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• 제20권3호
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• pp.197-207
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• 2000

Al-Si alloys were solidified in a rotating cylindrical mold by a vertical centrifugal casting process. Under a certain casting condition, there are four distinct zones such as the chill zone, the primary fine columnar zone, the equiaxed zone, and the secondary coarse columnar zone from the mold wall. The columnar-equiaxed transition (CET) and the equiaxed-columnar transition (ECT) were measured as functions of solute content, flow rate (mold velocity), pouring temperature and mold temperature. Within the critical value of solute content, as the flow rate increases, the columnar-equiaxed transition were found, but not the equiaxed-columnar transition. The aspect ratio of the primary columnar zone was more affected by the solute content than the flow rate. However the aspect ratio of the equiaxed zone was more affected by the flow rate than the solute content. The aspect ratio of the secondary columnar zone was affected by both the flow rate and the solute content.

• Bulletin of the Korean Chemical Society
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• 제19권11호
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• pp.1179-1184
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• 1998

Mesogenic and azo monomers were synthesized and copolymerized to obtain two copolymers composed of methacrylate and itaconate backbone. Glass transition temperatures of the copolymers were found to be slightly higher than ambient temperature. Both the copolymers showed liquid crystalline properties. Trans-cis isomerization in film state was observed under UV-irradiation with a light of 365 nm. Regarding the photochemical phase transition behavior, the transition rate of nematic-to-isotropic state was slightly faster in the methacrylate copolymer during irradiation at 365 nm and the rate of the reverse transition was much faster in itaconate copolymer under thermal effect.

• 한국초전도ㆍ저온공학회논문지
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• 제17권3호
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• pp.9-12
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• 2015

NbN thin films were deposited on thermally oxidized Si substrate at room temperature by using reactive magnetron sputtering in an $Ar-N_2$ gas mixture. Total sputtering gas pressure was fixed while varying $N_2$ flow rate from 1.4 sccm to 2.9 sccm. X-ray diffraction pattern analysis revealed dominant NbN(200) orientation in the low $N_2$ flow rate but emerging of (111) orientation with diminishing (200) orientation at higher flow rate. The dependences of the superconducting properties on the $N_2$ gas flow rate were investigated. All the NbN thin films showed a small negative temperature coefficient of resistance with resistivity ratio between 300 K and 20 K in the range from 0.98 to 0.89 as the $N_2$ flow rate is increased. Transition temperature showed non-monotonic dependence on $N_2$ flow rate reaching as high as 11.12 K determined by the mid-point temperature of the transition with transition width of 0.3 K. On the other hand, the upper critical field showed roughly linear increase with $N_2$ flow rate up to 2.7 sccm. The highest upper critical field extrapolated to 0 K was 17.4 T with corresponding coherence length of 4.3 nm. Our results are discussed with the granular nature of NbN thin films.

• ETRI Journal
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• 제45권6호
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• pp.974-981
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• 2023

This paper presents a transition-limited pulse-amplitude modulation (TLPAM) signaling method to enable a high data rate and robust wireline communications. TLPAM signaling addresses the impact of high intersymbol interference (ISI) ratios in conventional M-ary PAM signaling methods by limiting the maximum voltage transition level between adjacent symbols. The implementation of a TLPAM signaling encoder is realized by setting back the most significant bits (MSBs) in the queue. The correlation between TLPAM's maximum transition level, effective data rate, and eye width/height is analyzed with various channel loss parameters, followed by characterization and measurement results with a realistic channel setup. The analysis and experimental results reveal the effectiveness of the proposed TLPAM signaling scheme for achieving a high data rate with minimal interference.

• 한국연소학회지
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• 제13권4호
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• pp.16-25
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• 2008

Experiments have been conducted to clarify impacts of curtain flow and velocity ratio on low strain rate flame extinction, and to further display transition of shrinking flame disk to flame-hole. Critical mole fractions at flame extinction are examined in terms of velocity ratio, global strain rate, and nitrogen curtain flow rate. It is shown that multi-dimensional effects at low strain rate flames through global strain rate, velocity ratio, and curtain flowrate dominantly contribute to flame extinction and transition of shrinking flame disk to flame hole. Our concerns are particularly focused on the dynamic behavior of an edge flame in shrinking flame disk.