• Title/Summary/Keyword: transition of growth phase

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Refinement of Gd2O3 inclusions in the GdBa2Cu3O7-δ films fabricated by the RCE-DR process

  • Park, I.;Oh, W.J.;Lee, J.H.;Moon, S.H.;Yoo, S.I.
    • Progress in Superconductivity and Cryogenics
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    • v.20 no.4
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    • pp.46-49
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    • 2018
  • To improve in-field critical current densities ($J_c$) of $GdBa_2Cu_3O_{7-{\delta}}$ (GdBCO) coated conductors(CCs) fabricated by the reactive co-evaporation by deposition and reaction (RCE-DR) process, employing the nominal composition of Gd:Ba:Cu=1:1:2.5, we tried to refine the $Gd_2O_3$ particles trapped in the GdBCO superconducting matrix. For this purpose, we carefully selected the processing conditions on the stability phase diagram of GdBCO for this composition. By lowering the growth temperature of $Gd_2O_3$ in the liquid, we could refine the average particle size of $Gd_2O_3$ particles trapped in the GdBCO matrix and also achieve the zero-resistive transition temperatures ($T_{c,zero}$) of 92.3~94.2 K. Unfortunately, however, it was unsuccessful to achieve enhanced in-field $J_c$ values from these samples because of an air-contamination of the amorphous precursor film before its conversion into crystalline GdBCO film, suggesting that any exposure of the amorphous precursor film to air is fatal in obtaining high performance GdBCO CCs via the RCE-DR process.

Densification Behaviors of Mullite with Addition of Feldspar Formed by Pressureless Powder Packing Forming Method (무가압분말충전성형법에 의해 제조된 뮬라이트 성형체의 장석 첨가량에 따른 치밀화 거동)

  • 박정현;황명의;강민수;조철구
    • Journal of the Korean Ceramic Society
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    • v.36 no.2
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    • pp.186-192
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    • 1999
  • Dang-Chin feldspar powder with the mean particle size of 9.1 $\mu\textrm{m}$ was added to the synthesized mullite powder with the particle size of +325∼-200 mesh and the powder compact was prepared by PLPP(pressureless powder packing method). Densification behaviors were observed in sintering temperature range of 1200∼1400$^{\circ}C$. The binder solution of 4% PVA was infilterated into packed powder to the suitable strength. The PLPP method makes it possible to form compacts without clay as plasticizer. Therfore there was no defect caused by phase transition after sintering. Additionally, we observed the dense microstructure by the melting of feldspar. When the mullite compacts with feldspar of 30% were sintered at 1300$^{\circ}C$-4 hrs, we obtained the dense microstructure with zero water absorption and porosity <1%. When these compacts were sintered longer than 4 hrs at 1300$^{\circ}C$ or higher than 1400$^{\circ}C$, the examggerated grain growth of mullite was observed.

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Flowering and Inflorescence Development Characteristics of Korean Mint Affected by Different Photoperiods (광주기에 따른 배초향의 개화 및 화서 발달 특성)

  • Hwang, Hee Sung;Jeong, Hyeon Woo;Hwang, Seung Jae
    • Journal of Bio-Environment Control
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    • v.31 no.3
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    • pp.188-193
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    • 2022
  • The Korean mint (Agastache rugosa Kuntze) is used as a leaf vegetable. Therefore, it is important to improve the quality and quantity of leaves by maintaining vegetative growth. When the development of a plant is switched from vegetative to reproductive growth, leaf development may be lowered, leading to a decrease in marketability. Therefore, this study was conducted to investigate the effect of the photoperiod on the flowering characteristics and inflorescence development of the Korean mint to select an appropriate photoperiod for leaf production. The seeds were sown in 105-cell trays on 29 November 2021, and planted in each pot on 27 December 2021, when four main leaves appeared. After planting, the light/dark period was adjusted to 10/14hrs, 12/12hrs, 14/10hrs, 16/8hrs. After 19 days of planting, the first flowering occurred in 10/14hrs, which had a short photoperiod, and the 12/12hrs had 20 days for flowering, and other treatments had 21 days. In addition, it was confirmed that the Korean mint has the characteristics of facultative quantitative short-day plant, through the increase in the development of inflorescences as the light period is shorter than the dark period. As for the growth of Korean mint, the longer the photoperiod, the higher values were shown with leaf length, number of leaves, fresh weight, dry weight, and leaf area of the shoot. Therefore, it is considered that 14 h or more light period is suitable for increasing the productivity of Korean mint as a leafy vegetable.

The properties of AlGaN epi layer grown by HVPE (HVPE에 의해 성장된 AlGaN epi layer의 특성)

  • Jung, Se-Gyo;Jeon, Hun-Soo;Lee, Gang-Seok;Bae, Seon-Min;Yun, Wi-Il;Kim, Kyoung-Hwa;Yi, Sam-Nyung;Yang, Min;Ahn, Hyung-Soo;Kim, Suck-Whan;Yu, Young-Moon;Cheon, Seong-Hak;Ha, Hong-Ju
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.1
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    • pp.11-14
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    • 2012
  • The AlGaN layer has direct wide bandgaps ranging from 3.4 to 6.2 eV. Nowadays, it is becoming more important to fabricate optical devices in an UV region for the many applications. The high quality AlGaN layer is necessary to establish the UV optical devices. However, the growth of AlGaN layer on GaN layer is difficult due to the lattice mismatch and difference thermal expansion coefficient between GaN layer and AlGaN layer. In this paper, we attempted to grow the LED structure on GaN template by mixed-source HVPE method with multi-sliding boat system. We tried to find the optical and lattice transition of active layer by control the Al content in mixed-source. For the growth of epi layer, the HCl and $NH_3$ gas were flowed over the mixed-source and the carrier gas was $N_2$. The temperature of source zone and growth zone was stabled at 900 and $1090^{\circ}C$, respectively. After the growth, we performed the x-ray diffraction (XRD) and electro luminescence (EL) measurement.

A study on the interfacial reactions between electroless Ni-P UBM and 95.5Sn-4.0Ag-0.5Cu solder bump (무전해 Ni-P UBM과 95.5Sn-4.0Ag-0.5Cu 솔더와의 계면반응 및 신뢰성에 대한 연구)

  • ;;Sabine Nieland;Adreas Ostmann;Herbert Reich
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2002.05a
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    • pp.85-91
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    • 2002
  • Even though electroless Hi and Sn-Ag-Cu solder are widely used materials in electronic packaging applications, interfacial reactions of the ternary Ni-Cu~Sn system have not been known well because of their complexity. Because the growth of intermetallics at the interface affects reliability of solder joint, the intermetallics in Ni-Cu-Sn system should be identified, and their growth should be investigated. Therefore, in present study, interfacial reactions between electroless Ni UB7f and 95.5Sn-4.0Ag-0.5Cu alloy were investigated focusing on morphology of the IMCs, thermodynamics, and growth kinetics. The IMCs that appear during a reflow and an aging are different each other. In early stage of a reflow, ternary IMC whose composition is Ni$_{22}$Cu$_{29}$Sn$_{49}$ forms firstly. Due to the lack of Cu diffusion, Ni$_{34}$Cu$_{6}$Sn$_{60}$ phase begins growing in a further reflow. Finally, the Ni$_{22}$Cu$_{29}$Sn$_{49}$ IMC grows abnormally and spalls into the molten solder. The transition of the IMCs from Ni$_{22}$Cu$_{29}$Sn$_{49}$ to Ni$_{34}$Cu$_{6}$Sn$_{60}$ was observed at a specific temperature. From the measurement of activation energy of each IMC, growth kinetics was discussed. In contrast to the reflow, three kinds of IMCs (Ni$_{22}$Cu$_{29}$Sn$_{49}$, Ni$_{20}$Cu$_{28}$Au$_{5}$, and Ni$_{34}$Cu$_{6}$Sn$_{60}$) were observed in order during an aging. All of the IMCs were well attached on UBM. Au in the quaternary IMC, which originates from immersion Au plating, prevents abnormal growth and separation of the IMC. Growth of each IMC is very dependent to the aging temperature because of its high activation energy. Besides the IMCs at the interface, plate-like Ag3Sn IMC grows as solder bump size inside solder bump. The abnormally grown Ni$_{22}$Cu$_{29}$Sn$_{49}$ and Ag$_3$Sn IMCs can be origins of brittle failure.failure.

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Change of Electrochemical Characteristics Due to the Fe Doping in Lithium Manganese Oxide Electrode

  • Ju Jeh Beck;Kang Tae Young;Cho Sung Jin;Sohn Tae Won
    • Journal of the Korean Electrochemical Society
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    • v.7 no.3
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    • pp.131-137
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    • 2004
  • Sol-gel method which provides better electrochemical and physiochemical properties compared to the solid-state method was used to synthesize the material of $LiFe_yMn_{2-y}O_4$. Fe was substituted to increase the structural stability so that the effects of the substitution amount and sintering temperature were analyzed. XRD was used for the structural analysis of produced material, which in turn, showed the same cubic spinel structure as $LiMn_2O_4$ despite the substitution of $Fe^{3+}$. During the synthesis of $LiFe_yMn_{2-y}O_4$, as the sintering temperature and the doping amount of Fe(y=0.05, 0.1, 0.2)were increased, grain growth proceeded which in turn, showed a high crystalline and a large grain size, certain morphology with narrow specific surface area and large pore volume distribution was observed. In order to examine the ability for the practical use of the battery, charge-discharge tests were undertaken. When the substitution amount of $Fe^{3+}\;into\;LiMn_2O_4$ increased, the initial discharge capacity showed a tendency to decrease within the region of $3.0\~4.2V$ but when charge-discharge processes were repeated, other capacity maintenance properties turned out to be outstanding. In addition, when the sintering temperature was $800\~850^{\circ}C$, the initial capacity was small but showed very stable cycle performance. According to EVS(electrochemical voltage spectroscopy) test, $LiFe_yMn_{2-y}O_4(y=0,\;0.05,\;0.1,\;0.2)$ showed two plateau region and the typical peaks of manganese spinel structure when the substitution amount of $Fe^{3+}$ increased, the peak value at about 4.15V during the charge-discharge process showed a tendency to decrease. From the previous results, the local distortion due to the biphase within the region near 4.15V during the lithium extraction gave a phase transition to a more suitable single phase. When the transition was derived, the discharge capacity decreased. However the cycle performance showed an outstanding result.

A Study on the Microstructure of Organic Ultra Thin Films and Phase Transition of Langmuir Films in BAM (BAM을 이용한 L막의 상전이 현상과 유기초박막의 미세구조에 관한 연구)

  • Kim, Byung-Geun;Chon, Dong-Kue;Kim, Young-Keun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.938-941
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    • 2003
  • It is well known that the state of existence of molecules on the surface of water changes during compression of the molecules. Electric methods, such as measurement of the surface potential or displacement current are also useful for investigating dynamic changes of molecular state on the water surface during compression and Transformation of molecular film occurs only usually in air-water interface, 2 dimensions domain's growth and crash are achieved. Organic thin film that consist of growth of domain can understand correct special quality of accumulation film supplying information about fine structure and properties of matter of device observing information and so on that is surface forward player and optic enemy using AFM one of SPM application by nano electronics. In this paper Langmuir (L) that is one of basis technology to manufacture of organic matter device using biology material PBDG that is kind of polypeptide that have biology adaptedness. The Experiment method used ${\pi}-A$ isotherm and BAM(Brewster Angle Microscopy), using the BAM, we can to the molecular orientation of monolayer on the water surface and directly see the morphology of the films on water subphase as well as that of the films.

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Sectoral Innovation Studies: A Review of the Literature and Its Implications (한국 산업혁신연구의 현황과 과제)

  • Choung, Jae-Yong;Hwang, Hye-Ran
    • Journal of Technology Innovation
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    • v.25 no.3
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    • pp.115-154
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    • 2017
  • This article offers a review of the major literature about sectoral innovation studies of Korea and its implications over the past 30 years. The literature on the sectoral innovation studies in Korea has focused on analysing successful technological catch-up from an evolutionary perspective and most of research has centered on the issues about entry strategies, learning mechanisms. Recently "Emerging economies" like Korea in the 2000s face major challenges as they make a transition from (a) a phase of economic development characterised by 'catching up' with the global technological frontier, involving technological "imitation", to (b) a phase of continuing development based on the development of new knowledge for globally leading (post catch-up) product and process innovation. This paper reviews those bodies of literature of patterns of sectoral innovation, technological capability accumulation and catch-up process, catch-up innovation and institutions, and patterns of growth dynamics. Finally, given the importance of sectoral innovation studies, we suggest that industrial upgrading, transition towards leadership, dark side of catch-up issues are needed for future research directions.

Effect of pH of Aluminum Hydroxides Gel Obtained by Hydrolysis of Al2(SO4)3 Solution on Crystal Growth of α−Al2O3 (Al2(SO4)3 용액의 가수분해에 의해 얻어진 Aluminum Hydroxides Gel의 pH가 판상 α−Al2O3의 결정성장에 미치는 영향)

  • Choe, Dong-Uk;Park, Byung-Ki;Han, Myung-Wan
    • Journal of the Korean Ceramic Society
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    • v.44 no.10
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    • pp.562-567
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    • 2007
  • To precipitate the complex gels of the pH 6, 7, 8, 9 included in a flux and an aluminum hydroxides gel, an aqueous solution of a mixture of $Na_2CO_3\;and\;Na_2PO_4{\cdot}12H_2O$ was added with stirring in an aqueous solution of a mixture of $Al_2(SO_4){_3}{\cdot}18H_2O,\;Na_2SO_4\;and\;K_2SO_4$, and then the complex gels were aged in 20 h at $90^{\circ}C$. As the hydrolysis pH changed, it had an effect on the physical properties such as the crystal structure, crystal morphology and a phase transition temperature of the AlO(OH) gel, and also on the crystal structure, crystal morphology, particle size and particle size distribution of the ${\alpha}-Al_2O_3$ platelets prepared by molten-salt precipitation. Also, in this study, the complex gels were crystallized at $1,200^{\circ}C$ and thereafter dried at $110^{\circ}C$, and then it was investigated to effect of the hydrolysis pH on the crystal structure, morphology and particle size distribution of the ${\alpha}-Al_2O_3$ platelets crystals using XRD, DTA, SEM and particle size analyzer.

Synthesis of Ga2O3 powders by precipitation method (침전법을 이용한 Ga2O3 분말의 합성)

  • Jung, Jong-Yeol;Kim, Sang-Hun;Kang, Eun-Tae;Kim, Jin-Ho;Han, Kyu-Sung;Hwang, Kwang-Teak;Cho, Woo-Seok
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.1
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    • pp.8-14
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    • 2014
  • In this study, we investigated synthesis and characteristics of gallium oxide ($Ga_2O_3$) powders prepared by precipitation method. $Ga_2O_3$ powders were synthesized using $Ga(NO_3)_3$ as a starting material and $NH_4OH$ as a precipitant. The oxidation temperature of $Ga(OH)_3$ and phase transition temperature of $Ga_2O_3$ was revealed using TG-DSC analysis. The crystal structural change of $Ga_2O_3$ powders was investigated by XRD analysis. The morphologies and size distributions of $Ga_2O_3$ particles were analyzed using SEM.