• Title/Summary/Keyword: transformation ratio

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A Study on Synthesis of High Purity $\beta$-SiC Fine Powders from Ethyl Silicate(III) Effect of Additives (Ethyl Silicate를 이용한 고순도 $\beta$-SiC 미분말 합성에 관한 연구(III) 첨가제의 영향)

  • 최용식;박금철
    • Journal of the Korean Ceramic Society
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    • v.26 no.3
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    • pp.416-422
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    • 1989
  • The particle size of synthesized SiC powders was decreased with increasing carbon content when the mixture of carbon and silica was carbonized at 1, 45$0^{\circ}C$ after hydrolysis of the mixture with the ranges of 3.1 to 3.5 in the mole ratio of Carbon/Alkoxide. The reacted fraction of $\beta$-SiC nearly had nothing to do with the mole ratio of Carbon/Alkoxide. When the reaction was made by adding 0.5wt% additives in the composition of 3.1 in the mole ratio of carbon/alkoxide, the additives decreased the yield of $\beta$-SiC and its sequence was Ba2O3>B>Fe>Al>Al2O3>Si. The effect of additives promoted the transformation of $\beta$-SiC to $\alpha$-SiC form and shwoed the increasing tendency of lattice constant. The two colors of $\beta$-SiC powder came out : one was the black grey with addition of Al, Al2O3 and B the other the light grey with addition of Fe, B2O3 and Si.

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Optimization of Explosive Compounds (TNT and RDX) Biodegradation by Indigenous Microorganisms Activated by External Carbon Source (외부탄소원으로 활성화된 토착미생물에 의한 화약물질(TNT and RDX) 분해 최적화)

  • Park, Jieun;Bae, Bumhan
    • Journal of Soil and Groundwater Environment
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    • v.19 no.3
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    • pp.56-65
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    • 2014
  • Contamination of explosive compounds in the soils of military shooting range may pose risks to human and ecosystems. As shooting ranges are located at remote places, active remediation processes with hardwares and equipments are less practical to implement than natural solutions such as bioremediaton. In this study, a series of experiments was conducted to select a suitable carbon source and to optimize dosing rate for the enhanced bioremediation of explosive compounds in surface soils and sediments of shooting ranges with indigenous microorganisms activated by external carbon source. Treatability study using slurry phase reactors showed that the presence of indigenous microbial community capable of explosive compounds degradation in the shooting range soils, and starch was a more effective carbon source than glucose and acetic acid in the removal of TNT. However, at higher starch/soil ratio, i.e., 2.0, the acute toxicity of the liquid phase increased possibly due to transformation products of TNT. RDX degradation by indigenous microorganisms was also stimulated by the addition of starch but the acute toxicity of the liquid phase decreased with the increase of starch/soil ratio. Taken together, the optimum range of starch/soil ratio for the degradation of explosive compounds without significant increase in acute toxicity was found to be 0.2 of starch/soil.

Inheritance of Herbicide (glufosinate) Resistance in Transgenic Rice Plant through Anther Culture

  • Kang, Hyeon-Jung;Kim, Hyun-Soon;Nam, Jeong-Kwon;Lee, Young-Tae;Lee, Seung-Yeob;Kim, Chung-Kon
    • Korean Journal of Breeding Science
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    • v.40 no.3
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    • pp.211-214
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    • 2008
  • Haploid system by anther culture allows the development of homozygous lines when doubled. The response of anther culture to Basta (glufosinate) resistance was investigated on transgenic plants (cv. Anjungbyeo) in order to identify inheritance of bar gene associated with Basta. Most of the regenerated transgenic plants were sterile, and only a few plants produced viable seeds ($A_1$) in the greenhouse. The bar gene was analysis by PCR in basta resistant transgenic plant ($TA_0$). The transgenic seeds ($A_1$) were significantly germinated in Basta solution compared with non-transformed seeds. As a result of anther culture, in regenerated haploid plants, segregation ratio was 1:1 in five of eight cross combinations. In diploid plants, segregation ratio was 1:1 in seven of eight cross combinations. Although there was some differences in the cross combinations, most of the combinations had 1:1 segregation ratio which supports the theory. The difference may be a result of the small sample size or the difference of anther culture response caused by genotypic difference. Hence, when many cross combinations were anther-cultured the results would support the theory.

Evaluation of the Normalized Burn Ratio (NBR) for Mapping Burn Severity Base on IKONOS-Images (IKONOS 화상 기반의 산불피해등급도 작성을 위한 정규산불피해비율(NBR) 평가)

  • Kim, Choen
    • Korean Journal of Remote Sensing
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    • v.24 no.2
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    • pp.195-203
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    • 2008
  • Burn severity is an important role for rehabilitation of burned forest area. This factor led to the pilot study to determine if high resolution IKONOS images could be used to classify and delinenate the bum severity over burned areas of Samchock Fire and Cheongyang-Yesan Fire. The results of this study can be summarized as follows: 1. The modified Normalized Bum Ratio (NBR) for IKONOS imagery can be evaluated using burn severity mapping. 2. IKONOS-derived NBR imagery could provide fire scar and detail mapping of burned areas at Samchock fire and Cheongyang-Yesan Burns.

Characteristics and oxidation behavior of the hybrid-HVOF sprayed $Cr_3C_2$-7wt%(NiCr) coatings depending on $H_2/O_2$ ratio ($H_2/O_2$ 비에 따른 Hybrid HVOF 용사된 $Cr_3C_2$-7wt%(NiCr) 용사층의 특성 및 산화거동)

  • 김병희;서동수
    • Journal of Welding and Joining
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    • v.15 no.4
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    • pp.126-135
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    • 1997
  • $H_2/O_2$ 비에 따른 Hybrid HVOF 용사된 $Cr_3C_2$-7wt%(NiCr) 용사층의 특성 및 산화거동 This study was performed to investigate the influence of fuel/oxygen ratio (F/O=3.2, 3.0, 2.8) on the characteristics and the oxidation behavior of the hybrid-HVOF sprayed $Cr_3C_2$-7wt%NiCr coatings. Decomposition and the oxidation of the $Cr_3C_2$was occured during spraying. The degree of transformation from $Cr_3C_2$to $Cr_7C_3$ was increased with decreasing the F/O ratio. The microstructural differences of the as sprayed coating with F/O ratio can not be distinguished, However, large pores were diminished and then the coatings became dense by heat treatment. Microhardness of the as-sprayed specimen which sprayed with F/O=3.0 condition was hightest ($Hv_{300}$=1140) and the hardness was increased to 1500 after heat treatment at $600^{\circ}C$ for 50hrs in air. It was supposed that hardness was increased due to the formation of $Cr_2O_3$ within $Cr_3C_2$/$Cr_7C_3$matrix and the densification of coating layer during heat treatment. Apparent activation energy for oxidation was varied from 21.2 kcal$mol^{-1}K^{-1}$ to 23.8 kcal$mol^{-1}K^{-1}$ with respect to the F/O ratio. The surface morphology was changed to porous and oxide chusters were grown after oxidation $1000^{\circ}C$ for 50 hours by the aggressive evolution of gas phase ($CrO_3$ and$CO_2$). The oxide cluster was composed of Ni and Cr.

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Analysis of the 500M Short track speed skating starting motion according to the center of gravity position ratio (인체 무게 중심 분할에 따른 500m 숏트트랙 스피드 스케이팅 출발 기술 분석)

  • Back, Jin-Ho;Chung, Nam-Ju;Han, Ki-Hoon;Lee, Yong-Goo;Yoon, Dong-Seob;Lee, Yong-Sik
    • Korean Journal of Applied Biomechanics
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    • v.13 no.3
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    • pp.199-215
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    • 2003
  • The purpose of this study was to attempt new starting motion and supply present starting motion in the 500M short track speed skating according to the center of gravity position. The center of gravity position ratio was divided starting motion into five(type A : front 80%-back 20%, type B front 70%-back 30%, type C : front 50%-back 50%, type D : front 30%-back 70%, type E : front 20%-back 80%). The three dimension motion analysis with DLT(direct linear transformation) method was executed using two video cameras. The following conclusion was that It was appear that reaction and execution time in starting motion was the most short in type B. It was characteristic that step of skaters was shorten and center of gravity position ratio was not effect to change of the step in each event. It was appear that the displacement of type D and type E were longer than that type A and type B during the starting motion. It was appear that skill types of center of gravity position ratio to the front were lower than that to the back and contract a posture. Observing the above, it was conclusion that skill type B of center of gravity position ratio to the tent was more effect than that to the back. But it is important that these skill type was most used to the competition and estimate the result.

The effect of low temperature aging on the mechanical property & phase stability of Y-TZP ceramics

  • Kim, Hyung-Tae;Han, Jung-Suk;Yang, Jae-Ho;Lee, Jai-Bong;Kim, Sung-Hun
    • The Journal of Advanced Prosthodontics
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    • v.1 no.3
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    • pp.113-117
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    • 2009
  • STATEMENT OF PROBLEM. Recently Yttrium-stabilized tetragonal zirconia polycrystal (Y-TZP) has been introduced due to superior flexural strength and fracture toughness compared to other dental ceramic systems. Although zirconia has outstanding mechanical properties, the phenomenon of decrease in the life-time of zirconia resulted from degradation in flexural strength after low temperature aging has been reported. PURPOSE. The objective of this study was to investigate degradation of flexural strength of Y-TZP ceramics after various low temperature aging treatments and to evaluate the phase stability and micro-structural change after aging by using X-ray diffraction analysis and a scanning electron microscope (SEM). MATERIAL AND METHODS. Y-TZP blocks of Vita In-Ceram YZ (Vita Zahnfabrik, Bad $S\ddot{a}ckingen$, Germany) were prepared in 40 mm (length) $\times$ 4 mm (width) $\times$ 3 mm (height) samples. Specimens were artificially aged in distilled water by heat-treatment at a temperature of 75, 100, 125, 150, 175, 200, and $225^{\circ}C$ for 10 hours, in order to induce the phase transformation at the surface. To measure the mechanical property, the specimens were subjected to a four-point bending test using a universal testing machine (Instron model 3365; Instron, Canton, Mass, USA). In addition, X-ray diffraction analysis (DMAX 2500; Rigaku, Tokyo, Japan) and SEM (Hitachi s4700; Jeol Ltd, Tokyo, Japan) were performed to estimate the phase transformation. The statistical analysis was done using SAS 9.1.3 (SAS institute, USA). The flexural strength data of the experimental groups were analyzed by one-way analysis of variance and to detect statistically significant differences ($\alpha$= .05). RESULTS. The mean flexural strength of sintered Vita In-Ceram YZ without autoclaving was 798 MPa. When applied aging temperature at below $125^{\circ}C$ for 10 hours, the flexural strength of Vita In-Ceram YZ increased up to 1,161 MPa. However, at above $150^{\circ}C$, the flexural strength started to decrease. Although low temperature aging caused the tetragonal-to-monoclinic phase transformation related to temperature, the minimum flexural strength was above 700 MPa. CONCLUSION. The monoclinic phase started to appear after aging treatment above $100^{\circ}C$. With the higher aging temperature, the fraction of monoclinic phase increased. The ratio of monoclinic/tetragonal + monoclinic phase reached a plateau value, circa 75% above $175^{\circ}C$. The point of monoclinic concentration at which the flexural strength begins to decrease was between 12% and 54%.

Mineralization of Cattle Manure Compost at Various Soil Moisture Content (우분퇴비 시용후 토양수분 조절에 따른 질소 및 탄소의 전환)

  • Kim, P.J.;Chung, D.Y.;Chang, K.W.;Lee, B.L.
    • Korean Journal of Environmental Agriculture
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    • v.16 no.4
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    • pp.295-303
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    • 1997
  • To investigate the transformation characteristics of nitrogen and carbon from cow manure compost amended in soil under different moisture conditions, dynamics of nitrogen and carbon were determined periodically for 15 weeks of aerobic incubation at room temperature during July${\sim}$November, 1996. Cow manure compost matured with mixing saw dust was amended with the 4 ratios (0, 2, 4, 6%(wt/wt)) in Ap horizon soil, which collected from green house in Yesan, Chungnam. Moisture was controlled with 0.2, 0.3, 0.4, and 0.5 of mass water conte nt (${\theta}$m) to air dried soil, and water loss was compensated at every sampling. During incubation, soil pH was decreased continuously, that was caused by hydrogen generated from nitrification of ammonium nitrogen. And pH became higher with inclining cow manure compost amendment and water treatment, that meaned the increase of mineralization of organic-N to $NH_4\;^+-N$. Total nitrogen was reduced with increasing water content, but total carbon showed the contrast tendency with that of nitrogen. Therefore, C/N ratio slightly decreased in the low water condition (${\theta}$m 0.2) during incubation, but increased continuously in high water condition over ${\theta}$m 0.4. As a result, it was assumed that soil fertility is able to be reduced in the high water content over available water content. Nitrate transformation rate increased lasting in the low water content less than ${\theta}$m 0.3. Itdropped significantly in the first $2{\sim}3$ weeks of incubation over ${\theta}$m 0.4. In particular, nitrate was not detected in ${\theta}$m 0.5 of water content after the first $2{\sim}3$ weeks. In contrast, ammonium transformation was inclined with increasing water treatment. Nitrogen mineralization rate, which calculated with percentage ratio of (the sum of ex.$NH_4\;^+-N$ and $NO_3\;^--N$)/total nitrogen, was continuously increased in the low water content of ${\theta}$m 0.2 and 0.3. But it saw the different patterns in high water content over ${\theta}$m 0.4 that was drastically declined in the initial stage and then gradually inclined . From the above results, nitrogen transformation patterns differentiated decisively in water content between ${\theta}$m 0.3 and 0.4 in soil. Thus, it is very important for the maintain of suitable soil water content to enhance fertility of soil amended with manure compost. However, excess treatment of manure compost might enhance the possibility of contamination of small watershed and ground water around agricultural area.

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The Comparative Study of the Harmony of Coloration according to Transformation of Color Area-Ratio in Traditional Korean Dress of Korean and American Students - On the similarity and contrast coloration - (치마$\cdot$저고리의 색상 면적비 변화에 따른 한$\cdot$미 여대생의 조화감 비교 연구 - 유사배색과 대비배색을 중심으로 -)

  • Kang Kyung-Ja;Moon Ju-young;Lim Ji-Young
    • Journal of the Korea Fashion and Costume Design Association
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    • v.7 no.3
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    • pp.17-26
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    • 2005
  • In this research, in order to find out the effect of the area ratio in the harmonic sense assessment of the coloration of Korean clothes, the coloration of a Korean jacket and a skirt was compounded with a similar coloration and a contrast coloration. The respondents were asked to evaluate 16 stimuli of the traditional Korean skirt and jacket with the coloration of the Korean jacket/ skirt, the skirt/ Korean jacket was separately compounded to be 4 tones such as vivid, light, dull, dark. The subjects were 44 female undergraduate students. The results of each can be summerized as follows. As to similar coloration, the korean yellow jacket and red skirt, Korean students feel vivid and dull tone was harmonious, and American students feel vivid, light, and dark tone were harmonious coloration. In inversed case, red korean jacket and yellow skirt, both countries' students recognized that the vivid tone was harmonious. Korean students gave higher points to korean traditional dress in similar coloration such as yellow korean jacket which was small area and red skirt which was large area coloration than inversed color area ratio which red korean jacket and yellow skirt. As to contrast coloration, the korean green jacket and red skirt, Korean students feel vivid tone was harmonious, and American students feel vivid, dark tone were harmonious coloration. In inversed case, red korean jacket and green skirt were recognized that any tone was not harmonious for both countries' students. Both countries of student showed the culture gap. Compared with American students, Korean students were familiar with korean dress's traditional coloration, as a result familiar coloration was recognized harmonious coloration.

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Effects os Cold Drawing Ratio on the Hardness of Inconel 718 Wire (Inconel 718 선재의 경도에 미치는 냉간신선가공의영향)

  • Jeong, Yong-Kwon;Jo, Chang-Yong;Jung, Byong-Ho;Kim, In-Bae
    • Korean Journal of Materials Research
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    • v.8 no.4
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    • pp.354-358
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    • 1998
  • Effect of cold drawing ratio and aging time on the hardness of lnconel 718 wire aged at 11l6K were investi¬gated by hardness measurement and scanning & transmission electron microscopy. Hardness which was 245Hv in as¬solution treated condition increased very rapidly to 450Hv as cold drawing ratio increased to 50%. The hardness in the early stage of aging was increased by the precipitation of $\gamma^{'}$ and $\gamma^{'}$ phases and after the peak hardness, the hardness was decreased by the transformation of $\gamma^{'}$ phase to $\delta$ phase. The time to reach peak hardness during aging appeared to be reduced with the increase of cold drawing ratio, and those times were 30, 10, and 5 minutes for 0, 30 and 50% cold drawn materials, respectively. For the 50% cold drawn material. $\gamma^{'}$ and $\gamma^{'}$ were precipitated by aging for 5 minutes at 1116K. The hardness in the same material was largely decreased under the initial hardness by the recrystallization.

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