• Title/Summary/Keyword: trans

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MO Interpretation for the trans Effect of Square Planar Type Pt(Ⅱ) Complexes (사각평면형 백금(Ⅱ) 착물의 트란스효과에 대한 분자궤도함수론적 해석)

  • Byung-Kak Park;Lee Sang-Hyup;Hwhan-Jin Yeo;Iee-Yeung Cho
    • Journal of the Korean Chemical Society
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    • v.32 no.5
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    • pp.495-500
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    • 1988
  • The trans effect has been interpreted for a series of trans-[PtNH$_3$Cl$_2$2L] (L = H$_2$O, NH$_3$, Cl$^-$, Br$^-$, I$^-$, CH$_3$ and PH$_3$) and PtCl$_4^{-2}$ by means of our modified-EHMO method. The calculation shows that reduced overlap population(ROP) of Pt-N bond trans to L is decreased with a better trans director. That is, the trans effect has been found to be enhanced with a better trans director. Accordingly, it could be interpreted quantum chemically the trans effect for a general trans-PtTL$_2$X complex.

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Effect of Temperature on Composition of Monohydroperoxide Isomers Formed in Oxidation of Methyl Linoleate (Methyl Linoleate의 산화중 형성된 Monohydroperoxide 이성체들의 조성에 미치는 온도의 영향)

  • Kim, In-Hwan;Kim, Chul-Jin;Kim, Dong-Hoon
    • Korean Journal of Food Science and Technology
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    • v.28 no.3
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    • pp.440-445
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    • 1996
  • An attempt was made to study the relative composition of Monohydroperoxide isomers of methyl linoleate oxidized to different peroxide values at 60, 90, 120 and $150^{\circ}C$, respectively. HPLC was used to analyze and isolate the monohydroperoxide isomers fractionated by silica gel column after reduction with NaBH.. GC-MS was used to identify four monnhydroperoxide isomers as trimethylsilyl (TMS) in mixtures of oxidized methyl linoleate In the geometrical isomers, the proportions of 9/13-OOH-trans, trant-diene were higher than those of 9/13-OOH-cis, trans-diene at $60^{\circ}C$ and $90^{\circ}C$. However in the initial stage at $150^{\circ}C$, the proportions of 9/13-OOH-cis, trans-diene were slightly higher than those of 9/13-OOH-trans, trans-diene. In case of positional isomers, equal proportions of 9-OOH-10, 12-diene and 13-OOH-9, 11-diene were found in all samples of methyl linoleate oxidized at different temperatures and peroxide levels.

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Characteristic Impact Odorants of Changpo (Acorus calamus var. angustatus Bess) Root Essential Oil

  • Choi, Hyang-Sook
    • Food Science and Biotechnology
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    • v.14 no.4
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    • pp.450-455
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    • 2005
  • This study was conducted to determine firstly the composition of the essential oil from fresh changpo (Acorus calamus var. angustatus Bess) roots quantitatively and qualitatively by use of two internal standards, and secondly volatile compounds which are primarily responsible for the aroma of changpo roots. Simultaneous steam distillation and extraction method was used for essential oil extraction, and aroma extract dilution analysis (AEDA) and sniffing test by gas chromatography/olfactometry (GC/O) were used to detect the characteristic impact odorants. According to the instrumental analysis of changpo root essential oil, cis, trans-famesol (47.56 mg/kg of fresh wt), octanoic acid (23.73 mg/kg of fresh wt), trans-2-dodecenal (20.28 mg/kg of fresh wt) and trans, trans-farnesol (13.81 mg/kg of fresh wt) were the most abundant compounds. Geranyl acetate, trans-nerolidol and trans, trans-farnesyl acetate were evaluated as the characteristic impact odorants of changpo roots from results of AEDA and sniffing test. Especially, geranyl acetate was considered as the most similar odor component to changpo roots by organoleptic evaluation with GC/O.

A Case Study of Line Friends Character TransMedia Branding ('라인 프렌즈' 캐릭터의 트랜스미디어 브랜딩 사례연구)

  • Chang, Hyo Jin;Kim, Young Jae
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.11 no.2
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    • pp.153-166
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    • 2015
  • This paper proposes a trans-media branding for the trans-media-based cultural content marketing strategy. Trans-media brand analytical framework is proposed with previous studies. And mobile messenger Character 'Line Friends' is analyzed for the text. Trans-media branding is accessible through a multi-platform in the technological environment. Consumer culture, as well as participate include business models to generate revenue also as brand equity. While the character elements that make up the story from the perspective of cultural content storytelling act as an independent cultural goods. Character is segmented elements. Therefore, trans- media branding of the characters are more meaningful. 'Line Friends' trans-media branding can be summarized as follows: First, it takes advantage of the characteristics of the existing Information-Technology-based mobile. Second, it puts consistently found the content of the attributes of Mobile Messenger 'communication' and 'friendship'. And third, while the content of each platform is constantly linked with other platforms, the brand is positioned inside the window effect.

Trans-Parasocial Relation Between Influencers and Viewers on Live Streaming Platforms: How Does it Affect Viewer Stickiness and Purchase Intention?

  • Kim, Jeeyeon;Liu, Jui-Ting;Chang, Sue Ryung
    • Asia Marketing Journal
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    • v.24 no.2
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    • pp.39-50
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    • 2022
  • Live streaming has become one of the most important communication tools for influencers to synchronously interact with viewers. It is critical to understand the effect of the reciprocal and synchronously interactive relations built between influencers and viewers, so-called trans-parasocial relations, in the context of live streaming. In this study, we investigate how trans-parasocial relations impact viewers' stickiness and purchase intention on live streaming platforms. Furthermore, we investigate fanship as a mediating factor in the relationship between trans-parasocial relations and viewers' behaviors. Overall, the results reveal significant direct and indirect effects of trans-parasocial relations on viewers' stickiness and purchase intention. Higher trans-parasocial relations further lead to stronger viewers' fanship toward influencers and increases their willingness to stay longer or make purchases on live streaming platforms. These findings further the understanding of influencer-viewer relations and viewers' behavior on live streaming platforms and provide valuable insights into influencer marketing and live streaming.

Preparation and Structure of trans-Bis(tert-butylamine)dichloropalladium(II), trans-[$PdCl_2(t-BuNH_2)_2$] (trans-Bis(tert-butylamine)dichloropalladium(II), trans-[$PdCl_2(t-BuNH_2)_2$의 합성 및 구조)

  • 김혜진;한원석;이순원
    • Korean Journal of Crystallography
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    • v.12 no.1
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    • pp.10-13
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    • 2001
  • Compound PdCl₂(PhCN)₂(1) reacted with tert-butylamine(t-BuNH₂) to give trans-[PdCl₂(t-BuNH₂)₂] (2) Compound 2 was characterized by spectroscopy (¹H-NMR, /sup 13/C{¹H}-NMR, and IR) and X-ray diffraction. Crystallographic data for f2: monoclinic space group p2₁/c, a=6.298(1)Å, b=20.740(2)Å, c=10.731(1)Å, β=92.58(1)°, Z=4, R(wR₂)=0.0207(0.0543).

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ON 3-DIMENSIONAL TRANS-SASAKIAN MANIFOLDS WITH RESPECT TO SEMI-SYMMETRIC METRIC CONNECTION

  • Pahan, Sampa
    • Journal of the Chungcheong Mathematical Society
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    • v.34 no.3
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    • pp.235-251
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    • 2021
  • The aim of the present paper is to study 3-dimensional trans-Sasakian manifold with respect to semi-symmetric metric connection. Firstly, we prove that extended generalized M-projective 𝜙-recurrent 3-dimensional trans-Sasakian manifold with respect to semi-symmetric metric connection is an 𝜂-Einstein manifold with respect to Levi-Civita connection under some certain conditions. Later we study some curvature properties of 3-dimensional trans-Sasakian manifold admitting the above connection.

Two Phenolic Amides from Cocculus diversifolius

  • Kim, Youn-Chul;Kingston, David G.I
    • Korean Journal of Pharmacognosy
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    • v.26 no.3
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    • pp.273-275
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    • 1995
  • Two phenolic amides were isolated from the stem of Cocculus diversifolius (Menispermaceae) and identified as N-trans-feruloyl tyramine and N-trans-feruloyl 3-methyldopamine by spectroscopic methods.

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INDEFINITE TRANS-SASAKIAN MANIFOLD WITH A TRANSVERSAL HALF LIGHTLIKE SUBMANIFOLD

  • Jin, Dae Ho
    • East Asian mathematical journal
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    • v.33 no.5
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    • pp.533-542
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    • 2017
  • We study the geometry of indefinite trans-Sasakian manifold ${\bar{M}}$ admitting a half lightlike submanifold M such that the structure vector field of ${\bar{M}}$ belongs to the transversal vector bundle of M. We prove several classification theorems of such an indefinite trans-Sasakian manifold.