• Title/Summary/Keyword: time-dependent state

Search Result 515, Processing Time 0.026 seconds

Photodissocaition Dynamics of Propiolic Acid at 212 nm: The OH Production Channel

  • Shin, Myeong Suk;Lee, Ji Hye;Hwang, Hyonseok;Kwon, Chan Ho;Kim, Hong Lae
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.11
    • /
    • pp.3618-3624
    • /
    • 2012
  • Photodissociation dynamics of propiolic acid ($HC{\equiv}C-COOH$) at 212 nm in the gas phase was investigated by measuring rotationally resolved laser-induced fluorescence spectra of OH ($^2{\Pi}$) radicals exclusively produced in the ground electronic state. From the spectra, internal energies of OH and total translational energy of products were determined. The electronic transition at 212 nm responsible for OH dissociation was assigned as the ${\pi}_{C{\equiv}C}{\rightarrow}{\pi}^*{_{C=O}}$ transition by time-dependent density functional theory calculations. Potential energy surfaces of both the ground and electronically excited states were obtained employing quantum chemical calculations. It was suggested that the dissociation of OH from propiolic acid excited at 212 nm should take place along the $S_1/T_1$ potential energy surfaces after internal conversion and/or intersystem crossing from the initially populated $S_2$ state based upon the potential energy calculations and model calculations for energy partitioning of the available energy among products.

Electro-Optic Characteristics of the Fringe-Field driven Reflective Hybrid Aligned Nematic Liquid Crystal Display (Fringe-Field 구동형 반사형 Hybrid Aligned Nematic 액정 디스플레이의 전기-광학 특성)

  • 정태봉;박지혁;손정석;송제훈;이승희
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.17 no.2
    • /
    • pp.201-206
    • /
    • 2004
  • We have performed computer simulation and experiment to obtain electro-optic characteristics of reflective hybrid aligned nematic (R-HAN) cell driven by fringe field, in which the cell consists of polarizer, optical compensation film, LC layer and reflector. Conventional R-HAN cell driven by fringe field using only the LC layer shows high wavelength dispersion at dark-state and thus viewing angle characteristic is strongly wavelength-dependent. In order to improve this demerit, we added one optical compensation film to conventional R-HAN cell. The display with optimized cell parameters shows low wavelength dispersion at dark-state and exhibits a wide viewing angle without the occurrence of grey scale inversion over a wide range of viewing angles and the contrast ratio greater than 5 over exists about 120$^{\circ}$ in vortical direction and 160$^{\circ}$in horizontal direction. Experimental results show good agreements with theoretical results and fast response time.

NUMERICAL ANALYSIS OF THERMAL STRATIFICATION IN THE UPPER PLENUM OF THE MONJU FAST REACTOR

  • Choi, Seok-Ki;Lee, Tae-Ho;Kim, Yeong-Il;Hahn, Dohee
    • Nuclear Engineering and Technology
    • /
    • v.45 no.2
    • /
    • pp.191-202
    • /
    • 2013
  • A numerical analysis of thermal stratification in the upper plenum of the MONJU fast breeder reactor was performed. Calculations were performed for a 1/6 simplified model of the MONJU reactor using the commercial code, CFX-13. To better resolve the geometrically complex upper core structure of the MONJU reactor, the porous media approach was adopted for the simulation. First, a steady state solution was obtained and the transient solutions were then obtained for the turbine trip test conducted in December 1995. The time dependent inlet conditions for the mass flow rate and temperature were provided by JAEA. Good agreement with the experimental data was observed for steady state solution. The numerical solution of the transient analysis shows the formation of thermal stratification within the upper plenum of the reactor vessel during the turbine trip test. The temporal variations of temperature were predicted accurately by the present method in the initial rapid coastdown period (~300 seconds). However, transient numerical solutions show a faster thermal mixing than that observed in the experiment after the initial coastdown period. A nearly homogenization of the temperature field in the upper plenum is predicted after about 900 seconds, which is a much shorter-term thermal stratification than the experimental data indicates. This discrepancy may be due to the shortcoming of the turbulence models available in the CFX-13 code for a natural convection flow with thermal stratification.

Hybrid Learning-Based Cell Morphology Profiling Framework for Classifying Cancer Heterogeneity (암의 이질성 분류를 위한 하이브리드 학습 기반 세포 형태 프로파일링 기법)

  • Min, Chanhong;Jeong, Hyuntae;Yang, Sejung;Shin, Jennifer Hyunjong
    • Journal of Biomedical Engineering Research
    • /
    • v.42 no.5
    • /
    • pp.232-240
    • /
    • 2021
  • Heterogeneity in cancer is the major obstacle for precision medicine and has become a critical issue in the field of a cancer diagnosis. Many attempts were made to disentangle the complexity by molecular classification. However, multi-dimensional information from dynamic responses of cancer poses fundamental limitations on biomolecular marker-based conventional approaches. Cell morphology, which reflects the physiological state of the cell, can be used to track the temporal behavior of cancer cells conveniently. Here, we first present a hybrid learning-based platform that extracts cell morphology in a time-dependent manner using a deep convolutional neural network to incorporate multivariate data. Feature selection from more than 200 morphological features is conducted, which filters out less significant variables to enhance interpretation. Our platform then performs unsupervised clustering to unveil dynamic behavior patterns hidden from a high-dimensional dataset. As a result, we visualize morphology state-space by two-dimensional embedding as well as representative morphology clusters and trajectories. This cell morphology profiling strategy by hybrid learning enables simplification of the heterogeneous population of cancer.

Optimal path planning for the capturing of a moving object

  • Kang, Jin-Gu;Lee, Sang-Hun;Hwang, Cheol-Ho;Lee, Jang-Myung
    • 제어로봇시스템학회:학술대회논문집
    • /
    • 2004.08a
    • /
    • pp.1419-1423
    • /
    • 2004
  • In this paper, we propose an algorithm for planning an optimal path to capture a moving object by a mobile robot in real-time. The direction and rotational angular velocity of the moving object are estimated using the Kalman filter, a state estimator. It is demonstrated that the moving object is tracked by using a 2-DOF active camera mounted on the mobile robot and then captured by a mobile manipulator. The optimal path to capture the moving object is dependent on the initial conditions of the mobile robot, and the real-time planning of the robot trajectory is definitely required for the successful capturing of the moving object. Therefore the algorithm that determines the optimal path to capture a moving object depending on the initial conditions of the mobile robot and the conditions of a moving object is proposed in this paper. For real-time implementation, the optimal representative blocks have been utilized for the experiments to show the effectiveness of the proposed algorithm.

  • PDF

Optimal path planning for the capturing of a moving object

  • Hwang, Cheol-Ho;Lee, Sang-Hun;Ko, Jae-Pyung;Lee, Jang-Myung
    • 제어로봇시스템학회:학술대회논문집
    • /
    • 2003.10a
    • /
    • pp.186-190
    • /
    • 2003
  • In this paper, we propose an algorithm for planning an optimal path to capture a moving object by a mobile robot in real-time. The direction and rotational angular velocity of the moving object are estimated using the Kalman filter, a state estimator. It is demonstrated that the moving object is tracked by using a 2-DOF active camera mounted on the mobile robot and then captured by a mobile manipulator. The optimal path to capture the moving object is dependent on the initial conditions of the mobile robot, and the real-time planning of the robot trajectory is definitely required for the successful capturing of the moving object. Therefore the algorithm that determines the optimal path to capture a moving object depending on the initial conditions of the mobile robot and the conditions of a moving object is proposed in this paper. For real-time implementation, the optimal representative blocks have been utilized for the experiments to show the effectiveness of the proposed algorithm.

  • PDF

Droplet Vaporization in High Pressure Environments with Pressure Oscillations (강한 압력 교란에 구속된 고압 액적의 천이 기화)

  • 김성엽;윤웅섭
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2003.10a
    • /
    • pp.157-163
    • /
    • 2003
  • A systematic numerical experiment has been conducted to study droplet gasification in high pressure environments with pressure oscillations. The general frame of previous rigorous model[1] is retained but tailored for flash equilibrium calculation of vapor-liquid interfacial thermodynamics. Time-dependent conservation equations of mass, momentum, energy, and species concentrations are formulated in axisymmetric coordinate system for both the droplet interior and ambient gases. In addition, a unified property evaluation scheme based on the fundamental equation of state and empirical methods are used to find fluid thermophysical properties over the entire thermodynamic domain of interest. The governing equations with appropriate physical boundary conditions are numerically time integrated using an implicit finite-difference method with a dual time-stepping technique. A series of calculation have been carried out to investigate the gasification of an isolated n-pentane droplet in a nitrogen gas environment over a wide range of ambient pressures and frequencies. Results show that the mean pressures and frequencies of the ambient gas have strong influences on the characteristics of the droplet gasification. The amplitude of the response increases with increasing pressure, and the magnitude of the vaporization response increases with the frequency.

  • PDF

Copula-ARMA Model for Multivariate Wind Speed and Its Applications in Reliability Assessment of Generating Systems

  • Li, Yudun;Xie, Kaigui;Hu, Bo
    • Journal of Electrical Engineering and Technology
    • /
    • v.8 no.3
    • /
    • pp.421-427
    • /
    • 2013
  • The dependence between wind speeds in multiple wind sites has a considerable impact on the reliability of power systems containing wind energy. This paper presents a new method to generate dependent wind speed time series (WSTS) based on copulas theory. The basic feature of the method lies in separating multivariate WSTS into dependence structure and univariate time series. The dependence structure is modeled through the use of copulas, which, unlike the cross-correlation matrix, give a complete description of the joint distribution. An autoregressive moving average (ARMA) model is applied to represent univariate time series of wind speed. The proposed model is illustrated using wind data from two sites in Canada. The IEEE Reliability Test System (IEEE-RTS) is used to examine the proposed model and the impact of wind speed dependence between different wind regimes on the generation system reliability. The results confirm that the wind speed dependence has a negative effect on the generation system reliability.

Jet-grouting in ground improvement and rotary grouting pile installation: Theoretical analysis

  • Wang, You;Li, Lin;Li, Jingpei;Sun, De'an
    • Geomechanics and Engineering
    • /
    • v.21 no.3
    • /
    • pp.279-288
    • /
    • 2020
  • The permeation grouting is a commonly used technique to improve the engineering geology condition of the soft ground. It is of great significance to predict the permeation range of the grout so as to ensure the effects of grouting. This paper conducts a theoretical analysis of jet-grouting effects in ground improvement and rotary grouting pile installation by utilizing deformation-permeation coupled poroelastic solutions based on Biot's theory and Laplace-Fourier integral transform technique. The exponential function and the intermittent trigonometric function are chosen to represent time-dependent grouting pressure usually encountered in ground improvement and rotary grouting pile installation process, respectively. The results, including the radial displacement, the hoop stress, the excess pore fluid pressure, the radial discharge, and the permeation radius of grout, are presented for different grouting time, radial positions and grouting lengths. Parametric study is conducted to explore the effects of variation of the exponent in the exponential grouting pressure-time relationship on grouting-induced responses. It is expected that the proposed solutions can be used to estimate the permeation range of grouting in ground improvement and rotary grouting pile installation.

Application of Optimal Control Techniques to SWATH Motion Control (반잠수 쌍동선의 최적 운동제어기 설계)

  • Chan-Wook Park;Bo-Hyeon Heo;Chun-Tae Song
    • Journal of the Society of Naval Architects of Korea
    • /
    • v.31 no.2
    • /
    • pp.65-77
    • /
    • 1994
  • This paper presents a derailed application procedure of the linear quadratic(LQ) theory for a SWATH heave and pitch control. A time domain model of coupled, linear time-invariant second order differential equations is derived from the frequency response model with the frequency dependent added mass and damping approximated as constant values at the heave natural frequency. Wave exciting forces are modeled as a sum of sinusoids. A systematic selection procedure of state and control weighting matrices is presented to obtain good transient behavior and acceptable fin movement. The validity of this controller design process is throughly investigated by simulations both in time domain and frequency domain and singular value plots of transfer function matrices. The finally designed control system shows good overall performances revealing that the applicability of the present study is proved successful.

  • PDF