• Title/Summary/Keyword: time-dependent diffusion

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Effect of Latex on Corrosion Resistance of Steel Rebar in Concrete (콘크리트 내에서 보강철근의 부식저항성에 미치는 라텍스의 효과)

  • Park, Sung-Ki;Won, Jong-Pil;Sung, Sang-Kyung;Park, Chan-Gi
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.409-412
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    • 2008
  • This study were evaluated the corrosion threshold reached at steel reinforcement in latex modified concrete(LMC). Accelerated testing was accomplished to the evalate the diffusion coefficient of LMC mix, and the time dependent constants of diffusion. Also, average chloride diffusion coefficient was estimated. From the average chloride ion diffusion coefficient, the time which critical chloride contents at depth of reinforcement steel was estimated. Test results indicated that the corrosion threshold reached at reinforcement in LMC are effected on the mix proportion factor including latex content, and water-cement ratio.

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Derivation of the First-Order Mass-Transfer Equation for a Diffusion-Dominated Zone of a 2-D Pore (2차원으로 구현한 다공성 매질의 확산주도영역에 관한 1차 물질이동 방정식의 유도)

  • Kim, Young-Woo;Seo, Byong-Min;Hwang, Seung-Min;Park, Cha-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.2
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    • pp.99-103
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    • 2010
  • A new analytic solution was derived for the diffusion into or from an immobile zone of a rectangular 2-D pore. For a long time, the new solution converges to a traditional mobile-immobile zone (MIM) model, but only if the latter is used with an apparent initial concentration that is smaller by almost 20% than the true one. This is the tradeoff for using a simple MIM model instead of an exact model based on the diffusion equation. The mass-transfer coefficient was found to be constant for a sufficiently long time; it was proportional to the molecular diffusion and inversely proportional to the square of the pore depth. The mass-transfer coefficient was time-dependent for a sufficiently short time and may be significantly larger than its asymptotic value.

Reactor core analysis through the SP3-ACMFD approach. Part I: Static solution

  • Mirzaee, Morteza Khosravi;Zolfaghari, A.;Minuchehr, A.
    • Nuclear Engineering and Technology
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    • v.52 no.2
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    • pp.223-229
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    • 2020
  • The present work proposes a solution to the static Boltzmann transport equation approximated by the simplified P3 (SP3) on angular, and the analytic coarse mesh finite difference (ACMFD) for spatial variables. Multi-group SP3-ACMFD equations in 3D rectangular geometry are solved using the GMRES solution technique. As the core time dependent analysis necessitates the solution of an eigenvalue problem for an initial condition, this work is hence devoted to development and verification of the proposed static SP3-ACMFD solver. A 3D multi-group static diffusion solver is also developed as a byproduct of this work to assess the improvement achieved using the SP3 technique. Static results are then compared against transport benchmarks to assess the proximity of SP3-ACMFD solutions to their full transport peers. Results prove that the approach can be considered as an acceptable interim approximation with outputs superior to the diffusion method, close to the transport results, and with the computational costs less than the full transport approach. The work would be further generalized to time dependent solutions in Part II.

Prediction of RC structure service life from field long term chloride diffusion

  • Safehian, Majid;Ramezanianpour, Ali Akbar
    • Computers and Concrete
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    • v.15 no.4
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    • pp.589-606
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    • 2015
  • It is well-documented that the major deterioration of coastal RC structures is chloride-induced corrosion. Therefore, regional investigations are necessary for durability based design and evaluation of the proposed service life prdiction models. In this paper, four reinforced concrete jetties exposed to severe marine environment were monitored to assess the long term chloride penetration at 6 months to 96 months. Also, some accelerated durability tests were performed on standard samples in laboratory. As a result, two time-dependent equations are proposed for basic parameters of chloride diffusion into concrete and then the corrosion initiation time is estimated by a developed probabilistic service life model Also, two famous service life prediction models are compared using chloride profiles obtained from structures after about 40 years in the tidal exposure conditions. The results confirm that the influence of concrete quality on diffusion coefficients is related to the concrete pore structure and the time dependence is due to chemical reactions of sea water ions with hydration products which lead a reduction in pore structure. Also, proper attention to the durability properties of concrete may extend the service life of marine structures greater than fifty years, even in harsh environments.

Reactor core analysis through the SP3-ACMFD approach Part II: Transient solution

  • Mirzaee, Morteza Khosravi;Zolfaghari, A.;Minuchehr, A.
    • Nuclear Engineering and Technology
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    • v.52 no.2
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    • pp.230-237
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    • 2020
  • In this part, an implicit time dependent solution is presented for the Boltzmann transport equation discretized by the analytic coarse mesh finite difference method (ACMFD) over the spatial domain as well as the simplified P3 (SP3) for the angular variable. In the first part of this work we proposed a SP3-ACMFD approach to solve the static eigenvalue equations which provide the initial conditions for temp dependent equations. Having solved the 3D multi-group SP3-ACMFD static equations, an implicit approach is resorted to ensure stability of time steps. An exponential behavior is assumed in transverse integrated equations to establish a relationship between flux moments and currents. Also, analytic integration is benefited for the time-dependent solution of precursor concentration equations. Finally, a multi-channel one-phase thermal hydraulic model is coupled to the proposed methodology. Transient equations are then solved at each step using the GMRES technique. To show the sufficiency of proposed transient SP3-ACMFD approximation for a full core analysis, a comparison is made using transport peers as the reference. To further demonstrate superiority, results are compared with a 3D multi-group transient diffusion solver developed as a byproduct of this work. Outcomes confirm that the idea can be considered as an economic interim approach which is superior to the diffusion approximation, and comparable with transport in results.

A HYBRID METHOD FOR HIGHER-ORDER NONLINEAR DIFFUSION EQUATIONS

  • KIM JUNSEOK;SUR JEANMAN
    • Communications of the Korean Mathematical Society
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    • v.20 no.1
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    • pp.179-193
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    • 2005
  • We present results of fully nonlinear time-dependent simulations of a thin liquid film flowing up an inclined plane. Equations of the type $h_t+f_y(h) = -{\in}^3{\nabla}{\cdot}(M(h){\nabla}{\triangle}h)$ arise in the context of thin liquid films driven by a thermal gradient with a counteracting gravitational force, where h = h(x, t) is the fluid film height. A hybrid scheme is constructed for the solution of two-dimensional higher-order nonlinear diffusion equations. Problems in the fluid dynamics of thin films are solved to demonstrate the accuracy and effectiveness of the hybrid scheme.

A diffusion approximation for time-dependent queue size distribution for M/G/m/N system

  • Park, Bong-Dae;Shin, Yang-Woo
    • Journal of the Korean Mathematical Society
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    • v.32 no.2
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    • pp.211-236
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    • 1995
  • The purpose of this paper is to provide a transient diffusion approximation of queue size distribution for M/G/m/N system. The M/G/m/N system can be expressed as follows. The interarrival times of customers are exponential and the service times of customers have general distribution. The system can hold at most a total of N customers (including the customers in service) and any further arriving customers will be refused entry to the system and will depart immediately without service. The queueing system with finite capacity is more practical model than queueing system with infinite capacity. For example, in the design of a computer system one of the important problems is how much capacity is required for a buffer memory. It its capacity is too little, then overflow of customers (jobs) occurs frequently in heavy traffic and the performance of system deteriorates rapidly. On the other hand, if its capacity is too large, then most buffer memories remain unused.

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A Study fur Wettability of Silicate Glasses on Silicon Nitride (질화규소와 실리케이트계 유리의 젖음성에 관한 연구)

  • 안병국
    • Journal of Welding and Joining
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    • v.20 no.3
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    • pp.116-121
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    • 2002
  • For the accumulation of a fundamental knowledge about the behavior of glass solder during the joining of ceramics, the wettability of solder on silicon nitride have been measured by sessile drop method. $SiO_2-MgO-Al_2O_3$ g1ass solder and oxynitride glass solders were selected as examples while silicon nitride which were used as substrates. Contact angle of solder on silicon nitride didn't decrease with time at high nitrogen content in the solder, but low nitrogen content in solders have the time-dependent property. Reason which contact angle of low nitrogen content in solders decrease on silicon nitride was that diffusion of nitrogen take place between solder and silicon nitride.

Influences of boron and silicon in insert alloys on microstructure and isothermal solidification during TLP bonding of a duplex stainless steel using MBF-35 and MBF-30

  • Yuan, Xinjian;Kim, Myung-Bok;Kang, Chung-Yun
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.59-59
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    • 2009
  • The influences of B and Si in the filler metals on microstructure and isothermal solidification during transient liquid-phase (TLP) bonding of a nitrogen-containing duplex stainless steel with MBF-30 (Ni-4.5wt.%Si-3.2wt.%B) and MBF-35 (Ni-7.3wt.%Si-2.2wt.%B), were studied at the temperature range of $1030-1090^{\circ}C$ with various times from 60 s to 3600 s under a vacuum of approximately $10^{-5}$ Torr. In case of the former, BN, $Ni_3B$ and $Ni_3Si$ precipitates were formed in the bonding region. BN and $Ni_3Si$ secondary phases were present in the joint for the latter case. The formation of $Ni_3B$ within the joint centerline is dependent on B content. The morphology of $Ni_3Si$ is dominated by Si concentration. A difference between the times for complete isothermal solidification obtained by the experiments and the conventional TLP bonding diffusion model was observed when using MBF-35. According to the simulated results, the isothermal solidification completion time for MBF-35 case was smaller than that in MBF-30. However, this experimental value obtained using MBF-35 was notably larger than that obtained using MBF-30. Isothermal solidification of liquid MBF-30 is controlled by the first isothermal solidification regime dependent on B diffusion model, whereas that of liquid MBF-35 experiences two isothermal solidification regimes and is mainly controlled by the second isothermal solidification dependent on Si diffusion model. In addition, only if Si content exceeds a critical value, the slower 2nd solidification regime will commence.

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Evaluation of Chloride Diffusion Characteristics in Concrete with Fly Ash Cured for 2 Years (2년 양생된 Fly Ash 콘크리트의 염화물 확산 특성 평가)

  • Yoon, Yong-Sik;Hwang, Sang-Hyeon;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.1
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    • pp.8-15
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    • 2019
  • When RC(Reinforced Concrete) structures are exposed to harsh environment, deterioration phenomenon occurs, and the corrosion in rebar due to chloride intrusion is known as representative deterioration, so called chloride attack. In this paper, chloride resistance performance of 2 years aged concrete is evaluated considering 3 levels of water to binder ratio(0.37, 0.42, and 0.47) and 2 levels of substitution ratio of fly ash(0% and 30%). Accelerated chloride diffusion coefficient tests referred to Tang's method, total passed charge tests referred to ASTM C 1202, and compressive strength tests referred to KS F 2405 are performed. With adaptation of the previous test results and the results from this study, time-dependent chloride diffusion characteristics are analyzed for each concrete. The FA(Fly Ash) concrete has higher chloride resistance performance than OPC(Ordinary Portland Cement) concrete. According to the evaluation standard of ASTM C 1202, the FA concrete has "Moderate" grade after 49 days while OPC concrete does "Moderate" grade after 365 days. As the results of time-parameter for chloride diffusion, OPC concrete and FA concrete show the decreasing behavior of time-parameters with increasing water to binder ratio. Also, FA concrete has 1.57~2.74 times of time-parameter than OPC concrete. That's cause is thought that the time-parameter indicates the gradient of decreasing of diffusion coefficient. FA concrete has higher time-parameters than OPC concrete by pozzolanic reaction of FA.