• 제목/요약/키워드: three-electrode system

검색결과 194건 처리시간 0.025초

인지질에 따른 아조벤젠기를 함유한 지방산의 전기화학적 특성 (Electrochemical Properties of Fatty Acid Containing Azobenzene for Phospholipid)

  • 박근호;손태철;이경구;김남석;박태곤
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 센서 박막재료 반도체재료 기술교육
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    • pp.43-46
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    • 2002
  • We have investgated the photoisomerization using light irradiation 8A5H-phospholipid( L-$\alpha$-dimyristoylphosphatidylcholine[DMPC], L-$\alpha$-dilauroylphosphatidylcholine[DLPC]mixture LB film accumulated by monolayer on an ITO. We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode measured in $NaClO_{4}$ solution at a variable concentration and variable number layers LB film. The scan rate was 100mV/s.

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Electrochemical Detection of Pesticide in Living Plant and Fish Brain Cell

  • Lee, Chang-Hyun;Ly, Suw-Young
    • 한국환경과학회지
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    • 제19권8호
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    • pp.941-949
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    • 2010
  • The three electrode system was used to detect the pesticide fenitrothion ($C_9H_{12}NO_5PS$. MW=277.24) using cyclic voltammetry (CV) and square wave anodic stripping voltammetry (SWASV). The working electrode was mercury immobilized on a carbon nanotube paste electrode (Hg-CNTPE). At the optimized condition, the limit of detection (LoD) was 0.6 ppt ($2.16{\times}10^{-12}\;M$), and the relative standard deviation was 0.035% (n=15). And there is more sensitive in detecting fenitrothion than common type carbon nanotube paste electrode. When it was implanted into the brain of live fish (carp), the existence of fenitrothion was measured without any destruction or damage of tissue.

The Three-Dimensional Temporal Behavior Measurement of Light Emitted From Plasma Display Panel

  • Choi, Hoon-Young;Kwon, Hyung-Seok;Lee, Seok-Hyun;Lee, Seung-Gol
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.598-600
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    • 2002
  • To improve the luminance and efficiency of AC PDP, the effects of a square pulse applied to the address electrode during a sustain-period is investigated. Through this experiment, we confirmed the improvement of luminance and efficiency. We performed the temporal behavior measurement for the light emitted from AC PDP at floating state of the address electrode and at various auxiliary voltages (including ground state) applied to the address electrode using the scanned point detecting system. In the case of using an auxiliary voltage pulse, emission starts at the inner edges of the anode and cathode simultaneously. Also, we obtained the larger two discharge volumes compared with the normal sustain discharge where address electrode is floated.

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물분해로부터 수소 제조를 위한 광촉매용 텅스텐 산화물 박막 제조 (Preparation of WO3 by using sol-gel method for photoelectrode and its application for PEC cell)

  • 홍은미;임동찬
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2015년도 춘계학술대회 논문집
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    • pp.101-101
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    • 2015
  • Photoelectrochemical water splitting is considered as a promising method of transforming solar energy into chemical energy stored in the type of hydrogen. An n-type $WO_3$ semiconductor is one of the most promising photoanodes for hydrogen production from water splitting. Films annealed at lower temperatures consisted of amorphous, whereas films annealed above $500^{\circ}C$ comprised solely of monoclinic $WO_3$. In this study, we observed photoactivity of $WO_3$ as increasing thickness of $WO_3$. And it shows good photoacivity as thickness increases. Also we tried to improve photoactivity through surface modification and bulk modification by using hydrogen treatment and conducting polymer. The photocurrent was measured in potentiostatic method with the three electrode system. A Pt wire and Ag / AgCl electrode were used as the counter electrode and the reference electrode, respectively. photocurrent-time (I-T) curve was measured at a bias potential of 0.79 V.

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아조벤젠기를 가진 지방산과 인지질 혼합 LB막의 전기화학적 특성 (Electrochemical Properties of Mixture Langmuir-Blogett Films of Fatty Acid containing Azobenzene and Phospholipid)

  • 박근호;최성현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.920-923
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    • 2004
  • We have investgated on the monolayer LB film of BASH-DMPC mixture on an ITO for the photoisomerization by light irradiation. We measured electrochemical properties by using cyclic voltammetry with a three-electrode system, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode in $NaClO_4$ solution at a variable concentration and monolayer LB films. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rate were 50, 100, 150 and 200 mV/s. As a results, LB films of 8A5H-DMPC appeared reversible process caused by the reduction-oxidation current from the cyclic voltammogram.

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AC Electrical Treeing Phenomena in an Epoxy System with Low-chlorine BDGE at Various Electric Field Frequencies

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • 제14권6호
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    • pp.324-328
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    • 2013
  • An alternating current (AC) electrical treeing phenomena in an epoxy system with low chlorine BDGE (1,4-butanediol diglycidyl ether) was studied in a needle-plate electrode arrangement. To measure the treeing propagation rate and breakdown time, a constant AC of 10 kV with three different electric field frequencies (60, 500, and 1,000 Hz) was applied to the needle-plate electrode specimen at $130^{\circ}C$ in aninsulating oil bath. The treeing propagation rate of the DGEBA/high-chlorine BDGE system was higher than that of the DGEBA/low-chlorine BDGE system and the breakdown time of the system with high-chlorine BDGE was lower than that of the system with low-chlorine BDGE. These results implied that chlorine had a negative effect on the electrical insulation property of the epoxy system. As the electric field frequency increased, the treeing propagation rate increased and the breakdown time decreased.

신경회로망과 Classifier를 이용한 부분방전패턴의 인식 (Recognition of Partial Discharge Patterns using Classifiers and the Neural Network)

  • 이준호;이진우
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 1999년도 학술대회논문집-국제 전기방전 및 플라즈마 심포지엄 Proceedings of 1999 KIIEE Annual Conference-International Symposium of Electrical Discharge and Plasma
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    • pp.132-135
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    • 1999
  • In this work, two approaches were proposed for the recognition of partial discharge patterns. The first approach was neural network with backpropagation algorithm, and the second approach was angle calculation between two operator vectors. PD signal were detected using three electrode systems; IEC(b), needle-plane and CIGRE method II electrode system. Both of neural network and angle comparison method showed good recognition performance for the patte군 similar to the trained patterns. And the number of operators to be used had a great influence on the recognition performance to the untrained patterns.

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Photoelectrocatalytic Degradation of Dyes in Aqueous Solution Using CNT/TiO2 Electrode

  • Zhang, Feng-Jun;Liu, Jin;Chen, Ming-Liang;Oh, Won-Chun
    • 한국세라믹학회지
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    • 제46권3호
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    • pp.263-270
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    • 2009
  • The effect of photoelectrocatalytic (PEC) degradation for different dyes with the CNT/$TiO_2$ electrode was studied. The prepared electrode was characterized with surface properties, structural crystallinity, elemental identification, and PEC activity. The $N_2$ adsorption data showed that the composites had decreased surface area compared with the pristine CNT. This indicated the blocking of micropores on the surface of CNT, which was further supported by observation via FESEM. XRD patterns of the composites showed that the CNT/$TiO_2$ composite contained a mixing anatase and rutile phase. EDX spectra showed the presence of C, O and Ti peaks for all samples. The decomposition efifciency of the prepared electrode was evaluated by the PEC degradation of three dyes (methylene blue (MB), rhodamine B (RH.B), methyl orange (MO)). The variations of the FT-IR spectra and pH value of dye solutions were measured during the PEC system; it was found that the CNT/$TiO_2$ electrode has better PEC degradation for MB solution than that of RH.B and MO. The proposed degradation mechanism was present.

내부식성과 경량성 향상을 위한 비금속 재질 집진판의 2단 전기집진기 집진효율 연구 (The study on collection efficiency of two-stage electrostatic precipitator using non-metallic electrode for improve corrosion resistance and light weight)

  • 안소희;이예완;김예슬;김용진;한방우;김학준
    • 한국입자에어로졸학회지
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    • 제17권2호
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    • pp.21-27
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    • 2021
  • We developed non-metallic electrodes that can replace metallic electrodes of the electrostatic precipitator(ESP) for the purpose of light weight, corrosion resistance, cost reduction. We manufactured three types of collection electrodes made of stainless steel (M), Carbon ink coating layer-Plastic sheet-Carbon ink coating layer (CPC), and Plastic sheet-Carbon ink coating layer-Plastic sheet (PCP). We studied the collection efficiency of a two-stage ESP using oil mist particles with and without collection stage by changing the flow rate, the material of collection electrode, and the applied voltage of the pre-charger module and the collection module. Here we measured concentrations of particles at diameters of 0.45 ㎛ (CMD; count median diameter) and 3.0 ㎛ (MMD : mass median diameter), as well as PM2.5 and PM10. As a result of the experiment, two-stage ESP had 22~25% higher collection efficiency in PM2.5 than one-stage ESP at the same applied voltage. The difference in collection efficiency by varying the materials of collection electrodes was less than 5%. The weight of the non-metallic electrode was only one eighth the weight of the metal electrode. CPC electrode had a thickness of 0.27 mm, which was 1.5 times thinner than a thickness of PCP electrode, so when the flow rate increased, the CPC electrodes couldn't be kept at equal intervals due to the fluttering unlike PCP electrodes. In addition, the PCP-CPC collection module of the present experiment followed the theoretical efficiency based on Deutsch equation and Cochet's charging theory.

3전극방식을 활용한 철근 콘크리트의 교류임피던스 측정 시 전기화학 셀저항의 영향 (Effect of Total Resistance of Electrochemical Cell on Electrochemical Impedance of Reinforced Concrete Using a Three-Electrode System)

  • 무함마드 알 마스루르 칸;김제경;이정재;기성훈
    • 한국구조물진단유지관리공학회 논문집
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    • 제26권6호
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    • pp.82-92
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    • 2022
  • 본 연구의 목적은 3전극방식으로 전기화학적 임피던스분광법(EIS)를 활용한 콘크리트 속 철근의 분극저항을 측정할 때 전기화학 셀저항에 따른 인가전압의 변화를 실험적으로 확인하고, 안정적인 측정값을 획득을 위한 실험조건을 찾는 것이다. 본 연구에서는 셀저항을 구성하는 요소 중 콘크리트 건조상태, 전극의 커플링상태(접촉저항) 및 상대전극의 면적을 주요변수 설정하였다. 본 연구에서는 지름 200mm인 정사각형 콘크리트 실험체 중심에 D22 철근이 부분적으로 매입된 실험체를 준비하여, 주요변수의 조합으로 구성된 다양한 실험조건에서 EIS을 수행하였으며 이때 포텐쇼스탯에서 인가된 전압을 측정하였다. 본 연구의 실험결과를 통하여, 3전극 방식으로 콘크리트 속 철근의 부식속도를 측정할 경우, 측정장치의 추종전압보다 측정 시 요구되는 인가전압이 충분히 큰 경우 셀저항의 변화는 EIS 측정에 큰 영향을 주지 않는 것을 확인하였다. 참조전극과 기준전극을 콘크리트 표면에 부착된 상태에서 EIS에서 콘크리트의 건조상태 및 상대전극의 면적에 대한 영향에 비하여 전극과 표면의 접촉저항의 영향이 지배적인 것을 확인하였다. 본 연구의 결과는 해양환경에 노출된 콘크리트와 같이 침지 및 건조 반족 조건에 노출된 콘크리트에서 3전극방식의 EIS 측정으로 철근 부식속도 및 상태평가를 위한 센서 개발에 기본 데이터로 활용될 수 있다.