• Title/Summary/Keyword: three-electrode system

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A Study on the Thermodynamic and Electrochemical Properties of MmNi5 System Hydrogen Absorbing Alloys Mixed with Nickel Powder (니켈분말 첨가에 따른 MmNi5계 수소저장합금의 열역학 및 전기화학적 특성)

  • Choi, Weon-Kyung;Cho, Tae-Hwan
    • Transactions of the Korean hydrogen and new energy society
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    • v.7 no.1
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    • pp.63-69
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    • 1996
  • Effect of nickel powder to added to the hydrogen absorbing alloy electrode of $MmNi_{4.5}-xCoxMn_{0.3}Al_{0.2}$ system alloy was investigated. The addition of nickel powder was effective for the improvement of discharging characteristic. It was found that the discharge capacity was 310mAhig when the alloy negative electrode was mixed $MmNi_{3.75}CO_{0.75}Mn_{0.3}Al_{0.2}$ and nickel powder with a mix of one to three. Still another, we have investigated thermodynamic stability of hydrogen in the alloy negative electrode. As a result, enthalpy of hydrogen and hydrogen equilibrium pressure in the alloy negative electrode were a suitable value to easy hydrogen absorption-desorption.

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A Review of Ac-impedance Models for the Analysis of the Oxygen Reduction Reaction on the Porous Cathode Electrode for Solid Oxide Fuel Cell

  • Kim, Ju-Sik;Pyun, Su-Il
    • Journal of the Korean Electrochemical Society
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    • v.8 no.2
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    • pp.106-114
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    • 2005
  • This article covers the theoretical ac-impedance models for the analysis of oxygen reduction on the porous cathode electrode f3r solid oxide fuel cell (SOFC). Firstly, ac-impedance models were explained on the basis of the mechanism of oxygen reduction, which were classified into the rate-determining steps; (i) adsorption of oxygen atom on the electrode surface, (ii) diffusion of adsorbed oxygen atom along the electrode surface towards the three-phase (electrode/electrolyte/gas) boundaries, (iii) surface diffusion of adsorbed oxygen atom m ixed with the adsorption reaction of oxygen atom on the electrode surface and (iv) diffusion of oxygen vacancy through the electrode coupled with the charge transfer reaction at the electrode/gas interface. In each section for ac-impedance model, the representative impedance plots and the interpretation of important parameters attributed to the oxygen reduction reaction were explained. Finally, we discussed in detail the applications of the proposed theoretical ac-impedance models to the real electrode of SOFC system.

A brief review on graphene applications in rechargeable lithium ion battery electrode materials

  • Akbar, Sameen;Rehan, Muhammad;Liu, Haiyang;Rafique, Iqra;Akbar, Hurria
    • Carbon letters
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    • v.28
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    • pp.1-8
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    • 2018
  • Graphene is a single atomic layer of carbon atoms, and has exceptional electrical, mechanical, and optical characteristics. It has been broadly utilized in the fields of material science, physics, chemistry, device fabrication, information, and biology. In this review paper, we briefly investigate the ideas, structure, characteristics, and fabrication techniques for graphene applications in lithium ion batteries (LIBs). In LIBs, a constant three-dimensional (3D) conductive system can adequately enhance the transportation of electrons and ions of the electrode material. The use of 3D graphene and graphene-expansion electrode materials can significantly upgrade LIBs characteristics to give higher electric conductivity, greater capacity, and good stability. This review demonstrates several recent advances in graphene-containing LIB electrode materials, and addresses probable trends into the future.

Fabrication of Micro Tool Electrode for Machining Micro Structures using Wire Electrical Discharge Grinding(WEDG) (WEDG 방법을 이용한 마이크로 구조물 가공용 미세공구 제작)

  • Park Sung-Jun;Ahn Hyun-Min;Lee Kyo-Seung
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.14 no.5
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    • pp.13-20
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    • 2005
  • Micro EDM process is generally used for machining microholes, cavities, and three dimensional shapes. For machining micro structures, first of all, micro tool electrode is indispensable and WEDG system is proposed for tool fabrication method. When using WEDG, its machining characteristics are highly affected by many EDM parameters such as applied voltage, current, rotation speed, capacitance, and pulse duration. Therefore, the design of experiment is introduced to fully understand the effect of the EDM parameters on machining tool electrode. And an attempt has been made to develop the mathematical model for predicting the size of the tool electrode by calculating spark distance. The suggested model was verified with experiment and predicted working gap distance is in good accord with the measured value.

Removal of COD and T-N caused by ETA from Nuclear Power Plant Wastewater using 3D Packed Bed Bipolar Electrode System (3D 복극충진전기분해를 이용한 원전 ETA에 의해 유발된 폐수 내 COD 및 T-N 제거)

  • Kim, Han-Ki;Jeong, Joo-Young;Shin, Ja-Won;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.3
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    • pp.409-421
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    • 2012
  • Ethanolamine (ETA) is mainly used to prevent corrosion of pipe in secondary cooling system of nuclear power plant. Condensed ETA in wastewater could increase COD and T-N when it was emitted to natural water system. Compared to conventional treatments, electrochemical oxidation process using packed bed bipolar electrodes was adopted to treat COD and T-N. According to arrangement of feeder electrode, single packed bed bipolar electrode reactor and multi-paired packed bed bipolar reactor were developed and conventional zero-valent iron (ZVI) was selected as conducting bipolar electrode. Bipolar electrodes were coordinated three-dimensionally in the reactor. The experimental results showed that COD and T-N was little removed in unit system at different pH condition (pH 8 and 11) on 100V. However, in multi-paired system that applied 600V, COD was eliminated 80.85% (anode-cathode-anode, A-C-A) and 85.11% (cathode-anode-cathode, C-A-C), respectively. T-N was also removed 96.88% (A-C-A) and 90.63% (C-A-C), simultaneously. Current efficiency was estimated both single and multi-paired system. At unit bipolar packed bed reactor, current efficiency was almost zero, however in multi-paired system, current efficiency was 300~500% at A-C-A and 250~350% at C-A-C. Current efficiency was over 100% hence it was confirmed that this system is more effective than conventional electrochemical oxidation system.

Effects of Intramuscular Electrical Stimulation Using Inversely Placed Electrodes on Myofascial Pain Syndrome in the Shoulder - A Case Series

  • Shanmugam, Sukumar;Mathias, Lawrence;Thakur, Ajay;Kumar, Dhanesh
    • The Korean Journal of Pain
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    • v.29 no.2
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    • pp.136-140
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    • 2016
  • Myofascial pain syndrome (MPS) is one of the common musculoskeletal conditions of the shoulder which may develop sensory-motor and autonomic dysfunctions at the various level of the neuromuscular system. The pain and dysfunction caused by MPS were primarily treated with physical therapy and pharmacological agents in order to achieve painfree movements. However, in recent years intramuscular electrical stimulation (IMES) with conventional electrode placement was used by researchers to maximise therapeutic values. But, in this study an inverse electrode placement was used to deliver electrical impulses intramuscularly to achieve neuro-modulation at the various level of the nervous system. Nine patients with MPS were treated with intramuscular electrode stimulation using inversely placed electrodes for a period of three weeks. All nine subjects recovered from their shoulder pain and disability within the few weeks of intervention. So, this inverse electrode placement may be more appropriate for chronic pain management.

Properties of Stretchable Electrode Pattern Printed on Urethane Film (우레탄 필름에 인쇄된 신축 가능한 전극 패턴의 특성)

  • Nam, Su-Yong;Kwon, Bo-Seok;Nam, Hyun-Jin;Nam, Ki-Woo;Park, Hyo-Zun
    • Journal of Power System Engineering
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    • v.22 no.1
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    • pp.64-71
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    • 2018
  • Currently, functional patterns are formed by screen printing on stretchable films, and they are applied to wearable and stretchable devices. In this study, three types of silver paste were prepared using three polyester binders with different Tg and molecular weights in order to impart elasticity to the conductive pattern itself. Rheological properties and DSC measurements were performed for each silver paste. Then, each silver paste was screen printing and cured by an IR dryer to evaluate adhesive strength, pencil hardness, resistance and surface shape change according to strain. As a result, it was found that the silver paste using a binder with a low Tg and a high molecular weight has the smallest resistance change depending on the strain. Namely, it was found that it is most preferable to use a binder with a low Tg and a high molecular weight as the stretchable electrode.

Enhancement of Processing Capabilities of Hippocampus Lobe: A P300 Based Event Related Potential Study

  • Benet, Neelesh;Krishna, Rajalakshmi;Kumar, Vijay
    • Korean Journal of Audiology
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    • v.25 no.3
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    • pp.119-123
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    • 2021
  • Background and Objectives: The influence of music training on different areas of the brain has been extensively researched, but the underlying neurobehavioral mechanisms remain unknown. In the present study, the effects of training for more than three years in Carnatic music (an Indian form of music) on the discrimination ability of different areas of the brain were tested using P300 analysis at three electrode placement sites. Subjects and Methods: A total of 27 individuals, including 13 singers aged 16-30 years (mean±standard deviation, 23±3.2 years) and 14 non-singers aged 16-30 years (mean age, 24±2.9 years), participated in this study. The singers had 3-5 years of formal training experience in Carnatic music. Cortical activities in areas corresponding to attention, discrimination, and memory were tested using P300 analysis, and the tests were performed using the Intelligent Hearing System. Results: The mean P300 amplitude of the singers at the Fz electrode placement site (5.64±1.81) was significantly higher than that of the non-singers (3.85±1.60; t(25)=3.3, p<0.05). The amplitude at the Cz electrode placement site in singers (5.90±2.18) was significantly higher than that in non-singers (3.46±1.40; t(25)=3.3, p<0.05). The amplitude at the Pz electrode placement site in singers (4.94±1.89) was significantly higher than that in non-singers (3.57±1.50; t(25)=3.3, p<0.05). Among singers, the mean P300 amplitude was significantly higher in the Cz site than the other placement sites, and among non-singers, the mean P300 amplitude was significantly higher in the Fz site than the other placement sites, i.e., music training facilitated enhancement of the P300 amplitude at the Cz site. Conclusions: The findings of this study suggest that more than three years of training in Carnatic singing can enhance neural coding to discriminate subtle differences, leading to enhanced discrimination abilities of the brain, mainly in the generation site corresponding to Cz electrode placement.

Enhancement of Processing Capabilities of Hippocampus Lobe: A P300 Based Event Related Potential Study

  • Benet, Neelesh;Krishna, Rajalakshmi;Kumar, Vijay
    • Journal of Audiology & Otology
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    • v.25 no.3
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    • pp.119-123
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    • 2021
  • Background and Objectives: The influence of music training on different areas of the brain has been extensively researched, but the underlying neurobehavioral mechanisms remain unknown. In the present study, the effects of training for more than three years in Carnatic music (an Indian form of music) on the discrimination ability of different areas of the brain were tested using P300 analysis at three electrode placement sites. Subjects and Methods: A total of 27 individuals, including 13 singers aged 16-30 years (mean±standard deviation, 23±3.2 years) and 14 non-singers aged 16-30 years (mean age, 24±2.9 years), participated in this study. The singers had 3-5 years of formal training experience in Carnatic music. Cortical activities in areas corresponding to attention, discrimination, and memory were tested using P300 analysis, and the tests were performed using the Intelligent Hearing System. Results: The mean P300 amplitude of the singers at the Fz electrode placement site (5.64±1.81) was significantly higher than that of the non-singers (3.85±1.60; t(25)=3.3, p<0.05). The amplitude at the Cz electrode placement site in singers (5.90±2.18) was significantly higher than that in non-singers (3.46±1.40; t(25)=3.3, p<0.05). The amplitude at the Pz electrode placement site in singers (4.94±1.89) was significantly higher than that in non-singers (3.57±1.50; t(25)=3.3, p<0.05). Among singers, the mean P300 amplitude was significantly higher in the Cz site than the other placement sites, and among non-singers, the mean P300 amplitude was significantly higher in the Fz site than the other placement sites, i.e., music training facilitated enhancement of the P300 amplitude at the Cz site. Conclusions: The findings of this study suggest that more than three years of training in Carnatic singing can enhance neural coding to discriminate subtle differences, leading to enhanced discrimination abilities of the brain, mainly in the generation site corresponding to Cz electrode placement.

Research to Achieve Uniform Plasma in Multi-ground Capacitive Coupled Plasma

  • Park, Gi-Jeong;Lee, Yun-Seong;Yu, Dae-Ho;Lee, Jin-Won;Lee, Jeong-Beom;Jang, Hong-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.247.1-247.1
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    • 2014
  • The capacitive coupled plasma is used widely in the semiconductor industries. Especially, the uniformity of the industrial plasma is heavily related with defect ratio of devices. Therefore, the industries need the capacitive coupled plasma source which can generate the uniform plasma and control the plasma's uniformity. To achieving the uniformity of the large area plasma, we designed multi-powered electrodes. We controlled the uniformity by controlling the power of each electrode. After this work, we started to research another concept of the plasma device. We make the plasma chamber that has multi-ground electrodes imaginary (CST microwave studio) and simulate the electric field. The shape of the multi-ground electrodes is ring type, and it is same as the shape of the multi-power electrodes that we researched before. The diameter of the side electrode's edge is 300mm. We assumed that the plasma uniformity is related with the impedance of ground electrodes. Therefore we simulated the imaginary chamber in three cases. First, we connected L (inductor) and C (capacitor) at the center of multi-ground electrodes. Second, we changed electric conductivity of multi-ground electrode. Third, we changed the insulator's thickness between the center ground electrode and the side ground electrode. The driving frequency is 2, 13.56 and 100 MHz. We switched our multi-powered electrode system to multi-ground electrode system. After switching, we measured the plasma uniformity after installing a variable vacuum capacitor at the ground line. We investigate the effect of ground electrodes' impedance to plasma uniformity.

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