• Title/Summary/Keyword: three different solutions

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Removal of Cu(II) with the Recycled Hydroxylapatite from Animal Bones (동물뼈로부터 재활용된 hydroxylapatite를 이용한 Cu(II) 제거)

  • Kim, Mu-Nui;Kim, Won-Gee;Lee, Seung-Mok;Yang, Jae-Kyu
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.9
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    • pp.735-742
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    • 2009
  • The bone of spinal animals has a hydroxylapatite ($Ca_{10}(PO_4)_6(OH)_2$, HAp) structure which is well known as an excellent inorganic ion exchanger for various heavy metal ions in solutions. In this study, the reusability of cow-bone, pig-bone and fish-bone as a potential material for the removal of heavy metals in solutions was evaluated from the removal of Cu(II) ion in batch tests. The surface properties of three bones, calcined at different temperatures, were measured with SEM, XRD, FT-IR analyses. From the SEM analysis, a clear development of heterogeneity as well as pores having small diameter was observed as the calcination temperature increased. The results of X-ray diffraction analysis showed well developed crystallinity on the surface of calcined bones obtained at higher temperatures, suggesting a transform of amorphous type to crystalline type. Fourier transform infrared (FT-IR) analysis showed disappearance of water molecule on the surface of HAp and organic functional groups of the HAp with increasing the calcination temperatures. Cu(II) removal in the control test was below 15%. By the way, additional 40% increase of Cu(II) removal was observed in the presence of calcined bones. For three bones, Cu(II) removal was decreased as the calcined temperature increased. Cu(II) removal was increased as the solution pH increased due to a favorable condition for the cation exchange as well as precipitation.

Effects of Exposure to Vitrification Solution on Maturation, Fertilization and Development of Immature Porcine Oocytes In Vitro (유리화 동결액 노출이 돼지 미성숙 난포란의 성숙율, 수정율 및 배발달율에 미치는 영향)

  • Choi I. K.;Seok S. H.;Kim K. S.;Song H. B.
    • Reproductive and Developmental Biology
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    • v.28 no.3
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    • pp.173-179
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    • 2004
  • This study was conducted to investigate the toxi-cological effects of different vitrification solution on development of immature porcine oocytes in vitro. Oocytes were exposed to EFS solution [40% ethylene glycol (EG) + 18% Ficoll + 0.3M sucrose], ES solution (5.5M EG + 1.0M sucrose) or GE solution [10% glycol (G) + 20% EG], and these oocytes were transferred to sucrose solution directly. Maturation rates were significantly (P<0.05) higher in the ES solution (44.5%) and control (57.6%) than in the EFS solution (38.8%) and GE solution (22.4%). No differences among three solution were found in fertilization rates. Cleavage rates was significantly (P<0.05) higher in the ES solution (47.1%) and control (65.9%) than in the EFS solution (21.9%) and GE solution (19.0%), but no difference among three solutions was found in the blastocyst formation rates. These results indicate that combination of EG and sucrose solutions had effects on development of immature porcine oocytes.

Study on analysis of PAHs in consumer products (공산품 함유 PAHs 분석법에 관한 연구)

  • Song, Moon Hwan;Cho, Young Dal;Choe, Eun Kyung
    • Analytical Science and Technology
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    • v.27 no.4
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    • pp.201-212
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    • 2014
  • Polycyclic aromatic hydrocarbons (PAHs) that are carcinogenic and persistent will be restricted in consumer products from December 27, 2015 by EU REACH regulation. Pretreatment using Soxhlet extraction and quantitative analysis by GC-MS were studied to develop the method for analyzing 18 PAHs in consumer products as well as to detect the amounts and the kinds of PAHs in consumer products such as grips of a bag and a hammer, a cable and a plastic sandal. Linearity and precisions were evaluated by analyses of the standard PAH solutions ranging from 0.3125 mg/L to 5.00 mg of each of 18 PAHs. Linearity of resulting standard curves for all 18 PAHs were obtained with $R^2$ above 0.999. Precisions of the retention times and the peak areas were found to be 0.00%~0.05% and 1.16%~3.69% of relative standard deviations, respectively. The recoveries for spiked samples were all around 95%~105% after Soxhlet extration using three different solvents such as dichloromethane, hexane and toluene. The limits of quantitation for 18 PAHs in solutions and polymer samples by GC-MS were evaluated to be 0.327 mg/L (Benzo[ghi]perylene)~0.464 mg/L (Acenaphthylene) and 1.635 mg/kg (Benzo[ghi]perylene)~2.32 mg/kg (Acenaphthylene) based upon dilution factor of 5, respectively. Under the developed analytical method, only trace amounts of phenanthrene were detected in three samples while 15 kinds of PAHs including phenanthrene were detected in a grip of hammer with concentrations of maximum 83.4 mg/kg of Phenanthrene and minimum 8.5 mg/kg of Acenaphthylene. Further studies are needed to decrease the quantitation limit and to check the feasibility of decreasing Soxhlet time as well as to demonstrate cases that the clean up is required.

Exploring the Epistemic Goals and Features of Biology-Related Knowledge Construction Activities Shaped by Pre-Service Elementary Teachers as Epistemic Agents (초등 예비교사가 인식적 행위주체로서 고안한 생명과학 관련 지식 구성 활동의 인식적 목표 및 특성 탐색)

  • Ha, Heesoo
    • Journal of The Korean Association For Science Education
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    • v.41 no.1
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    • pp.47-57
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    • 2021
  • This study aims to explore the epistemic goals that pre-service elementary teachers can construct in their biology-related knowledge construction activities, how these goals are constructed, and how the shaping of the knowledge construction activities around the goals was afforded or constrained. The research participants were 26 pre-service teachers, divided into 11 groups of two or three to engage in the activity. Their discussions and products were collected and used as data for this study. The analysis revealed that the teachers constructed three types of epistemic goals: making sense of natural phenomena, proposing the most effective course of action, and proposing solutions to problems based on their causes. Construction of different types of goals depended on the conclusions the pre-service teachers expected to draw based on the explored natural phenomena. It was found that the elicitation of the pre-service teachers' epistemic goals could facilitate their shaping of the knowledge construction activity as an evidence-based justification. The participants planned the construction of mechanistic explanations of natural phenomena with the epistemic goals of 'making sense of natural phenomena' or 'proposing solutions to problems based on their causes.' However, enacting their knowledge construction plans with sophisticated epistemic features was constrained due to the limited resources available. This study can contribute to developing instructional strategies that facilitate learners' epistemic agency and addressing epistemic agency in the development of pre-service teacher education methods.

Effects of the Water Quality on the Dispersion Properties of Bentonites Used for Drilling Fluid (시추이수용 벤토나이트의 분산 특성에 미치는 수질의 영향)

  • Akther, Shamima;Hwang, Jin-Yeon;Lee, Hyo-Min
    • Journal of the Mineralogical Society of Korea
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    • v.20 no.1 s.51
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    • pp.21-33
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    • 2007
  • The dispersion/flocculation behavior of bentonite is a major concern in performance of drilling fluid. We studied the dispersion/flocculation characteristics of three commercial bentonites [two CMC (carboxymethyl cellulose) treated and one untreated] in waters of different pHs and salt concentrations. We also examined changes in the viscosity of bentonite suspensions in such waters as a major rheological property of drilling fluid. The dispersion/flocculation behaviors of bentonites were measured by two methods: colorimetric and light scattering method. Light scattering method allows estimating the floc diameter and flocculation rate. The dispersion and flocculation behaviors were diverse with the different bentonites and water qualities. In distilled water, all the bentonites were well dispersed up to first 10 minutes. After that, the CMC-bearing bentonites were flocculated. In salt waters, all the samples were flocculated and the flocculation rate is varied with salt concentration and polymer content. The volume of settled flocs decreased with increasing salt concentration. The flocculation rate and floc diameter increased with decreasing pH of solutions, whereas the volume of settled flocs increased with increasing pH of solutions. The bentonites of fast flocculation behavior had low viscosity. The results of the present study will be helpful in applying bentonites to drilling fluids in diverse environments.

The heat transfer characteristics of viscoelastic non-newtonian fluids in the entrance region of circular tube flows (원형관속을 유동하는 점탄성 유체의 입구 영역 열전달 특성에 관한 연구)

  • 엄정섭;황태성;유상신
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.5
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    • pp.1032-1043
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    • 1989
  • The heat transfer characteristics of the drag reducing polymer solutions are investigated experimentally in the thermal entrance region of circular tube flows. Fluids used in experiments are the aqueous solutions of high molecular polymer, polyacrylamide Separan AP-273 and the range of polymer concentrations is from 20 to 1000 wppm. Two stainless steel tubes with inside diameter 8.5mm(L/D=712) and 10.3mm(L/D=1160) are used for the heat transfer flow loops. The flow loop is set up to measure friction factors and heat transfer coefficients of test sections in two different modes; the recirculating flow system and once-through flow system. The test tubes are heated directly by electricity to apply the constant heat flux boundary conditions to the wall. Three different types of adaptors are used to observe the effects of the upstream flow conditions of the heat transfer test sections. The viscosity and characteristic relaxation time of the test fluids circulating in the flow system are measured by the capillary tube viscometer and falling ball viscometer at regular time intervals. The installed adaptors exhibit slight effect on the entrance heat transfer of Newtonian fluid. However, no noticeable effects are observed for the entrance heat transfer of the drag reducing fluids. The order of magnitude of the thermal entrance lengths of the drag reducing fluids which follow the minimum friction asymptote is much longer than that of Newtonian fluids in turbulent flows. A new dimensionless parameter, the viscoelastic Graetz number, is defined and all the experimental data are recasted in terms of the viscoelastic Graetz number. The local Nusselt number of the viscoelastic fluids is represented as a function of flow behavior index n and the viscoelastic Graetz number. As degradation continues the viscosity and the characteristic relaxation time of the testing fluids decrease. Weissenberg number defined by the relaxation time and D/V appears to be a proper dimensionless parameter in describing degradation effects on heat transfer of the viscoelastic fluids.

THE EFFECT OF IMMERSION DISINFECTION ON THE DIMENSIONAL STABILITY OF RUBBER IMPRESSION MATERIALS (침적 소독이 고무 인상재의 크기 안정성에 미치는 영향)

  • Min, Geun-Nam;Vang, Mong-Sook
    • The Journal of Korean Academy of Prosthodontics
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    • v.36 no.3
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    • pp.496-505
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    • 1998
  • The purpose of this study was to evalute the effect of immersion disinfection on the dimensional stability of rubber impression materials. The metallic master model was made in order to simulate the intraoral arch form. Impressions were made from four impression materials (Exaflex, Extrude, Reprosil, Impregum-F) and immersed in three disinfectant solutions (Wydex, Vi-Pon, Potadine). Casts from the impressions were measured according to the interpreparation distance. The A-B and The B-D abutment distance were compared with the control group and disinfected groups. The results were as follows; 1. The measurements of the stone cast increased relative to the master model and there was a significant difference (P<0.05). 2. The relative dimensional change of the stone cast as compared with master model ranged from 0.10% to 0.56% in the A-B distance and ranged from 0.04% to 0.27% in the B-D distance. 3. The dimensional change of the disinfected groups as compared with the control group was significantly different in the three impression materials except for Impregum-F (P<0.05). 4. The relative dimensional change of the disinfected groups compared with the control group ranged from 0% to 0.20% in the A-B distance and ranged from -0.09% to 0.11% in the B-D distance. These results suggest that immersion disinfection of rubber impression materials by chemical disinfectants causes very small dimensional change and the change is clinically acceptable for prothesis fabrication

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A Study on Preservation of Chicken Products (계육의 보존성에 관한 연구)

  • Seo Jeong-Sook;Bang Byung-Ho;Jeong Eun-Ja
    • The Korean Journal of Food And Nutrition
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    • v.19 no.1
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    • pp.47-52
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    • 2006
  • This study was carried out to improve the preservation and the functionality of chicken legs. Three precipitation solutions of common solution(A), herb solution(B) and herb solution containing chitosan(C) were prepared. The chicken legs were treated with A, B and C solution, respectively, during 4 hours. And the chicken legs treated with each solution were stored at $7^{\circ}C$ for 8 days. The quality changes of each groups were examined by pH, total bacteria, VBN(volatile basic nitrogen) values and sensory evaluation. The pH values of three groups were not different. Chicken legs treated with C solution showed the lowest VBN values and total bacteria cell count and the highest sensory scores in color and flavor.

Desorption of Adsorbed Humic Acid on Carbon nano Tubes (카본나노튜브에 흡착된 휴믹산의 탈착에 관한 연구)

  • Jo, Mihyun;Lee, Jai-Young
    • Journal of Soil and Groundwater Environment
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    • v.18 no.7
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    • pp.81-89
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    • 2013
  • Concerns have been raised over the impact of nano materials on soil and groundwater environment with the increasing attention to the potential applications of carbon nano materials in various fields. Particularly, carbon nano materials introduced into water environment readily make complexes with humic acid (HA) due to their hydrophobic nature, so there have been increasing numbers of studies on the interaction between HA and carbon nano materials. In this study, we investigated the solubility of HA and multiwalled carbon nanotubes (MWCNT) in three different surfactant solutions of sodium dodecyl sulfate (SDS), Brij 30 and Triton X-100, and evaluated whether the HA can be effectively desorbed from the surface of MWCNT by surfactant. The objective of this study was to determine the optimal adsorption condition for HA to MWCNT. Futhermore, sodium dodecyl sulfate (SDS), Brij 30, Triton X-100 were used to elucidate the effect of desorption and separation on adsorbed HA on MWCNT. As a result, HA solution with 12.7 mg of total organic carbon (TOC) and 5 mg of MWCNT showed the highest adsorption capacity at pH 3 reacted for 72 hrs. Weight solubilizing ratio (WSR) of surfactants on HA and MWCNT was calculated. HA had approximately 2 times lower adsorption capacity for the applied three surfactants compared to those of MWCNT, implying that the desorption of HA may occur from the HA/MWCNT complex. According to the results of adsorption isotherm and weight solubilizing ratio (WSR), the most effective surfactants was the SDS 1% soluiton, showing 53.63% desorption of HA at pH 3.

Characteristic Analysis of Voltage Sags Due to Faulted Distribution Lines (배전선로 고장에 의한 Voltage Sag의 특성 해석)

  • ;Madhat M. Morcos
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.16 no.1
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    • pp.76-84
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    • 2002
  • Voltage sags caused by line faults in transmission and distribution lines have become one of the most important power quality problems facing industrial customers and utilities. Voltage sags are normally described by characteristics of both magnitude and duration, but phase angle shifts should be taken account in identifying sag phenomena and finding their solutions. In this paper, voltage sags due to line faults such as three phase-to-ground, single line-to-ground, and line-to-line faults are characterized by using symmetrical component analysis, for fault impedance variations. Voltage sags and their effect on the magnitude and phase angle are examined. Balanced sags of three phase-to-ground faults show that voltages and currents are changed with equivalent levels to all phases and the zero sequence components become zero. However, for unbalanced faults such as single line-to-ground and line-to-line faults, voltage sags give different magnitude variations and phase angle shifts for each phase. In order to verify the analyzed results, some simulations based on power circuit models are also discussed.