• 제목/요약/키워드: thixotropic index

검색결과 20건 처리시간 0.029초

SBR, 폴리우레탄 및 에폭시 라텍스를 혼합한 폴리초산비닐 에멀젼 수지의 점성에 관한 연구 (A Study on the Viscous Properties of Polyvinyl Acetate Emulsion Mixed with SBR, Polyurethane and Epoxy Latex)

  • 최상구;서원동;박인숙
    • Elastomers and Composites
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    • 제33권2호
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    • pp.83-92
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    • 1998
  • SBR latex, polyurethane latex and epoxy latex were mixed with polyvinyl acetate emulsion in 0~15% (wt.%). For the mixtures, the viscous properties were examined. The viscosity was influenced by the dispersed phase and the chain structures of polymer, and decreased with the rising of temperatures. The viscosity was increased with mixing of epoxy latex, but decreased with addition of SBR latex or polyurethane latex. Thixotropic index was influenced on the size of micelle and hydrogen bond. The thixotropic index was increased with mixing of epoxy latex or polyurethane latex within 5%, but keep up equality over that. The thixotropic index was decreased with mixing of SBR latex within 5%, but keep up equality over that. The relative viscosity were influenced on the activity of molecule and the interference of dispersed phases, was increased with the rising of temperatures. The relative viscosity was decreased with mixing of epoxy latex, but increased with mixing of SBR latex or polyurethane latex.

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제산제 알루미나수화물의 콜로이드성과 제산능 (Collodial Properties and Acid Consuming Capacity of Hydrous Aluminum Oxide Suspension)

  • 이계주;이기명
    • 약학회지
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    • 제35권4호
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    • pp.277-282
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    • 1991
  • Rheological, colloidal and micromeritical properties were followed to investigate aging mechanisms of hydrous aluminum oxide suspension using Zeta-meter systems, BET adsorption apparatus, Master sizer and electronmicroscope. The results indicate that hydrous aluminum oxide suspension revealed plastic flow with thixotropy. The viscosity, thixotropy and yield value were increased with increasing concentration. During aging process, the viscosity and thixotropic index were increased by an addition of glycerin, however, sorbitol stabilized aging process of the suspension being accompanied with growth of particle size and reduction in specific surface area, pore area and pore volume, and consistency. Diminution of adsorptive power of the particles was also protected by addition of sorbitol to hydrous aluminum oxide suspension. From these results, one of aging mechanism of hydrous aluminum oxide suspension assumed growth and/or crystallization of colloidal particles in aqueous suspension.

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고추장의 유동(流動) 특성(特性)에 관(關한) 연구(硏究) (Studies on Rheological Characteristics of Red Pepper Pastes)

  • 변유량;이신영;이상규;유주현;권윤중
    • 한국식품과학회지
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    • 제12권1호
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    • pp.18-23
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    • 1980
  • 회전 점도계를 사용하여 온도 $25{\sim}55^{\circ}C$에서 시판고추장의 유동학적 거동을 조사하고 다음의 결과를 얻었다. 1. 고추장은 전단 속도 $0.323{\sim}1.653\;sec^{-1}$에서 의가소성을 나타내며 항복치를 가지며 시간 의존성을 나타내는 thixotropic 식품이었다. 2. 전단 속도 0.978 $sec^{-1}$에서 유동 지수, 조밀도 지수, 항복치는 각각 0.597, 192.3 dyne $sec^s/cm^{2}$, 91 dyne/$cm^{2}$ 이었다. 3. 고추장의 시간 경과에 따른 겉보기 점도 변화는 초기 20분 동안에는 2차 반응 속도식에 따라 붕괴되었으나 그 이후는 시간에 거의 무관하였다. 4. 고추장의 온도 변화에 따른 겉보기 점도 변화는 Andrade 식에 따랐으며 이 식으로부터 구한 유동에 대한 활성화 에너지는 1.03 kcal/$g{\cdot}mole$이었다.

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토마토케찹 현탁액의 리올로지 특성과 점성예측모델 (Rheological Characteristics and Viscosity Prediction Models of Tomato Ketchup Suspensions)

  • 하성권;최용희
    • 한국식품과학회지
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    • 제20권6호
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    • pp.812-819
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    • 1988
  • 토마토케찹의 리올로지 성질을 온도 $30-90^{\circ}C$, 농도 15-50% 전단속도 $0-250sec^{-1}$띤 범위에서 Brabender viscotron를 사용하여 측정한 결과는 다음과 같다. 토마토케찹은 전단속도 $0-210sec^{-1}$에서 의가소성을 나타내며, 항복응력을 가지는 Binghampseudoplastic으로 시간의존성을 나타내는 thixotropic 식품이었다. 전단속도 $0-210sec^{-1}$, 온도 $30^{\circ}C$, 농도 33%의 경우 유동지수, 점조도지수 및 항복응력은 각각 0.2131, 22.5047$(Pasec^{-n})$ 및 8.5443(Pa)이었다. 토마토케찹의 온도 및 농도에 따른 겉보기 점도 관계식은 각각 Andrade및 Power type식으로 나타낼 수 있었으며, 또한 온도와 농도에 따른 겉보기점도 관계식은 지수함수 모델로 표현할 수 있었다. 활성화 에너지는 농토 15,20,30,33,40 및 50%에서 3.973, 4.985, 5.078, 5.226, 5.357 및 7.655 kcal/g mole이었다.

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쌀의 지방과 단백질이 쌀가루 호화액의 리올리지 특성에 미치는 영향 (Effect of Rice Lipid and Protein on Rheological Characteristics of Gelatinized Rice Flour Solutions)

  • 이영순;김인호;김현정;이상효;이현유;박광희
    • 한국식품영양과학회지
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    • 제28권6호
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    • pp.1293-1297
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    • 1999
  • Effect of rice protein and lipid on rheological properties of gelatinized rice flour solutions(4%) with three rice varieties(Dongjin, Jinmi, Tamjin) known for varying taste of cooked rice was investigated with Haake viscometer. The rheological behaviors of all rice flour solutions were illustrated by Herschel Bulkley equation and exhibited pseudoplastic behavior with yield stress. When rice flour solutions treated with protease and dithiothreitol, there was decreased in flow behavior index value. Flow behavior index was decreased by dealbumin and deglutelin rice flour solutions among deprotein groups. The Jinmi rice flour solutions exhibited slightly lower consistency index than Dongjin and Tamjin. Defatted rice flour solutions exhibited lower consistency index than rice flour solutions, while dealbumin, deglutelin rice flour solutions exhibited high consistency index. Protease treated rice flour solutions exhibited increase in Dongjin and Tamjin. The yield stress was increased in sequence eating quality. Yield stress of defatted rice flour solutions was decreased, while deglutelin and rice starch flour solutions was increased. The time dependent charac teristics of all rice flour solutions appeared forming hysteresis loop and thixotropic behavior showed. The time dependent characteristics was appeared in sequence eating quality. Rice starch and deglutelin flour solutions appeared greatly time dependent characteristics, but defatted rice flour solutions appeared very little.

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된장 현탁액의 리올로지적 성질 (Rheological Properties of Doen-Jang(Korea Fermented Soybean Paste) Suspensions)

  • 이철원;황응수;이신영;변유량
    • 한국식품과학회지
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    • 제22권2호
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    • pp.111-115
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    • 1990
  • 원료 성분조성이 다른 시판용 정맥 및 소맥된장의 두 종류 시료를 대상으로 하여 여러 농도의 물 현탁액 (50-200v/w%)을 조제하고 각 현탁액의 리올로지적 거동을 검토하였다. 각 시료 된장 현탁액은 모두 thixotropic 거동을 보였으며, 가수량이 125% 이하인 고농도 현탁액의 경우 전단상승곡선과 하강곡선이 교차하는 Figure-eight 현상을 나타내었다. 시료 모두 가열에 따라 겉보기 점도가 뚜렷한 증가 경향을 보였으며 단백질의 등전점 부근에서 겉보기 점도가 가장 높은점, 가수량 200%의 묽은 현탁액의 경우 $60^{\circ}C$이상으로 가열했을 때 Figure-eight 현상을 보이는 점 등을 종합하여 볼 때 점성거동은 단백질 존재상태와 밀접한 관련을 갖는 것으로 추정되었다.

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Rheological Characterization of Hydrogen Peroxide Gel Propellant

  • Jyoti, B.V.S.;Baek, Seung Wook
    • International Journal of Aeronautical and Space Sciences
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    • 제15권2호
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    • pp.199-204
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    • 2014
  • An experimental investigation on the rheological behavior of gelled hydrogen peroxide at different ambient temperature (283.15, 293.15 and 303.15 K) was carried out in this study. The gel propellant was rheologically characterized using a rheometer, in the shear rate ranges of 1 to $20s^{-1}$, and 1 to $1000s^{-1}$. Hydrogen peroxide gel was found to be thixotropic in nature. The apparent viscosity value with some yield stress (in-case of shear rate 1 to $20s^{-1}$) drastically fell with the shear rate. In the case of the shear rate range of 1 to $20s^{-1}$, the apparent viscosity and yield stress of gel were significantly reduced at higher ambient temperatures. In the case of the shear rate range of 1 to $1000s^{-1}$, no significant effect of varying the ambient temperature on the gel apparent viscosity was observed. The up and down shear rate curves for hydrogen peroxide gel formed a hysteresis loop that showed no significant change with variation in temperature for both the 1 to $20s^{-1}$ and the 1 to $1000s^{-1}$ shear rate ranges. No significant change in the thixotropic index of gel was observed for different ambient temperatures, for both low and high shear rates. The gel in the 1 to $20s^{-1}$ shear rate range did not lead to a complete breakdown of gel structure, in comparison to that in the 1 to $1000s^{-1}$ shear rate range.

폴리아미드가 함유된 PVC졸 실란트의 유변학적 물성 (Rheological Properties of Polyamide-Modified PVC-sol Sealants)

  • 이승진;이원기;강태규;조원제;하창식
    • Elastomers and Composites
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    • 제33권5호
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    • pp.345-354
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    • 1998
  • 폴리아미드 수지가 첨가된 PVC졸 실란트의 유변학적 물성에 대해 연구하였다. PVC졸은 디옥틸프탈레이트로 PVC를 가소화시켜 제조된 것이다. 아민가가 달라 점도가 다른 두 종류의 폴리아미드를 사용하였는데 PVC졸의 점도, 틱소트로피 및 비중에 미치는 폴리아미드 수지 종류와 함량의 영향을 고찰하였다. 폴리아미드가 첨가된 PVC졸 실란트의 점도는 폴리아미드의 종류에 관계없이 시간에 따라 증가되었으나 폴리아미드 함량의 영향에 관해서는 아민가가 낮은 폴리아미드 수지 A가 첨가된 PVC졸 실란트의 점도는 폴리아미드 A함량에 따라 증가되고, 반면 아민가가 높은 폴리아미드B가 첨가된 PVC졸 실란트의 점도는 폴리아미드 B함량에 따라 감소되었다. 폴리아미드가 첨가된 PVC졸 실란트의 틱소트로피는 폴리아미드의 종류에 관계없이 그 함량에 따라 다른 거동을 보였다. $45^{\circ}C$의 수조에서 숙성한 후의 폴리아미드가 첨가된 PVC졸 실란트의 점도거동과 충진제인 $CaCO_3$ 함량의 영향도 고찰하였다.

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Ag Paste Using Ag Nanowires

  • Hong, Jun-Ui;Kim, Dae-Jin;Kong, Byung-Seon;Kim, Sang-Ho
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.546-546
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    • 2012
  • Traditional screen printing is still a dominant method to print electrodes on c-Si solar cells. In order to achieve higher efficiency for c-Si solar cells, improvement of the electrode material is one of the key approaches. Shadowing loss can be reduced by using high aspect ratio finger electrode with width of finger electrode less than 80um. The rheological properties of Ag paste for applying c-Si solar cells are improved by using Ag nanowires. The printing properties including the aspect ratio of printed electrode can be improved with higher Thixotropic index (T.I.) values.

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고무상 복합물로 표면처리 된 실리카를 충전한 에폭시수지의 점성에 관한 연구 (Viscous Properties of Epoxy Resin Filled with Rubber Complex-Treated Silica)

  • 홍석표;최상구
    • Elastomers and Composites
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    • 제26권4호
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    • pp.296-303
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    • 1991
  • Surface of crystalline silica was sequentially reacted with silane(A 187), liquid $rubber(CTBN{\times}8)$, and vinyl monomer(GMA) in existence of TEA(triethylamine) or BPO(benzoyl peroxide). It was mixed with epoxy resin at a ratio $0{\times}60%$ (vol. % ) of total component. For mixtures, viscous properties were investigated experimentally. 1) Coating ratio depended on pH of mixture and quantity of catalyst. 2) Treated silica represented lower viscosity than untreated. 3) Thixotropic index represented best at silica_content $15{\sim}23%$ and showed more large deviation over $120^{\circ}C$. 4) Relative viscosity followed kernel's at $0{\times}10%$ of silica content and get out of Mooney's at more than 15%.

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