• Title/Summary/Keyword: thixotropic index

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A Study on the Viscous Properties of Polyvinyl Acetate Emulsion Mixed with SBR, Polyurethane and Epoxy Latex (SBR, 폴리우레탄 및 에폭시 라텍스를 혼합한 폴리초산비닐 에멀젼 수지의 점성에 관한 연구)

  • Choi, Sang-Goo;Suh, Won-Dong;Park, In-Suk
    • Elastomers and Composites
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    • v.33 no.2
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    • pp.83-92
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    • 1998
  • SBR latex, polyurethane latex and epoxy latex were mixed with polyvinyl acetate emulsion in 0~15% (wt.%). For the mixtures, the viscous properties were examined. The viscosity was influenced by the dispersed phase and the chain structures of polymer, and decreased with the rising of temperatures. The viscosity was increased with mixing of epoxy latex, but decreased with addition of SBR latex or polyurethane latex. Thixotropic index was influenced on the size of micelle and hydrogen bond. The thixotropic index was increased with mixing of epoxy latex or polyurethane latex within 5%, but keep up equality over that. The thixotropic index was decreased with mixing of SBR latex within 5%, but keep up equality over that. The relative viscosity were influenced on the activity of molecule and the interference of dispersed phases, was increased with the rising of temperatures. The relative viscosity was decreased with mixing of epoxy latex, but increased with mixing of SBR latex or polyurethane latex.

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Collodial Properties and Acid Consuming Capacity of Hydrous Aluminum Oxide Suspension (제산제 알루미나수화물의 콜로이드성과 제산능)

  • 이계주;이기명
    • YAKHAK HOEJI
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    • v.35 no.4
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    • pp.277-282
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    • 1991
  • Rheological, colloidal and micromeritical properties were followed to investigate aging mechanisms of hydrous aluminum oxide suspension using Zeta-meter systems, BET adsorption apparatus, Master sizer and electronmicroscope. The results indicate that hydrous aluminum oxide suspension revealed plastic flow with thixotropy. The viscosity, thixotropy and yield value were increased with increasing concentration. During aging process, the viscosity and thixotropic index were increased by an addition of glycerin, however, sorbitol stabilized aging process of the suspension being accompanied with growth of particle size and reduction in specific surface area, pore area and pore volume, and consistency. Diminution of adsorptive power of the particles was also protected by addition of sorbitol to hydrous aluminum oxide suspension. From these results, one of aging mechanism of hydrous aluminum oxide suspension assumed growth and/or crystallization of colloidal particles in aqueous suspension.

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Studies on Rheological Characteristics of Red Pepper Pastes (고추장의 유동(流動) 특성(特性)에 관(關한) 연구(硏究))

  • Pyun, Yu-Ryang;Lee, Shin-Young;Lee, Sang-Kyo;Yu, Ju-Hyun;Kwon, Yoon-Jung
    • Korean Journal of Food Science and Technology
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    • v.12 no.1
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    • pp.18-23
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    • 1980
  • Rheological behaviors of red pepper paste acre investigated with rotational viscometer at $25{\sim}55^{\circ}C$ and the following results were obtained. 1. At shear rate of $0.323{\sim}1.653\;sec^{-1}$, red pepper paste was found to be a thixotropic food product which showed pseudoplastic proper ties and also exhibited a yield stress and time dependent characteristics. 2. At a shear rate of 0.978 $sec^{-1}$, flow behavior index, consistency index and yield stress were 0.597, 192.3 dyne $sec^s/cm^{2}$, and 91 dyne/$cm^{2}$ respectively. 3. Variation of consistency of red pepper paste with time was found to be decayed by a second order kinetic equation and thereafter nearly time independent. 4. Variation of consistency of red pepper paste with temperature was found to follow Andrade's equation and the activation energy as calculated on the basis of this equation was $1.03\;kcal/g{\cdot}mole$.

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Rheological Characteristics and Viscosity Prediction Models of Tomato Ketchup Suspensions (토마토케찹 현탁액의 리올로지 특성과 점성예측모델)

  • Ha, Sung-Kwon;Choi, Yong-Hee
    • Korean Journal of Food Science and Technology
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    • v.20 no.6
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    • pp.812-819
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    • 1988
  • Rheological properties of rehydrated suspensions of freeze dried tomato ketchup were measured by Brabender Viscotron at the temperature range of $30-90^{\circ}C$, at the concentration of 15-50%, and at the shear rate of $0-250sec^{-1}$. At the shear rate of $0-210sec^{-1}$, tomato ketchup was found to be a thixotropic food product. The values of flow behavior index, consistency index and yield stress at the shear rate of $0-210sec^{-1}$, at the temperature of $30^{\circ}C$ and at the concentration of 33% , were 0.2131, 22.5047 $Pa\;sec^{-n}$, and 8.544 Pa, respectively. It was found that the apparent viscosity model for temperature was expressed by Andrade model and the model for concentration was expressed by Power model, and the model for both temperature and concentration was described by exponential and power models. The activation energies at the concentrations of 15, 20, 30, 33, 40, and 50% were 3.973, 4.985. 5.078, 5.226, 5.357, and 7.655 $kcal/g{\cdot}mole$, respectively.

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Effect of Rice Lipid and Protein on Rheological Characteristics of Gelatinized Rice Flour Solutions (쌀의 지방과 단백질이 쌀가루 호화액의 리올리지 특성에 미치는 영향)

  • 이영순;김인호;김현정;이상효;이현유;박광희
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.28 no.6
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    • pp.1293-1297
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    • 1999
  • Effect of rice protein and lipid on rheological properties of gelatinized rice flour solutions(4%) with three rice varieties(Dongjin, Jinmi, Tamjin) known for varying taste of cooked rice was investigated with Haake viscometer. The rheological behaviors of all rice flour solutions were illustrated by Herschel Bulkley equation and exhibited pseudoplastic behavior with yield stress. When rice flour solutions treated with protease and dithiothreitol, there was decreased in flow behavior index value. Flow behavior index was decreased by dealbumin and deglutelin rice flour solutions among deprotein groups. The Jinmi rice flour solutions exhibited slightly lower consistency index than Dongjin and Tamjin. Defatted rice flour solutions exhibited lower consistency index than rice flour solutions, while dealbumin, deglutelin rice flour solutions exhibited high consistency index. Protease treated rice flour solutions exhibited increase in Dongjin and Tamjin. The yield stress was increased in sequence eating quality. Yield stress of defatted rice flour solutions was decreased, while deglutelin and rice starch flour solutions was increased. The time dependent charac teristics of all rice flour solutions appeared forming hysteresis loop and thixotropic behavior showed. The time dependent characteristics was appeared in sequence eating quality. Rice starch and deglutelin flour solutions appeared greatly time dependent characteristics, but defatted rice flour solutions appeared very little.

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Rheological Properties of Doen-Jang(Korea Fermented Soybean Paste) Suspensions (된장 현탁액의 리올로지적 성질)

  • Lee, Chul-Weon;Hwang, Eung-Soo;Lee, Shin-Young;Pyun, Yu-Ryang
    • Korean Journal of Food Science and Technology
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    • v.22 no.2
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    • pp.111-115
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    • 1990
  • The rheological properties of soybean paste suspensions as affected by concentrations and heating were studied. All suspensions of soybean paste showed thioxotropic plastic behavior. The concentrated suspensions below the ratio of water to soybean paste, 1.25 exhibited Figure-eight phenomena which were presented by two Intersections of the up curve with the dorm curve of shear rate. The dilute suspension (soybean paste: water=1:2) showed H type hysteresis loop at low temperature. But increasing the heating temperature above $60^{\circ}C$, the hysteresis loop exhibited a Figure eight phenomenon. Consistency index of the suspensions increased remarkably by heating and showed the highest value around isoelectric point of the protein. It was suggested that the proteinous nitrogen might be the main component taking part in viscous behavior under different pH and heat treatment.

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Rheological Characterization of Hydrogen Peroxide Gel Propellant

  • Jyoti, B.V.S.;Baek, Seung Wook
    • International Journal of Aeronautical and Space Sciences
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    • v.15 no.2
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    • pp.199-204
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    • 2014
  • An experimental investigation on the rheological behavior of gelled hydrogen peroxide at different ambient temperature (283.15, 293.15 and 303.15 K) was carried out in this study. The gel propellant was rheologically characterized using a rheometer, in the shear rate ranges of 1 to $20s^{-1}$, and 1 to $1000s^{-1}$. Hydrogen peroxide gel was found to be thixotropic in nature. The apparent viscosity value with some yield stress (in-case of shear rate 1 to $20s^{-1}$) drastically fell with the shear rate. In the case of the shear rate range of 1 to $20s^{-1}$, the apparent viscosity and yield stress of gel were significantly reduced at higher ambient temperatures. In the case of the shear rate range of 1 to $1000s^{-1}$, no significant effect of varying the ambient temperature on the gel apparent viscosity was observed. The up and down shear rate curves for hydrogen peroxide gel formed a hysteresis loop that showed no significant change with variation in temperature for both the 1 to $20s^{-1}$ and the 1 to $1000s^{-1}$ shear rate ranges. No significant change in the thixotropic index of gel was observed for different ambient temperatures, for both low and high shear rates. The gel in the 1 to $20s^{-1}$ shear rate range did not lead to a complete breakdown of gel structure, in comparison to that in the 1 to $1000s^{-1}$ shear rate range.

Rheological Properties of Polyamide-Modified PVC-sol Sealants (폴리아미드가 함유된 PVC졸 실란트의 유변학적 물성)

  • Lee, Seung-Jin;Lee, Won-Ki;Kang, Tae-Kyu;Jo, Won-Je;Ha, Chang-Sik
    • Elastomers and Composites
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    • v.33 no.5
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    • pp.345-354
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    • 1998
  • Rheological properties of polyamide-modified poly(vinyl choride) (PVC)-sol sealants were investigated. PVC-sol was prepared by plasticization with dioctyl phthalate(DOP). Two kinds of polyamide rosins having different amino values and thus different viscosities were compared. The effects of the polyamide types and contents on the viscosities, thixotropic indices, and specific gravities of the PVC-sol were discussed. It was found that viscosities of the PVC-sol sealants were significantly affected by the types of the added polyamide resins, and the thixotropic index of the polyamide-modified PVC-sol sealant was observed to be dependent on the contents(not on the types of the polyamides). The viscosity behaviors of the polyamide-modified PVC-sol sealants aged at $45^{\circ}C$ and the effect of the addition of $CaCO_3$ were also discussed.

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Ag Paste Using Ag Nanowires

  • Hong, Jun-Ui;Kim, Dae-Jin;Kong, Byung-Seon;Kim, Sang-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.546-546
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    • 2012
  • Traditional screen printing is still a dominant method to print electrodes on c-Si solar cells. In order to achieve higher efficiency for c-Si solar cells, improvement of the electrode material is one of the key approaches. Shadowing loss can be reduced by using high aspect ratio finger electrode with width of finger electrode less than 80um. The rheological properties of Ag paste for applying c-Si solar cells are improved by using Ag nanowires. The printing properties including the aspect ratio of printed electrode can be improved with higher Thixotropic index (T.I.) values.

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Viscous Properties of Epoxy Resin Filled with Rubber Complex-Treated Silica (고무상 복합물로 표면처리 된 실리카를 충전한 에폭시수지의 점성에 관한 연구)

  • Hong, Suk-Pyo;Choi, Sang-Goo
    • Elastomers and Composites
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    • v.26 no.4
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    • pp.296-303
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    • 1991
  • Surface of crystalline silica was sequentially reacted with silane(A 187), liquid $rubber(CTBN{\times}8)$, and vinyl monomer(GMA) in existence of TEA(triethylamine) or BPO(benzoyl peroxide). It was mixed with epoxy resin at a ratio $0{\times}60%$ (vol. % ) of total component. For mixtures, viscous properties were investigated experimentally. 1) Coating ratio depended on pH of mixture and quantity of catalyst. 2) Treated silica represented lower viscosity than untreated. 3) Thixotropic index represented best at silica_content $15{\sim}23%$ and showed more large deviation over $120^{\circ}C$. 4) Relative viscosity followed kernel's at $0{\times}10%$ of silica content and get out of Mooney's at more than 15%.

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