• Title/Summary/Keyword: thin multiwalled carbon nanotube

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Hydrogen Bonding-Driven Assembling of Thin Multiwalled Carbon Nanotubes (수소결합에 의한 얇은 다중벽 탄소나노튜브의 자기조립)

  • Han, Joong-Tark;Kim, Sun-Young;Woo, Jong-Seok;Lee, Gun-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.426-427
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    • 2007
  • Here we describe the formation of a self-assembled film of thin multiwalled carbon Nanotubes(t-MWNT) modified with hydroxy groups through hydrogen peroxide treatment. Morphologies of t-MWNT films could be controlled by the various coating method, such as filtering, drop casting, spraying method, etc. The results show that on densification of the CNT suspension during drying, multiple hydroxy group-modified MWNTs can be self-assembled through strong surface hydrogen bond interaction while MWNTs usually exist an entangled state in the film. The interaction between t-MWNT was illustrated from Raman spectrum of spray coated films.

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Study on the Thin-walled carbon nanotubes (TWNTs)/Amine epoxy additive composite via supercritical fluid process (초임계 공정을 이용한 Thin-walled carbon nanotubes (TWNTs)/아민계 에폭시 첨가제의 복합체 제조)

  • Kim, Yong-Ryeol;Jeong, Hyeon-Taek
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.3
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    • pp.486-491
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    • 2014
  • We have been fabricated Thin-walled carbon nanotubes (TWNTs)/amine epoxy additives composite using Eco-friendly solvent system such as supercritical process and dry mixed process. TWNTs/amine epoxy additives composite has used as a curing agent for urethane based bisphenol A type epoxy resin. The thermo-mechanical property of the epoxy resin cured by TWNTs/amine epoxy additives composite is characterized by dynamic mechanical analysis(DMA) and dispersability of the nanotubes in the epoxy matrix is also confirmed by scanning electron microscope(SEM). As a results, the epoxy resin cured by TWNTs/amine epoxy additives composite with supercritical process shows enhanced dispersability of the TWNTs in the matrix and thermo-mechanical property when compare to dry mixed process.

Electrical Property of Electrospun PCL/MWCNTs Nanofiber with Additive Silver Thin Film (은 박막이 첨가된 전기방사법으로 제작한 PCL/MWCNTs 나노섬유의 전기적 특성)

  • Kim, Jin Un;Kim, Kyong Min;Park, Kyoung Wan;Sok, Jung Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.4
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    • pp.238-243
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    • 2018
  • A nanofiber was fabricated with carbon nanotubes for transparent electrodes. It was prepared with a composite solution of bio-molecules polycaprolactone (PCL) and multiwalled carbon nanotubes (MWCNTs) by electrospinning on a glass substrate, following which its electrical characteristics were investigated. The content of MWCNTs was varied during electrospinning, while that of PCL was fixed. Further, a nanometer-thick thin film of silver was deposited on the nanofiber layer using a thermal evaporator to improve the electrical characteristics; the sheet resistance significantly reduced after this deposition. The results showed that this carbon nanotube nanofiber has potential applications in biotechnology and as a flexible transparent display material.

Fabrication of Carbon Nanotubes Monolayer Film using Liquid/Liquid Interface

  • Matsui, Jun;Yamamoto, Kohei;Inokuma, Nobuhiro;Orikasa, Hironori;Kyotani, Takashi;Miyashita, Tokuji
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.279-279
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    • 2006
  • We report a fabrication of carbon nanotube (CNT) monolayer thin film using liquid-liquid interface. The multiwalled carbon nanotube (MWCNT), which were synthesized by the alumina template method formed a monolayer at the liquid-liquid interface after sonicating the MWCNT water-oil dispersion. Moreover, with the addition of ethanol, the MWCNT monlayer was also formed at the liquid-liquid interface. The monolayer is transferable onto solid substrates and the transferred film was observed using atomic force microscopy (AFM)

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Electrochemical Oxidations of Alcohols on Platinum/Carbon Nanotube Composites

  • Kim, Jungsoo;Nam, Dae-Geun;Oh, Weontae
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.3
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    • pp.125-129
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    • 2013
  • Composites of platinum and multiwalled carbon nanotubes (MWNTs) were prepared in various reduction conditions and characterized using cyclic voltammetry. The MWNTs were functionalized with carboxylic acid and/or hydroxyl groups in acidic solutions prior to the formation of MWNT-Pt composites. Platinum nanoparticles were deposited onto the chemically-oxidized MWNTs in 1-propanol and 1,3-propanediol. The reduction of Pt precursors in other solutions could induce differences in their morphologies in composite thin films. The morphologies of MWNTs with Pt deposited were dependent on the reduction solutions, and the electrocatalytic activities on alcohols changed accordingly. The electrochemical activities of the as-prepared MWNT-Pt thin films on common alcohols such as methanol and ethanol were investigated.

Buckling characteristics of multiwalled carbon nanotubes under external pressure

  • Sato, Motohiro;Shima, Hiroyuki
    • Interaction and multiscale mechanics
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    • v.2 no.2
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    • pp.209-222
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    • 2009
  • This article describes recent work on mechanics of carbon nanotubes, one of the most fundamental and amazing man-made nanostructures. The noteworthy point is that "nano"-scale mechanics of carbon nanotubes can be well described by the continuum elastic theories for "macro"-scale thin shells. This provides an efficient means to elucidate mechanical deformation effects of carbon nanotubes on their physical and chemical properties, which is significant to develop new-generation nanomaterials based on nanotubes and their composites. Potential applications of the mechanical deformation of nanotubes in nano-electronics and nano-biology are also commented. In addition, theoretical investigations regarding external pressure buckling is carried out here and we have numerically confirmed that larger N (the number of layers) and a smaller D (the innermost diameter) make "corrugation modes" with a larger mode-index k be energetically favored.

Catalytic growth of carbon nanotubes using plasma enhanced chemical vapor deposition(PECVD) (플라즈마 화학 증착법을 이용한 탄소나노튜브의 촉매 성장에 관한 연구)

  • 정성회;장건익
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.935-938
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    • 2001
  • Carbon nanotubes(CNTs) was successfully grown on Ni coated silicon wafer substrate by applying PECVD technique(Plasma Enhanced Chemical Vapor Deposition). As a catalyst, Ni thin film of thickness ranging from 15∼30nm was prepared by electron beam evaporator method. In order to find the optimum growth condition, the type of the gas mixture such as C$_2$H$_2$-NH$_3$was systematically investigated by adjusting the gas mixing ratio in temperature of 600$^{\circ}C$ under the pressure of 0.4 torr. The diameter of the grown CNTs was 40∼150nm. As NH$_3$etching time increased the diameters of the nanotubes decreased whereas the density of nanotubes increased. TEM images clearly demonstrated synthesized nanotubes was multiwalled. We investigated electrical properties for the application of FED.

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Growth of Carbon Nanotubes Depending on Etching Condition of Ni-catalytic Layer (Ni 박막 촉매 Etching 조건에 따른 탄소나노튜브 성장)

  • 정성희;장건익;류호진
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.9
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    • pp.751-756
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    • 2001
  • Carbon nanotubes(CNTs) was successfully grown on Ni coated silicon wafer substrate by PECVD technique(Plasma Enhanced Chemical Vapor Deposition). As a catalyst, Ni thin film of thickness ranging from 15∼30nm was prepared by electron beam evaporator system. In order to find the find the optimum growth condition, initially two different types of gas mixtures such as C$_2$H$_2$-NH$_3$ and C$_2$H$_2$-NH$_3$-Ar were systematically investigated by adjusting the gas mixing ratio in temperature of 600$^{\circ}C$ under 0.4 torr. The diameter of the grown CNTs was 40∼200nm. The diameter of the CNTs increases with increasing the Ni particles size. TEM images clearly demonstrated synthesized nanotubes to be multiwalled.

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Characterization of Conducting Polymer/CdTe Nanoparticles/Carbon Nanotube Composites in Thin Films (전도성 고분자/CdTe 나노입자/탄소 나노튜브 복합박막의 특성 연구)

  • Kim, Do-Hoon;Shim, Seong Eun;Kim, Jungsoo;Nam, Dae-Geun;Oh, Weontea
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.4
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    • pp.315-320
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    • 2013
  • The composites composed of conducting polymer (MEH-PPV), CdTe nanoparticles, and multiwalled carbon nanotubes (MWNTs) were spectroscopically and electrically characterized in their thin films. The composite films were prepared by spray coating. These composites were prepared from the mixture solution of MEH-PPV and CdTe-embedded MWNTs, in which CdTe nanoparticles were electrostatically bound to MWNTs. UV/vis and PL spectra were analyzed to investigate the optical absorbance and emission of the composite films. In addition, their structural, electrochemical, and electrical properties were studied by transmission electron microscopy, cyclic voltammetry, and I-V measurement.

Fabrication and characterization of a carbon nanotube-based point electron source

  • Choi, Ha-Kyu;Kim, G.Y.;Song, Y.I.;Jeong, H.J.;Lim, S.C.;Lee, Y.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1536-1537
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    • 2005
  • We have made point electron sources using carbon nanotubes (CNTs). For the fabrication of point electron sources, CNTs were dispersed in a solution and attached on electrochemically etched W tips using electrophoresis. In our study, we have utilized various CNTs such as single-walled CNT (SWCNT), multiwalled CNT (MWCNT), and thin-MWCNT and threshold current, turn-on voltage, filed enhancement factor of each emitter have been studied upon a tube/bundle diameter and length. In addition, fieldemitted electron energy distribution of various CNT emitters is characterized.

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