• Title/Summary/Keyword: thick coating

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Corrosion of Carbon Steel with and without Aluminized Coating in (O, S, H)-containing Gases at 500-800℃

  • Lee, Dong Bok;Abro, Waheed Ali;Lee, Kun Sang;Abro, Muhammad Ali
    • Journal of the Korean institute of surface engineering
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    • v.50 no.2
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    • pp.85-90
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    • 2017
  • The carbon steel formed the thick, somewhat porous, loosely adherent iron oxide scale when oxidized at $500-800^{\circ}C$ for 15 h in air. It formed the thicker, more porous, nonadherent scale consisting of FeS plus iron oxides in $Ar/1%SO_2$-mixed gas. It formed the much thicker, more porous, nonadherent scale consisting of FeS plus iron oxides in Ar/0.1% $H_2S$-mixed gas. However, the aluminized carbon steel formed the thin, protective $Al_2O_3$ surface scale even in $Ar/1%SO_2$-, and $Ar/0.1%H_2S$-mixed gas. Aluminizing drastically improved the corrosion resistance in (O, S, H)-containing gas.

Thickness Dependence of CVD-SiC-Based Composite Ceramic for the Mold of the Curved Cover Glass (곡면 커버 글라스용 금형 코팅을 위한 CVD-SiC 기반 세라믹 복합체의 두께에 따른 특성 연구)

  • Kim, Kyoung-Ho;Jeong, Seong-Min;Lee, Myung-Hyun;Bae, Si-Young
    • Journal of the Korean institute of surface engineering
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    • v.52 no.6
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    • pp.310-315
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    • 2019
  • The use of a silicon carbide (SiC)-based composite ceramic layer for the mold of a curved cover glass was demonstrated. The stress of SiC/VDR/graphite-based mold structure was evaluated via finite element analysis. The results revealed that the maximum tensile stress primarly occured at the edge region. Moreover, the stress can be reduced by employing a relatively thick SiC coating layer and, therefore, layers of various thicknesses were deposited by means of chemical vapor deposition. During growth of the layer, the orientation of the facets comprising the SiC grain became dominant with additional intense SiC(220) and SiC(004). However, the roughness of the SiC layer increased with increasing thickness of the layer and. Hence, the thickness of the SiC layer needs to be adjusted by values lower than the tolerance band of the curved cover glass mold.

A study on the crystalline orientation and electric properties of sol-gel PZT thin film for piezoelectric sensors (졸겔 법으로 제조한 압전 센서용 PZT 박막의 결정 배향 및 전기적 특성 연구)

  • Byun, Jin-Moo;Lee, Ho-Nyun;Lee, Hong-Kee;Lee, Seong-Eui;Lee, Hee-Chul
    • Journal of Sensor Science and Technology
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    • v.19 no.3
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    • pp.202-208
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    • 2010
  • This study examined the dependency of crystalline orientation and electric properties of sol-gel PZT film on hydrolysis, a $PbTiO_3$ seed layer and a concentration of sol-gel solution. The PZT thin films were prepared by using 2-Methoxyethanol-based sol-gel method and spin-coating on Pt/Ti/$SiO_2$/Si substrates. The 1-${\mu}m$-thick PZT films were coated and then fired in a furnace by direct insert method. The highly (111) oriented PZT film of pure perovskite structure could be obtained. We could control the degree of orientation by various parameters such as hydrolysis, a $PbTiO_3$ seed layer and a concentration of sol-gel solution. The highest measured remanent polarization, dielectric constant and piezoelectric coefficient are $24.16\;{\mu}C/cm^2$, 2808, and 159 pC/N, respectively.

Stability of Organic Thin-Film Transistors Fabricated by Inserting a Polymeric Film (고분자막을 점착층으로 사용한 유기 박막 트랜지스터의 안정성)

  • Hyung, Gun-Woo;Pyo, Sang-Woo;Kim, Jun-Ho;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.61-62
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    • 2006
  • In this paper, it was demonstrated that organic thin- film transistors (OTFTs) were fabricated with the organic adhesion layer between an organic semiconductor and a gate insulator by vapor deposition polymerization (VDP) processing. In order to form polymeric film as an adhesion layer, VDP process was also introduced instead of spin-coating process, where polymeric film was co-deposited by high-vacuum thermal evaporation from 6FDA and ODA followed by curing. The saturated slop in the saturation region and the subthreshold nonlinearity in the triode region were c1early observed in the electrical output characteristics in our organic thin film transistors using the staggered-inverted top-contact structure. Field effect mobility, threshold voltage, and on-off current ratio in 15-nm-thick organic adhesion layer were about $0.5\;cm^2/Vs$, -1 V, and $10^6$, respectively. We also demonstrated that threshold voltage depends strongly on the delay time when a gate voltage has been applied to bias stress.

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Effects of Organic Passivation Layers by Vapor Deposition Polymerization(VDP) for Organic Thin-Film Transistors(OTFTs) (Vapor Deposition Polymerization(VDP)을 이용한 페시베이션이 유기박막트렌지스터에 주는 영향)

  • Park, Il-Houng;Hyung, Gun-Woo;Choi, Hak-Bum;Kim, Jae-Hyeuk;Kim, Woo-Young;Kim, Young-Kwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.114-115
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    • 2007
  • In this paper, it was demonstrated that organic thin-film transistors (OTFTs) were fabricated with the organic passivation layer by vapor deposition polymerization (VDP) processing, In order to form polymeric film as an passivation layer, VDP process was also introduced instead of spin-coating process, where polymeric film was co-deposited by high-vacuum thermal evaporation from 6FDA and ODA followed by curing, Field effect mobility, threshold voltage, and on-off current ratio with 450-nm-thick organic passivation layer were about $0.21\;cm^2/Vs$, IV, and $1\;{\times}\;10^5$, respectively.

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Enhancing Breakdown Strength and Energy Storage Efficiency of Glass-Pb(Zr,Ti)O3 Composite Film (유리-PZT 혼합 후막의 절연 파괴 전압 및 에너지 저장 효율 향상)

  • Kim, Samjeong;Lim, Ji-Ho;Jeong, Dae-Yong
    • Korean Journal of Materials Research
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    • v.31 no.10
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    • pp.546-551
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    • 2021
  • To improve ferroelectric properties of PZT, many studies have attempted to fabricate dense PZT films. The AD process has an advantage for forming dense ceramic films at room temperature without any additional heat treatment in low vacuum. Thick films coated by AD have a higher dielectric breakdown strength due to their higher density than those coated using conventional methods. To improve the breakdown strength, glass (SiO2-Al2O3-Y2O3, SAY) is mixed with PZT powder at various volume ratios (PZT-xSAY, x = 0, 5, 10 vol%) and coating films are produced on silicon wafers by AD method. Depending on the ratio of PZT to glass, dielectric breakdown strength and energy storage efficiency characteristics change. Mechanical impact in the AD process makes the SAY glass more viscous and fills the film densely. Compared to pure PZT film, PZT-SAY film shows an 87.5 % increase in breakdown strength and a 35.3 % increase in energy storage efficiency.

Research Trends of Cathode Materials for Next Generation Lithium Ion Battery (리튬이온전지(Lithium Ion Battery) 양극 물질 연구동향)

  • Na, Sung Min;Park, Hyun Gyu;Kim, Sun Wook;Cho, Hyuk Hee;Park, Kwanggjin
    • Prospectives of Industrial Chemistry
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    • v.23 no.1
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    • pp.3-17
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    • 2020
  • 리튬이온전지(LIB)는 기존의 다른 이차전지와 다른 확실한 몇 가지 장점이 있다. 높은 작동 전압과 높은 에너지 밀도, 긴 수명, 그리고 낮은 자체 방전 속도이다. 이러한 장점으로 모바일 제품에서부터 전기 자동차(battery electric vehicle, BEV), 최근에는 전기저장장치(energy storage system, ESS)까지 다양한 분야에서 사용되고 있다. 하지만 사용 범위가 증가함에 따라 높은 안정성을 가지며 더 큰 에너지 용량을 나타내는 리튬이온전지에 대한 요구가 점점 더 커지게 되었다. 리튬이온전지의 용량 증가는 전지의 설계보다는 양극 및 음극 재료, 분리막 및 전해질과 같은 주요 전지 재료의 기술적 진보에 달려 있다. 주요 전지 소재 중에 전지의 성능에 가장 큰 영향을 미치는 것은 전지 반응에 의한 과전압과 가격이 가장 비싼 양극이다. 본 기획 특집에서는 리튬이차전지의 성능에 가장 큰 영향을 미치는 양극 물질의 종류와 향후 연구동향에 대해서 소개하고자 한다. 양극 물질의 발전 방향, 안정성과 용량 증대를 위해서 최근 연구되고 있는 방향에 대해서 자세하게 소개한다.

MOD-processed YBCO coated conductors on the $CeO_2$-buffered IBAD-MgO template

  • Shin, G.M.;Ko, R.K.;Oh, S.S.;Moon, S.H.;Yoo, S.I.
    • Progress in Superconductivity and Cryogenics
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    • v.11 no.4
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    • pp.20-24
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    • 2009
  • YBCO coated conductors (CC) on the $CeO_2$-buffered IBAD-MgO template were fabricated by metal-organic deposition (MOD) Process with Ba-trifluoroacetate and fluorine-free Y and Cu precursor materials. The precursor solution was coated on $CeO_2$-buffered IBAD MgO templates using the multiple dip-coating method, decomposed into inorganic precursors by pyrolysis up to $400^{\circ}C$ within 3 h, and finally fired at $740{\sim}800^{\circ}C$ in a reduced oxygen atmosphere. Microstructure, texture, and superconducting properties of YBCO films were found highly sensitive to both the firing temperature and time. The high critical current density ($J_C$) of $1.15\;MA/cm^2$ at 77.3K in the self-field could be obtained from $1\;{\mu}m$ thick YBCO CC, fired at $740^{\circ}C$ for 3.5 h, implying that high performance YBCO CC is producible on IBAD MgO template. Further enhancement of $J_C$ values is expected by improving the in-plane texture of $CeO_2$-buffer layer and avoiding the metal substrate contamination.

Study of the Indicators of Each Pattern Identification Based on Korean Standard Differentiation of the Symptoms and Signs for Stroke (한국형 중풍 변증 표준안-Ⅱ의 변증별 변증지표의 분포 및 타당도에 관한 연구)

  • Moon, Seung-Hee;Kang, Byung-Gab;An, Joung-Jo;Jo, Hyun-Kyung;Yoo, Ho-Rhyong;Seol, In-Chan;Kim, Yoon-Sik
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.22 no.2
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    • pp.487-496
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    • 2008
  • The purpose of this study is to investigate clinical frequency and priority of five pattern identification settled by Korean Standard Differentiation of the Symptoms and Sign for Stroke. The present study was done over 177 hospitalized patient with stroke in the Daejeon University Oriental Medical Hospital in the period of November 2006 to July 2007. Stroke patients had been interviewed by residents and specialists who studied standard operation procedures in Fundamental study for Standardization and Objectification of Differentiation and Pattern Identification of Syndrome of Oriental Medicine for Stroke. In Heat-transformation pattern group, men showed significantly high frequency and in Deficiency of Gi pattern group, women showed significantly high frequency. In Heat-transformation pattern group, the indicators such as 'aversion to heat during fever', 'flushed face', 'full and rapid pulse', 'dryness of the eyes, 'yellow coating of the tongue', 'feverishness of the limbs', 'dryness of the eyes' showed significantly high frequency. In Dampphlegm syndrome group, the indicators such as 'white coating of the tongue', 'yellowish face', 'thick coating of the tongue', 'wheezing in the throat with sputum', 'swollen tongue', 'slippery pulse' showed significantly high frequency. In Deficiency of Gi pattern group, the indicators such as 'pale tongue', 'lassitude', 'pale face', 'weakness pulse' showed significantly high frequency. In Deficiency of Eum group, the indicators such as 'short and rapid pulse', 'mirror-like tongue' showed significantly high frequency. For more sensitive Korean Standard Differentiation of the Symptoms and Signs for Stroke, Large scale study is to be done, giving weight on the important indicators.

Prediction Method for Moisture-release Surface Deformation of a Large Mirror in the Space Environment (우주환경에서 대형 반사경의 습기 방출에 의한 형상 변화 예측방법)

  • Song, In-Ung;Yang, Ho-Soon;Khim, Hagyong;Kim, Seong-Hui;Lee, Hoi-Yoon;Kim, Sug-Whan
    • Korean Journal of Optics and Photonics
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    • v.29 no.4
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    • pp.166-172
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    • 2018
  • In this paper, we propose a new method to predict a mirror's surface deformation due to the stress of moisture release by a coating in the environment of outer space. We measured the surface deformation of circular samples 50 mm in diameter and 1.03 mm thick, using an interferometer. The results were analyzed using Zernike fringe polynomials. The coating stress caused by moisture release was calculated to be 152.7 MPa. This value was applied to an analytic model of a 1.25 mm thickness sample mirror, confirming that the change of surface deformation could be predicted within the standard deviation of the measurement result ($78.9{\pm}5.9nm$). Using this methodology, we predicted the surface deformation of 600 mm hyperbolic mirror for the Compact Advanced Satellite, which will be launched in 2019. The result is only $2.005{\mu}m$ of focal shift, leading to 2.3% degradation of modulation transfer function (MTF) at the Nyquist frequency, which satisfies the requirement.