• 한국태양에너지학회:학술대회논문집
• /
• 한국태양에너지학회 2011년도 추계학술발표대회 논문집
• /
• pp.169-176
• /
• 2011

The two-step water splitting thermochemical cycle is composed of the T-R (Thermal Reduction)and W-D (Water Decomposition)steps. The mechanism of this cycle is oxidation-reduction, which produces hydrogen. The reaction temperature necessary for this thermochemical cycle can be achieved by a dish-type solar thermal collector (Inha University, Korea). The purpose of this study is to validate a water splitting device in the field. The device is studied and fabricated by Kodama et al (2010, 2011). The validation results show that the foam device, when loaded with $NiFe_2O_4/m-ZrO_2$powder, was successfully achieved hydrogen production with 9 (10 with a Xe-light solar simulator, 2009, Kodama et al.) repeated cycles under field conditions. Two foam device used in this study were tested for validation before an experiment was performed. The lab scale ferrite-conversion rate was in the range of 24~76%. Two foam devices were designed to for structural stability in this study. In the results of the experiments, the hydrogen percentage of the weight of each foam device was 7.194 and $9.954{\mu}mol\;g^{-1}$ onaverage, and the conversion rates 4.49~29.97 and 2.55~58.83%, respectively.

• Nuclear Engineering and Technology
• /
• 제53권6호
• /
• pp.2066-2073
• /
• 2021

The use of nuclear reactors is a large studied possible solution for thermochemical water splitting cycles. Nevertheless, there are several problems that have to be solved. One of them is to increase the efficiency of the cycles. Hence, in this paper, a thermal energy optimization of a Sulfur-Iodine nuclear hydrogen production cycle was performed by means a heuristic method with the aim of minimizing the energy targets of the heat exchanger network at different minimum temperature differences. With this method, four different heat exchanger networks are proposed. A reduction of the energy requirements for cooling ranges between 58.9-59.8% and 52.6-53.3% heating, compared to the reference design with no heat exchanger network. With this reduction, the thermal efficiency of the cycle increased in about 10% in average compared to the reference efficiency. This improves the use of thermal energy of the cycle.

• 한국수소및신에너지학회논문집
• /
• 제18권4호
• /
• pp.356-364
• /
• 2007

The partial reduction and water splitting properties of metal substituted ferrite mediums for two-step thermochemical hydrogen production, were carried out by TPR/O(Temperature programmed reduction/oxidation) method at a temperature of below 1173 K and under atmospheric pressure. $ZrO_2$ was added to the ferrite as a binder to prevent the sintering. As the results, the reactivity of the metal species added to the ferrite mediums decreased in the order of Cu>Co>Ni>Mn, on the basis of water-splitting temperature. It was also found that the produced hydrogen amounts in the water-splitting step on partial reduced mediums were corresponding to the consumed hydrogen amounts in the previously partial reduction step.

• 한국수소및신에너지학회논문집
• /
• 제13권3호
• /
• pp.249-258
• /
• 2002

Thermochemical water-splitting IS(Iodine-Sulfur) process has been investigating for large-scale hydrogen production. For the construction of an efficient process scheme, two kinds of membrane technologies are under investigating to improve the hydrogen producing HI decomposition step. One is a concentration of HI in quasi-azeotropic HIx ($HI-H_2O-I_2$) solution by elecro-electrodialysis. It was confirmed that HI concentrated from the $HI-H_2O-I_2$ solution with a molar ratio of 1:5:1 at $80^{\circ}C$. The other is a membrane reactor to enhance the one-pass conversion of thermal decomposition reaction of gaseous hydrogen iodide (HI). It was found from the simulation study that the conversion of over 0.9 would be attainable using the membrane reactor using the gas permeation properties of the prepared silica hydrogen permselective membrane by chemical vapor deposition (CVD). Design criterion of the membrane reactor was also discussed.

• 한국수소및신에너지학회논문집
• /
• 제18권2호
• /
• pp.109-115
• /
• 2007

Solar energy conversion to hydrogen was carried out via a two-step thermochemical water splitting using metal oxide redox pair. To simulate the solar radiation, a 7 kW short arc Xe-lamp was used. Partially reduced iron oxide and cerium oxide have the water splitting ability, respectively. So, $Fe_3O_4$ supported on $CeO_2$ was selected as the active material. $Fe_3O_4/CeO_2$(20 wt/80 wt%) was prepared by impregnation method, then the active material was washcoated on the ceramic honeycomb monolith made of mullite and cordierite. Oxygen was released at the reduction step($1673{\sim}1823\;K$) and hydrogen was produced from water at lower temperature($873{\sim}1273\;K$). The result demonstrate the possibility of the 2-step thermochemical water splitting hydrogen production by the active material washcoated monolith. And hydrogen and oxygen was produced separately without any separation process in a monolith installed reactor. But the SEM and EDX analysis results revealed that the support used in this experiment is not suitable due to the thermal instability and coating material migration.

• Korean Chemical Engineering Research
• /
• 제44권1호
• /
• pp.16-22
• /
• 2006

생물학적 수소생산 공정은 다른 열화학적 공정이나 전기화학적 공정에 비하여 환경친화적이며 에너지를 덜 소모하는 공정이다. 생물학적 수소생산 공정은 크게 두 가지로 구별할 수 있는데, 광합성에 의한 수소생산과 혐기발효에 의한 수소생산이 그것이다. 광합성에 의한 수소생산 공정은 주로 물로부터 수소를 생산하고 동시에 공기 중의 이산화탄소도 저감하는 특징을 가지고 있으며, 혐기발효에 의한 수소생산 공정은 유기 탄소원을 섭취하는 박테리아에 의한 발효를 통해 이루어지는 공정이다. 본 논문에서는 생물학적 수소생산 공정에 대한 그간의 연구들에 대하여 살펴 보았다.

• 한국수소및신에너지학회논문집
• /
• 제18권4호
• /
• pp.464-480
• /
• 2007

There are several methods for the hydrogen production such as steam reforming of natural gas, photochemical method, biological method, electrolysis and thermochemical method, etc. These days it has been widely studied for the hydrogen production method having low hydrogen production cost and high efficiency. In this paper, patents in the hydrogen production by steam reforming of natural gas were gathered and analyzed. The search range was limited in the open patents of USA(US), European Union(EP), Japan(JP), and Korea(KR) from 1996 to 2006. Patents were gathered by using key-words searching and extracted by filtering criteria. The trends of the patents was analyzed by the years, countries, companies, and technologies.

• 한국수소및신에너지학회논문집
• /
• 제18권1호
• /
• pp.95-108
• /
• 2007

There are several methods for the hydrogen production such as steam reforming of natural gas, photocatalytic method, biological method, electrolysis and thermochemical method, etc. These days it has been widely studying for the hydrogen production method having low hydrogen production cost and high efficiency. In this paper, patents in the hydrogen production by water electrolysis were gathered and analyzed. The search range was limited in the open patents of USA(US), European Union(EP), Japan(JP), and Korea(KR) from 1996 to 2005. Patents were gathered by using key-words searching and filtered by filtering criteria. The trends of the patents was analyzed by the years, countries, companies, and technologies.

• 한국막학회:학술대회논문집
• /
• 한국막학회 2004년도 추계 총회 및 학술발표회
• /
• pp.300-303
• /
• 2004

• 한국전기화학회:학술대회논문집
• /
• 한국전기화학회 2005년도 수소연료전지공동심포지움 2005논문집
• /
• pp.355-358
• /
• 2005