• Journal of Energy Engineering
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• v.26 no.4
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• pp.74-83
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• 2017

Coal-fired power plants supply roughly 50 percent of the nation's electricity but produce a disproportionate share of electric utility-related air pollution. Coal combustion technology can facilitate volume reduction of up to 90%, with the inorganic contaminants being captured in furnace bottom ash and fly ash residues. These disposal coal ash residues are however governed by the potential release of constituent contaminants into the environment. Accelerated carbonation process has been shown to have a potential for improving the chemical stability and leaching behavior of bottom ash residues. The aim of this work was to quantify the volume of $CO_2$ that could be sequestrated with a view to reducing greenhouse gas emissions and stabilize the contaminated heavy metals from bottom ash samples. In this study, we used PC boiler bottom ash, Kanvera reactor (KR) slag and calcined waste lime for measuring chemical analysis and heavy metals leaching tests were performed and also the formation of calcite resulting from accelerated carbonation process was investigated by thermo gravimetric and differential thermal analysis (TG/DTA).

• Structural Engineering and Mechanics
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• v.58 no.5
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• pp.931-947
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• 2016

The effects of nanotechnology and smartness on the buckling reduction of pipes are the main contributions of present work. For this ends, the pipe is simulated with classical piezoelectric polymeric cylindrical shell reinforced by armchair double walled boron nitride nanotubes (DWBNNTs), The structure is subjected to combined electro-thermo-mechanical loads. The surrounding elastic foundation is modeled with a novel model namely as orthotropic nonhomogeneous Pasternak medium. Using representative volume element (RVE) based on micromechanical modeling, mechanical, electrical and thermal characteristics of the equivalent composite are determined. Employing nonlinear strains-displacements and stress-strain relations as well as the charge equation for coupling of electrical and mechanical fields, the governing equations are derived based on Hamilton's principal. Based on differential quadrature method (DQM), the buckling load of pipe is calculated. The influences of electrical and thermal loads, geometrical parameters of shell, elastic foundation, orientation angle and volume percent of DWBNNTs in polymer are investigated on the buckling of pipe. Results showed that the generated ${\Phi}$ improved sensor and actuator applications in several process industries, because it increases the stability of structure. Furthermore, using nanotechnology in reinforcing the pipe, the buckling load of structure increases.

• Corrosion Science and Technology
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• v.12 no.3
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• pp.132-141
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• 2013

This work is concerning a methodology of Ni-base superalloy development for a very high temperature gas-cooled reactor(VHTR) using design of experiments(DOE) and thermodynamic calculations. Total 32 sets of the Ni-base superalloys with various chemical compositions were formulated based on a fractional factorial design of DOE, and the thermodynamic stability of topologically close-packed(TCP) phases of those alloys was calculated by using the THERMO-CALC software. From the statistical evaluation of the effect of the chemical composition on the formation of TCP phase up to a temperature of 950 oC, which should be suppressed for prolonged service life when it used as the structural components of VHTR, 16 sets were selected for further calculation of the mechanical properties. Considering the yield and ultimate tensile strengths of the selected alloys estimated by using the JMATPRO software, the optimized chemical composition of the alloys for VHTR application, especially intermediate heat exchanger, was proposed for a succeeding experimental study.

• Journal of Microbiology
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• v.43 no.6
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• pp.561-568
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• 2005

A newly-isolated thermophilic strain of the zygomycete fungus Rhizomucor pusillus 13.36 produced highly active dextrinogenic and saccharogenic enzymes. Cassava pulp was a good alternative substrate for amylase production. Dextrinogenic and saccharogenic amylases exhibited optimum activities at a pH of 4.0-4.5 and 5.0 respectively and at a temperature of $75^{\circ}C$. The enzymes were highly thermostable, with no detectable loss of saccharogenic or dextrinogenic activity after 1 hand 6 h at $60^{\circ}C$, respectively. The saccharogenic activity was inhibited by $Ca^{2+}$ while the dextrinogenic was indifferent to this ion. Both activities were inhibited by $Fe^{2+}\;and\;Cu^{2+}$ Hydrolysis of soluble starch by the crude enzyme yielded $66\%$ glucose, $19.5\%$ maltose, $7.7\%$ maltotriose and $6.6\%$ oligosaccharides.

• BMB Reports
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• v.40 no.1
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• pp.107-112
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• 2007

To study the functioning of HSP70 in Escherichia coli, we selected NtHSP70-2 (AY372070) from among three genomic clones isolated in Nicotiana tabacum. Recombinant NtHSP70-2, containing a hexahistidine tag at the amino-terminus, was constructed, expressed in E. coli, and purified by $Ni^{2+}$ affinity chromatography and Q Sepharose Fast Flow anion exchange chromatography. The expressed fusion protein, $H_6NtHSP70$-2 (hexahistidine-tagged Nicotiana tabacum heat shock protein 70-2), maintained the stability of E. coli proteins up to 90$^{\circ}C$. Measuring the light scattering of luciferase (luc) revealed that NtHSP70-2 prevents the aggregation of luc without ATP during high-temperature stress. In a functional bioassay (1 h at 50$^{\circ}C$) for recombinant $H_6NtHSP70$-2, E. coli cells overexpressing $H_6NtHSP70$-2 survived about seven times longer than those lacking $H_6NtHSP70$-2. After 2 h at 50$^{\circ}C$, only the E. coli overexpressing $H_6NtHSP70$-2 survived under such conditions. Our NtHSP70-2 bioassays, as well as in vitro studies, strongly suggest that HSP70 confers thermo-tolerance to E. coli.

• Carbon letters
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• v.27
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• pp.81-89
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• 2018

The present study aimed to prepare a novel efficient flame retardant additive for polypropylene. The new flame retardant was prepared by chemical grafting of melamine to graphene oxide with the aid of thionyl chloride. Fourier-transform infrared spectroscopy and thermogravimetric analysis proved that melamine had been successfully grafted to the graphene oxide. The modified graphene oxide was incorporated into polypropylene via solution mixing followed by anti-solvent precipitatio. Homogeneous distribution as well as exfoliation of the nanoplatelets in the polymer matrix was observed using transmission electron microscopy. Thermogravimetric analysis showed a significant improvement in the thermo-oxidative stability of the polymer after incorporating 2 wt% of the modified graphene oxide. The modified graphene oxide also enhanced the limiting oxygen index of the polymer. However, the amount of improvement was not enough for the polymer to be ranked as a self-extinguishing material. Cone calorimetry showed that incorporating 2 wt% of the modified graphene oxide lowered total heat release and the average production rate of carbon monoxide during burning of the polymer by as much as 40 and 35%, respectively. Hence, it was concluded that the new flame retardant can retard burning of the polymer efficiently and profoundly reduce suffocation risk of exposure to burning polymer byproducts.

• Textile Coloration and Finishing
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• v.17 no.6 s.85
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• pp.27-35
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• 2005

Conventional pad- dry-cure(thermo-fixation) process usually produces functional performance on both sides of a fabric. UV curing technique was applied to impart water- and oil-repellent finish effective only on the face of a PET knitted fabric. The preferential one-side coating, by virtue of the limited penetration of UV light, was achieved by W curing after padding of a fluorocarbon agent without special coating or printing equipments. The difference in the functional property of face and back sides was examined by measuring water and oil repellency at each side of the treated fabric. The influence of pre/post-irradiation dose and agent concentration on the performance of the finished fabrics were investigated. While increase in both resin concentration and post-irradiation did not have significant effect on the finish, UV pre-irradiation of PET fabrics caused remarkable influence presumably due to appropriate surface modification of PET fabrics required for facile wetting of the resin. The dimensional stability and color change of the UV cured fabrics measured by FAST and reflectance spectrophotometry showed significantly decreased color difference and increased percent extension compared with the samples pre-irradiated without agent application.

• Advances in nano research
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• v.6 no.4
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• pp.377-397
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• 2018

In the present investigation, thermal buckling and free vibration characteristics of functionally graded (FG) Timoshenko nanobeams subjected to nonlinear thermal loading are carried out by presenting a Navier type solution. The thermal load is assumed to be nonlinear distribution through the thickness of FG nanobeam. Thermo-mechanical properties of FG nanobeam are supposed to vary smoothly and continuously throughout the thickness based on power-law model and the material properties are assumed to be temperature-dependent. Eringen's nonlocal elasticity theory is exploited to describe the size dependency of nanobeam. Using Hamilton's principle, the nonlocal equations of motion together with corresponding boundary conditions based on Timoshenko beam theory are obtained for the thermal buckling and vibration analysis of graded nanobeams including size effect. Moreover, in following a parametric study is accompanied to examine the effects of the several parameters such as nonlocal parameter, thermal effect, power law index and aspect ratio on the critical buckling temperatures and natural frequencies of the size-dependent FG nanobeams in detail. According to the numerical results, it is revealed that the proposed modeling can provide accurate frequency results of the FG nanobeams as compared some cases in the literature. Also, it is found that the small scale effects and nonlinear thermal loading have a significant effect on thermal stability and vibration characteristics of FG nanobeams.

• Advances in nano research
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• v.10 no.1
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• pp.43-57
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• 2021

In this study, thermally induced bifurcation buckling of shallow composite cylindrical panels reinforced with aligned single-walled carbon nanotubes is investigated. Distribution of carbon nanotubes across the thickness of the cylindrical panel as reinforcements may be either uniform or functionally graded. Thermo-mechanical properties of the matrix and reinforcements are considered to be temperature dependent. Properties of the cylindrical panel are obtained using a refined micromechanical approach which introduces the auxiliary parameters into the rule of mixtures. The governing equations are obtained by using the static version of the Hamilton principle based on the first-order shear deformation theory and considering the linear strain-displacement relation. An energy-based Ritz method and an iterative process are used to obtain the critical buckling temperature of composite cylindrical panel with temperature dependent material properties. In addition, the effect of various parameters such as the boundary conditions, different geometrical conditions, distribution pattern of CNTs across the thickness and their volume fraction are studied on the critical buckling temperature and buckled pattern of cylindrical panels. It is shown that FG-X type of CNT dispersion is the most influential type in thermal stability.

• Steel and Composite Structures
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• v.50 no.6
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• pp.609-625
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• 2024

This paper presents an in-depth analysis of the nonlinear vibration of microbeams, with a particular emphasis on their application in sports monitoring systems. The research utilizes classical beam theory, modified couple stress theory, and von-Kármán nonlinear parameters to explore the behavior of microbeams. These microbeams are characterized by a non-uniform geometry, with materials that continuously change along the beam radius and a thickness that varies along the beam length. The main contribution lies in its exploration of the stability of smart sensors in sports structures, particularly those with non-uniform geometries. The research findings indicate that these non-uniform microbeams, when used in smart systems made of functionally graded temperature-dependent materials, can operate effectively in thermal environments. The smart system developed in this study demonstrates significant potential for use in sports applications, particularly in monitoring and gathering information. The insights gained from this research contribute to the understanding of the performance and optimization of microbeams in sports applications, particularly in the context of non-uniform geometries. This research, therefore, provides a foundation for the development of advanced, reliable, and efficient monitoring systems in sports applications.