• Journal of Microbiology
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• 제42권4호
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• pp.346-352
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• 2004

Poly(3-Hydroxybutyrate-co­3-Hydroxyvalerate), poly(3HB-co-3HV), copolyesters with a variety of 3HV contents (ranging from 17 to $60\;mol\%$) were produced by Alcaligenes sp. MT-16 grown on a medium containing glucose and levulinic acid in various ratios, and the effects of hydrophilicity and crystallinity on the degradability of the copolyesters were evaluated. Measurements of thermo-mechanical pro­perties and Fourier-transform infrared spectroscopy in the attenuated total reflectance revealed that the hydrophilicity and crystallinity of poly(3HB-co-3HV) copolyesters decreased as 3HV content in the copolyester increased. When the prepared copolyester film samples were non-enzymatically hydrolysed in 0.01 N NaOH solution, the weights of all samples were found to have undergone no changes over a period of 20 weeks. In contrast, the copolyester film samples were degraded by the action of extra­cellular polyhydroxybutyrate depolymerase from Emericellopsis minima W2. The overall rate of weight loss was higher in the films containing higher amounts of 3HV, suggesting that the enzymatic degra­dation of the copolyester is more dependent on the crystallinity of the copolyester than on its hydro­philicity. Our results suggest that the degradability characteristics of poly(3HB-co-3HV) copolyesters, as well as their thermo-mechanical properties, are greatly influenced by the 3HV content in the copoly­esters.

• Journal of Korean Tunnelling and Underground Space Association
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• 제21권4호
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• pp.501-518
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• 2019

The rock properties measured under in-situ geological condition can be used to increase the reliability in numerical simulations with regard to the long-term performance of a high-level waste repository. In this study, the change in mechanical properties of KURT (Korea atomic energy research institute Underground Research Tunnel) granite was evaluated under the simulated THM (Thermo-Hydro-Mechanical) coupled condition due to a deep geological formation in the disposal repository. The rock properties such as uniaxial compression strength, indirect tensile strength, elastic modulus and Poisson's ratio were measured under the coupled test conditions (M, HM, TM, THM). It was found that the mechanical properties of KURT granite is more susceptible to the change in saturation rather than temperature within the test condition of this study. The changes in uniaxial compression strength and indirect tensile strength from the rock samples of dried or saturated conditions showed the maximum relative error of about 20% and 13% respectively under the constant temperature condition. Therefore, it is necessary to use the material properties of rock measured under the coupled THM condition as input parameters for the numerical simulation of long-term performance assessment of a disposal repository

• Tunnel and Underground Space
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• 제8권1호
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• pp.17-25
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• 1998

This paper investigates coupled thermal, mechanical and hydraulic phenomena in deep rock mass especially for underground heat storage system. Firstly, concepts of underground heat storage were presented and coupling phenomena in this area were illustrated. In order to understand the basic mechanism of thermal, hydraulic and deformation behavior in rock cavern disturbed by thermal gradient about 10$0^{\circ}C$, various numerical experiments were conducted using several codes. The study involves the behavior of fractured rock mass including rock joint. In spite of the limitation of codes modelling fully coupled effects, these codes could be applied in analysis of underground heat storage. The heat loss in rock mass, which is a major factor in heat storage, is insignificant in all results.

• Proceedings of the Korean Geotechical Society Conference
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• 한국지반공학회 2010년도 추계 학술발표회
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• pp.808-812
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• 2010

A great deal of attention is focused on coupled Thermo-Hydro-Mechanical (THM) behavior of multiphase porous media in diverse geo-mechanical and geo-environmental areas. This paper presents general governing equations for coupled THM processes in unsaturated porous media. Coupled partial differential equations are derived from 3 mass balances equations (solid, water, and air), energy balance equation, and force equilibrium equation. Finite element code is developed from the Galerkin formulation and time integration of these governing equations for 4 main variables (displacement $\underline{u}$, gas pressure $P_g$, liquid pressure $P_l$), and temperature T). The code is validated with theoretical solutions for linear material with simple boundary conditions.

• Steel and Composite Structures
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• 제33권1호
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• pp.93-109
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• 2019

In the present study, vibration analysis of double bonded micro sandwich cylindrical shells with saturated porous core and carbon/boron nitride nanotubes (CNT/BNNT) reinforced composite face sheets under multi-physical loadings based on Cooper-Naghdi theory is investigated. The material properties of the micro structure are assumed to be temperature dependent, and each of the micro-tubes is placed on the Pasternak elastic foundations, and mechanical, moisture, thermal, electrical, and magnetic forces are effective on the structural behavior. The distributions of porous materials in three distributions such as non-linear non-symmetric, nonlinear-symmetric, and uniform are considered. The relationship including electro-magneto-hydro-thermo-mechanical loadings based on modified couple stress theory is obtained and moreover the governing equations of motion using the energy method and the Hamilton's principle are derived. Also, Navier's type solution is also used to solve the governing equations of motion. The effects of various parameters such as material length scale parameter, temperature change, various distributions of nanotube, volume fraction of nanotubes, porosity and Skempton coefficients, and geometric parameters on the natural frequency of double bonded micro sandwich cylindrical shells are investigated. Increasing the porosity and the Skempton coefficients of the core in micro sandwich cylindrical shell lead to increase the natural frequency of the structure. Cylindrical shells and porous materials in the industry of filters and separators, heat exchangers and coolers are widely used and are generally accepted today.

• Tunnel and Underground Space
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• 제31권3호
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• pp.167-183
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• 2021

It is essential to understand the complex thermo-hydro-mechanical-chemical (THMC) coupled behavior in the engineered barrier system and natural barrier system to secure the high-level radioactive waste repository's long-term safety. The heat from the high-level radioactive waste induces thermal pressurization and vaporization of groundwater in the repository system. Groundwater inflow affects the saturation variation in the engineered barrier system, and the saturation change influences the heat transfer and multi-phase flow characteristics in the buffer. Due to the complexity of the coupled behavior, a numerical simulation is a valuable tool to predict and evaluate the THMC interaction effect on the disposal system and safety assessment. To enhance the knowledge of THMC coupled interaction and validate modeling techniques in geological systems. DECOVALEX, an international cooperation project, was initiated in 1992, and KAERI has participated in the projects since 2008 in Korea. In this study, we introduced the main contents of all tasks in the DECOVALEX-2023, the current DECOVALEX phase, to the rock mechanics and geotechnical researchers in Korea.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 한국방사성폐기물학회 2004년도 학술논문집
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• pp.194-198
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• 2004

The thermo-hydro-mechanical (T-H-M) process is one of major issues in the performance assessment of a high level waste (HLW) repository. An engineering-scale test was planned and its experimental set-up has being installed, to validate the T-H-M behavior in the buffer of a reference disposal system. The experimental set-up consists of 4 major components: the confining cylinder with its hydration water tank, the bentonite block, the heating system, and the sensors and instruments. The monitoring and data acquisition system is employed to control the heater to maintain the temperature of $95^{\circ}C$ at the interface of the heater and bentonite blocks and to collect signals from sensors and instruments installed in the bentonite blocks.

• Proceedings of the KSME Conference
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• 대한기계학회 2008년도 추계학술대회B
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• pp.1967-1972
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• 2008

Reburning is an efficient combustion technology to reduce nitrogen oxide by injecting hydro-carbon fuel to the downstream of the main combustion. In this paper LPG has been used not only as main fuel but also as reburn fuel and air was used as an oxidizer with 15kW swirl burner. Experimental studies have been done to evaluate effect of reburning for NOx reduction. Also to examine the effect of the amount of burnout air for complete combustion by reburn fuel on NOx reduction, test was conducted by reducing the amount of burnout air. Computational fluid dynamic (CFD) simulation was performed using the commercial CFD code FLUENT 6.3 to simulate experimental results and investigate the thermo-chemical characteristics. An evaluation of reaction models for swirl burner has been carried out for propane-air with two step finite-rate eddy-dissipation model in FLUENT.

• Journal of the Korean Geotechnical Society
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• 제29권8호
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• pp.65-73
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• 2013

Ground-coupled heat pump system has attracted attention as a promising renewable energy technology due to its improving energy efficiency and eco-friendly mechanism for space cooling and heating. Pipes buried in the ground play a role of direct thermal interaction between circulating fluid inside the pipe and surrounding soils in the geothermal exchange system. However, both complexities of turbulent flow coupling thermal-hydraulic phenomena and very long aspect ratio of the pipe make it difficult to model the heat exchange system directly. Energy balance for fluid flow inside the pipe was derived to model thermal-hydraulic phenomena, and one-dimensional pipe element was proposed through Galerkin formation and time integration of the equation. Developed element is combined to pre-developed FEM code for THM phenomena in porous media. Numerical results of Thermal Response Test showed that line-source model overestimates equivalent thermal conductivity of surrounding soils due to thermal interaction between adjacent pipes and finite length of the pipe. Thus, inverse analysis for the TRT simulation was conducted to present optimal transformation matrix with utmost convergence.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• 제17권2호
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• pp.183-202
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• 2019

For design and performance assessment of a high-level radioactive waste (HLW) disposal system, it is necessary to understand the characteristics of coupled thermo-hydro-mechanical (THM) behavior. However, in previous studies for the Korean Reference HLW Disposal System (KRS), thermal analysis was performed to determine the spacing of disposal tunnels and interval of disposition holes without consideration of the coupled THM behavior. Therefore, in this study, TOUGH2-MP/FLAC3D is used to conduct THM modeling for performance assessment of the Korean Reference HLW Disposal System (KRS). The peak temperature remains below the temperature limit of $100^{\circ}C$ for the whole period. A rapid rise of temperature caused by decay heat occurs in the early years, and then temperature begins to decrease as decay heat from the waste decreases. The peak temperature at the bentonite buffer is around $96.2^{\circ}C$ after about 3 years, and peak temperature at the rockmass is $68.2^{\circ}C$ after about 17 years. Saturation of the bentonite block near the canister decreases in the early stage, because water evaporation occurs owing to temperature increase. Then, saturation of the bentonite buffer and backfill increases because of water intake from the rockmass, and bentonite buffer and backfill are fully saturated after about 266 years. The stress is calculated to investigate the effect of thermal stress and swelling pressure on the mechanical behavior of the rockmass. The calculated stress is compared to a spalling criterion and the Mohr-Coulumb criterion for investigation of potential failure. The stress at the rockmass remains below the spalling strength and Mohr-Coulumb criterion for the whole period. The methodology of using the TOUGH2-MP/FLAC3D simulator can be applied to predict the long-term behavior of the KRS under various conditions; these methods will be useful for the design and performance assessment of alternative concepts such as multi-layer and multi-canister concepts for geological spent fuel repositories.