• 제목/요약/키워드: thermal stabilization

검색결과 186건 처리시간 0.021초

PVC의 저온 열안정성 향상에 관한 연구 (Improvement of low temperature thermal stability on PVC)

  • 정광보;전인기;안성환
    • 한국응용과학기술학회지
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    • 제26권4호
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    • pp.440-450
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    • 2009
  • Metal(Zinc) soap and mixed metal(Zn/Ba) soap were synthesized with good structures and characterized by IR and H-NMR. The H-NMR spectrums of the synthesized soaps were in very good accordance with the structures proposed by earlier workers. The mixed metal soaps with various costabilizers(acid or metal content effect), which added in order to investigate the thermal stabilization effect at low and high temperature, were investigated the thermal stabilization effect. The temperature effect is relation to the metal content effect than acid effect. In case of mixed metal soap, the high thermal stabilization effect improved with increasing Barium content. As the Zinc content increase the low temperature thermal stabilization effect improved, but the high temperature thermal stabilization effect showed an opposite tendency.

Using MZIs for Optical PSBT Transmissions: Requirements for Thermal Stabilization

  • Ducournau, Guillaume;Latry, Olivier;Ketata, Mohamed
    • ETRI Journal
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    • 제28권5호
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    • pp.615-620
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    • 2006
  • In this paper, we discuss the quantification of Mach-Zehnder interferometer (MZI) thermal stabilization which is needed in optical phase shaped binary transmission (PSBT) links. Considering the thermo-optic and thermal expansion effects, we revisit the analytical expression for the thermal drift (GHz/$^{\circ}C$) of the MZI center frequency (denoted here by the 'MZI spectral drift'). An MZI is then used in an experimental transmission system using the optical PSBT format. We study the effect of spectral MZI drift by using a thermally stabilized interferometer and applying a frequency shift to the optical carrier. By using the thermal drift coefficient of the MZI, we find that to ensure low bit error rate fluctuations due to the MZI drift, the thermal stabilization of the device must have an accuracy of $0.5^{\circ}C$.

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복합금속비누와 안정화조제를 이용한 PVC의 열안정화에 대한 연구 (Study of thermal stability on PVC using mixed metal soap and stabilizer)

  • 전인기;안성환;정광보
    • 한국응용과학기술학회지
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    • 제27권4호
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    • pp.552-558
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    • 2010
  • Zinc soap and Zn/Ba mixed metal soap were synthesized and PVC plastisol with mixed metal soap and various costabilizers were also synthesized with good structures and characterized by IR and $^1H$-NMR. The IR spectrums and $^1H$-NMR spectrums of the synthesized soaps were in very good accordance with the structures proposed by earlier workers. In using phosphite as a costabilizer, TIDP phosphite was shown to be the excellent thermal stabilization effect at the low temperature and TNPP phosphite was shown to be the excellent thermal stabilization effect at the high temperature. In case of antioxidant, it was revealed that antioxidant was not effective in the low temperature thermal stabilization effect while highly effective in the high temperature thermal stability. $NaClO_4$ solution with sorbitol solvent had the best thermal stabilization effect among $NaClO_4$ solution series at low and high temperature.

Thermal Stabilization of Aspergillus phytase by L-Arginine

  • Sunghoon Ryu;Park, Tae-Gwan
    • Biotechnology and Bioprocess Engineering:BBE
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    • 제3권1호
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    • pp.32-34
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    • 1998
  • Phytase from Aspergillus species is a very heat unstable enzyme which inactivates to a great extent during the thermal processing of animal feed formulation. Various protein stabilization additives were tested to improve its heat stability. Among them, a basic amino acid, L-arginine remarkably increased the thermal stability of phytase in an aqueous solution state.

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영구자석 안정화 자세제어 방식이 적용된 큐브위성의 열적 특성분석 (Numerical Investigation of On-orbit Thermal Characteristics for Cube Satellite with Permanent Magnet Attitude Stabilization Method)

  • 강수진;정현모;오현웅
    • 항공우주시스템공학회지
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    • 제7권3호
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    • pp.26-32
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    • 2013
  • Passive attitude stabilization method has been widely usde for attitude determination and control of cube satellite due to its advantage of system simplicity. The permanent magnet installed on the cube satellite passively controls the attitude of the satellite such that the satellite is aligned with the earth magnetic field. In this paper, on-orbit thermal behavior of the cube satellite with the permanent magnet attitude stabilization method has been investigated through on-orbit thermal analysis. THe orbit profile obtained from the aforementioned attitude control method has been reflected in the analysis. The analysis results indicate that the thermal design proposed in this study is effective for satisfying the temperature requirements of the commericial mission equipments.

인산처리 유·무에 따른 레이온직물의 열수축과 열안정성에 미치는 안정화 공정 조건의 영향 (Effect of Stabilization Processing Conditions on the Thermal Shrinkage and the Thermal Stability of Rayon Fabrics Untreated and Surface-Treated with Phosphoric Acid)

  • 조동환;이종문;박종규
    • 접착 및 계면
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    • 제5권3호
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    • pp.10-17
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    • 2004
  • 본 연구에서는 레이온직물에 대하여 승온속도, 안정화온도, 분위기가스, 화학적 표면처리 등 여러가지 조건에서 안정화공정을 행한 후, 직물의 열수축과 열안정성, 그리고 미세구조에 미치는 공정 조건의 영향을 조사하였다. 레이온직물의 열수축과 중량변화에 인산처리 유무와 승온속도가 가장 중요한 영향을 미쳤다. 특히, 인산처리를 한 경우가 하지 않은 경우보다 레이온직물의 두께변화는 약 80%, 길이변화는 약 20%, 그리고 중량변화는 약 26%가 줄어드는 열수축 억제 효과를 보여주었다. 안정화 된 레이온직물의 열안정성에는 안정화온도와 인산처리 그리고 분위기가스와 승온속도 등 주어진 안정화공정 조건 모두가 영향을 주었다. 또한 안정화섬유의 표면 상태 및 섬유직경 변화도 공정 전에 행한 인산처리의 유무에 의존하였다.

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Studies on the Stabilization of Rayon Fabrics for Preparing Carbon Fabrics: 2. Fast Isothermal Stabilization Processes at High Temperature

  • Yoon, Sung-Bong;Cho, Chae-Wook;Cho, Dong-Hwan;Park, Jong-Kyoo;Lee, Jae-Yeol
    • Carbon letters
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    • 제9권4호
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    • pp.308-315
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    • 2008
  • In the present study, fast isothermal stabilization processes for rayon precursor fabrics were performed at $350^{\circ}C$ and $400^{\circ}C$ within 3 minutes and the chemical and physical characteristics of the stabilized fabrics were investigated. In addition, rayon precursor fabrics were pre-treated with three different phosphorous-based flame retardants and then stabilized. The effect of flame retardants on the chemical composition, thermal shrinkage, weight change, thermal stability and XRD results was examined, comparing with those of the precursor fabrics. The result showed that the stabilization of rayon fabrics was most effective as the stabilization temperature was $350^{\circ}C$, the stabilization time was 3 min, and the pre-treatment with phosphoric acid of 1 vol%. The carbon contents of stabilized rayon fabrics were increased with increasing stabilization temperature and time, whereas the oxygen contents were decreased. Also, it is likely that the pre-treatment with phosphoric acid plays a role in retarding the change of chemical structure of rayon fabric. The XRD result was quite consistent with the result showing the effect of phosphoric acid on the chemical composition, thermal shrinkage and weight reduction of rayon fabric.

휴대용 열 영상 관측 장비를 위한 전자적 영상 안정화 (Electronic Image Stabilization for Portable Thermal Image Camera)

  • 김종호
    • 한국군사과학기술학회지
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    • 제19권3호
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    • pp.288-293
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    • 2016
  • Electronic Image Stabilization(EIS) is widely used as a technique for correcting a shake of an image. The case requiring the EIS function has been increased in high magnification thermal image observation on portable military equipment. Projection Algorithm(PA) for EIS is easy to implement but its performance is sensitive to the projection area. Especially, projection profiles of thermal image have very modest change and are difficult to extract image shifts between frames. In this paper, we proposed algorithm to extract a feature image for the thermal image and compared Block Matching Algorithm(BMA) with PA using our proposed feature image. When using our proposed feature image, BMA was simply implemented using FPGA's internal small memory. And we were able to obtain 30 % PSNR improved results compared to PA.

탄소섬유용 레이온섬유의 안정화공정 후 중량, 직경 및 열안정성에 미치는 인계 난연제의 영향 (Effect of Phosphorous-Based Flame Retardants on the Weight, Diameter, and Thermal Stability after Stabilization Processes of Rayon Fibers for Carbon Fibers)

  • 윤성봉;조동환;박종규
    • 폴리머
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    • 제29권2호
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    • pp.211-215
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    • 2005
  • 안정화공정은 선구물질(precursor) 섬유를 화학적, 물리적, 열적 그리고 구조적으로 안정한 탄소섬유로 전환시키는데 반드시 필요한 공정이다. 특히, $400^{\circ}C$ 이하에서 행하는 안정화공정 단계에서 발생하는 심각한 중량감소와 열수축을 동반하는 레이온섬유의 경우 그 중요성은 더욱 강조된다 레이온섬유의 안정화공정은 안정화온도뿐 아니라 승온속도, 화학전처리, 분위기가스 등 공정인자에 중요하게 의존한다. 본 연구에서는 안정화공정 승온속도 및 세 종류의 인계 난연제 처리의 유${\cdot}$무 및 농도 변화에 따라 얻어진 레이온섬유에 대하여 안정화공정 동안 열처리로 내부에서 발생하는 중량감소, 섬유직경 변화 그리고 안정화공정을 거친 레이온섬유의 열안정성을 조사하였다. 레이온섬유의 중량, 직경 및 열안정성은 승온속도 및 난연제 종류와 함량에 의존하였으며, $3\;vol\%$ 이하의 농도에서 인산으로 전처리하여 안정화공정을 수행하는 것이 레이온섬유에 대하여 후속 탄화공정을 준비하기에 가장 적절할 것으로 판단되었다.

저가형 탄소섬유 개발을 위한 자외선 조사 기반 의류용 PAN 섬유의 연속식 안정화 공정 개발 (Developing Continuous Stabilization Process for Textile-Grade PAN Fiber-Based Carbon Fiber Using UV Irradiation)

  • 문준하;성홍규;유지선;조세연;최재원
    • 한국분말재료학회지
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    • 제29권5호
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    • pp.418-423
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    • 2022
  • Carbon fibers (CFs) are considered promising composite materials for various applications. However, the high cost of CFs (as much as $26 per kg) limits their practical use in the automobile and energy industries. In this study, we developed a continuous stabilization process for manufacturing low-cost CFs. We employed a textile-grade polyacrylonitrile (PAN) fiber as a low-cost precursor and UV irradiation technique to shorten the thermal stabilization time. We confirmed that UV irradiation on the textile-grade PAN fibers could lower the initial thermal stabilization temperature and also lead to a higher reaction. These resulted in a shorter overall stabilization time and enhancement of the tensile properties of textile-grade PAN-based CFs. Our study found that only 70 min of stabilization time with UV irradiation was required to prepare textile-grade PAN-based low-cost CFs with a tensile strength of 2.37 ± 0.22 GPa and tensile modulus of 249 ± 5 GPa.