DOI QR코드

DOI QR Code

Developing Continuous Stabilization Process for Textile-Grade PAN Fiber-Based Carbon Fiber Using UV Irradiation

저가형 탄소섬유 개발을 위한 자외선 조사 기반 의류용 PAN 섬유의 연속식 안정화 공정 개발

  • Moon, Joon Ha (Department of Chemistry, Gyeongsang National University) ;
  • Seong, Honggyu (Department of Chemistry, Gyeongsang National University) ;
  • Yoo, Jiseon (Carbon composite Materials Research Center, Korea Institute of Science and Technology (KIST)) ;
  • Cho, Se Youn (Carbon composite Materials Research Center, Korea Institute of Science and Technology (KIST)) ;
  • Choi, Jaewon (Department of Chemistry, Gyeongsang National University)
  • 문준하 (경상국립대학교 화학과) ;
  • 성홍규 (경상국립대학교 화학과) ;
  • 유지선 (한국과학기술연구원 탄소융합소재센터) ;
  • 조세연 (한국과학기술연구원 탄소융합소재센터) ;
  • 최재원 (경상국립대학교 화학과)
  • Received : 2022.10.13
  • Accepted : 2022.10.19
  • Published : 2022.10.28

Abstract

Carbon fibers (CFs) are considered promising composite materials for various applications. However, the high cost of CFs (as much as $26 per kg) limits their practical use in the automobile and energy industries. In this study, we developed a continuous stabilization process for manufacturing low-cost CFs. We employed a textile-grade polyacrylonitrile (PAN) fiber as a low-cost precursor and UV irradiation technique to shorten the thermal stabilization time. We confirmed that UV irradiation on the textile-grade PAN fibers could lower the initial thermal stabilization temperature and also lead to a higher reaction. These resulted in a shorter overall stabilization time and enhancement of the tensile properties of textile-grade PAN-based CFs. Our study found that only 70 min of stabilization time with UV irradiation was required to prepare textile-grade PAN-based low-cost CFs with a tensile strength of 2.37 ± 0.22 GPa and tensile modulus of 249 ± 5 GPa.

Keywords

Acknowledgement

This work was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT). (NRF-2020R1F1A1072441, NRF-2021R1C1C1011436). This research was supported by "Regional Innovation Strategy (RIS)" through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (MOE) (2021RIS-003) and Following are results of a study on the "Leaders in INdustry-university Cooperation 3.0" Project, supported by the Ministry of Education and National Research Foundation of Korea. This work was supported by the Technological Development for Commercialization by using techbridge platform [RS-2022-00141871] funded by the Ministry of Small and Medium-sized Enterprises (SMEs) and Startups (MSS, Korea).

References

  1. D. D. Edie: Carbon, 36 (1998) 345. https://doi.org/10.1016/S0008-6223(97)00185-1
  2. P. Morgan: Carbon Fibers and Their Composites, CRC press (2005).
  3. D. Choi, H. Kil and S. Lee: Carbon, 142 (2019) 610. https://doi.org/10.1016/j.carbon.2018.10.028
  4. D. Jang, M. E. Lee, J. Choi, S. Y. Cho and S. Lee: Carbon, 186 (2022) 644. https://doi.org/10.1016/j.carbon.2021.10.061
  5. M. A. Spalding: Scale-up of Novel Low-cost Carbon Fibers Leading to High-volume Commercial Launch, U.S Department of Energy (2014).
  6. D. A. Baker and T. G. Rials: J. Appl. Polym. Sci., 130 (2013) 713. https://doi.org/10.1002/app.39273
  7. D. C. Warren: Lightweighting Composites and Lower Cost Carbon Fiber, U.S. Department of Energy (2013).
  8. K. Naito, Y. Tanaka, J. M. Yang and Y. Kagawa: Carbon, 46 (2008) 189. https://doi.org/10.1016/j.carbon.2007.11.001
  9. D. C. Warren: Low Cost Carbon Fiber Overview, U.S. Department of Energy (2011).
  10. A. A. Ogale, M. Zhang and J. Jin: J. Appl. Polym. Sci., 133 (2016) 43794.
  11. J. W. Kim and J. S. Lee: Carbon, 94 (2015) 524. https://doi.org/10.1016/j.carbon.2015.06.074
  12. B.-J. Kim, T. Kotegawa, Y. Eom, J. An, I.-P. Hong, O. Kato, K. Nakakbayasi, J. Miyawaki, B. C. Kim, I. Mochida and S.-H. Yoon: Carbon, 99 (2016) 649. https://doi.org/10.1016/j.carbon.2015.12.082
  13. M.-A. Kim, D. Jang, S. Tejima, R. Cruz-Silva, H.-I. Joh, H. C. Kim and S. Lee: Sci. Rep., 6 (2016) 22988. https://doi.org/10.1038/srep22988
  14. P. Miao, D. Wu, K. Zeng, G. Xu, C. Zhao and G. Yang: Polym. Degrad. Stab., 95 (2010) 1665. https://doi.org/10.1016/j.polymdegradstab.2010.05.028
  15. S.-Y. Son, A. Y. Jo, G. Y. Jung, Y.-S. Chung and S. Lee: J. Ind. Eng. Chem., 73 (2019) 47. https://doi.org/10.1016/j.jiec.2019.01.012
  16. A. Y. Jo, S. H. Yoo, Y.-S. Chung and S. Lee: Carbon, 144 (2019) 440. https://doi.org/10.1016/j.carbon.2018.12.012
  17. S.-Y. Kim, S. Lee, S. Park, S. M. Jo, H.-S. Lee and H.-I. Joh: Carbon, 94 (2015) 412. https://doi.org/10.1016/j.carbon.2015.07.012
  18. S. Tiwari and J. Bijwe: Proc. Technol., 14 (2014) 505. https://doi.org/10.1016/j.protcy.2014.08.064
  19. A. G. Dumanli and A. H. Windle: J. Mater. Sci., 47 (2012) 4236. https://doi.org/10.1007/s10853-011-6081-8
  20. W. Qin and J. F. Kadla: Ind. Eng. Chem. Res., 50 (2011) 12548.
  21. J. Zhu, S. W. Park, H.-I. Joh, H. C. Kim and S. Lee: Carbon. Lett., 14 (2013) 94.
  22. H. Lee, L.-W. Lee, S.-W. Lee, H.-I. Joh, S.-M. Jo and S. Lee: e-Polymers, 14 (2014) 217. https://doi.org/10.1515/epoly-2013-0080
  23. H. K. Shin, J. P. Jeun, H. B. Kim and P. H. Kang: J. Radiat. Ind., 5 (2011) 41.
  24. S.-W. Lee, H.-Y. Lee, S.-Y. Jang, S.-M. Jo, H.-S. Lee and S. H. Lee: Carbon Lett., 12 (2011) 16. https://doi.org/10.5714/CL.2011.12.1.016
  25. R.-X. Zhao, P.-F. Sun, R.-J. Liu, Z.-H. Ding, X.-S. Li, X.-Y. Liu, X.-D. Zhao and Z.-M. Gao: Appl. Surf. Sci., 433 (2018) 321. https://doi.org/10.1016/j.apsusc.2017.09.252
  26. T. Takahagi, I. Shimada, M. Fukuhara, K. Morita and A. Ishitani: J. Polym. Sci. Pol. Chem., 24 (1986) 3101. https://doi.org/10.1002/pola.1986.080241134
  27. K. Morita, Y. Murata, A. Ishitani, K. Murayama, T. Ono and A. Nakajima: Pure Appl. Chem., 58 (1986) 455. https://doi.org/10.1351/pac198658030455
  28. X. Qiao, C. Zhao, Z. Zhou, Q. Guan and W. Li: ACS Sustain. Chem. Eng., 7 (2019) 17979.
  29. T. H. H. Elagib, E. A. M. Hassan, B. Liu, K. Han and M. Yu: Carbon Lett., 30 (2020) 235. https://doi.org/10.1007/s42823-019-00092-2
  30. S. Faraji, M. F. Yardim, D. S. Can and A. S. Sarac: J. Appl. Polym. Sci., 134 (2017) 44381.
  31. Y. Zhu, M. A. Wilding and S. K. Mukhopadhyay: J. Mater. Sci., 31 (1996) 3831. https://doi.org/10.1007/BF00352799
  32. A. Gupta and I. R. Harrison: Carbon, 34 (1996) 1427. https://doi.org/10.1016/S0008-6223(96)00094-2
  33. A. Kumar, V. N. Khatri and S. K. Gupta: SN Appl. Sci., 2 (2020) 315.