• Title/Summary/Keyword: thermal retention stability

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Effects of Beef Fat Replacement with Gelled Emulsion Prepared with Olive Oil on Quality Parameters of Chicken Patties

  • Meltem, Serdaroglu;Berker, Nacak;Merve, Karabiylkoglu
    • Food Science of Animal Resources
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    • v.37 no.3
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    • pp.376-384
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    • 2017
  • The objective of this study was to investigate the effect of using gelled emulsion (olive oil 46%, inulin 9%, gelatin 3%) as fat replacer on some quality parameters of chicken patties. For this purpose GE, prepared with olive oil, gelatin and inulin was replaced with beef fat at a level of 0%, 25%, 50%, 100% (C, G25, G50, G100). In this study syneresis, thermal stability, centrifuge and creaming stability of gelled emulsion were analyzed. Chemical composition, technological paramerers (cooking yield, water holding capacity, diameter reduction, fat and moisture retention) and textural and sensory properites were evaluated in comparision to control patties. High thermal stability was recorded in GE (93%), also creaming stability results showed that GE protected its stability without any turbidity and separation of the layer. The complete replacement of beef fat with GE showed detrimental effect on all investigated cooking characteristics except fat retention. Replacement of beef fat with GE at a level of 50% resulted similar cooking characteristics with C samples. Color parameters of samples were affected by GE addition, higher CIE $b^*$ values observed with respect to GE concentration. The presence of GE significantly affected textural behaviors of samples (p<0.05). Our results showed that GE prepared with inulin and olive oil is a viable fat replacer for the manufacture of chicken patty.

Thermal and Electrochemical Studies of Tris(2,4,6-trimethoxyphenyl)Phosphine as a Flame Retardant Additive for Li-ion Battery (리튬이차전지 난연성 전해액 첨가제로서의 Tris(2,4,6-trimethoxyphenyl)Phosphine의 열적, 전기화학적 특성)

  • Ahn, Se-Young;Kim, Ke-Tack;Kim, Hyun-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.12
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    • pp.1130-1134
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    • 2008
  • Thermal and electrochemical properties were discussed with tris(2,4,6-trimethoxyphenyl)Phosphine (TTMPP) as a flame retradant additive for Li-ion battery. TTMPP showed excellent thermal stability with charged cathodes. Addition of 1 wt.% of the additive to the electrolyte improved the thermal stability without damaging the performance of the battery. The oxygne evolution reaction delayed nearly by $60^{\circ}C$. The capacity retention ratio in cycle life tests of the battery with 1 wt.% TTMPP was slightly improved comparing to the no additive cells.

Enhanced Stability of Perovskite Solar Cells using Organosilane-treated Double Polymer Passivation Layers

  • Park, Dae Young;Byun, Hye Ryung;Kim, Hyojung;Kim, Bora;Jeong, Mun Seok
    • Journal of the Korean Physical Society
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    • v.73 no.11
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    • pp.1787-1793
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    • 2018
  • The power conversion efficiency of perovskite solar cells has reached 23.3%. Although significant developments have been made through intensive studies, the stability issue is still challenging. Passivation of perovskite solar cells with a transparent polymer provides better stability; however, there are a few disadvantages of organic polymer such as low thermal stability, weak adhesion and the lack of water retention ability. In this work, we prepared a dual Parylene-F/C layer with 3-methacryloxypropyltrimethoxysilane, A-174, to combine the advantages of organic and inorganic materials. As a result, A-174 treated dual Parylene-F/C layer demonstrated improved passivation effects compared to a single Parylene layer due to the strong binding of Parylene and the water retention ability by $SiO_2$ formed from A-174. This synergetic effects can be expanded to the combination of other organic materials and organosilane compounds.

Study on Improving the Mechanical Stability of 3D NAND Flash Memory String During Electro-Thermal Annealing (3D NAND 플래시메모리 String에 전열어닐링 적용을 가정한 기계적 안정성 분석 및 개선에 관한 연구)

  • Kim, Yu-Jin;Park, Jun-Young
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.3
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    • pp.246-254
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    • 2022
  • Localized heat can be generated using electrically conductive word-lines built into a 3D NAND flash memory string. The heat anneals the gate dielectric layer and improves the endurance and retention characteristics of memory cells. However, even though the electro-thermal annealing can improve the memory operation, studies to investigate material failures resulting from electro-thermal stress have not been reported yet. In this context, this paper investigated how applying electro-thermal annealing of 3D NAND affected mechanical stability. Hot-spots, which are expected to be mechanically damaged during the electro-thermal annealing, can be determined based on understanding material characteristics such as thermal expansion, thermal conductivity, and electrical conductivity. Finally, several guidelines for improving mechanical stability are provided in terms of bias configuration as well as alternative materials.

Surface modified ceramic fiber separators for thermal batteries

  • Cheong, Hae-Won;Ha, Sang-Hyeon;Choi, Yu-Song
    • Journal of Ceramic Processing Research
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    • v.13 no.spc2
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    • pp.308-311
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    • 2012
  • A wide range of possible hazards existing in thermal batteries are mainly caused by thermal runaway, which results in overheating or explosion in extreme case. Battery separators ensure the separation between two electrodes and the retention of ion-conductive electrolytes. Thermal runaways in thermal batteries can be significantly reduced by the adoption of these separators. The high operating temperature and the violent reactivity in thermal batteries, however, have limited the introduction of conventional separators. As a substitute for separators, MgO powders have been mostly used as a binder to hold molten salt electrolyte. During recent decades the fabrication technology of ceramic fiber, which has excellent mechanical strength and chemical stability, has undergone significant improvement. In this study we adopted wet-laid nonwoven paper making method instead of the electrospinning method which is costly and troublesome to produce in volume. Polymeric precursor can readily be coated on the surface of wet-laid ceramic paper, and be formed into ceramic film after heat treatment. The mechanical strength and the thermo-chemical stability as well as the wetting behaviors of ceramic separators with various molten salts were investigated to be applicable to thermal batteries. Due to their excellent chemical, mechanical, and electrical properties, wet-laid nonwoven separators made from ceramic fibers have revealed positive possibility as new separators for thermal batteries which operate at high temperature with no conspicuous sign of a short circuit and corrosion.

Enhancement of Electrochemical Activity of Ni-rich LiNi0.8Mn0.1Co0.1O2 by Precisely Controlled Al2O3 Nanocoatings via Atomic Layer Deposition

  • Ramasamy, Hari Vignesh;Sinha, Soumyadeep;Park, Jooyeon;Gong, Minkyung;Aravindan, Vanchiappan;Heo, Jaeyeong;Lee, Yun-Sung
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.196-205
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    • 2019
  • Ni-rich layered oxides $Li(Ni_xCo_yMn_z)O_2$ (x + y + z = 1) have been extensively studied in recent times owing to their high capacity and low cost and can possibly replace $LiCoO_2$ in the near future. However, these layered oxides suffer from problems related to the capacity fading, thermal stability, and safety at high voltages. In this study, we use surface coating as a strategy to improve the thermal stability at higher voltages. The uniform and conformal $Al_2O_3$ coating on prefabricated electrodes using atomic layer deposition significantly prevented surface degradation over prolonged cycling. Initial capacity of 190, 199, 188 and $166mAh\;g^{-1}$ is obtained for pristine, 2, 5 and 10 cycles of ALD coated samples at 0.2C and maintains 145, 158, 151 and $130mAh\;g^{-1}$ for high current rate of 2C in room temperature. The two-cycle $Al_2O_3$ modified cathode retained 75% of its capacity after 500 cycles at 5C with 0.05% capacity decay per cycle, compared with 46.5% retention for a pristine electrode, at an elevated temperature. Despite the insulating nature of the $Al_2O_3$ coating, a thin layer is sufficient to improve the capacity retention at a high temperature. The $Al_2O_3$ coating can prevent the detrimental surface reactions at a high temperature. Thus, the morphology of the active material is well-maintained even after extensive cycling, whereas the bare electrode undergoes severe degradation.

Stability of the enzyme-modified starch-based hydrogel model premix with curcumin during in vitro digestion (효소변형 전분기반 하이드로젤 모델 프리믹스 내 탑재된 커큐민의 소화과정 중 안정성)

  • Kang, Jihyun;Rho, Shin-Joung;Lee, Jiyoung;Kim, Yong-Ro
    • Korean Journal of Food Science and Technology
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    • v.53 no.4
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    • pp.365-374
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    • 2021
  • In this study, the effect of enzyme-modified starch used in the preparation of filled hydrogel powder loaded with curcumin (FHP) on redispersibility, thermal and UV stability, and curcumin retention during in vitro digestion was investigated. FHP maintained stability without layer separation when redispersed and showed more stability against UVB than the emulsion powder (EMP). There was no significant difference in the chemical stability of curcumin between rice starch-based filled hydrogel powder (RS-FHP) and enzyme-modified starch-based filled hydrogel powder (GS-FHP). However, the gel matrix of GS-FHP maintained greater stability of lipid droplets in the stomach compared to RS-FHP, thereby improving the retention rate of curcumin after in vitro digestion. GS-FHP could be used as a novel material for developing premixes that require stable formulation and maintenance of functional substances, as it can increase the dispersion stability and retention rate of functional substances after digestion.

Interfacial Magnetic Anisotropy of Co90Zr10 on Pt Layer

  • Gil, Jun-Pyo;Seo, Dong-Ik;Bae, Gi-Yeol;Park, Wan-Jun;Choe, Won-Jun;No, Jae-Seong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.356.2-356.2
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    • 2014
  • Spin Transfer Torque (STT) is of great interest in data writing scheme for the Magneto-resistive Random Access Memory (MRAM) using Magnetic Tunnel Junction (MTJ). Scalability for high density memory requires ferromagnetic electrodes having the perpendicular magnetic easy axis. We investigated CoZr as the ferromagnetic electrode. It is observed that interfacial magnetic anisotropy is preferred perpendicular to the plane with thickness dependence on the interfaces with Pt layer. The anisotropy energy (Ku) with thickness dependence shows a change of magnetic-easy-axis direction from perpendicular to in-plane around 1.2 nm of CoZr. The interfacial anisotropy (Ki) as the directly related parameters to switching and thermal stability, are estimated as $1.64erg/cm^2$ from CoZr/Pt multilayered system.

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Preparation and Characterization of Polysulfone Substrate for Reinforced Composite Membrane Fuel Cell Membrane (연료전지 전해질 복합막 제조를 위한 폴리설폰계 지지체의 제조와 물성)

  • Nam, Sang-Yong;Kim, Deuk-Ju;Hwang, Rae-Young;Kim, Hyoung-Juhn
    • Membrane Journal
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    • v.19 no.1
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    • pp.63-71
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    • 2009
  • In this study, polysulfone which has excellent mechanical and thermal stability with low cost was used for preparing a non-conducting polymer matrix as a reinforced composite membrane for fuel cell application. The membranes were prepared by phase separation method. Polymer concentration and retention time were controlled to investigate the effects on the membrane morphology. The resaltant membranes showed all sponge-like structure independent of polymer concentration. The mechanical and thermal stability were improved with increasing polymer concentration in contrast to the membrane porosity. As a result, the membranes prepared with the retention time for 2 mins using 20 wt% of polymer solution was suitable for a fuel cell compositite membrane providing optimum properties such as approximately 80% of high porosity, 1.3 MPa of tensile strength, and less than 1% of thermal shrinkage both machine and transverse direction.

Measurement and Verification of Unfrozen Water Retention Curve of Frozen Sandy Soil Based on Pore Water Salinity (간극수 염분농도에 따른 동결 사질토의 부동수분곡선 산정 및 검증 연구)

  • Kim, Hee-Won;Go, Gyu-Hyun
    • Journal of the Korean Geotechnical Society
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    • v.39 no.11
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    • pp.53-62
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    • 2023
  • The characteristics of unfrozen water content in frozen soils significantly impact the thermal, hydraulic, and mechanical behavior of the ground. A thorough analysis of the unfrozen water content characteristics of the target subsoil material is crucial for evaluating the stability of frozen ground. This study conducted indoor experiments to measure the freezing point and unfrozen water content of sandy soil while considering pore water salinity. Utilizing the experimental data, we introduced a novel empirical model to conveniently estimate the unfrozen water retention curve. Furthermore, the validity of the unfrozen water retention curve was assessed by comparing the experimental data with the results of a simulation model that utilized the proposed empirical model as input data.