• 제목/요약/키워드: thermal reduction

검색결과 1,648건 처리시간 0.034초

화력발전소에서 용융회가 열전달 감소에 미치는 영향에 관한 연구 (A Study on the Heat Transfer Reduction due to the Clinker in the Thermal Poorer Plant)

  • 강희찬;이규욱
    • 동력기계공학회지
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    • 제4권1호
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    • pp.13-19
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    • 2000
  • This study was conducted for the heat transfer reduction due to the clinker formed in the furnace of the thermal power plant. The thermal properties of clinker such as thermal conductivity, specific heat, density and void fraction were measured. The thermal conductivities of the clinker were ranged $0.32-0.54W/m{\cdot}K$ and the average specific heat and the void fraction were $930J/kg{\cdot}K$ and 0.36 respectively. The thermal resistance of clinker was the greatest among the thermal resistances. It was found that the clinker reduces more than 90% of the heat transfer if the clinker is thicker than 10 cm.

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금속산화물(Cu-ferrite)를 이용한 수소제조 연구 (Study on the hydrogen production using the metal oxide (Cu-ferrite))

  • 박주식;서인태;김정민;이상호;황갑진
    • 한국수소및신에너지학회논문집
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    • 제15권3호
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    • pp.201-207
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    • 2004
  • Redox characteristics of metal oxide for hydrogen production by thermochemical water-splitting were investigated. $CuFe_2O_4$ as a redox pair that had a different molar ratio of Cu and Fe were prepared by co-precipitation method. Hydrogen production consisted of water-splitting step and thermal reduction step was performed below 1200K. Redox characteristics of Cu-ferrites were studied using the thermal gravimetric analysis technique. Also, structure change of Cu-ferrite during thermal reduction was investigated using the high temperature controlled XRD. In results, oxygen release of Cu-ferrite during the thermal reduction was initiated at oxygen site combined with Cu. Consequently, oxygen release amount of Cu-ferrite was increased with increase of Cu molar ratio of Cu-ferrite. It was found that thermal reduction of Cu-ferrite was begun at $875^\circ{C}$. It was confirmed that structure of Cu-ferrite was changed to metal and cation excess metal oxide during the thermal reduction step.

전처리 방법에 따른 슬러지 가용화가 혐기소화에서 메탄 생산과 슬러지 감량에 미치는 영향 (Sludge Solubilization by Pre-treatment and its Effect on Methane Production and Sludge Reduction in Anaerobic Digestion)

  • 김동진;김혜영
    • Korean Chemical Engineering Research
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    • 제48권1호
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    • pp.103-109
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    • 2010
  • 하폐수 처리과정에서 발생되는 슬러지는 주로 혐기소화에 의해 처리되며 슬러지를 감량하고 메탄을 생산할 수 있어 많이 이용되고 있다. 슬러지의 전처리는 혐기소화의 율속단계인 가수분해를 높여 처리속도를 향상시키므로 많은 연구가 진행 중이다. 본 연구에서는 열, 초음파, 열-알칼리의 전처리 기술에 따른 슬러지의 가수분해(가용화) 효과와 전처리한 슬러지를 혐기소화하여 메탄 생산량과 슬러지의 감량 효과를 비교하였다. 하수와 폐수 슬러지 가용화율은 열-알칼리 동시 처리한 경우에는 67과 70%로 가장 높았고 다음으로 초음파 처리와 열처리가 40% 이상의 비슷한 가용화율을 보였다. 혐기소화 가스의 메탄 함량은 45~70% 범위로 유지되었고 전처리한 슬러지가 control에 비해 높게 나타났다. 메탄 생산량은 열처리, 초음파 처리, 열-알칼리를 같이 처리한 경우가 control에 비해 각각 하수슬러지는 2.6, 2.7, 3.5배, 폐수 슬러지는 3.5, 4.1, 4.2배 증가하였다. 혐기소화 슬러지의 감량효과는 전처리한 슬러지가 control에 비해 5~19% 포인트 높게 나타났으며 열-알칼리 처리한 경우가 초음파와 열처리에 비해 우수한 감량 효과를 보였다. 위의 결과로부터 전처리가 메탄 생산량에서 뿐만 아니라 슬러지 처리처분 비용 절감에 있어서도 중요한 역할을 함을 확인할 수 있었고 열-알칼리 동시 처리가 가장 우수한 성능을 보였다.

$CO_2$ 첨가가 $CH_4$-공기 대향류 확산화염의 구조 및 NOx 생성에 미치는 영향 (Effect of $CO_2$ Addition on Flame Structure and NOx Formation of $CH_4-Air$ Counterflow Diffusion Flames)

  • 이승로;한지웅;이창언
    • 한국연소학회지
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    • 제4권2호
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    • pp.97-108
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    • 1999
  • This numerical study was to investigate the effect of $CO_2$ addition on the structures and NOx formation characteristics in $CH_4$ counterflow diffusion flame. The importance of radiation effect was identified and $CO_2$ addition effect was investigated in terms of thermal and chemical reaction effect. Also the causes of NOx reduction were clarified by separation method of each formation mechanisms. The results were as follows : The radiation effect was intensified by $CO_2$ addition. Thermal effect mainly contributed to the changes in flame structure and the amount of NO formation but the chemical reaction effect also cannot be neglected. The reduction of thermal NO was dominant with respect to reduction rate, but that of prompt NO was dominant with respect to total amount.

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Characterization of Graphite Oxide Reduced by Thermal and/or Chemical Treatments

  • Kim, Jungsoo;Nam, Dae-Geun;Yeum, Jeong Hyun;Suh, Sungbu;Oh, Weontae
    • Transactions on Electrical and Electronic Materials
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    • 제16권5호
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    • pp.274-279
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    • 2015
  • Reduced graphite oxides (rGOs) were prepared by the common graphite oxidation method and the subsequent reductions. The reduction of graphite oxides (GOs) was conducted chemically and/or thermally. To further reduce the as-prepared rGOs, GOs were treated with chemical/thermal reductions or thermal/chemical reductions, in which the reduction sequence was also considered. The structural changes of as-prepared rGOs, depending on reduction methods, were investigated by X-ray diffraction analyses, Raman spectroscopy, X-ray photoelectron spectroscopy, and scanning electron microscopy. In addition, we discuss the structural change of the rGOs and their closely related physical and electrical properties, such as thermogravimetry, nitrogen adsorption isotherm, and sheet resistance.

밀폐계 유동시스템내에서 고분자물질의 퇴화에 관한 실험적 연구 (An Experimental Study on the Degradation of Polymer in Closed Flow System)

  • 김재근
    • Journal of Advanced Marine Engineering and Technology
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    • 제23권5호
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    • pp.679-686
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    • 1999
  • This study is to investigate the effect of a substantial drag reduction caused by the polymer(A611P) when the working fluids flow to the vertical direction in the vertical cylindrical equipment of closed flow system. The drag reduction is associated with the mechanical degrada-tion thermal degradation and heat transfer. By ignore the heat fluxs within the closed system the pressure drop due to the polymer concentration the flow velocity and flow time have been mea-sured. By taking into account the mechanical and thermal degradation in the closed system an experiment has been focused on the determination of the condition which could improve the pump capacity in the heat union electric power plant. Under the condition of non-boiling it has been found out that the change of heat flux has little influence on the drag reduction.

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열화학싸이클 수소를 제조를 위한 (Cu0.5Mn0.5)Fe2O4의 열적 거동 (Thermal Behaviors of (Cu0.5Mn0.5)Fe2O4 for H2 production by thermochemical cycles)

  • 김진웅;최승철;주오심;정광덕
    • 한국수소및신에너지학회논문집
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    • 제15권1호
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    • pp.32-38
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    • 2004
  • Thermal behaviors of $(Cu_{0.5}Mn_{0.5})Fe_2O_4$, prepared by a solid method, were investigated for $H_2$ production by a thermochemical cycle. The thermal reduction of $(Cu_{0.5}Mn_{0.5})Fe_2O_4$ started from $300^\circ{C}$ and the weight loss was 1.3 wt% up to 1200. XRD shows the prepared ferrite has the spinel structure with a lattice constant of $8.414{\AA}$ and changed to the oxygen deficient structure by thermal reduction. Oxygen and hydrogen can be separately produced by the cycles of thermal reduction and water oxidation of the oxygen deficient ferrite.

플라스틱 온실(溫室)의 열저장(熱貯藏) 시스템의 개발(開發)에 관(關)한 연구(硏究)(II) -수경재배용(水耕栽培用) 태양열(太陽熱) 온실(溫室) 시스템의 열적(熱的) 성능(性能)- (Development of Thermal Storage System in Plastic Greenhouse(II) -Thermal performance of solar greenhouse system for hydroponic culture-)

  • 김용현;고학균;김문기
    • Journal of Biosystems Engineering
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    • 제15권2호
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    • pp.123-133
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    • 1990
  • Thermal performance of a solar heating plastic greenhouse designed for a hydroponic system was studied. The system was constructed with the air-water heat exchanger and thermal storage tank that were combined with hydroponic water beds. Experiments were carried out to investigate the daily average heat stored and released in thermal storage tank, average solar energy collection efficiency, average coefficient of performance, average oil reduction factor of thermal storage system, and the heat transfer coefficient during the nighttime in plastic greenhouse. The results obtained in the present study are summarized as follows. 1. Daily average heat stored in thermal storage tank and released from the thermal storage tank was 1,259 and $797KJ/m^2$ day, respectively. 2. The average solar energy collection efficiency of thermal storage tank was 0.125 during the experiment period. And the average coefficient of performance of thermal storage system in plastic greenhouse was 3.6. 3. The average oil reduction factor of thermal storage system and the heat transfer coefficient during the nighttime in plastic greenhouse were found to be 0.52 and $4.3W/m^2\;hr\;^{\circ}C$, respectively.

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베이퍼챔퍼 제조기술을 적용한 LED 투광등기구의 열 특성 비교에 관한 연구 (A Study on the Thermal Characteristics Comparison of the LED Floodlight Luminaire using Vapor Chamber Manufacturing Technology)

  • 서진국;유영문
    • 조명전기설비학회논문지
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    • 제29권1호
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    • pp.15-21
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    • 2015
  • The purpose of this paper is to analyze thermal characteristics of the heat sinks to maximize the thermal diffusivity for LED floodlight. The 2 kind of samples were prepared by vapor chamber manufacturing technology using the heat pipe principle. It was analyzed the maximum temperature reduction effect and the thermal diffusion from the heat source depending on the types of chambers with 3 kind of working fluids. As a result, it was confirmed that thermal conductivity 23% increased, GVC-R type than IVC-R type.

EGR 장착 스파크 점화 LPG 엔진의 성능 및 배기특성 (Performance and Emission Characteristics in a Spark-Ignition LPG Engine with Exhaust Gas Recirculation)

  • 조윤호;구준모;장진영;배충식
    • 한국자동차공학회논문집
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    • 제10권1호
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    • pp.24-31
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    • 2002
  • An experimental study was conducted to investigate the effects of EGR (Exhaust Gas Recirculation) variables on performance and emission characteristics in a 2-liter 4-cylinder spark-ignition LPG fuelled engine. The effects of EGR on the reduction of thermal loading at exhaust manifold were also investigated because the reduced gas temperature is desirable for the reliability of an engine in light of both thermal efficiency and material issue of exhaust manifold. The steady-state tests show that the brake thermal efficiency increased and the brake specific fuel consumption decreased with the increase of EGR rate in hot EGR and with the decrease of EGR temperature in case of cooled EGR, while the stable combustion was maintained. The increase of EGR rate or the decrease of EGR temperature results in the reduction of NOx emission even in the increase of HC emission. Furthermore, decreasing EGR temperature by $180^{\circ}C$ enabled the reduction of exhaust gas temperature by $15^{\circ}C$ in cooled EGR test at 1600rpm/370kPa BMEP operation, and consequently the reduction of thermal load at exhaust. The optimization strategy of EGR application is to be discussed by the investigation on the effect of geometrical characteristics of EGR-supplying pipe line.