• Applied Chemistry for Engineering
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• v.35 no.4
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• pp.309-315
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• 2024

Silicon and carbon composite (SiC) is considered one of the most promising anode materials for the commercialization of Si-based anodes, as it could simultaneously satisfy the high theoretical capacity of Si and the high electronic conductivity of carbon. However, SiC active material undergoes repeated volumetric changes during charge/discharge processes, leading to continuous electrolyte decomposition and capacity fading, which is still considered an issue that needs to be addressed. To solve this issue, we suggest a 4,4'-Methylenebis(cyclohexyl isocyanate) (H₁₂MDI)-based waterborne polyurethane binder (HPUD), which forms a 3D network structure through thermal cross-linking reaction. The cross-linked HPUD (denoted as CHPU) was prepared using an epoxy ring-opening reaction of the cross-linker, triglycidyl isocyanurate (TGIC), via simple thermal treatment during the SiC anode drying process. The SiC anode with the CHPU binder, which exhibited superior mechanical and adhesion properties, not only demonstrated excellent rate and cycling performance but also alleviated the volume expansion of the SiC anode. This work implies that eco-friendly binders with cross-linked structures could be utilized for various Si-based anodes.

• International Journal of Automotive Technology
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• v.6 no.1
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• pp.15-21
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• 2005

The purpose of this paper is to experimentally investigate the engine pollutant emissions and combustion characteristics of diesel engine fueled with ethanol-diesel blended fuel (bio-diesohol). The experiments were performed on a single-cylinder DI diesel engine. Two blend fuels were consisted of $15\%$ ethanol, $83.5\%$ diesel and $1.5\%$ solublizer (by volume) were evaluated: one without cetane improver (E15-D) and one with a cetane improver (E15-D+CN improver). The engine performance parameters and emissions including fuel consumption, exhaust temperature, lubricating oil temperature, Bosch smoke number, CO, NOx, and THC were measured, and compared to the baseline diesel fuel. In order to gain insight into the combustion characteristics of bio-diesohol blends, the engine combustion processes for blended fuels and diesel fuel were observed using an Engine Video System (AVL 513). The results showed that the brake specific fuel consumption (BSFC) increased at overall engine operating conditions, but it is worth noting that the brake thermal efficiency (BTE) increased by up to $1-2.3\%$ with two blends when compared to diesel fuel. It is found that the engine fueled with ethanol-diesel blend fuels has higher emissions of THC, lower emissions of CO, NOx, and smoke. And the results also indicated that the cetane improver has positive effects on CO and NOx emissions, but negative effect on THC emission. Based on engine combustion visualization, it is found that ignition delay increased, combustion duration and the luminosity of flame decreased for the diesohol blends. The combustion is improved when the CN improver was added to the blend fuel.

• Journal of the Korean Society of Clothing and Textiles
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• v.36 no.3
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• pp.259-268
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• 2012

This study suggests quantitative guidelines for inside clothing temperatures to improve the heat tolerance of 20's females in summer. First, the inside clothing temperatures ($T_{cl}$) of each subject was measured in daily use. The subjects were asked to record subjective thermal sensations, clothing items worn, clothing weight, and activities during an experiment designed to determine the comfort zone of $T_{cl}$. In a thermally neutral state, the comfort zone of $T_{cl}$ was decided on a mean value $T_{cl}{\pm}1{\sigma}$. Second, the subjects were asked to wear clothing that would enable them to feel 'slightly warm but still comfortable'. The rest of the processes were the same as previous steps that were designed to understand the way and degree of clothing control. The comfort zone of $T_{cl}$ was decided in the same manner as the previous step. The two comfort zones were combined and named the combined comfort zone of the definitive comfort zone. The results were as follows: 1. Thermally comfortable $T_{cl}$, Hcl were $34.0{\pm}1.1^{\circ}C$, $40{\pm}9%%RH$ and the thermally comfortable ambient climate was $25.0{\pm}1.6^{\circ}C$, $53{\pm}7%$RH. 2. When subjects were asked to wear 'slightly warm but still comfortable', there were difference in thermally comfortable $T_{cl}$, clothing weight and clothing layer by subject. 3. In this study, the optimal $T_{cl}$ was decided on the mid-point of the definitive comfort zone of $T_{cl}$.

• Journal of the Korean Ceramic Society
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• v.51 no.5
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• pp.505-510
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• 2014

The properties of black ceramic pigments including thermal and glaze stability were systematically investigated so that these pigments could be used to decorate porcelain products. Various compositions of $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ and $Co(Fe,Cr)_2O_4$ powders were synthesised using a solid state reaction method. The obtained $Co(Fe,Cr)_2O_4$ and $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ powders showed single phases of spinel structure after calcination processes at $1000^{\circ}C$ and $1200^{\circ}C$, respectively. CIE $L^*a^*b^*$ colourimetric parameters of glazed $Co(Fe,Cr)_2O_4$ and $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ pigments were analyzed according to the different amounts of Cr substitution. In addition, the amount of $Cr^{+6}$ remaining in the $Co(Fe,Cr)_2O_4$ and $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ pigments was also measured.

• Journal of the Institute of Electronics Engineers of Korea TE
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• v.39 no.3
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• pp.8-14
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• 2002

UV, heat, and discharge treatments are arbitrary simulated for finding out the initiations and processes of surface degradation on the polymer surface. Especially, this study is focused on the inter-relation between chemical changes and electrical properties. In contact angle to measure the change of activated degree, that of polymers surface shows a slight hydrophobicity of 73$^{\circ}$~91$^{\circ}$. But, discharge treatment and UV treatment of 300 nm wavelength changed it to the hydrophilic one with the decrease of contact angle, 13.8$^{\circ}$ and 20$^{\circ}$ respectively. Thermal-treatment and UV treatment of 430~500 nm wavelength changed the surface to the hydrophobic one with the increase of contact angle, 90$^{\circ}$ and 80.1$^{\circ}$ respectively.  

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.335.2-335.2
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• 2016

The fixed negative charge of the Al2O3 passivation layer gives excellent passivation performance for both n-type and p-type silicon wafers. For the best passivation quality, annealing is known to be a prerequisite step and a lot of studies concerning annealing effect on the passivation characteristics have been performed. Meanwhile, for manufacturing a crystalline silicon solar cell, firing process is applied to the Al2O3 passivation layer. Therefore, study on not only annealing effect but also on firing effect is necessary. In this work, Al2O3 passivation performance (minority carrier lifetime) for p-type silicon wafer was evaluated with Quasi-Steady-State Photoconductance(QSSPC) measurement after annealing at different temperatures. For the samples which showed different aspects, C-V measurement was performed for the cause - whether it is due to the chemical effect or field-effect. The change in Al2O3 passivation property after firing processes was investigated and the mechanism for the change could be estimated.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.410.2-410.2
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• 2016

Tandem structure is promising in organic solar cells because of its double open-circuit voltage (VOC) and efficient photon energy conversion. In a typical tandem device, the two single sub-cells are stacked and connected by an interconnecting layer. The fabrication of two sub-cells are usually carried out in a glovebox filled with nitrogen or argon gas, which makes it expensive and laborious. We report a glovebox-free fabricated inverted tandem organic solar cells wherein the tandem structure comprises sandwiched interconnecting layer based on p-doped hole-transporting, metal, and electron-transporting materials. Complete fabrication process of the tandem device was performed outside the glove box. The tandem solar cells based on poly(3-hexylthiophene) (P3HT) and (6,6)-phenyl C61-butyric acid methyl ester (PCBM) can realize a high VOC, which sums up of the two sub-cells. The tandem device structure was ITO/ZnO/P3HT:PCBM/PEDOT:PSS/MoO3/Au/Al/ZnO-d/P3HT:PCBM/PEDOT:PSS/Ag. The separate sub-cells were morphologically and thermally stable up to 160 oC. The high stability of the active layer benefits in the fabrication processes of tandem device. The performance of tandem organic solar cells comes from the sub-cells with an 50 nm thick active layer of P3HT:PCBM, achieving an average power conversion efficiency (PCE) of 2.9% (n=12) with short-circuit current density (JSC) = 4.26 mA/cm2, VOC = 1.10 V, and fill factor (FF) = 0.62. Based on these findings, we propose a new method to improve the performance and stability of tandem organic solar cells.

• KEPCO Journal on Electric Power and Energy
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• v.2 no.3
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• pp.433-436
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• 2016

In the area of environmental chemistry of power plant, flow analysis of the reactor with built-in impeller is a very important part from the perspective of the improvement of the efficiency of the entire process. As a wide range of methods are being proposed for the analysis of the flow pattern within the reactor, this study analyzed the flow within the reactor according to the baffle structure (height) installed on the internal wall of the reactor in order to improve the reaction efficiency through the inducing of the up and down stirring with the reactor. As the results of the execution of the flow analysis for each of a diverse range of cases by utilizing the Computational Fluid Dynamics (CFD) method, it was possible to confirm that the flow is markdely improved by inducing the up and down stirring among the reactants within the reactor if the baffle is elevated to the level below the water surface. In particular, as the results of the analysis of the general cases in which the baffle is elevated all 4 steps and the cases in which the baffle is elevated only 2 steps, elevating the baffle only 2 steps achieve the same effect as the elevating of the baffle by 4 steps. Therefore, it was possible to expect to improve the efficiency with out the need to increase the use of electric power substantially if the outcomes of this study is applied to the actual sites of power plants in the future.

• KEPCO Journal on Electric Power and Energy
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• v.4 no.1
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• pp.33-38
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• 2018

This study applied upgrades to the processes of a 10 MW wet amine $CO_2$ capture pilot plant and conducted performance evaluation. The 10 MW $CO_2$ Capture Pilot Plant is a facility that applies 1/50 of the combustion flue gas produced from a 500 MW coal-fired power plant, and is capable of capturing up to 200 tons of $CO_2$. This study aimed to quantitatively measure efficiency improvements of post-combustion $CO_2$ capture facilities resulting from process upgrades to propose reliable data for the first time in Korea. The key components of the process upgrades involve absorber intercooling, lean/rich amine exchanger efficiency improvements, reboiler steam TVR (Thermal Vapor Recompression), and lean amine MVR (Mechanical Vapor Recompression). The components were sequentially applied to test the energy reduction effect of each component. In addition, the performance evaluation was conducted with the absorber $CO_2$ removal efficiency maintained at the performance evaluation standard value proposed by the IEA-GHG ($CO_2$ removal rate: 90%). The absorbent used in the study was the highly efficient KoSol-5 that was developed by KEPCO (Korea Electric Power Corporation). From the performance evaluation results, it was found that the steam consumption (regeneration energy) for the regeneration of the absorbent decreased by $0.38GJ/tonCO_2$ after applying the process upgrades: from $2.93GJ/ton\;CO_2$ to $2.55GJ/tonCO_2$. This study confirmed the excellent performance of the post-combustion wet $CO_2$ capture process developed by KEPCO Research Institute (KEPRI) within KEPCO, and the process upgrades validated in this study are expected to substantially reduce $CO_2$ capture costs when applied in demonstration $CO_2$ capture plants.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.1
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• pp.61-69
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• 1998

Vapor Axial Deposition (VAD), one of optical fiber preform fabrication processes, is performed by deposition of submicron-size silica particles that are synthesized by combustion of raw chemical materials. In this study, flow field is assumed to be a forced uniform flow perpendicularly impinging on a rotating disk. Similarity solutions obtained in our previous study are utilized to solve the particle transport equation. The particles are approximated to be in a polydisperse state that satisfies a lognormal size distribution. A moment model is used in order to predict distributions of particle number density and size simultaneously. Deposition of the particles on the disk is examined considering convection, Brownian diffusion, thermophoresis, and coagulation with variations of the forced flow velocity and the disk rotating velocity. The deposition rate and the efficiency directly increase as the flow velocity increases, resulting from that the increase of the forced flow velocity causes thinner thermal and diffusion boundary layer thicknesses and thus causes the increase of thermophoretic drift and Brownian diffusion of the particles toward the disk. However, the increase of the disk rotating speed does not result in the direct increase of the deposition rate and the deposition efficiency. Slower flow velocity causes extension of the time scale for coagulation and thus yields larger mean particle size and its geometric standard deviation at the deposition surface. In the case of coagulation starting farther from the deposition surface, coagulation effects increases, resulting in the increase of the particle size and the decrease of the deposition rate at the surface.