• Title/Summary/Keyword: thermal impact

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Preparation of Properties of PC/PBT Alloy Using MBS Compatibility (MBS상용화제를 사용한 PC/PET Alloy의 제조와 그 물성)

  • Lee, Yong-Moo;Kang, Doo-Whan
    • Applied Chemistry for Engineering
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    • v.5 no.1
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    • pp.54-62
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    • 1994
  • Bisphenol A polycarbonate(PC) and polyethylene terephthalate(PET) was blended with methylmethacrylate-butadiene-styrene(MBS) copolymer for the improvement of impact resistance strength PC/PET alloy blending with PC more than 15 parts to 100 parts of PET usually have poor compatability, but increased the compatability characteristics of PC/PET alloy prepared by addition of MBS compatabilizer. The compatability of PC and PET using compatabilizer, MBS was determined by measuring the thermal characteristics of Tg difference between PC and PET, and crystallization temperature, Tcc. As the Tg difference becoming narrow to $60^{\circ}C$, and Tcc decreasing to $150^{\circ}C$, the comparability of PC and PET was increased. And also tough rate impact strength to PC/PET alloy using MBS was increased, in case more than 15 parts of PC being blended to PET.

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The Effect of Sb/RE on the As-Cast Morphology of Graphite and Mechanical Properties of Heavy Section Ferritic Ductile Cast Iron (후육 페라이트 구상흑연주철의 주방상태 흑연형상 및 기계적 성질에 미치는 Sb/RE의 영향)

  • Shin, Ho-Chul;Yun, Ho-Sung;Shin, Je-Sik;Lee, Sang-Mok;Moon, Byung-Moon
    • Journal of Korea Foundry Society
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    • v.25 no.5
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    • pp.195-202
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    • 2005
  • In this study, we investigated the effect of Sb/RE on the microstructure and mechanical properties of as-cast heavy sectioned, over 250mm thickness, ferritic ductile cast iron. Exothermic and thermal insulation material were equipped on the wall of sand cast mold having the dimensions of $250{\times}250{\times}250$ mm. The nominal composition of the molten metal was controlled to be on the eutectic composition and Sb was added about 0, 0.005 and 0.02% respectively. In the center of as-cast ingot without Sb addition, the solidification of chunky graphite was induced by the eutectic reaction that took long time, which caused the decrease of elongation and impact energy. In case that the value of Sb/RE is 0.8, the solidification of chunky graphite could be suppressed and the improvement of nodularity was observed. On the other hand, the excessive addition of Sb suppressed the solidification of chunky graphite but gave rise to the solidification of flake graphite and the increase of pearlite contents. This results in poor elongation and impact energy which is lower than those in the case of no Sb addition.

Improving Policies and Regulations for Environmental-friendly Ocean Renewable Energy Development in Korea (해양에너지 개발사업의 친환경적 개발을 위한 정책 및 제도개선 방안)

  • Park, Jeong-Il;Kim, Taeyun
    • Journal of Environmental Impact Assessment
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    • v.23 no.4
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    • pp.237-250
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    • 2014
  • A wide range of projects for ocean renewable energy are currently in development around the world and ocean energy industries continue to receive significant support from their governments. Surrounded by sea on three sides, Korea has potentially abundant renewable ocean energy resources, which include tidal current, tidal range, offshore wind power, osmotic pressure and ocean thermal energy. Numerous ocean renewable energy projects has been developed in Korea. Nevertheless, there are some concerns that those developments often select an environmentally unsuitable location and/or there are very few existing information on those environmental effects. The purpose of this study is to improve supporting policies and regulation systems of ocean renewable energy development in Korea by reviewing and compiling government policies and environmental assessment systems related to ocean renewable energy development around the world. The study suggests several policy implications for its environmental-friendly development in Korea, including requirements of strategic environmental assessment for proactive and environmentally suitable site selection of ocean renewable energy development and continuous post-development environmental monitoring, and so on.

Semiconductor CdTe-Doped CdO Thin Films: Impact of Hydrogenation on the Optoelectronic Properties

  • Dakhel, Aqeel Aziz;Jaafar, Adnan
    • Korean Journal of Materials Research
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    • v.30 no.1
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    • pp.1-7
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    • 2020
  • Doping or incorporation with exotic elements are two manners to regulate the optoelectronic properties of transparent conducting (TCO) cadmium oxide (CdO). Nevertheless, the method of doping host CdO by CdTe semiconductor is of high importance. The structural, optical, and electrical properties of CdTe-doped CdO films are studied for the sake of promoting their conducting parameters (CPs), including their conductivity, carrier concentration, and carrier mobility, along with transparency in the NIR spectral region; these are then compared with the influence of doping the host CdO by pure Te ions. X-ray fluorescence (XRF), X-ray diffraction (XRD), optical absorption spectroscopy, and electrical measurements are used to characterise the deposited films prepared by thermal evaporation. Numerous results are presented and discussed in this work; among these results, the optical properties are studied through a merging of concurrent BGN (redshift) and BGW (blue shift) effects as a consequence of doping processes. The impact of hydrogenation on the characterisations of the prepared films is investigated; it has no qualitative effect on the crystalline structure. However, it is found that TCO-CPs are improved by the process of CdTe doping followed by hydrogenation. The utmost TCO-CP improvements are found with host CdO film including ~ 1 %Te, in which the resistivity decreases by ~ 750 %, carrier concentration increases by 355 %, and mobility increases by ~ 90 % due to the increase of Ncarr. The improvement of TCO-CPs by hydrogenation is attributed to the creation of O-vacancies because of H2 molecule dissociation in the presence of Te ions. These results reflect the potential of using semiconductor CdTe -doped CdO thin films in TCO applications. Nevertheless, improvements of the host CdO CPs with CdTe dopant are of a lesser degree compared with the case of doping the host CdO with pure Te ions.

Preparation of the Conducting Polyaniline-HIPS Blends for Injection Molding by Toluene Solution Casting (Toluene 용액 캐스팅에 의한 차출용 전도성 Polyaniline-HIPS 블렌드 제조)

  • Lee, Jong-Hyeok;Kim, Eun-Ok
    • Polymer(Korea)
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    • v.33 no.3
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    • pp.203-206
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    • 2009
  • Polyaniline Emeraldine salt (PANI-salt) prepared by the common chemical oxidative polymerization caused the corrosion of the metallic injection mold by protonic acid such as HCl which used as a dopant. PANI-salt, polyaniline doped with dodecylbenzenesulfonic acid (DBSA), was obtained by the emulsion polymerization in nonpolar organic solvent, toluene. In this study DBSA was used as a dopant along with a surfactant. PANI-salt and high impact polystyrene (HIPS) have a good solubility in toluene. Blends with different ratio of PANI and HIPS were prepared through a solution-cast blending. The structure of PANI-salt was characterized by FT-IR and UV-Vis. The morphology, thermal, and electrical properties for PANI-HIPS blends were investigated. Injection molded under $103^{\circ}C$, 120 psi, PANI-HIPS showed the highest electrical conductivity ($6.02{\times}10^{-5}\;S/cm$) after blending PANI (50 mL) and HIPS (1 g).

The use of HRSEM to characterize new and aged membranes in drinking water production

  • Wyart, Y.;Nitsche, S.;Chaudanson, D.;Glucina, K.;Moulin, P.
    • Membrane and Water Treatment
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    • v.2 no.4
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    • pp.251-266
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    • 2011
  • This work deals with the use of High Resolution Scanning Electron Microscopy (HRSEM) to verify ultrafiltration membrane selectivity at the end of the production line as well as membrane ageing. The first part of this work is focused on new membranes. It is shown that it is better to use sputtering metallization than vacuum deposition, as this latter technique entails thermal damage to the skin layer. Moreover, the impact of the metallization layer on the determination of the membrane pore size is studied and it is observed that no impact of the metallization step can be clearly defined for a metallization layer ranging from 3 to 12 nm. For example, an average pore size of 16.9 nm and a recovery rate of 6.5 % are observed for a 150 kDa cellulose acetate membrane. These results are in agreement with those given by the manufacturer: pore size ranging from 10 to 15 nm and recovery rate ranging from 5 to 10 %. The second part of this work focuses on the study of membrane ageing. A PVDF hollow fibre membrane is studied. It is shown that a 65 % decrease in the permeate flux can be linked to a decrease in the number of pores at the surface of the membrane and a decrease in the recovery rate. In conclusion, a mapping of the pores is performed for several new hollow fibre membranes used to produce drinking water, made of different materials, with different geometries and molecular weight cut-off. These results provide reference data that will help better understand the phenomena of membrane fouling and membrane ageing.

Comparison of the Impact of an Optimized Ice Cooling Vest and a Paraffin Cooling Vest on Physiological and Perceptual Strain

  • zare, Mansoor;dehghan, Habibollah;yazdanirad, Saeid;khoshakhlagh, Amir hossein
    • Safety and Health at Work
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    • v.10 no.2
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    • pp.219-223
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    • 2019
  • Background: Ice cooling vests can cause tissue damage and have no flexibility. Therefore, these two undesirable properties of ice cooling vest were optimized, and the present study was aimed to compare the impact of the optimized ice cooling vest and a commercial paraffin cooling vest on physiological and perceptual strain under controlled conditions. Methods: For optimizing, hydrogel was used to increase the flexibility and a layer of the ethylene vinyl acetate foam was placed into the inside layer of packs to prevent tissue damage. Then, 15 men with an optimized ice cooling vest, with a commercial paraffin cooling vest, and without a cooling vest performed tests including exercise on a treadmill (speed of 2.8 km/hr and slope of %0) under hot ($40^{\circ}C$) and dry (40 %) condition for 60 min. The physiological strain index and skin temperature were measured every 5 and 15 minutes, respectively. The heat strain score index and perceptual strain index were also assessed every 15 minutes. Results: The mean values of the physiological and perceptual indices differed significantly between exercise with and without cooling vests (P < 0.05). However, the difference of the mean values of the indices except the value of the skin temperature during the exercises with the commercial paraffin cooling vest and the optimized ice cooling vest was not significant (P > 0.05). Conclusions: The optimized ice cooling vest was as effective as the commercial paraffin cooling vest to control the thermal strain. However, ice has a greater latent heat and less production cost.

Evaluation of Microstructure and Mechanical Properties on Post-Weld Heat Treatment in the Heat Affected Zone of SA508 Gr.4N Ni-Mo-Cr Low Alloy Steel for Reactor Pressure Vessel (원자로압력용기용 SA508 Gr.4N Ni-Mo-Cr계 저합금강 용접열영향부의 용접후열처리에 따른 미세조직과 기계적 특성 평가)

  • Lee, Yoon-Sun;Kim, Min-Chul;Lee, Bong-Sang;Lee, Chang-Hee
    • Korean Journal of Metals and Materials
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    • v.47 no.3
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    • pp.139-146
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    • 2009
  • The heat-affected zone (HAZ) of SA508 Gr.4N Ni-Mo-Cr low alloy steel, which has higher Ni and Cr contents than SA508 Gr.3 Mn-Mo-Ni low alloy steel, was investigated on the microstructure and mechanical properties. The HAZ was categorized into seven characteristic zones (CGCG, FGCG, ICCG, SCCG, FGFG, ICIC and SCSC-HAZ) according to the peak temperature from the thermal cycle experienced during multi-pass welding. Post Weld Heat Treatment (PWHT) was conducted in the temperature range of $550{\sim}610^{\circ}C$ for 30 hours to evaluate the effect of PWHT conditions on the microstructure and mechanical properties. Before PWHT, CGHAZ and FGFGHAZ showed high yield strength (YS) ranging from 1000 to 1250 MPa, while YS of SCSCHAZ decreased from 607 MPa (observed for base metal) to 501 MPa. The Charpy impact energies of sub-HAZs fell below 100J at $-29^{\circ}C$, except in the SCSCHAZ. By applying PWHT to sub-HAZ specimens, YS decreased as the PWHT temperature increased. In the case of CGHAZs and FGFGHAZ heat-treated at $610^{\circ}C$, YS dropped drastically to the range of 654~686 MPa. From the Charpy impact test, the upper-shelf energy (USE) increased to approximately 250J and Index temperature ($T_{68J}$) decreased below $-50^{\circ}C$. Specifically, in FGFG, ICIC and SCSC-HAZ, $T_{68J}$ was below -110, which was lower than the case of base metal.

Urban Heat Mitigation Effect Analysis based on the Land Use Location Distribution by Using an Ecosystem Service Valuation Model (생태계 서비스 가치평가 모형을 이용한 토지이용 위치분배에 따른 도시 열저감 효과분석)

  • Sangjun, Kang
    • Journal of Environmental Impact Assessment
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    • v.31 no.6
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    • pp.369-377
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    • 2022
  • The purpose of this study is to explore whether open spaces with land use characteristics of forest green areas can have different influence on the urban heat reduction depending on the location distribution, through the case of Gangneung-si downtown area. As a research method, the InVest Urban Cooling Model, which is a thermal phenomenon analysis model, is employed based on the most recent data available in 2018. In order to focus on the effect of location distribution of open space in the city, the downtown area is set as the observation area, not the entire city. The analysis of the land use location distribution scenarios shows that large-scale forests or clustered forests are more effective in reducing atmospheric heat in the region than several small-scale forests.

Advantages and disadvantages of renewable energy-oil-environmental pollution-from the point of view of nanoscience

  • Shunzheng Jia;Xiuhong Niu;Fangting Jia;Tayebeh Mahmoudi
    • Advances in concrete construction
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    • v.16 no.1
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    • pp.69-78
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    • 2023
  • This investigation delves into the adverse repercussions stemming from the impact of arsenic on steel pipes concealed within soil designated for rice cultivation. Simultaneously, the study aims to ascertain effective techniques for detecting arsenic in the soil and to provide strategies for mitigating the corrosion of steel pipes. The realm of nanotechnology presents promising avenues for addressing the intricate intersection of renewable energy, oil, and environmental pollution from a novel perspective. Nanostructured materials, characterized by distinct chemical and physical attributes, unveil novel pathways for pioneering materials that exert a substantial impact across diverse realms of food production, storage, packaging, and quality control. Within the scope of the food industry, the scope of nanotechnology encompasses processes, storage methodologies, packaging paradigms, and safeguards to ensure the safety of consumables. Of particular note, silver nanoparticles, in addition to their commendable antibacterial efficacy, boast anti-fungal and anti-inflammatory prowess, environmental compatibility, minimal irritability and allergenicity, resilience to microbial antagonism, thermal stability, and robustness. Confronting the pressing issue of arsenic contamination within both environmental settings and the food supply is of paramount importance to preserve public health and ecological equilibrium. In response, this study introduces detection kits predicated upon silver nanoparticles, providing an expeditious and economically feasible avenue for identifying arsenic concentrations ranging from 0.5 to 3 ppm within rice. Subsequent quantification employs Hydride Atomic Absorption Spectroscopy (HG-AAS), which features a detection threshold of 0.05 ㎍/l. A salient advantage inherent in the HG-AAS methodology lies in its capacity to segregate analytes from the sample matrix, thereby significantly reducing instances of spectral interference. Importantly, the presence of arsenic in the soil beneath rice cultivation establishes a causative link to steel pipe corrosion, with potential consequences extending to food contamination-an intricate facet embedded within the broader tapestry of renewable energy, oil, and environmental pollution.