• 제목/요약/키워드: thermal degradation temperature

검색결과 578건 처리시간 0.027초

리튬이온 배터리 방전 시 발열 특성 및 냉각 실험과 유한요소 해석 (Thermal Characteristics and Cooling Experiments and Analysis of Finite Elements in the Discharge of Lithium-Ion Batteries)

  • 김석일;강신유
    • 산업기술연구
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    • 제43권1호
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    • pp.15-23
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    • 2023
  • Lithium-ion batteries are predominantly employed in electric vehicles and energy storage devices, offering the advantage of high energy density. However, they are susceptible to efficiency degradation when operated at high temperatures due to their sensitivity to the external environment. In this study, we conducted experiments using an indirect cooling method to prevent thermal runaway and explosions in lithium-ion batteries. The results were validated by comparing them with heat transfer simulations conducted through a commercial finite element analysis program. The experiments included single-cell exothermic tests and cooling experiments on a battery pack with 10 cells connected in series, utilizing 21700 lithium-ion batteries. To block external temperature influences, the experimental environment featured an extrusion method insulation in the environmental chamber. The cooling system, suitable for indirect cooling, was constructed with copper tubes and pins. The heat transfer analysis began by presenting a single-cell heating model using commercial software, which was then employed to analyze the heating and cooling of the battery pack.

Development of Micro Tensile Test of CVD-SiC coating Layer for TRISO Nuclear Fuel Particles at elevated temperature

  • Lee, Hyun-Min;Park, Kwi-Il;Kim, Do-Kyung
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2012년도 춘계학술발표대회
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    • pp.95.1-95.1
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    • 2012
  • Very High Temperature gas cooler Reactor (VHTR) has been considered as one of the most promising nuclear reactor because of many advantages including high inherent safety to avoid environmental pollution, high thermal efficiency and the role of secondary energy source. The TRISO coated fuel particles used in VHTR are composed of 4 layers as OPyC, SiC, IPyC and buffer PyC. The significance of CVD-SiC coatings used in tri-isotropic(TRISO) nuclear coated fuel particles is to maintain the strength of the whole particle. Various methods have been proposed to evaluate the mechanical properties of CVD-SiC film at room temperature. However, few works have been attempted to characterize properties of CVD-SiC film at high temperature. In this study, micro tensile system was newly developed for mechanical characterization of SiC thin film at elevated temperature. Two kinds of CVD-SiC films were prepared for micro tensile test. SiC-A had [111]-preferred orientation, while SiC-B had [220]-preferred orientation. The free silicon was co-deposited in SiC-B coating layer. The fracture strength of two different CVD-SiC films was characterized up to $1000^{\circ}C$.The strength of SiC-B film decreased with temperature. This result can be explained by free silicon, observed in SiC-B along the columnar boundaries by TEM. The presence of free silicon causes strength degradation. Also, larger Weibull-modulus was measured. The new method can be used for thin film material at high temperature.

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Ge mole fraction에 따른 SGOI MOSFET의 아날로그 특성 (Analog performances of SGOI MOSFET with Ge mole fraction)

  • 이재기;김진영;조원주;박종태
    • 대한전자공학회논문지SD
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    • 제48권5호
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    • pp.12-17
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    • 2011
  • 본 연구에서는 $Si_xGe_{1-x}$ 버퍼층 위에 성장된 strained-Si에 Ge 농도에 따라 n-MOSFET를 제작하고 소자 제작 후의 열처리 온도에 따른 소자의 아날로그 성능을 측정 분석하였다. 전자의 유효 이동도는 Ge 농도가 증가함에 따라 증가하였으나 32%로 높을 때에는 열처리 온도에 상관없이 오히려 감소하는 것으로 측정되었다. 상온에서 Ge 농도가 증가함에 따라 증가 소자의 아날로그 성능 지수가 우수하였으나 32% 농도에서는 오히려 좋지 않았다. 고온에서 strained-Si의 전자 유효이동도 저하가 Si보다 심하기 때문 SGOI 소자의 아날로그 성능 저하가 SOI 소자보다 심한 것을 알 수 있었다.

Performance-based structural fire design of steel frames using conventional computer software

  • Chan, Y.K.;Iu, C.K.;Chan, S.L.;Albermani, F.G.
    • Steel and Composite Structures
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    • 제10권3호
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    • pp.207-222
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    • 2010
  • Fire incident in buildings is common, so the fire safety design of the framed structure is imperative, especially for the unprotected or partly protected bare steel frames. However, software for structural fire analysis is not widely available. As a result, the performance-based structural fire design is urged on the basis of using user-friendly and conventional nonlinear computer analysis programs so that engineers do not need to acquire new structural analysis software for structural fire analysis and design. The tool is desired to have the capacity of simulating the different fire scenarios and associated detrimental effects efficiently, which includes second-order P-D and P-d effects and material yielding. Also the nonlinear behaviour of large-scale structure becomes complicated when under fire, and thus its simulation relies on an efficient and effective numerical analysis to cope with intricate nonlinear effects due to fire. To this end, the present fire study utilizes a second-order elastic/plastic analysis software NIDA to predict structural behaviour of bare steel framed structures at elevated temperatures. This fire study considers thermal expansion and material degradation due to heating. Degradation of material strength with increasing temperature is included by a set of temperature-stress-strain curves according to BS5950 Part 8 mainly, which implicitly allows for creep deformation. This finite element stiffness formulation of beam-column elements is derived from the fifth-order PEP element which facilitates the computer modeling by one member per element. The Newton-Raphson method is used in the nonlinear solution procedure in order to trace the nonlinear equilibrium path at specified elevated temperatures. Several numerical and experimental verifications of framed structures are presented and compared against solutions in literature. The proposed method permits engineers to adopt the performance-based structural fire analysis and design using typical second-order nonlinear structural analysis software.

Alumimium Titanate-Mullite 복합체: Part1, 열적 내구성 (Alumimium Titanate-Mullite Composites : Part1,Thermal Durability)

  • 김익진;강원호;고영신
    • 한국재료학회지
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    • 제3권6호
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    • pp.624-631
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    • 1993
  • Alumimium Titanate-Mullite 복합체는 $Al_{2}O_{3}$분말 알콜용액에서 $Si(OC_{2}H_{5})_{4}$$Ti(OC_{2}H_{5})_4$ 의 단계적인 가수분해로 합성하였다. Sol-Gel 방법으로 합성된 모든 분말은 비정질과 단분산이고 좁은 분말크기의 분포를 보였다. 소결체($1600 ^{\circ}C$/2h)는 임계분해온도인 $1100^{\circ}C$에서 100시간 동안과 750와 $1400^{\circ}C$ 100시간동안 반복적인 열적 내구성 및 열충격 시험을 수행하였다. 가장 좋은 열적 내구성은 aluminium titanate함유량이 70rhk 80vol%일때 얻어졌으며, 이들은 위 실험을 한후 아주 적은 미세구조와 열팽창 곡선의 변화를 나타내었다. 소결체 미세구조의 붕괴는 주사현미경, X-선회절분석과 Dil-atometer로 연구하였다. 위 연구는 이와같은 과정에 의하여 합성된 aluminium titanate-mullite복합체의 서비스 수명을 예상하기 위하여 시도되었다.

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NiPt/Co/TiN을 이용한 Ni Germanosilicide 의 열안정성 향상 및 Ge 비율 (x) 에 따른 특성 분석 (Thermal Stability Improvement or Ni Germanosilicide Using NiPt/Co/TiN and the Effect of Ge Fraction (x) in $Si_{l-x}Ge_x$)

  • 윤장근;오순영;황빈봉;김용진;지희환;김용구;차한섭;허상범;이종근;왕진석;이희덕
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2004년도 하계종합학술대회 논문집(2)
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    • pp.391-394
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    • 2004
  • In this study, highly thermal stable Ni Germanosilicide has been utilized using NiPt alloy and novel NiPt/Co/TiN tri-layer. And, the Ni Germanosilicide Properties were characterized according to different Ge ratio (x) in $Si_{l-x}Ge_x$ for the next generation CMOS application. The sheet resistance of Ni Germanosilicide utilizing pure-Ni increased dramatically after the post-silicidation annealing at $600^{\circ}C$ for 30 min. Moreover, more degradation was found as the Ge fraction increases. However, using the proposed NiPt/Co/TiN tri-layer, low temperature silicidation and wide range of RTP process window were achieved as well as the improvement of the thermal stability according to different Ge fractions by the subsequent Co and TiN capping layer above NiPt on the $Si_{l-x}Ge_x$. Therefore, highly thermal immune Ni Germanosilicide up to $600^{\circ}C$ for 30 min is utilized using the NiPt/Co/TiN tri-layer promising for future SiGe based ULSI technology.

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The Effect of Nitrogen Plasma Treatment on Tribological Behaviors of Plasma-sprayed Zirconia Coatings

  • Lim, Dae-Soon;Shin, Jong-Han;Lee, Jung-Yeob;Cho, Chang-Hee
    • 한국세라믹학회지
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    • 제38권7호
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    • pp.602-607
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    • 2001
  • Zirconia powder containing 3 mol% yttria (3Y-PSZ) was casted on the cast iron substrate by plasma spraying method. Coated specimens were then heat treated at 500$\^{C}$ in nitrogen plasma. Wear tests were performed on nitrogen heat treated and non heat treated samples at temperatures from 25$\^{C}$ to 600$\^{C}$. Wear results showed that the friction coefficient and the wear loss of both the treated and the non-treated samples showed maximum value at 400$\^{C}$. These results were explained by low temperature thermal degradation due to the monoclinic transformation. Nitrogen plasma treatment significantly improved the tribological performance. The effect of nitrogen heat treatment on tribological behavior was explained by the increased micro-hardness and decreased monoclinic faction.

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열분석시험을 통한 항공기 복합재료 부품의 수리 시 반복경화에 따른 물성변화 측정에 관한 연구 (A Study on the Evaluation of the properties change of Aircraft Composites Parts During Repair by Thermal Analysis Test)

  • 엄수현;이상언;한중원;김국진;김영식;김윤해
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2002년도 추계학술발표대회 논문집
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    • pp.33-37
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    • 2002
  • Recently, composites have been widely applied in the sporting goods, automobile, aerospace industry. As the use of advanced composites increase, specific techniques have been developed to repair damaged composite structures. In order to repair the damaged part, it is required that the material in the damaged area be removed first by utilizing the proper method, and prepreg be laid up in the area and cured under vacuum using the vacuum bagging materials. In curing process, either in an oven or autoclave is to be delamination can be occurred in the sound areas during and/or after the exposure to the elevated curing temperature in case that the repair process is repeated. Therefore, this study was conducted to evaluate the degree of degradation of properties of the cured parts and how it affects to the delamination phenomenon between laminated skin and honeycomb core.

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동시경화 강철-복합재료 원형 단일 겹치기 조인트의 최적설계 (Optimum Design of Co-cured Steel-Composite Tubular Single Lap Joints)

  • 조덕현;이대길
    • 대한기계학회논문집A
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    • 제24권5호
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    • pp.1203-1214
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    • 2000
  • In this paper, a failure model for co-cured steel-composite tubular single lap joints has been proposed incorporating the nonlinear mechanical behavior of steel adherends and different failure mode s such as steel adherend failure and composite adherend failure. The characteristics of the co-cured steel-composite tubular single lap joint were investigated with respect to the test temperature, the stacking sequence of composite adherend, the thickness ratio of steel adherend to composite adherend, and the scarf ratio of steel adherend. Thus, the optimum design method for the co-cured steel-composite tubular single lap joint was suggested.

유지식품의 조리 중 기능성분의 변화 (Changes of Functional Components Present in Lipid Foods during Cooking)

  • 최은옥
    • 한국식품조리과학회지
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    • 제21권5호
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    • pp.742-758
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    • 2005
  • Lipid-based functional components present in foods undergo chemical changes during cooking. Useful n-3 and n-6 fatty acids, phytosterols, tocopherols, and carotenoids are degraded by thermal cooking such as frying, resulting in loss of their physiological functions. However, conjugated linoleic acid and diacylglycerols can be formed during heating, which would be beneficial to the health. Degree of degradation and formation of the functional components depends on the cooking method, cooking temperature and time, lipid matrix containing the components, and the presence of other materials. Although it is clear that the content of each functional component varies during long-heating in a model system consisting of small numbers of components, the real foods cooked in a small scale for a limited cooking time do not show highly significant differences in the functional components contents from raw food materials.