• Macromolecular Research
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• 제11권5호
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• pp.303-310
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• 2003

The phase behavior of binary blends of dimethylpolycarbonate-tetramethyl polycarbonate (DMPCTMPC) copolycarbonates and styrene-acrylonitrile (SAN) copolymers has been examined and then compared with that of DMPC/TMPC/SAN ternary blends having the same chemical components and compositions except that the DMPC and TMPC were present in the form of homopolymers. Both binary and ternary blends were miscible at certain blends compositions, and the miscible blends showed the LCST-type phase behavior or did not phase separated until thermal degradation temperature. The miscible region of binary blends is wider than that of the corresponding ternary blends. Furthermore, the phase-separation temperatures of miscible binary blends are higher than those of miscible ternary blends at the same chemical compositions. To explain the destabilization of polymer mixture with the increase of the number of component, interaction energies of binary pairs involved in these blends were calculated from the phase separation temperatures using lattice-fluid theory and then the phase stability conditions for the polymer mixture was analyzed with volume fluctuation thermodynamics.

• 한국가스학회지
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• 제17권1호
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• pp.35-41
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• 2013

본 연구에서는 페놀 폼의 난연성을 증가시키기 위하여 널리 사용되고 있는 인계 난연제의 첨가에 따른 페놀 폼과 폴리우레탄 폼의 난연 성능을 비교 평가하였다. 난연제가 첨가된 페놀 폼과 폴리우레탄 폼을 각각 열분석(TGA)을 통하여 열분해 거동을 알아보았고 Cone calorimeter를 이용하여 열방출량(HRR), 연기발생량(TSR) 및 CO 및 $CO_2$ 발생량과 산소한계지수(Limited oxygen index, LOI)를 통하여 난연성능을 평가하였다. 실험 결과 페놀폼이 폴리우레탄 폼에 비해 초기 분해는 빠르지만 $800^{\circ}C$에서 잔존량이 월등히 많았으며 낮은 열방출속도 값을 나타내었다. 또한 질량 감소율, 연기발생량도 폴리우레탄 폼보다 낮아 우수한 난연성능을 가지는 것을 알 수 있다.

• Corrosion Science and Technology
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• 제11권6호
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• pp.218-224
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• 2012

Liquid droplet impingement erosion (LDIE) known to be generated in aircraft and turbine blades is recently appeared in nuclear piping. UT thickness measurements with both A-scan and B-scan UT inspection equipments were performed for a component estimated as susceptible to LDIE in feedwater heater vent system. The thickness data measured with B-Scan equipment were compared with those of A-Scan. Thermal hydraulic analysis based on ANSYS FLUENT code was performed to analyze the behavior of liquid droplets inside piping. The wall thinning rate and residual lifetime based on both existing Sanchez-Caldera equation and measuring data were also calculated to identify the applicability of the existing equation to the LDIE management of nuclear piping. Because Sanchez-Caldera equation do not consider the feature of magnetite formed inside piping, droplet size, colliding frequency, the development of new evaluation method urgently needs to manage the pipe wall thinning caused by LDIE.

• Journal of Electrical Engineering and Technology
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• 제13권6호
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• pp.2412-2420
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• 2018

The thermal degradation of low density polyethylene (LDPE) will accelerate the production of carbonyl groups (C=O), which can act as the induced dipoles under high voltage. In this paper, we researched the dielectric properties and space charge behavior of LDPE after thermal aging, which can help us to understand the correlation between carbonyl groups (C=O) and electrical properties of LDPE. The spectra results show that LDPE exhibit obvious thermooxidative reactions when the aging time is 35 days and the productions mainly contain carboxylic acid, carboxylic eater and carboxylic anhydride, whose amount increase with the increasing of aging time. The dielectric properties show that the real permittivity of LDPE is inversely proportional to temperature before aging and subsequently become proportional to temperature after thermal aging. Furthermore, both the real and imaginary permittivity increase sharply with the increasing of aging time. The fitting results of imaginary permittivity show that DC conductivity become more sensitive about temperature after thermal aging. On this basis, the active energies of materials calculated from DC conductivity increase first and then decrease with the increasing of aging time. In addition, the space charge results show that the heterocharges accumulated near electrodes in LDPE change to the homocharges after thermal aging and the mean volume charge density increase with the increasing of aging time. It is considered that the overlaps caused by electrical potential area is the main reason for the increase of DC conductivity.

• 설비공학논문집
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• 제10권6호
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• pp.649-657
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• 1998

In this study, the effects of the various conditions of frosting and defrosting on the behavior of defrosting in a fin-tube heat exchanger have been examined experimentally. The electric heater is used for defrosting in a fin-tube heat exchanger It is shown that there are several local maxima in the water draining rate. The amount of residual water on the heat exchanger after the completion of defrosting is kept constant due to surface tension on the heat exchanger. Without considering the degradation of the thermal performance due to the frosting, the defrosting efficiency is improved with increasing amount of the frost irrespective of the frosting condition. The defrosting behavior is affected by the frosting density as well as the frost accumulation, which vary with the experimental operating conditions during the frosting period. The heat loss to the surrounding air decreases, and the melting and defrosting efficiencies show high values with decreasing heat input.

• Tribology and Lubricants
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• 제9권1호
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• pp.62-69
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• 1993

Friction and wear behavior of a carbon/carbon composite material for aircraft brake material was experimentally investigated. Friction and wear test setup was designed and built for the experiment. Friction and wear tests were conducted under various sliding conditions. Friction coefficients were measured and processed by a data acquisition system and amount of wear measured by a balance. Stainless steel disk was used as the counterface material. Temperature was also measured by inserting thermocouple 2.5 mm beneath the sliding surface of the carbon/carbon composite specimen. Wear surfaces were observed by SEM, and analyzed by EDAX. The experimental results showed that sliding speed and normal force did not have significant effects on friction coefficient and wear factor of the composite. Temperature increase just below the surface was not large enough to cause any thermal degradation or oxidation which occurred at higher temperature when tested by TGA. Wear film was generated both on the specimen and on the counterface at relatively low sliding speed but cracks, grooves, and wear debris were observed at high sliding speed. Friction coefficient remained almost constant when the sliding speed or normal load was varied. It is believed that the adhesive and abrasive components contributed mainly to the friction coefficient. Wear behavior at low sliding speed was governed by wear film formation and adhesive wear mechanism. At high speed, fiber orientation, ploughing by counterface asperities, and fiber breakage dominated wear of the carbon/carbon composite.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1996년도 춘계학술발표회논문집(2)
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• pp.637-642
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• 1996

This paper presents the analysis results for the core degradation processes and the fission product release of the PHEBUS FPT0 experiment using MELCOR1.8.3. The objective of this study is to assess models associated with the core damage and fission product behavior in MELCOR. The calculation results were much improved through sensitivity studies. Thermal/hydraulic behavior in the core and the circuit was well predicted under the intact core geometry. In non-eutectic model case. the UO$_2$ dissolution model in the MELCOR always showed such a tendency that the resulting dissolved UO$_2$ mass was small at the highly oxidized condition due to the model logic. Total H$_2$ generation mass was underpredicted because the stiffner was not modeled and the liner in the shroud was not allowed to be oxidized in MELCOR. Some difficulties were found in modeling the activation product were solved by manipulating the RN input associated with the initial fission product inventory. These problem were occurred because there are no control rod model in MELCOR. Generally the fission product release ratio showed a similar trend compared with the measured data except the activation product. which have no model to simulate in MELCOR.

• Computers and Concrete
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• 제20권5호
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• pp.529-537
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• 2017

Excessively elevated temperature can lead to cracks in prestressed concrete (PC) continuous bridge with box girder on the pier top at cement hydration age. This paper presents a case study for evaluating the behavior of PC box girder during the early hydration age using a two-stage computational model, in the form of computer program ANSYS, namely, 3-D temperature evaluation and determination of mechanical response in PC box girders. A numerical model considering time-dependent wind speed and ambient temperature in ANSYS for tracing the thermal and mechanical response of box girder is developed. The predicted results were compared to show good agreement with the measured data from the PC box girder of the Zhaoshi Bridge in China. Then, based on the validated numerical model three parameters were incorporated to analyze the evolution of the temperature and stress within box girder caused by cement hydration heat. The results of case study indicate that the wind speed can change the degradation history of temperature and stress and reduce peak value of them. The initial casting temperature of concrete is the most significant parameter which controls cracking of PC box girder on pier top at cement hydration age. Increasing the curing temperature is detrimental to prevent cracking.

• 폴리머
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• 제33권3호
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• pp.198-202
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• 2009

Poly(ethylene terephthalate)(PET)의 올리고머인 oligo(ethylene terephthalate)(OET), oligo(ethylene succinate-co-terephthalate)(OEST) 및 oligo(butylene succinate-co-terephthalate)(OBST)를 각각 합성한 후, Pseudomonas cepacia 유래의 lipase PS를 사용하여, 올리고머의 분해실험을 실시, 분해시간에 의한 잔존중량 및 분해생성물의 분석에 의한 생분해기구를 해명함을 목적으로 하였다. OEST와 OBST의 합성에서는 배합 몰비에 대한 조성비의 조절이 가능한 올리고머를 얻을 수 있었으며, 조성비의 상이함에 의해 열적 성질이 현저한 차이가 있음을 확인하였다. 분해실험에서는 OEST, OBST 모두 lipase PS에 의해 분해가 발생되나, terephthalic acid의 조성이 높아질수록 분해능력이 저하됨을 확인하였고, lipase PS는 지방족에 가까운 조성을 가진 polyester를 쉽게 분해시킴을 확인하였다.

• 설비공학논문집
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• 제2권1호
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• pp.37-48
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• 1990

The drag and heat transfer reduction phenomena and degradation effects of drag reducing polymer solutions which are known as the viscoelastic fluids are investigated experimentally for the turbulent circular tube flows. Two stainless steel tubes are used for the experimental flow loops. Aqueous solutions of Polyacrylamide Separan AP-273 with concentrations from 300 to 1000 wppm are used as working fluids. Flow loops are set up to measure the friction factors and heat transfer coefficients of test tubes in the once-through system and the recirculating flow system. Test tubes are heated by power supply directly to apply constant heat flux boundary conditions on the wall. Capillary tube viscometer and falling ball viscometer are used to measure the viscous characteristics of fluids and the characteristic relaxation time of a fluid is determined by the Powell-Eyring model. The order of magnidude of the thermal entrance length of a drag reducing polymer solution is close to the order of magnitude of the laminar entrance length of Newtonian fluids. Dimensionless heat transfer coefficients of the viscoelastic non-Newtonian fluids may be represented as a function of flow behavior index n and newly defined viscoelastic Graetz number. As degradation continues viscosity and the characteristic relaxation time of the testing fluids decrease and heat transfer coefficients increase. The characteristic relaxation time is used to define the Weissenberg number and variations of friction factors and heat transfer coefficients due to degradation are presented in terms of the Weissenberg number.