• Title/Summary/Keyword: thermal cycles

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High Temperature Gas Leak Behavior of Glass-Ceramic Fiber Composite Seals for SOFC Applications (SOFC용 유리-세라믹섬유 복합기밀재의 고온 기체누설 거동)

  • Lee, Jae-Chun;Kwon, Hyuk-Chon;Kwon, Young-Pil;Park, Sung;Jang, Jin-Sik;Lee, Jongho;Kim, Joosun;Lee, Hae-Won
    • Journal of the Korean Ceramic Society
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    • v.42 no.12 s.283
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    • pp.842-845
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    • 2005
  • Glass composites containing ceramic fiber have been developed for Solid Oxide Fuel Cell (SOFC) seals. Effect of glass type, loading pressure and thermal cycle the leak rates of composite seals was investigated. Seal performance of two commercial glasses was compared with that of $SiO_2BaO-B_2O_3$ glass synthesized in this work. The leak rate for seals made of pyrex(R) increases from $\~0.0005\;to\;\~0.004sccm/cm$ as the gas pressure increases from 10 to 50 kPa. The soda lime silicate glass seal shows the leak rate two times higher than the one made of pyrex(R) or $SiO_2BaO-B_2O_3$ glass. The viscosity of glass at the seal test temperature is presumed to affect the leak rate of the glass seal. As the applied loading pressure increases from 0.4 to 0.8 MPa at $750^{\circ}C$, the leak rate decreases from 0.038 to 0.024 sccm/cm for composite seals. It has been found that during 50 thermal cycles between $450^{\circ}C\;to\;700^{\circ}C$ leak rates remained almost constant, ranging from 0.025 to 0.03sccm/cm. The results showed an excellent thermal cycle stability as well as sealability of the glass matrix ceramic fiber composite seals.

Evaluation of Composite Laminates for Aircraft Primary-Structure Applications Using Non-Linear Parameter of Ultrasonic Guided Wave (유도초음파의 비선형 파라미터를 이용한 항공기 구조체의 복합재료 적층판 열화 평가)

  • Cho, Youn-Ho;Kim, Do-Youn;Choi, Heung-Soap;Lee, Joon-Hyun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.2
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    • pp.126-131
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    • 2010
  • The purpose of this study is to assess the condition of composites used in aircraft under varying temperature environment with ultrasound guided wave technique. Investigation of crucial influential factor on the composite health monitoring related to aircraft operational environments such as the number of thermal cycles and temperature deviation between ground level and flight altitude has been of a great concern for aircraft safety issue. In this study, ultrasonic guided wave health monitoring scheme is proposed to evaluate composite specimens damaged with the thermal fatigue simulating aircraft operational condition. Guided wave dispersion curves are used to select right modes which show a promising sensitivity to each different thermal fatigue damage level. The present approach can be also implemented as one of on-lines health monitoring tools for aircraft.

Activities and Outlook of IEA about Concentrated Solar Power (태양열 발전에 대한 IEA의 활동 및 전망)

  • Lee, Hyunjin;Kim, Jongkyu;Kang, YongHeack
    • Journal of Institute of Convergence Technology
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    • v.2 no.1
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    • pp.13-17
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    • 2012
  • Concentrated Solar Power (CSP) is a renewable energy to generate electricity by using solar thermal energy as a heat source to drive turbines or engines for thermodynamic cycles. This paper introduces ongoing projects in SolarPACES(Solar Power and Chemical Energy systems) under the REWP(Renewable Energy Working Party) in the IEA(International Energy Agency). Then, the current status of international CSP markets and domestic activities is summarized. Finally, the CSP outlook by IEA and the key technological challenges to be overcome for its realization are presented.

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Designing of a Novel Core-Shell-Structured Co-free Cathode Material with Enhanced Thermal and Structural Stability for Lithium Ion Batteries

  • Shin, Ji-Woong;Nam, Yun-Chae;Son, Jong-Tae
    • Journal of the Korean Electrochemical Society
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    • v.22 no.4
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    • pp.172-176
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    • 2019
  • The first commercialized cathode material, $LiCoO_2$, suffers from disadvantages such as high cost and toxicity and also possesses safety problems. The nickel-rich $LiNi_{0.9}Mn_{0.1}O_2$ cathode material, used as an alternative to $LiCoO_2$, has highly reversible capacity and high energy density. So, the nickel-rich $LiNi_{0.9}Mn_{0.1}O_2$ cathode material is widely used as an alternative to $LiCoO_2$ due to its highly reversible capacity and high energy density. However, $LiNi_{0.9}Mn_{0.1}O_2$ has several disadvantages as well, such as poor cycle performance and poor thermal instability. To address these problems, we synthesized a new material, $LiNi_{0.5}Mn_{0.5}O_2$, as a shell on the surface of a core to suppress the surface degradation. The new material showed high structural and thermal stabilities and could also maintain a high capacity. The capacity retention of the core-shell cathode (87.7%) was better than that of the core cathode (76.9%) after 50 cycles. Analysis using differential scanning calorimetry revealed that the heat generation in the core-shell cathode ($65.9Jg^{-1}$) was lower than that in the core cathode ($559.7Jg^{-1}$).

Thermal Stability and Lifetime Prediction of PAG and POE Oils for a Refrigeration System

  • Park, Keun-Seo;Kang, Byung-Ha;Park, Kyoung-Kuhn;Kim, Suk-Hyun
    • International Journal of Air-Conditioning and Refrigeration
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    • v.15 no.2
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    • pp.78-83
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    • 2007
  • An experimental study has been carried out to analyze the thermal stability and to estimate the lifetime of refrigerating lubricants. PAG and POE oil are considered as test oils in this study. The viscosity of PAG and POE oil was measured by the vibration type viscometer while temperature is varied periodically in the range of $0^{\circ}C{\sim}100^{\circ}C$. In order to estimate lifetime of PAG and POE oil with temperature, the viscosity was measured while the test temperature of oils was maintained continuously at $180,\;200\;and\;220^{\circ}C$. The lifetime of oils is estimated as the decrease in viscosity change by 15%. The results indicate that the reduction rates of viscosity of PAG and POE oil are less than 5% after 510 temperature variation cycles. However, when the oils are kept at high temperature, it is found that the lifetimes of PAG oil is seen to be 244, 177 and 89 hours at the test temperature of $180,\;200\;and\;220^{\circ}C$, respectively, where as the lifetimes of POE oil are estimated to be 1,744, 1,007 and 334 hours at the temperature of $180,\;200\;and\;220^{\circ}C$, respectively. Thus, the lifetime of POE oil is found to be much longer than that of PAG oil. The lifetime correlations of PAG and POE oil are also obtained by Arrhenius's equation method in this paper.

Evaluation on Thermal Shock Damage of Smart Composite using Nondestructive Technique (비파괴 기법을 이용한 스마트 복합재료의 열충격손상평가)

  • Lee, Jin-Kyung;Park, Young-Chul;Lee, Kyu-Chang;Lee, Joon-Hyun
    • Composites Research
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    • v.20 no.3
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    • pp.37-42
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    • 2007
  • Tensile residual stress is occurred by difference of coefficients of thermal expansion between fiber and matrix is one of the serious problems in metal matrix composite(MMC). TiNi alloy fiber was used to solve the problem of the tensile residual stress as the reinforced material. TiNi alloy fiber improves the tensile strength of composite with occurring of compressive residual stress in the matrix by its shape memory effect. A hot press method was used to create the optimal fabrication condition for a Shape Memory Alloy(SMA) composite. The bonding effect of the matrix and the reinforcement within the SMA composite by the hot press method was strengthened by cold rolling. In addition, acoustic emission technique was used to quantify the microscopic damage behavior of cold rolled TiNi/A16061 shape memory alloy composite at low temperature. The damage degree for the specimen that underwent thermal shock cycles was also discussed.

Analysis of DC insulation and properties of epoxy/ceramic composites with nanosized ZnO/TiO2 fillers

  • Kwon, Jung-Hun;Kim, Yu-Min;Kang, Seong-Hwa;Kim, Pyung-Jung;Jung, Jong-Hoon;Lim, Kee-Joe
    • Journal of Ceramic Processing Research
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    • v.13 no.spc2
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    • pp.332-335
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    • 2012
  • A molded transformer is maintenance-free, which makes it unnecessary to replace the insulating material, like in an oil-filled transformer, because the epoxy, which is a molded insulating resin, does not suffer variations in its insulating performance for heat cycles over a long time, as compared to insulating oil. In spite of these advantages, a molded transformer may still be accessed by the user, which is not good in regards to reliability or noise compared to the oil transformers. In particular, a distrust exists regarding reliability due to the long-term insulating performance. These properties have been studied in regards to the improvement of epoxy composites and molded transformer insulation. There have nevertheless been insufficient investigations into the insulation properties of epoxy composites. In this study, it is a researching of the epoxy for insulating material. In order to prepare the specimens, a main resin, a hardener, an accelerator, and a nano/micro filler were used. Varying amounts of TiO2 and ZnO nano fillers were added to the epoxy mixture along with a fixed amount of micro silica. This paper presents the DC insulation breakdown test, thermal expansion coefficient, and thermal conductivity results for the manufactured specimens. From these results, it has been found that the insulating performance of nano/micro epoxy composites is improved as compared to plain molded transformer insulation, and that nano/micro epoxy composites contribute to the reliability and compactness of molded transformers.

Variations in the Thermal Performance of R22 and R410A Refrigeration Systems Depending on Operation Conditions

  • Jeong, Ji-Hwan;Kweon, Young-Chel;Chang, Keun-Sun
    • International Journal of Air-Conditioning and Refrigeration
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    • v.12 no.1
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    • pp.10-20
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    • 2004
  • Experiments have been conducted in order to make comparisons of characteristics of a R410a cycle with a R22 cycle in terms of cooling capacity and coefficient of performance (COP). The parameters examined in the present work include air flow rate, indoor and outdoor air temperatures, and indoor relative humidity. These two refrigeration cycles constructed for this study share all components except compressor, accumulator, oil separator, and piping. The measurements were made using a psychrometric calorimeter. The experimental results show that the R410A cycle has several advantages for indoor units while the R22 cycle yields better performance for outdoor units.

A Study on the Electrical Characteristics by Accelerating Degradation for Traction Motor in Urban Transit EMU (전동차용 견인전동기의 가속열화에 의한 전기적 특성 연구)

  • Park, H.J.;Kim, G.D.;Jang, D.U.;Choi, J.S.;Kim, J.S.
    • Proceedings of the KIEE Conference
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    • 2002.07b
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    • pp.1235-1237
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    • 2002
  • Insulation system(200 class} for stator coil is designed for traction motor with VVVF inverter. Sample coils for stator of the traction motor were tested by accelerative thermal degradation which composed of heat, vibration, moisture, and overvoltage apply. Reliability and expected life were evaluated on the insulation system for 200 class traction motor. After aging of 10 cycles, tan ${\delta}$ increased with voltage. This result is due to increase of internal defects and change of insulation structure.

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Ferroelectric Properties of PZT thin Films by Rapid Thermal Annealing (RTA처리한 PZT 박막의 강유전 특성)

  • Jeong, Kyu-Won;Park, Young;Ju, Pil-Yeon;Cho, Ik-Hyun;Lim, Dong-Gun;Yi, Jun-Sin;Song, Joon-Tae
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.4
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    • pp.232-238
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    • 2000
  • PZT thin films(3500 ) have been prepared onto $Pt/Ti/SiO_2/Si$ substrates with a RF magnetron sputtering system using PB1.05(Zr0.52,Ti0.48)O3 ceramic target. We used two-step annealing techniques. As the RTA times and temperatures were increased, crystallization of PZT thin films were enhanced. The ferroelectric characteristics of PZT capacitors fabricated at $700^{\circ}C$ for 60 seconds were like these remanent polarization were $12.1 \muC/cm^2$, coercive field were 110 kV/cm, leakage current density were $4.1\times10-7 A/cm^2,\; \varepsilonr=442,$ and remanent polarization were decreased by 22% after 1010 cycles, respectively.

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