• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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• pp.81-82
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• 2006

The purposes of the present study are to produce a high thermal efficient of oil-based nanofluids which can be used as ultra-high voltage transformer oil, and to investigate their thermal and physical properties under static and dynamic conditions. Three kinds of nanofluids are prepared by dispersing $Al_2O_3$ or AlN nanoparticles in transformer oil. The thermal conductivities of the nanoparticles-oil mixtures increase with temperature, particle volume concentration and thermal conductivity of solid particle itself. It was quite important to eliminate $H_2O$ as byproducts of esterification and excess oleic acid which did not form stable chemical bonds with powder surface to get high dispersion stability.

• Journal of Advanced Marine Engineering and Technology
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• 제38권1호
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• pp.1-7
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• 2014

기본유체에 나노분말을 분산시킨 나노유체는 기본유체보다 높은 열전도도를 보인다. 이러한 특성으로 인해, 에너지 효율을 향상시키기 위한 대안으로서 나노유체가 주목받고 있으며, 고효율을 필요로 하는 열교환기의 작동유체로 적용하기 위한 많은 연구가 진행되고 있다. 본 연구에서는 상용 열교환기의 작동유체로서 많이 사용되고 있는 증류수, 에틸렌글리콜, 에틸알코올에 나노다이아몬드 분말을 적용한 나노유체의 열전도도를 측정하였다. 나노유체는 매트릭스 합성 분산법을 이용하여 제조하였으며, 나노다이아몬드의 혼합량은 0.1, 0.3, 0.5, 1vol%로 하였다. 측정결과 모든 기본유체 조건에서 나노유체의 열전도도가 증가하였으며, 특히 증류수에 분산된 1vol%의 나노유체에서 23%의 높은 열전도도 향상 경향을 보였다.

• 한국수소및신에너지학회논문집
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• 제27권6호
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• pp.642-650
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• 2016

One of the most feasible solution for reducing the excessive energy consumption and carbon dioxide emission is usage of more efficient fuel such as hydrogen. As is well known, there are three viable technologies for storing hydrogen fuel: compressed gas, metal hydride absorption, and cryogenic liquid. In these technologies, the storage for liquid hydrogen has better energy density by weight than other storage methods. However, the cryogenic liquid storage has a significant disadvantage of boiling losses. That is, high performance of thermal insulation systems must be studied for reducing the boiling losses. This paper presents an experimental study on the effective thermal conductivities of the composite layered insulation with aerogel blankets($Cryogel^{(R)}$ Z and $Pyrogel^{(R)}$ XT-E) and Multi-layer insulation(MLI). The aerogel blankets are known as high porous materials and the good insulators within a soft vacuum range($10^{-3}{\sim}1$ Torr). Also, MLI is known as the best insulator within a high vacuum range(<$10^{-6}{\sim}10^{-3}$ Torr). A vertical axial cryogenic experimental apparatus was designed to investigate the thermal performance of the composite layered insulators under cryogenic conditions as well as consist of a cold mass tank, a heat absorber, annular vacuum space, and an insulators space. The composite insulators were laminated in the insulator space that height was 50 mm. In this study, the effective thermal conductivities of the materials were evaluated by measuring boil-off rate of liquid nitrogen and liquid argon in the cold mass tank.

• 공업화학
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• 제22권3호
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• pp.266-271
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• 2011

단일벽 탄소나노튜브(single-walled carbon nanotube, SWCNT)의 우수한 열적 특성을 이용하여 에폭시 수지의 열전도도 특성을 향상시키기 위해 SWCNT와 에폭시 수지 복합체를 제작하여 열전도도를 측정하였다. SWCNT에 카보닐기와 아민기를 도입하여 분산도 향상을 유도하였으며 diglycidyl ether of bisphenol A (DGEBA)와 bisphenol F (DGEBF) 두 종류의 에폭시 레진에 각각의 SWCNT를 첨가하여 제작한 복합체들은 파단면 분석을 통하여 분산 특성을 관찰하였다. 각 복합체의 분산도는 표면 처리를 거치면서 생성된 극성분자와 에폭시 간의 상호작용으로 인하여 SWCNT를 첨가한 것이 순수한 SWCNT 복합체와 비교하여 높은 분산성을 나타내었다. SWCNT/에폭시 복합체의 열전도도는 DGEBA와 DGEBF 두 종류의 에폭시에서 산처리한 SWCNT 복합체가 가장 높은 값을 가지는 것으로 측정되었다.

• 자원환경지질
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• 제42권6호
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• pp.591-598
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• 2009

본 연구에서는 남한일대에서 화성암, 변성암, 퇴적암의 총 2511개의 암석을 채취하여 열물성을 측정하고 각 암종별로 일반적인 통계분석을 실시하였다. 화성암, 변성암, 퇴적암의 평균 열전도도는 각각 3.10W/m-K, 3.76W/m-K, 3.54W/m-K 이다. 화성암의 암석 분류에 따라 심성암, 반심성암, 화산암으로 분류하였으며, 각각의 평균 열전도도는 3.16 W/m-K, 3.26 W/m-K, 2.77 W/m-K이다. 퇴적암에서 쇄설성 퇴적암 보다 비쇄설성 퇴적암의 열전도도가 비교적 높은 분포를 보이고 있다. 측정된 암석의 시대별 열전도도는 고생대가 중생대 보다 높은 나타나며, 이는 높은 열전도도를 갖는 구성 광물에 의한 것으로 판단된다. 암석의 공극률은 열전도도에 영향을 미치는 요소이며 퇴적암의 경우 공극률이 증가할 수록 열전도도는 대체적으로 감소하는 경향을 보인다. 암석의 열전도도와 열확산율은 선형의 상관관계를 보이며, 화성암, 변성암, 퇴적암의 선형 회귀분석 상관계수는 각각 0.775, 0.855 0.876로 높은 값을 보인다.

• 한국표면공학회지
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• 제29권4호
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• pp.229-237
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• 1996

Porous matrices for PAFC were prepared with chemically synthesized polyaniline powders. Phosphoric acid doped polyaniline showed decreasing electric conductivities as the temperature increased. Above $100^{\circ}C$, it showed negligible conductivities. It was stable in phosphoric acid up to $250^{\circ}C$. SiC powders or SiC whiskers were added to polyaniline to decrease the thermal expansion of polyaniline. 10% of polytetrafluoroethylene(PTFE) was also added as a binder. The bubble pressures and wettabilities of matrices were investigated and compared with the porosities measured by porosimeter. Based on these data, the optimum manufacturing condition was determined. The bubble pressure of the matrix made by adding 25w/o SiC whiskers was 345mmHg, the wettability was 235w/o, and the porosity was 83%. In the unit cell operation, the performances of polyaniline matrices were as good as those of SiC matrices. This result suggested that polyaniline can be a possible candidate for the matrix material of PAFC.

• Bulletin of the Korean Chemical Society
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• 제20권6호
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• pp.701-704
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• 1999

Metallophthalocyanines [PcM, Pc: phthalocyanine, M: Fe 2+ , Co 2+ ] were reacted with α-isocyanonaphthalene( α-in) and α-isocyanoanthracene (α-ia) to form monomeric complexes. The synthesis and coordination behaviour of the isocyanides as a ligand (L) are discussed. All the products were characterized by spectroscopic methods and instrumental analysis. The electrical conductivities of these complexes, which were not treated with dopant, were attributed to the metal-ligand electron delocalization in the PcML2 complexes. The complexes have an enlarged macrocycle where the π-electron back donating ability of PcM is stronger than the σ-electron coordinating ability of the isonitrile ligands. Their electrical conductivities were measured as σRT = 2.1×10 -9 ~3×10 -10 S/cm. Also thermal stability was investigated in this study.

• Geomechanics and Engineering
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• 제11권6호
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• pp.771-785
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• 2016

The thermal conductivity of soils is an important property in energy-related geotechnical structures, such as underground heat pumps and underground electric power cable tunnels. This study explores the effects of geotechnical engineering properties on the thermal conductivity of soils. The thermal conductivities of quartz sands and Korean weathered silty sands were documented via a series of laboratory experiments, and its variations with effective stress, porosity, and water saturation were examined. While thermal conductivity was found to increase with an increase in the effective stress and water saturation and with a decrease in porosity, replacing air by water in pores the most predominantly enhanced the thermal conductivity by almost one order of magnitude. In addition, we have suggested an improved model for thermal conductivity prediction, based on water saturation, dry thermal conductivity, saturated thermal conductivity, and a fitting parameter that represents the curvature of the thermal conductivity-water saturation relation.

• 오토저널
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• 제13권2호
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• pp.88-102
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• 1991

In this study, thermophysical properties of the ceramic dielectrics such as BaOTiO$_{2}$, SrOTiO$_{2}$, MgOTiO$_{2}$, were measured by a single rectangular pulse heating method. The values of thermal diffusivities, specific heats, and thermal conductivities were measured as a function of temperature range from room temperature to 1300k. The measured thermal properties of one group of ceramic material were compared with those of other group and discussed in detail in connection with the chemical composition. Thus, some criteria for thermal design with the electric-electronic ceramic material were proposed.

• 오토저널
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• 제4권3호
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• pp.40-47
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• 1982

Heat transfer on packed bed is considered to be important for the effective designs of chemical reaction equipment, air conditioning system, and storage type heat exchanger, etc. Currently studies are being carried out quite actively in this field in order to increase the heat transfer efficiency. The effect of heat transfer is closely relater to materials, shapes, porosities and packing states of packed bed as well as mutual dimensional relations between particles and the container. Investigation shows that heat transfer results appear to be influenced by such parameters as fluid velocity through packed bed, mass flow, and thermal properties. It is noted that viscosity is also considered to be an important factor in this problem. In this study, effective thermal conductivities on packed bed, effects of thermal conductivity (Ke) and friction factor (Fk) according to change of porosity(.epsilon.) and Reynolds number(Reh(, and pressure loss of the fluid, are experimentally investigated. Results show that the effective thermal conductivity increases and the friction factor decreased, as against the increase of Reynolds number. But as the increase of porosity increase them both.